CN105505042A - Improved exterior wall paint and preparation method thereof - Google Patents

Improved exterior wall paint and preparation method thereof Download PDF

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CN105505042A
CN105505042A CN 201511013589 CN201511013589A CN105505042A CN 105505042 A CN105505042 A CN 105505042A CN 201511013589 CN201511013589 CN 201511013589 CN 201511013589 A CN201511013589 A CN 201511013589A CN 105505042 A CN105505042 A CN 105505042A
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parts
coating
exterior wall
latex
kaolin
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CN 201511013589
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Chinese (zh)
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辛范范
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辛范范
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses improved exterior wall paint. The improved exterior wall paint is prepared from the following raw materials in parts by weight: 20-30 parts of white latex, 12-18 parts of titanium powder, 2.3-4.5 parts of oxalic acid, 7.3-8.5 parts of deionized water, 5-10 parts of kaolin, 3.5-7.6 parts of tetramethyl caproaldehyole, 3.4-7.6 parts of tribenzyl phenol polyoxyethylene ether, 1.2-3.5 parts of butadiene resin binder and 2.2-4.6 parts of redispersible latex powder. Compared with the conventional latex coating, the improved exterior wall paint has the advantages that through the rheology behavior controlling performance of the kaolin and the titanium powder, the medium and high shearing strength of the coating is effectively enhanced, and the water diversion tendency of the coating is improved; through the efficient sterilizing performance of the tetramethyl hexaldehyde, the corrosion and demulsification of the coating are effectively prevented, and the storage period of the coating is prolonged; through reasonable matching of a butadiene resin binder, re-dispersible latex powder and other aids, the comprehensive performance of the coating is enhanced, low-cost and high-performance commercial latex paint is prepared.

Description

一种改进的外墙漆及其制备方法 An improved method of preparing and exterior wall

[0001] [0001]

技术领域 FIELD

[0002] 本发明涉及一种改进的外墙漆及其制备方法,属于建筑涂料领域。 [0002] The present invention relates to an improved exterior wall and its preparation method, the architectural coatings.

背景技术 Background technique

[0003] 乳胶漆又称为合成树脂乳液涂料,是有机涂料的一种,是以合成树脂乳液为基料加入颜料、填料及各种助剂配制而成的一类水性涂料。 [0003] The synthetic resin emulsion paint, also known as coating, an organic coating material, is a synthetic resin emulsion as a binder was added pigments, fillers and various additives prepared from a class of water-based paint. 根据生产原料的不同,乳胶漆主要有聚醋酸乙烯乳胶漆、乙丙乳胶漆、纯丙烯酸乳胶漆、苯丙乳胶漆等品种;根据产品适用环境的不同,分为内墙乳胶漆和外墙乳胶漆两种;根据装饰的光泽效果又可分为无光、哑光、半光、丝光和有光等类型。 Depending on the raw materials, mainly polyvinyl acetate latex latex, EPR latex, pure acrylic latex, styrene latex, and other varieties; depending on the products for the environment, and exterior latex paint into interior two kinds of paint; the gloss decorative effects can be divided into matte, matte, semi-gloss, satin, and other types of light. 现有技术中,乳胶漆大多采用多种配方消除有害有机物,但现有的环保乳胶漆在提高环保性能的同时,相应的降低了乳胶漆的其他使用性能,如耐磨性、抗老化性能等等,同时生产成本较高。 In the prior art, using a variety of paint formulations to eliminate most of the harmful organisms, but the conventional green latex while improving environmental performance, a corresponding reduction in other performance of the paint, such as abrasion resistance, aging resistance, etc. etc., and higher production costs. 因此,如何配制一种低成本、高性能的环保乳胶漆是本发明所要进行解决的课题。 Therefore, how to formulate a low-cost, high-performance green latex is object of the present invention to be solved.

