CN105586768A - 一种抗菌免烫阻燃整理液及其整理方法 - Google Patents

一种抗菌免烫阻燃整理液及其整理方法 Download PDF

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CN105586768A
CN105586768A CN201610109382.0A CN201610109382A CN105586768A CN 105586768 A CN105586768 A CN 105586768A CN 201610109382 A CN201610109382 A CN 201610109382A CN 105586768 A CN105586768 A CN 105586768A
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ironing
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fire retarding
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向陆生
任世军
洪五林
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Suntex Co Ltd
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Abstract

一种抗菌免烫阻燃整理液，包括以下重量份数的原料：乙二醛10-15份，柠檬酸10-15份，环状磷酸酯5-8份，甘草提取物5-8份，壳聚糖3-5份，氯化镁2-3份，次亚磷酸钠2-3份，渗透剂1-2份，偶联剂1-2份，柔软剂1-2份，乙二醇1-2份，纤维保护剂1-2份，pH调节剂1-2份，分散剂1-2份。制得多功能抗菌整理液，环保无污染且具有良好的免烫防缩、抗菌、阻燃的功效，可以满足人们对纺织品各种功能性方面的需求。

Description

一种抗菌免烫阻燃整理液及其整理方法
技术领域
本发明主要涉及一种纺织物的整理方法，尤其涉及一种抗菌免烫阻燃整理液及其整理方法。
背景技术
随着生活水平的日益提高，人们对于织物的质量的要求越来越高，尤其是对织物的功能性要求。目前市场上出售的纺织品大都功能比较单一，因此纺织品后整理已成为提高产品附加值和改善纺织品功能的重要途径之一。一般的织物多功能整理效果并不理想，且整理剂中含有各种有毒成分，不利于人体健康。如抗皱防缩，长期以来，使用的抗皱防缩整理剂大多数为甲醛化合物，在使用它们对织物进行免烫整理和随后的织物储存、生产、出售以及消费者使用和穿着时会持续释放出甲醛气体，不利于人们的健康。随着国际范围内绿色环保意识的日益增强，开发无甲醛整理剂代替传统的有害整理剂，已成为必然的发展趋势。
发明内容
根据现有技术中存在的问题，本发明涉及一种抗菌免烫阻燃整理液及其整理方法，整理效果显著，且环保无污染。
为了实现上述目的本发明采用如下技术方案：
一种抗菌免烫阻燃整理液，包括以下重量份数的原料：乙二醛10-15份，柠檬酸10-15份，环状磷酸酯5-8份，甘草提取物5-8份，壳聚糖3-5份，氯化镁2-3份，次亚磷酸钠2-3份，渗透剂1-2份，偶联剂1-2份，柔软剂1-2份，乙二醇1-2份，纤维保护剂1-2份，pH调节剂1-2份，分散剂1-2份。
所述的渗透剂为脂肪醇聚氧乙烯醚。
所述的偶联剂为硅烷偶联剂，如：KH-550、KH-560、KH-570。
所述的柔软剂为季铵化改性氨基硅油。
所述的纤维保护剂为乳状分散聚乙烯蜡。
所述的pH调节剂为柠檬酸-柠檬酸钠缓冲液或磷酸二氢钠-柠檬酸缓冲液。
所述的分散剂为单硬脂酸单甘油酯。
所述的甘草提取物，采用以下方法制备：称取甘草50g，粉碎成粗粉，加10-15倍甘草重量的水浸泡0.5-1h，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液1；向滤渣中加入8-10倍滤渣重量的水，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液2；再向滤渣中加入6-8倍滤渣重量的水，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液3；将滤液1、滤液2、滤液3合并，在温度为90-100℃条件下浓缩至甘草重量的5-8倍，即得甘草提取物。
