CN105714465A - Graphene modified fiber antistatic compound functional knitted fabric and weaving method thereof - Google Patents

Graphene modified fiber antistatic compound functional knitted fabric and weaving method thereof Download PDF

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Publication number
CN105714465A
CN105714465A CN201610199834.9A CN201610199834A CN105714465A CN 105714465 A CN105714465 A CN 105714465A CN 201610199834 A CN201610199834 A CN 201610199834A CN 105714465 A CN105714465 A CN 105714465A
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China
Prior art keywords
knitted fabric
graphene
weaving
jacquard
fabric
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CN201610199834.9A
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Inventor
张世安
关燕
位国栋
张洪宾
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QINGDAO XUEDA GROUP CO Ltd
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QINGDAO XUEDA GROUP CO Ltd
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Priority to CN201610199834.9A priority Critical patent/CN105714465A/en
Publication of CN105714465A publication Critical patent/CN105714465A/en
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10Patterned fabrics or articles
    • D04B1/12Patterned fabrics or articles characterised by thread material
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/22Physical properties protective against sunlight or UV radiation
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear

Abstract

The invention provides a graphene modified fiber antistatic compound functional knitted fabric and a weaving method thereof. The graphene modified fiber antistatic compound functional knitted fabric is characterized in that the knitted fabric is a double-layered jacquard woven knitted fabric formed by weaving jacquard weaves and compound changeable weaves of plain stitches, wherein the jacquard weaves are knitted by adopting graphene viscose yarns; the changeable plain stitches adopt combed cotton blended yarns and polyester filaments to knit on a needle disc; transverse wide jacquard patterns are additionally arranged in rhombus-shaped grids on the front surface of the fabric, and vertical strips are additionally arranged in a rhombus shape of the back surface; and the yarns are organically arrayed, and functions and effects of graphene fibers and the combed cotton blended yarns are sufficiently expressed, so that antistatic, antibacterial, anti-ultraviolet, soft and comfortable effects are realized. Meanwhile, the yarns are organically arrayed, so that the fabric has clear lines and prominent surface rhombus-shaped jacquard feeling. By selecting the raw materials, a reasonable weave structure, and a weaving, dyeing and finishing process path, the knitted fabric has warm-keeping and moisture-conducting performances, and the comfort and the cost performance are obviously improved.