发明内容 SUMMARY

[0004] 针对现有技术存在的不足,本发明所要解决的技术问题是,提供一种改进的外墙漆及其制备方法,低成本、高性能,便于施工,附着力强。 [0004] for the shortcomings of the prior art, the present invention is to solve the technical problem is to provide an improved exterior wall and its preparation method, low cost, high performance, ease of construction, strong adhesion.

[0005] 为解决上述技术问题,本发明采取的技术方案是,一种改进的外墙漆,由以下重量份数的原料制成:白乳胶20-30份、钛白粉12-18份、草酸2.3-4.5份、去离子水7.3-8.5份、高岭土5-10份、四甲基己醛3.5-7.6份、三苄基酚聚氧乙烯醚3.4-7.6份、丁二烯树脂成膜剂1.2-3.5份和可再分散乳胶粉2.2-4.6份。 [0005] To solve the above problems, the present invention takes technical solution, an improved exterior wall made of a material of the following parts by weight: 20-30 parts of white latex, 12-18 parts of titanium dioxide, oxalic acid 2.3 to 4.5 parts 7.3-8.5 parts of deionized water, 5-10 parts of kaolin, 3.5-7.6 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 3.4-7.6 parts, butadiene resin film formers 1.2 -3.5 parts redispersible powder and 2.2-4.6 parts.

[0006] 优化的,上述改进的外墙漆,由以下重量份数的原料制成:白乳胶23份、钛白粉15.5份、草酸3.3份、去离子水7.8份、高岭土7份、四甲基己醛4.8份、三苄基酚聚氧乙烯醚4.2份、丁二烯树脂成膜剂1.8份和可再分散乳胶粉3.7份。 [0006] Optimization of the improved exterior wall made of a material of the following parts by weight: 23 parts of white latex, 15.5 parts of titanium dioxide, 3.3 parts of oxalic acid, 7.8 parts of deionized water, 7 parts of kaolin, tetramethyl 4.8 parts of hexanal, tribenzyl phenol polyoxyethylene ether 4.2 parts, 1.8 parts of butadiene resin film formers and redispersible powder 3.7 parts.

[0007 ] -种改进的外墙漆的制备方法,包括以下步骤: 1) 按照配方称量,将白乳胶、去离子水和钛白粉加入分散罐中,以400-500r/min进行分散搅拌15-20min; 2) 然后加入草酸和高岭土,以1000-1200r/min高速分散20-35min ; 3) 再将四甲基己醛和三苄基酚聚氧乙烯醚按配方比例加入,将混合物加热到80-90°C, 并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入丁二烯树脂成膜剂和可再分散乳胶粉,继续升温到60 °C,该温度下保温45-50分钟,同时施加真空到0.09~0.095MPa,然后冷却即为成品。 [0007] - preparation of an improved kind of exterior wall, comprising the following steps: 1) in accordance with the Formulation, the white latex, deionized water and added to the dispersion of titanium dioxide tank to 400-500r / min was dispersed with stirring 15 -20min; 2) of oxalic acid was then added and kaolin, to 1000-1200r / min high speed disperser 20-35min; 3) and then tetramethyl-hexanal tribenzyl phenol polyoxyethylene ether according to the formula proportion added, the mixture was heated to 80-90 ° C, and maintained at this temperature for 2 hours; 4) after the mixture was cooled to room temperature, butadiene resin film formers and redispersible powders, continue to heat to 60 ° C, holding at this temperature for 45-50 minutes, while applying a vacuum to 0.09 ~ 0.095MPa, and then cooling is finished. [0008]本发明利用高岭土和钛白粉的控流变性能,有效提高了涂料的中、高剪切粘度,改善了涂料的分水倾向;利用加四甲基己醛的高效杀菌性能,有效防止了涂料的腐败破乳,提高了涂料的存储周期;通过丁二烯树脂成膜剂、可再分散乳胶粉及其它助剂的合理搭配,提尚了涂料的综合性能,制备出低成本尚性能商品的商品乳胶漆。 [0008] The present invention takes advantage of controlling the rheological properties of titanium dioxide and kaolin, to effectively improve the high shear viscosity of the coating, the coating tends to improve the water trap; efficient bactericidal properties using hexanal plus tetramethyl effectively prevent corruption breaking paint, coating improves storage period; by butadiene resin film formers, redispersible powders and other additives with a reasonable, yet provide the overall performance of the coating prepared performance yet cost product products latex paint.