一种抗菌免烫阻燃整理液的整理方法，包括以下步骤：
步骤一：将各原料加入水中，按总原料与水重量比为1:1混合搅拌均匀，得整理液；
步骤二：纺织物浸渍在整理液中10-15min，浸渍温度为35-40℃，采用两浸两轧，轧余率为50-70％；
步骤三：采用微波干燥处理，温度为100-110℃，时间为5-10min。
本发明的有益效果在于：加入乙二醛、柠檬酸复合免烫防缩整理剂，免烫防缩效果好，且不含甲醛环保无污染。柠檬酸具有较多的反应基团，可与纤维上的羟基形成共价交联，同时还可以作为其他整理剂与纤维的交联剂。采用环状磷酸酯整理剂可显著改善织物的阻燃性。采用天然抗菌剂甘草提取物，甘草中的黄酮类化合物是甘草抗菌抗原虫的主要活性成分，对大肠杆菌、革兰阳性芽胞杆菌、真菌和利什曼原虫疟原虫生长有较强有抑制活性，其中对耐药性金黄色葡萄球菌作用具有更大、更现实的意义。壳聚糖能够有效抑制一些真菌、细菌、和病毒的生长繁殖。且壳聚糖成膜性强，与纤维素化学结构相似，有很好的吸附和相容性，壳聚糖的羟基及一部分氨基与纤维的羟基形成众多的分子间氢键，加入适量的偶联剂等助剂，使得壳聚糖整理也能起到一定的抗皱防缩皱效果。各种整理剂及助剂间相互配合，制得多功能抗菌整理液，具有良好的免烫防缩、抗菌、阻燃的功效，可以满足人们对纺织品各种功能性方面的需求。
具体实施方式
下面通过对实施例的描述，对本发明作进一步详细的说明，以帮助本领域技术人员对本发明的发明构思、技术方案有更完整、准确和深入的理解。
实施例1
一种抗菌免烫阻燃整理液，包括以下重量份数的原料：乙二醛10份，柠檬酸10份，环状磷酸酯5份，甘草提取物5份，壳聚糖3份，氯化镁2份，次亚磷酸钠2份，渗透剂1份，偶联剂1份，柔软剂1份，乙二醇1份，纤维保护剂1份，pH调节剂1份，分散剂1份。
所述的渗透剂为脂肪醇聚氧乙烯醚。
所述的偶联剂为KH-550型硅烷偶联剂。
所述的柔软剂为季铵化改性氨基硅油。
所述的纤维保护剂为乳状分散聚乙烯蜡。
所述的pH调节剂为柠檬酸-柠檬酸钠缓冲液。
所述的分散剂为单硬脂酸单甘油酯。
所述的甘草提取物，采用以下方法制备：称取甘草50g，粉碎成粗粉，加10倍甘草重量的水浸泡0.5h，加热至90℃，煎煮提取0.5h，过滤得滤液1；向滤渣中加入8倍滤渣重量的水，加热至90℃，煎煮提取0.5h，过滤得滤液2；再向滤渣中加入6倍滤渣重量的水，加热至90℃，煎煮提取0.5h，过滤得滤液3；将滤液1、滤液2、滤液3合并，在温度为90℃条件下浓缩至甘草重量的5倍，即得甘草提取物。
一种抗菌免烫阻燃整理液的整理方法，包括以下步骤：
步骤一：将各原料加入水中，按总原料与水重量比为1:1混合搅拌均匀，得整理液；
步骤二：纺织物浸渍在整理液中10min，浸渍温度为35℃，采用两浸两轧，轧余率为50％；
步骤三：采用微波干燥处理，温度为100℃，时间为5min。
实施例2
一种抗菌免烫阻燃整理液，包括以下重量份数的原料：乙二醛15份，柠檬酸15份，环状磷酸酯8份，甘草提取物8份，壳聚糖5份，氯化镁3份，次亚磷酸钠3份，渗透剂2份，偶联剂2份，柔软剂2份，乙二醇2份，纤维保护剂2份，pH调节剂2份，分散剂2份。
所述的渗透剂为脂肪醇聚氧乙烯醚。
所述的偶联剂为KH-560型硅烷偶联剂。
所述的柔软剂为季铵化改性氨基硅油。
所述的纤维保护剂为乳状分散聚乙烯蜡。
所述的pH调节剂为磷酸二氢钠-柠檬酸缓冲液。
所述的分散剂为单硬脂酸单甘油酯。
所述的甘草提取物，采用以下方法制备：称取甘草50g，粉碎成粗粉，加10-15倍甘草重量的水浸泡1h，加热至100℃，煎煮提取1h，过滤得滤液1；向滤渣中加入10倍滤渣重量的水，加热至100℃，煎煮提取1h，过滤得滤液2；再向滤渣中加入8倍滤渣重量的水，加热至100℃，煎煮提取1h，过滤得滤液3；将滤液1、滤液2、滤液3合并，在温度为100℃条件下浓缩至甘草重量的8倍，即得甘草提取物。
一种抗菌免烫阻燃整理液的整理方法，包括以下步骤：
步骤一：将各原料加入水中，按总原料与水重量比为1:1混合搅拌均匀，得整理液；
步骤二：纺织物浸渍在整理液中15min，浸渍温度为40℃，采用两浸两轧，轧余率为70％；
步骤三：采用微波干燥处理，温度为110℃，时间为10min。

Claims (9)