Description

Graphene modified fibre antistatic composite functional knitted fabric and method for weaving thereof
Technical field
The invention belongs to textile product production technical field, relate to the improvement of knitting product and production technology thereof, specifically one Graphene modified fibre antistatic composite functional knitted fabric and method for weaving thereof.
Background technology
Functional fibre and function textile are the tencel material and the textile product that represent material, chemical industry, weaving and association area scientific and technical innovation level, are the focuses of scientific worker's concern in the fields such as fiber, weaving, dyeing and finishing, clothing, fine chemistry industry.The market demand with the protective function fibers such as antistatic, conduction, UV resistance, electromagnetic protection, flame-proof heat-resistant, ageing-resistant, the far infrared health care of anticorrosion and textile is huge, and industrialization prospect highlights.
At present, market has the textile of the functions such as electromagnetic protection, UV resistance, conduction intelligence mainly through adding function additive to realize above-mentioned simple function, big (> 10% of usual function additive addition), affect wearability and the endurance quality of textile, and above-mentioned multi-functional characteristic cannot be realized simultaneously.Graphene has above-mentioned characteristic (antistatic, conduction, UV resistance, electromagnetic protection, flame-proof heat-resistant, anticorrosion ageing-resistant, far infrared health care) due to its unique texture, and the interpolation of appropriate Graphene be equipped with rational weaving process, above-mentioned multiple-effect functional characteristic can be realized in fiber and textile, meanwhile, make product cost high.So, carrying out of Graphene modified fibre and new function textile project, it is possible to form certain market scale and good economic benefit in multifunctional textile product field.By the research and development of Graphene modified fibre and new function textile and industrialization, it is proposed that the concept of " wide spectrum function textile ", release multi-functional series function fiber and textile, it was predicted that the widespread demand having consumer can be subject to.
Summary of the invention
The present invention solves prior art Problems existing and deficiency, and a kind of Graphene modified fibre antistatic composite functional knitted fabric and method for weaving thereof are provided.By the selection of raw material and rational organizational structure and weaving process route, knitted fabric antistatic, antibacterial and comfortableness and cost performance is made all to be significantly improved.
It is an object of the invention to be achieved through the following technical solutions: a kind of Graphene modified fibre antistatic composite functional knitted fabric, it is characterized in that, described knitted fabric is to carry out, with the compound alternative construction of figured texture weave Yu flat pin, the double-layer jacquard knitted fabric weaved, figured texture weave adopts the braiding of Graphene spun rayon, change flat pin and adopt combed cotton blended yarn, polyester filament weaves at dials, fabric face rhombus grid adds width bar jacquard weave, reverse side rhombus adds longitudinal stripe, utilize organic arrangement of yarn, give full play to function effect of graphene fiber and combed cotton blended yarn, play antistatic, antibacterial, anti-ultraviolet, soft comfortable effect.Meanwhile, utilizing organic arrangement of yarn, make that fabric lines is clear, surface rhombus jacquard weave sense highlights, cost performance is high.
Improvement to technique scheme: described Graphene yarn is 9.8tex Graphene spun rayon, described combed cotton is 90/10 Graphene viscose glue/combed cotton 14.8tex mixed yarn, and described polyester filament is 100D dacron thread.
A kind of method for weaving of Graphene modified fibre antistatic composite functional knitted fabric, it is characterized in that, carry out weaving with the compound alternative construction of figured texture weave Yu flat pin and form double-layer jacquard knitted fabric, figured texture weave adopts the braiding of Graphene spun rayon, changing flat pin adopts combed cotton blended yarn, polyester filament to weave at dials, fabric face rhombus grid jacquard weave, reverse side longitudinal stripe, utilize organic arrangement of yarn, give full play to function effect of graphene fiber and combed cotton, play antistatic, antibacterial, anti-ultraviolet, soft comfortable effect.Meanwhile, utilize organic arrangement of yarn, make that fabric lines is clear, surface rhombus jacquard weave sense highlights.
Improvement to technique scheme: described Graphene yarn 9.8tex Graphene spun rayon, described combed cotton is 90/10 combed cotton/Graphene viscose glue 14.8tex mixed yarn, and described polyester filament is 100D dacron thread.