具体实施方式[0009] 实施例1 本发明为一种改进的外墙漆,由以下重量份数的原料制成:白乳胶20份、钛白粉12份、 草酸2.3份、去离子水7.3份、高岭土5份、四甲基己醛3.5份、三苄基酚聚氧乙烯醚3.4份、丁二烯树脂成膜剂1.2份和可再分散乳胶粉2.2份。 EXAMPLE 1 embodiment of the present invention DETAILED DESCRIPTION [0009] of an improved exterior wall made of a material of the following parts by weight: 20 parts of white latex, 12 parts of titanium dioxide, 2.3 parts of oxalic acid, 7.3 parts of deionized water, 5 parts of kaolin, 3.5 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 3.4 parts, 1.2 parts of butadiene resin film formers and redispersible powder 2.2 parts. 可再分散乳胶粉为乙烯与氯乙烯及月桂酸乙烯酯三元共聚胶粉,三者的混合物。 Redispersible powders of ethylene and vinyl chloride and vinyl laurate terpolymer powder, mixture of the three.

[0010] 一种改进的外墙漆的制备方法,包括以下步骤: 1) 按照配方称量,将白乳胶、去离子水和钛白粉加入分散罐中,以400r/min进行分散搅拌15min; 2) 然后加入草酸和高岭土,以1000r/min高速分散20min ; 3) 再将四甲基己醛和三苄基酚聚氧乙烯醚按配方比例加入,将混合物加热到80°C,并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入丁二烯树脂成膜剂和可再分散乳胶粉,继续升温到60 °C,该温度下保温45分钟,同时施加真空到0.09MPa,然后冷却即为成品。 [0010] An improved method for preparing exterior wall, comprising the following steps: 1) in accordance with the Formulation, the white latex, deionized water and added to the dispersion of titanium dioxide in the tank, at 400r / min dispersing stirred 15min; 2 ) of oxalic acid was then added and kaolin, to 1000r / min high speed disperser 20min; 3) and then tetramethyl-hexanal tribenzyl phenol polyoxyethylene ether according to the formula proportion added, the mixture was heated to 80 ° C, and the temperature incubated for 2 hours; 4) the mixture was cooled to room temperature, butadiene resin film formers and redispersible powders, continue to heat to 60 ° C, holding at this temperature for 45 minutes while vacuum is applied to 0.09MPa, then cooling is finished.

[0011] 实施例2 本发明为一种改进的外墙漆,由以下重量份数的原料制成:白乳胶30份、钛白粉18份、 草酸4.5份、去离子水8.5份、高岭土10份、四甲基己醛7.6份、三苄基酚聚氧乙烯醚7.6份、丁二烯树脂成膜剂3.5份和可再分散乳胶粉4.6份。 [0011] Example 2 of the present invention is an improved exterior wall made of a material of the following parts by weight: 30 parts of white latex, 18 parts of titanium dioxide, 4.5 parts of oxalic acid, 8.5 parts of deionized water, 10 parts of kaolin , 7.6 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 7.6 parts, 3.5 parts of butadiene resin film formers and redispersible powder 4.6 parts.

