CN105504660A - Insulated plastic material and preparation method thereof - Google Patents
Insulated plastic material and preparation method thereof Download PDFInfo
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- CN105504660A CN105504660A CN201610052490.9A CN201610052490A CN105504660A CN 105504660 A CN105504660 A CN 105504660A CN 201610052490 A CN201610052490 A CN 201610052490A CN 105504660 A CN105504660 A CN 105504660A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The invention discloses an insulated plastic material and a preparation method thereof. The insulated plastic material is prepared from, by weight, 65-70 parts of an acrylonitrile-butadiene-styrene copolymer, 11-16 parts of polyisobutene, 10-12 parts of kieselguhr, 8-10 parts of octadecyl glyceryl ether, 5-8 parts of polyhydroxybutyrate-hydroxyvalerate, 2-5 parts of butyl benzyl phthalate, 1-3 parts of deacetylasperulosidic acid methyl ester, 0.8-1.8 parts of 3,7-dimethyl-7-octenal, 0.8-1.6 parts of 5,7,8,4'-tetramethoxyflavone, 0.5-0.8 part of pyridine-2,6-dicarboxylic acid and 0.2-0.4 part of N-isobutyltetradecatetraenamide. The invention further provides the preparation method of the insulated plastic material.
Description
Technical field
The invention belongs to plastic material field, particularly a kind of dielectric plastic material and preparation method thereof.
Background technology
Plastic cement part is widely used in each field in life, such as household electrical appliance, instrument, electric wire, construction equipment, communication electronics, automotive industry, space flight and aviation, haberdashery and hardware etc.
The major ingredient of plastic material is carbon compound, by adding kind of auxiliary material or additive, can be processed to definite shape.Plastic cement has good insulativity, arc resistance, insulation, sound insulation, sound-absorbing, absorbing and acoustic attenuation performance.
Acrylonitrile-butadiene-styrene copolymer (being called for short ABS), being that a kind of intensity is high, good toughness, being easy to thermoplastics type's Polymer Materials ' Structure of machine-shaping, is vinyl cyanide, 1,3-butadiene, cinnamic terpolymer, there is good formability, and product surface is bright and clean.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of dielectric plastic material and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of dielectric plastic material, be made up of the component comprising following weight part:
Acrylonitrile-butadiene-styrene copolymer: 65-70 part, polyisobutene: 11-16 part,
Diatomite: 10-12 part, batyl alcohol: 8-10 part,
Polyhydroxybutyrate valeric acid copolyesters: 5-8 part, butyl benzyl phthalate: 2-5 part,
De-acetyl rubichloric acid acid methyl esters: 1-3 part,
3,7-dimethyl-7-octenal: 0.8-1.8 part,
5,7,8,4 '-tetramethoxy flavones: 0.8-1.6 part,
Pyridine-2,6-dicarboxylic acid: 0.5-0.8 part,
N-isobutyl-14 carbon tetraene acid amides: 0.2-0.4 part.
Described component also comprises polyacrylamide sodium salt: 0-1 weight part.
Described component also comprises toner: 0-1 weight part.
A preparation method for dielectric plastic material, the method comprises the following steps:
(1) acrylonitrile-butadiene-styrene copolymer 65-70 weight part, batyl alcohol 8-10 weight part, polyhydroxybutyrate valeric acid copolyesters 5-8 weight part, butyl benzyl phthalate 2-5 weight part, de-acetyl rubichloric acid acid methyl esters 1-3 weight part, 3 is taken, 7-dimethyl-7-octenal 0.8-1.8 weight part, 5,7,8,4 '-tetramethoxy flavones 0.8-1.6 weight part, pyridine-2,6-dicarboxylic acid 0.5-0.8 weight part, N-isobutyl-14 carbon tetraene acid amides 0.2-0.4 weight part, polyacrylamide sodium salt 0-1 weight part and toner 0-1 weight part;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 11-16 weight part, diatomite 10-12 weight part at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: a district temperature 170-190 DEG C, two district temperature 200-220 DEG C, three district temperature 220-230 DEG C, four district temperature 200-210 DEG C.
Compared with prior art, its beneficial effect is in the present invention:
(1) dielectric plastic material that the present invention obtains take acrylonitrile-butadiene-styrene copolymer as main raw material, by adding polyisobutene, diatomite, batyl alcohol, polyhydroxybutyrate valeric acid copolyesters, butyl benzyl phthalate, de-acetyl rubichloric acid acid methyl esters, 3,7-dimethyl-7-octenal, 5,7,8,4 '-tetramethoxy flavones, pyridine-2,6-dicarboxylic acid and N-isobutyl-14 carbon tetraene acid amides, obtained plastic material has good insulating property, and has good mechanical stretch performance and toughness.