Further improvement to technique scheme: in described double-layer jacquard knitted fabric, the percentage by weight of graphene-containing is 3%-5%.
Further improvement to technique scheme: described knitted fabric weaving process is as follows:
Adopt the direct needle selection braiding of JHW-PJ gear type two-sided floral disc jacquard knitting machine floral disc steel rice;
Isosorbide-5-Nitrae, 7,10 ... road, penetrate 9.8tex Graphene viscose yarn;
2nd, 5,8,11 ... road, penetrate the combed cotton blended yarn of 14.8tex;
3rd, 6,9,12 ... road, penetrate 100D polyester filament;
The loop length of described knitted fabric is:
Isosorbide-5-Nitrae, 7,10 ... road 330 ± 2mm/100 pin;
2nd, 5,8,11 ... road 300 ± 2mm/100 pin;
3rd, 6,9,12 ... road 110 ± 2mm/100 pin.
Further improvement to technique scheme: described knitted fabric dry weight: 180 ± 10g/, bar width: 0.2+0.3cm.
The present invention compared with prior art has the advantages that: the present invention is by the selection of raw material and rational organizational structure and weaving process route, produce the efficient antistatic complex function knitting fabric of graphene fiber double-layer jacquard, and there is good antistatic, antibacterial, anti-ultraviolet function and good wearing comfort and cost performance.
(1) compared to the application in energy storage field, textile fiber material is relatively more flexible and wide in range to the requirement of Graphene raw material, can according to textile fiber material difference purposes and demand, choose the Graphene of different structure and character, Graphene content in double-layer jacquard knitted fabric of the present invention is 3%-5%, reasonable mixture ratio.
(2) exploitation of double-layer jacquard knitted fabric of the present invention, it is with Graphene viscose rayon for solvent, select Graphene spun rayon and there is the combed cotton blended yarn of soft comfortable and Moisture Absorption Perspiration Polyester Filament intertexture, make the product processed, the various special efficacies that graphene fiber has can not only be given full play to, and multiple fiber is had complementary advantages, make fabric soft comfortable, surface density of charge is little, antistatic, antibacterial, anti-ultraviolet, is the knitting fabric of function comfortableness of a kind of high performance-price ratio.
(3) utilize organic arrangement of yarn, make that fabric lines is clear, concave-convex surface sense highlights, have diamond shape appearance, and soft comfortable, unique style, excellent performance.
(4) knitted fabric of the present invention reaches chemical fibre knitted underwear inherent quality technology requirement, and various functions index has been above existing Product Level, and surface density of charge is little, and antistatic, fungistatic effect are obvious.Therefore, knitted fabric of the present invention is a kind of function and comfortable high value added product of integrating, and to improving product specification, increases economic benefit significant.
Accompanying drawing explanation
Fig. 1 is the knitting needle arrangement figure adopted in the method for weaving of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 2 is the cam chart adopted in the method for weaving of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 3 is the braiding flower pattern front plan of weave (note: lattice represent that Graphene yarn becomes to punctuate, and crossed grid represents Graphene yarn flotation line point) of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 4 is the front flower pattern figure of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 5 is the reverse side flower-shape figure of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 6 is the horizontal section structural representation of Graphene modified fibre antistatic composite functional knitted fabric of the present invention;
Fig. 7 is the loop organization weave diagram of Graphene modified fibre antistatic composite functional knitted fabric of the present invention.
The present invention is described in further detail by detailed description of the invention below in conjunction with drawings and Examples.
Referring to Fig. 1-Fig. 7, the embodiment of the present invention a kind of Graphene modified fibre antistatic composite functional knitted fabric, described knitted fabric is to carry out, with the compound alternative construction of figured texture weave Yu flat pin, the double-layer jacquard knitted fabric weaved, figured texture weave adopts the braiding of Graphene spun rayon, changing flat pin adopts combed cotton blended yarn, polyester filament to weave at dials, fabric face rhombus grid adds width bar jacquard weave, reverse side rhombus adds longitudinal stripe, utilize organic arrangement of yarn, give full play to function effect of graphene fiber, play antistatic, bacteriostasis.