[0012] -种改进的外墙漆的制备方法,包括以下步骤: 1) 按照配方称量,将白乳胶、去离子水和钛白粉加入分散罐中,以500r/min进行分散搅拌20min; 2) 然后加入草酸和高岭土,以1200r/min高速分散35min ; 3) 再将四甲基己醛和三苄基酚聚氧乙烯醚按配方比例加入,将混合物加热到90°C,并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入丁二烯树脂成膜剂和可再分散乳胶粉,继续升温到60 °C,该温度下保温50分钟,同时施加真空到0.095MPa,然后冷却即为成品。 [0012] - preparation of an improved kind of exterior wall, comprising the following steps: 1) in accordance with the Formulation, the white latex, deionized water and added to the dispersion of titanium dioxide in the tank, at 500r / min dispersing stirred 20min; 2 ) of oxalic acid was then added and kaolin, to 1200r / min high speed disperser 35min; 3) and then tetramethyl-hexanal tribenzyl phenol polyoxyethylene ether according to the formula proportion added, the mixture was heated to 90 ° C, and the temperature incubated for 2 hours; 4) the mixture was cooled to room temperature, butadiene resin film formers and redispersible powders, continue to heat to 60 ° C, holding at this temperature for 50 minutes while vacuum is applied to 0.095MPa, then cooling is finished.

[0013] 实施例3 本发明为一种改进的外墙漆,由以下重量份数的原料制成:白乳胶23份、钛白粉15.5 份、草酸3.3份、去离子水7.8份、高岭土7份、四甲基己醛4.8份、三苄基酚聚氧乙烯醚4.2份、 丁二烯树脂成膜剂1.8份和可再分散乳胶粉3.7份。 [0013] Example 3 embodiment of the present invention is an improved exterior wall made of a material of the following parts by weight: 23 parts of white latex, 15.5 parts of titanium dioxide, 3.3 parts of oxalic acid, 7.8 parts of deionized water, 7 parts of kaolin , 4.8 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 4.2 parts, 1.8 parts of butadiene resin film formers and redispersible powder 3.7 parts.

[0014] -种改进的外墙漆的制备方法,包括以下步骤: 1) 按照配方称量,将白乳胶、去离子水和钛白粉加入分散罐中,以450r/min进行分散搅拌18min; 2) 然后加入草酸和高岭土,以1100r/min高速分散28min ; 3) 再将四甲基己醛和三苄基酚聚氧乙烯醚按配方比例加入,将混合物加热到85°C,并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入丁二烯树脂成膜剂和可再分散乳胶粉,继续升温到60 °C,该温度下保温48分钟,同时施加真空到0.092MPa,然后冷却即为成品。 [0014] - preparation of an improved kind of exterior wall, comprising the following steps: 1) in accordance with the Formulation, the white latex, deionized water and added to the dispersion of titanium dioxide in the tank, at 450r / min dispersing stirred 18min; 2 ) of oxalic acid was then added and kaolin, to 1100r / min high speed disperser 28min; 3) and then tetramethyl-hexanal tribenzyl phenol polyoxyethylene ether according to the formula proportion added, the mixture was heated to 85 ° C, and the temperature incubated for 2 hours; 4) the mixture was cooled to room temperature, butadiene resin film formers and redispersible powders, continue to heat to 60 ° C, holding at this temperature for 48 minutes while vacuum is applied to 0.092MPa, then cooling is finished.

[0015] 将上述实施例1-3中生产的涂料成品与现有技术中涂料成品对比,检测结果如下: [0015] The finished coating with the above-described prior art produced in Examples 1-3 in comparison paint finished, the detection results are as follows:

Figure CN105505042AD00051

施工性的评价以肉眼观察发生厚涂时明显下垂和薄涂时难以抹平的涂覆厚度为标准; 透水性评价参照JIS A6909进行试验; 耐水性评价在50°C的温水中浸泡,以出现明显的白化时间为标准; 耐冻融性评价是将涂层在-20°C环境下冻结2h后在10°C水中浸泡1小时,如此反复,以出现明显的开裂回数为标准; 硬化收缩率是在涂层静置干燥30天后测量的。 Evaluation of workability when visually observed to significantly sagging and thin coating occurred when a thick coating is difficult to smooth out coating thickness standard; Evaluation of Water Permeability test with reference to JIS A6909; evaluation of water resistance soaked in warm water at 50 ° C in order to appear significant whitening time standard; freeze-thaw resistance evaluation after the coating is frozen at -20 ° C for 2h at 10 ° C and ambient immersed water for 1 hour, and so forth, to significant number of cracks back to the standard; hardening shrinkage It is left to dry for 30 days measured in the coating. 经本发明配方和制备工艺得到的内墙漆,具有优异使用性能和施工性能,能够满足日益提高的使用要求。 And the paint formulation prepared by the process of the present invention is obtained, having excellent workability and performance, to meet the increasing requirements.

[0016] 可以看出,本发明涂料的各项指标远远超过国标,具有$父尚的抗压强度和粘结强度,耐水性好。 [0016] As can be seen, the indicators coating of the present invention is far more than the national standard, has a compressive strength and bond strength is still $ parent, and water resistance. 与现有的乳胶涂料相比,利用高岭土和钛白粉的控流变性能,有效提高了涂料的中、高剪切粘度,改善了涂料的分水倾向;利用加四甲基己醛的高效杀菌性能,有效防止了涂料的腐败破乳,提高了涂料的存储周期;通过丁二烯树脂成膜剂、可再分散乳胶粉及其它助剂的合理搭配,提尚了涂料的综合性能,制备出低成本尚性能商品的商品乳胶漆。 Compared with a conventional latex paint, using a control rheological properties of titanium dioxide and kaolin, to effectively improve the high shear viscosity of the coating, the coating tends to improve the water trap; using hexanal plus tetramethyl efficient sterilization property, effectively preventing the breaking of corruption coating, the coating increases the storage period; by butadiene resin film formers, redispersible powders and other additives with a reasonable, yet provide the overall performance of the coating prepared product performance yet low-cost commodity latex paint.

[0017] 对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。 [0017] The above description of the disclosed embodiments enables those skilled in the art to make or use the present invention. 对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。 Various modifications to these professionals skilled in the art of the present embodiments will be apparent, and the generic principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. 因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。 Accordingly, the present invention will not be limited to the embodiments shown herein but is to be accorded herein consistent with the principles and novel features disclosed widest scope.

Claims (3)