1.一种抗菌免烫阻燃整理液，其特征在于，包括以下重量份数的原料：乙二醛10-15份，柠檬酸10-15份，环状磷酸酯5-8份，甘草提取物5-8份，壳聚糖3-5份，氯化镁2-3份，次亚磷酸钠2-3份，渗透剂1-2份，偶联剂1-2份，柔软剂1-2份，乙二醇1-2份，纤维保护剂1-2份，pH调节剂1-2份，分散剂1-2份。
2.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的渗透剂为脂肪醇聚氧乙烯醚。
3.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的偶联剂为硅烷偶联剂。
4.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的柔软剂为季铵化改性氨基硅油。
5.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的纤维保护剂为乳状分散聚乙烯蜡。
6.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的pH调节剂为柠檬酸-柠檬酸钠缓冲液或磷酸二氢钠-柠檬酸缓冲液。
7.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的分散剂为单硬脂酸单甘油酯。
8.根据权利要求1所述的一种抗菌免烫阻燃整理液，其特征在于：所述的甘草提取物，采用以下方法制备：称取甘草50g，粉碎成粗粉，加10-15倍甘草重量的水浸泡0.5-1h，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液1；向滤渣中加入8-10倍滤渣重量的水，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液2；再向滤渣中加入6-8倍滤渣重量的水，加热至90-100℃，煎煮提取0.5-1h，过滤得滤液3；将滤液1、滤液2、滤液3合并，在温度为90-100℃条件下浓缩至甘草重量的5-8倍，即得甘草提取物。
9.一种权利要求1-8任一项所述的抗菌免烫阻燃整理液的整理方法，其特征在于，包括以下步骤：
步骤一：将各原料加入水中，按总原料与水重量比为1:1混合搅拌均匀，得整理液；
步骤二：纺织物浸渍在整理液中10-15min，浸渍温度为35-40℃，采用两浸两轧，轧余率为50-70％；
步骤三：采用微波干燥处理，温度为100-110℃，时间为5-10min。
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN109957970A (zh) * 2019-03-29 2019-07-02 苏州经贸职业技术学院 丝绸天然纳米功能整理剂的制备方法
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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA748349A (en) * 1966-12-13 M. Russell William Processes for treating cellulosic materials
CN1552989A (zh) * 2003-06-03 2004-12-08 陈立成 一种无甲醛织物防皱整理剂及制造方法
CN101230274A (zh) * 2007-12-27 2008-07-30 南京师范大学 环状膦酸酯或环状磷酸酯阻燃剂的制备方法
CN101638847A (zh) * 2009-07-24 2010-02-03 东莞市德能化工有限公司 一种用于纤维素纤维织物的无甲醛耐久免烫整理剂
CN102605630A (zh) * 2012-04-06 2012-07-25 南通市嘉宇斯纺织集团有限公司 一种具有抗菌功效的中药包合物及其织物整理方法
CN102634973A (zh) * 2012-04-16 2012-08-15 盛虹集团有限公司 真丝织物柠檬酸防皱整理工艺
CN103467520A (zh) * 2013-09-16 2013-12-25 苏州志向纺织科研股份有限公司 一种涤纶织物浸轧用阻燃剂环状磷酸酯的合成方法
CN103572588A (zh) * 2013-10-30 2014-02-12 东华大学 一种纳米材料增强棉织物抗皱整理液及其应用
CN104746338A (zh) * 2013-12-31 2015-07-01 广东德美精细化工股份有限公司 一种阻燃工作液及纯棉织物和/或涤棉混纺织物的阻燃整理方法
CN105064010A (zh) * 2015-08-03 2015-11-18 湖州吉昌丝绸有限公司 一种新型天然抗菌整理剂及其制备方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA748349A (en) * 1966-12-13 M. Russell William Processes for treating cellulosic materials
CN1552989A (zh) * 2003-06-03 2004-12-08 陈立成 一种无甲醛织物防皱整理剂及制造方法
CN101230274A (zh) * 2007-12-27 2008-07-30 南京师范大学 环状膦酸酯或环状磷酸酯阻燃剂的制备方法
CN101638847A (zh) * 2009-07-24 2010-02-03 东莞市德能化工有限公司 一种用于纤维素纤维织物的无甲醛耐久免烫整理剂
CN102605630A (zh) * 2012-04-06 2012-07-25 南通市嘉宇斯纺织集团有限公司 一种具有抗菌功效的中药包合物及其织物整理方法
CN102634973A (zh) * 2012-04-16 2012-08-15 盛虹集团有限公司 真丝织物柠檬酸防皱整理工艺
CN103467520A (zh) * 2013-09-16 2013-12-25 苏州志向纺织科研股份有限公司 一种涤纶织物浸轧用阻燃剂环状磷酸酯的合成方法
CN103572588A (zh) * 2013-10-30 2014-02-12 东华大学 一种纳米材料增强棉织物抗皱整理液及其应用
CN104746338A (zh) * 2013-12-31 2015-07-01 广东德美精细化工股份有限公司 一种阻燃工作液及纯棉织物和/或涤棉混纺织物的阻燃整理方法
CN105064010A (zh) * 2015-08-03 2015-11-18 湖州吉昌丝绸有限公司 一种新型天然抗菌整理剂及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
师昌绪 等: "《材料科学与工程手册 下 第12篇 生物医用材料篇》", 31 January 2004, 化学工业出版社 *

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