As illustrated in figures 4-5, utilize organic arrangement of yarn, make that fabric lines is clear, surface rhombus jacquard weave sense highlights.
The preferred specification of above-described embodiment Raw is: described Graphene yarn 9.8tex spun rayon, described combed cotton is the combed cotton blended yarn of 14.8tex, and described polyester filament is 100D dacron thread.
Referring to Fig. 1-Fig. 7, the embodiment of the method for weaving of the present invention a kind of Graphene modified fibre antistatic composite functional knitted fabric, carry out weaving with the compound alternative construction of figured texture weave Yu flat pin and form double-layer jacquard knitted fabric, figured texture weave adopts the braiding of Graphene spun rayon, changing flat pin adopts combed cotton blended yarn, polyester filament to weave at dials, fabric face rhombus grid jacquard weave, reverse side longitudinal stripe, utilize organic arrangement of yarn, give full play to function effect of graphene fiber and combed cotton, play antistatic, antibacterial, anti-ultraviolet, soft comfortable effect.
The preferred specification of above-mentioned raw materials is: described Graphene yarn 9.8tex spun rayon, described combed cotton is the combed cotton blended yarn of 14.8tex, and described polyester filament is 100D dacron thread.In above-mentioned double-layer jacquard knitted fabric, the percentage by weight of graphene-containing is 3%-5%.
Concrete knitted fabric weaving process is as follows:
(1) device parameter
Type: the two-sided floral disc jacquard knitting machine of JHW-PJ gear type
Plane No.: 20G/25.4mm
Barrel dliameter: 864mm(34 inch)
Total needle amount: 2088*2 piece
Way: 72F(uses way to be 54F)
(2) knitting technology
1, knitting arrangement:
AB arrangement pressed by dials knitting needle, and cylinder knitting needle presses C arrangement (as shown in Figure 1).
In figure: A represents the low bell pin of dials;B represents dials height bell pin;C represents cylinder knitting needle
2, Principle of selecting needle setup: dials carries out needle selection by triangle, syringe carries out needle selection by the steel rice installed on floral disc.
3, cam chart (see figure 2)
In figure: " ∧ " stitch cam " " flat pin triangle
4, entry mode:
Isosorbide-5-Nitrae, 7,10 tunnels, penetrate 9.8tex Graphene spun rayon,
2nd, 5,8,11 tunnel, penetrates 14.8tex Graphene viscose glue/combed cotton blended yarn,
3rd, 6,9,12 tunnel, penetrates 100D polyester filament.
5, graphene fiber fabric braiding flower pattern plan of weave (see figure 3).
6, technical parameter
(1) loop length:
Isosorbide-5-Nitrae, 7,10 tunnel 330 ± 2mm/100 pins;
2nd, 5,8,11 tunnel 300 ± 2mm/100 pin;
3rd, 6,9,12 tunnel 110 ± 2mm/100 pin.
(2) jacquard weave bar width: 0.2+0.3cm
(3) square metre dry weight: 180 ± 10g/m2
(4) machine fabric width under: (85cm × 2) ± 5cm.
(3) key problem in technology of the present invention
(1) carry out steel loading rice in strict accordance with technological requirement, distinguish lopping steel rice and tuck steel rice, the 9th piece of pin inside tuck steel rice, it is prevented that fabric mistake flower, broken hole occurs.
(2) noting the tension force regulating the jacquard weave of each road, point three gears are adjusted weaving cotton cloth, it is prevented that material cloth broken hole.
(3) arrangement of yarn, upper and lower one side are distinguished, it is prevented that wrong yarn.
(4), product the key technical indexes
By FZ/T73024-2014 " chemical fibre knitted underwear ", GB/T12703.2-2009 " the evaluation part 2 of textile antistatic property: surface density of charge " standard, the present invention has been carried out functional test, and its its functional attributes test result is shown in following table:
Its functional attributes Standard-required Measured value Evaluation
Air penetrability (mm/s) ≥180 867 Qualified
Surface density of charge (μ C/m2) ≤7 2.5 Qualified
Average intensification value (DEG C) in 30min ≥3.0 3.8 Qualified
Staphylococcus aureus (%) ≥80 AAA level 93.5 Meet
Escherichia coli (%) ≥70 AAA level 99.3 Meet
Candida albicans (%) ≥60 AAA level 91.0 Meet
As seen from the above table, the Graphene modified fibre antistatic composite functional knitted fabric of the present invention, its breathability, antistatic property, bacteriostasis property all meet GB or rower relevant criterion requirement, and what meet people takes demand.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention makees other form, and any those skilled in the art are changed or be modified as the Equivalent embodiments of equivalent variations possibly also with the technology contents of the disclosure above.But every without departing from technical solution of the present invention content, according to any simple modification, equivalent variations and remodeling that above example is made by the technical spirit of the present invention, still fall within the protection domain of technical solution of the present invention.