  1. 1. 一种改进的外墙漆,其特征在于:由以下重量份数的原料制成:白乳胶20-30份、钛白粉12-18份、草酸2.3-4.5份、去离子水7.3-8.5份、高岭土5-10份、四甲基己醛3.5-7.6份、三苄基酚聚氧乙烯醚3.4-7.6份、丁二烯树脂成膜剂1.2-3.5份和可再分散乳胶粉2.2-4.6份。 1. An improved exterior wall, characterized in that: the raw material is made of the following parts by weight: 20-30 parts of white latex, 12-18 parts of titanium dioxide, 2.3 to 4.5 parts of oxalic acid, deionized water 7.3-8.5 parts, 5-10 parts of kaolin, 3.5-7.6 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 3.4-7.6 parts 1.2-3.5 parts butadiene resin film formers and redispersible powders 2.2 4.6 parts.
  2. 2. 根据权利要求1所述的改进的外墙漆,其特征在于:由以下重量份数的原料制成:白乳胶23份、钛白粉15.5份、草酸3.3份、去离子水7.8份、高岭土7份、四甲基己醛4.8份、三苄基酚聚氧乙烯醚4.2份、丁二烯树脂成膜剂1.8份和可再分散乳胶粉3.7份。 2. The improvement according to claim 1 exterior wall, characterized in that: the raw material is made of the following parts by weight: 23 parts of white latex, 15.5 parts of titanium dioxide, 3.3 parts of oxalic acid, 7.8 parts of deionized water, kaolin 7 parts, 4.8 parts tetramethyl-hexanal, tribenzyl phenol polyoxyethylene ether 4.2 parts, 1.8 parts of butadiene resin film formers and redispersible powder 3.7 parts.
  3. 3. 根据权利要求1或者2所述的改进的外墙漆的制备方法,包括以下步骤: 1) 按照配方称量,将白乳胶、去离子水和钛白粉加入分散罐中,以400-500r/min进行分散搅拌15-20min; 2) 然后加入草酸和高岭土,以1000-1200r/min高速分散20-35min ; 3) 再将四甲基己醛和三苄基酚聚氧乙烯醚按配方比例加入,将混合物加热到80-90°C, 并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入丁二烯树脂成膜剂和可再分散乳胶粉,继续升温到60 °C,该温度下保温45-50分钟,同时施加真空到0.09~0.095MPa,然后冷却即为成品。 3. The improved method of claim 1 or 2 or preparation of the exterior wall, comprising the steps of claim: 1) in accordance with the Formulation, the white latex, deionized water and added to the dispersion of titanium dioxide tank to 400-500r / min was dispersed with stirring 15-20min; 2) of oxalic acid was then added and kaolin, to 1000-1200r / min high speed disperser 20-35min; 3) and then tetramethyl-hexanal tribenzyl phenol polyoxyethylene ether according to formula ratio was added, the mixture was heated to 80-90 ° C, and maintained at this temperature for 2 hours; 4) after the mixture was cooled to room temperature, butadiene resin film formers and redispersible powders, continue to heat up to 60 ° C, at this temperature for 45-50 minutes, while applying a vacuum to 0.09 ~ 0.095MPa, and then cooling is finished.
CN 201511013589 2015-12-31 2015-12-31 Improved exterior wall paint and preparation method thereof CN105505042A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87106049A (en) * 1986-09-03 1988-06-29 狮子株式会社 Oral composition
EP2166050A3 (en) * 2008-09-02 2010-09-29 Celanese International Corporation Low emission, high scrub VAE latex paints
CN103130448A (en) * 2011-11-30 2013-06-05 李建国 Efficient and environment-friendly emulsion paint
CN103387775A (en) * 2013-08-22 2013-11-13 吴江市冰心文教用品有限公司 Thermal-insulating waterproof pigment
CN104412978A (en) * 2013-08-30 2015-03-18 青岛好利特生物农药有限公司 Preparation method of metaldehyde
CN104610862A (en) * 2013-11-05 2015-05-13 韩可心 Moisture resistant coating
CN104804560A (en) * 2015-04-08 2015-07-29 田福东 Scrubbing-resistant environment-friendly interior-wall latex paint
CN104804577A (en) * 2015-04-17 2015-07-29 青岛保利康新材料有限公司 Durable exterior wall coating
CN105176214A (en) * 2015-09-29 2015-12-23 孙大龙 Water-based color spray paint and preparation method

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87106049A (en) * 1986-09-03 1988-06-29 狮子株式会社 Oral composition
EP2166050A3 (en) * 2008-09-02 2010-09-29 Celanese International Corporation Low emission, high scrub VAE latex paints
CN103130448A (en) * 2011-11-30 2013-06-05 李建国 Efficient and environment-friendly emulsion paint
CN103387775A (en) * 2013-08-22 2013-11-13 吴江市冰心文教用品有限公司 Thermal-insulating waterproof pigment
CN104412978A (en) * 2013-08-30 2015-03-18 青岛好利特生物农药有限公司 Preparation method of metaldehyde
CN104610862A (en) * 2013-11-05 2015-05-13 韩可心 Moisture resistant coating
CN104804560A (en) * 2015-04-08 2015-07-29 田福东 Scrubbing-resistant environment-friendly interior-wall latex paint
CN104804577A (en) * 2015-04-17 2015-07-29 青岛保利康新材料有限公司 Durable exterior wall coating
CN105176214A (en) * 2015-09-29 2015-12-23 孙大龙 Water-based color spray paint and preparation method

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