Claims (8)

1. a Graphene modified fibre antistatic composite functional knitted fabric, it is characterized in that, described knitted fabric is to carry out, with the compound alternative construction of figured texture weave Yu flat pin, the double-layer jacquard knitted fabric weaved, figured texture weave adopts the braiding of Graphene spun rayon, changing flat pin adopts combed cotton blended yarn, polyester filament to weave at dials, fabric face rhombus grid adds width bar jacquard weave, adds longitudinal stripe in reverse side rhombus.
2. the Graphene modified fibre antistatic composite functional knitted fabric described in claim 1, it is characterized in that, described Graphene yarn 9.8tex Graphene spun rayon, described combed cotton blended yarn is 90/10 Graphene viscose glue/combed cotton 14.8tex mixed yarn, and described polyester filament is 100D dacron thread.
3. the method for weaving of a Graphene modified fibre antistatic composite functional knitted fabric, it is characterized in that, carry out weaving with the compound alternative construction of figured texture weave Yu flat pin and form double-layer jacquard knitted fabric, figured texture weave adopts the braiding of Graphene spun rayon, changing flat pin adopts combed cotton blended yarn, polyester filament to weave at dials, fabric face rhombus grid jacquard weave, reverse side longitudinal stripe.
4. the method for weaving of the Graphene modified fibre antistatic composite functional knitted fabric described in claim 3, it is characterized in that, described Graphene yarn 9.8tex Graphene spun rayon, described combed cotton is 90/10 combed cotton/Graphene viscose glue 14.8tex mixed yarn, and described polyester filament is 100D dacron thread.
5. the method for weaving of the Graphene modified fibre antistatic composite functional knitted fabric described in claim 3 or 4, it is characterised in that in described double-layer jacquard knitted fabric, the percentage by weight of graphene-containing is 3%-5%.
6. the method for weaving of the Graphene modified fibre antistatic composite functional knitted fabric described in claim 3 or 4, it is characterised in that: described knitted fabric weaving process is as follows:
Adopt the direct needle selection braiding of JHW-PJ gear type two-sided floral disc jacquard knitting machine floral disc steel rice;
Isosorbide-5-Nitrae, 7,10 ... road, penetrate 9.8tex Graphene viscose yarn;
2nd, 5,8,11 ... road, penetrate 14.8tex Graphene viscose glue/combed cotton blended yarn;
3rd, 6,9,12 ... road, penetrate 100D polyester filament;
The loop length of described knitted fabric is:
Isosorbide-5-Nitrae, 7,10 ... road 330 ± 2mm/100 pin;
2nd, 5,8,11 ... road 300 ± 2mm/100 pin;
3rd, 6,9,12 ... road 110 ± 2mm/100 pin.
7. the method for weaving of the Graphene modified fibre antistatic composite functional knitted fabric described in claim 3 or 4, it is characterised in that described knitted fabric dry weight: 180 ± 10g/, bar width: 0.2+0.3cm.
8. the method for weaving of the Graphene modified fibre antistatic composite functional knitted fabric described in claim 6, it is characterised in that described knitted fabric dry weight: 180 ± 10g/, bar width: 0.2+0.3cm.
CN201610199834.9A 2016-04-01 2016-04-01 Graphene modified fiber antistatic compound functional knitted fabric and weaving method thereof Pending CN105714465A (en)

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CN107190404A (en) * 2017-06-08 2017-09-22 江门市大兴针织厂有限公司 A kind of graphene and bio-based fiber knitted fabric and its production method
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CN105951237A (en) * 2016-07-15 2016-09-21 义乌市麻尚生针织品有限公司 Blended yarn with hemp and cotton multifunctional fiber reinforced by graphene fiber
CN105951237B (en) * 2016-07-15 2018-10-30 义乌市麻尚生针织品有限公司 A kind of scribbled of the numb cotton multifunctional fibre of graphene fiber enhancing
CN106367882A (en) * 2016-08-28 2017-02-01 浙江真爱毯业科技有限公司 Production technology of ice jade fiber raschel blanket
CN107142602A (en) * 2017-04-14 2017-09-08 江南大学 Graphene fiber multi-functional warm seamless underwear is designed and method for weaving
CN107190404B (en) * 2017-06-08 2018-06-08 江门市大兴针织厂有限公司 A kind of graphene and biology base fiber knitted fabric and its production method
CN107190404A (en) * 2017-06-08 2017-09-22 江门市大兴针织厂有限公司 A kind of graphene and bio-based fiber knitted fabric and its production method
CN107299432A (en) * 2017-06-21 2017-10-27 南通双弘纺织有限公司 The mixed yarn and its technique of a kind of combed cotton and graphene nylon fibre mixed yarn
CN108265371A (en) * 2018-04-09 2018-07-10 聊城市全彩棉纺织品技术有限公司 A kind of antibacterial deodourizing moisture absorption Graphene towel and its manufacturing method
CN108486737A (en) * 2018-04-09 2018-09-04 聊城市全彩棉纺织品技术有限公司 A kind of antibacterial deodourizing moisture absorption graphene fabric and its manufacturing method
CN108677307A (en) * 2018-08-09 2018-10-19 魏桥纺织股份有限公司 A kind of graphene modified fibre scribbled, fabric and its production technology
CN108950840A (en) * 2018-08-22 2018-12-07 三六度(中国)有限公司 A kind of cotton washs the preparation method of two-sided woven roving knitting fabric

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Application publication date: 20160629