(2) dielectric plastic material that the present invention obtains has good ageing-resistant and stability.
(3) dielectric plastic material of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) acrylonitrile-butadiene-styrene copolymer 65kg, batyl alcohol 8kg, polyhydroxybutyrate valeric acid copolyesters 5kg, butyl benzyl phthalate 2kg, de-acetyl rubichloric acid acid methyl esters 1kg, 3 is taken, 7-dimethyl-7-octenal 0.8kg, 5,7,8,4 '-tetramethoxy flavones 0.8kg, pyridine-2,6-dicarboxylic acid 0.5kg and N-isobutyl-14 carbon tetraene acid amides 0.2kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 11kg, diatomite 10kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 170 DEG C, two district's temperature 200 DEG C, three district's temperature 220 DEG C, four district's temperature 200 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Embodiment 2
(1) acrylonitrile-butadiene-styrene copolymer 65kg, batyl alcohol 8kg, polyhydroxybutyrate valeric acid copolyesters 5kg, butyl benzyl phthalate 2kg, de-acetyl rubichloric acid acid methyl esters 1kg, 3 is taken, 7-dimethyl-7-octenal 0.8kg, 5,7,8,4 '-tetramethoxy flavones 0.8kg, pyridine-2,6-dicarboxylic acid 0.5kg, N-isobutyl-14 carbon tetraene acid amides 0.2kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 11kg, diatomite 10kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 170 DEG C, two district's temperature 200 DEG C, three district's temperature 220 DEG C, four district's temperature 200 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Embodiment 3
(1) acrylonitrile-butadiene-styrene copolymer 70kg, batyl alcohol 10kg, polyhydroxybutyrate valeric acid copolyesters 8kg, butyl benzyl phthalate 5kg, de-acetyl rubichloric acid acid methyl esters 3kg, 3 is taken, 7-dimethyl-7-octenal 1.8kg, 5,7,8,4 '-tetramethoxy flavones 1.6kg, pyridine-2,6-dicarboxylic acid 0.8kg, N-isobutyl-14 carbon tetraene acid amides 0.4kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 16kg, diatomite 12kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 190 DEG C, two district's temperature 220 DEG C, three district's temperature 230 DEG C, four district's temperature 210 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Embodiment 4
(1) acrylonitrile-butadiene-styrene copolymer 70kg, batyl alcohol 10kg, polyhydroxybutyrate valeric acid copolyesters 8kg, butyl benzyl phthalate 5kg, de-acetyl rubichloric acid acid methyl esters 1kg, 3 is taken, 7-dimethyl-7-octenal 0.8kg, 5,7,8,4 '-tetramethoxy flavones 1.6kg, pyridine-2,6-dicarboxylic acid 0.5kg, N-isobutyl-14 carbon tetraene acid amides 0.4kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 16kg, diatomite 12kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 190 DEG C, two district's temperature 220 DEG C, three district's temperature 230 DEG C, four district's temperature 210 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Embodiment 5
(1) acrylonitrile-butadiene-styrene copolymer 68kg, batyl alcohol 9kg, polyhydroxybutyrate valeric acid copolyesters 7kg, butyl benzyl phthalate 4kg, de-acetyl rubichloric acid acid methyl esters 2kg, 3 is taken, 7-dimethyl-7-octenal 1.2kg, 5,7,8,4 '-tetramethoxy flavones 1.2kg, pyridine-2,6-dicarboxylic acid 0.7kg, N-isobutyl-14 carbon tetraene acid amides 0.3kg, polyacrylamide sodium salt 0.5kg and toner 0.5kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 13kg, diatomite 11kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 180 DEG C, two district's temperature 210 DEG C, three district's temperature 225 DEG C, four district's temperature 205 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Comparative example 1
(1) acrylonitrile-butadiene-styrene copolymer 70kg, batyl alcohol 10kg, polyhydroxybutyrate valeric acid copolyesters 8kg, butyl benzyl phthalate 5kg, 3 is taken, 7-dimethyl-7-octenal 1.8kg, 5,7,8,4 '-tetramethoxy flavones 1.6kg, pyridine-2,6-dicarboxylic acid 0.8kg, N-isobutyl-14 carbon tetraene acid amides 0.4kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 16kg, diatomite 12kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 190 DEG C, two district's temperature 220 DEG C, three district's temperature 230 DEG C, four district's temperature 210 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Comparative example 2
(1) acrylonitrile-butadiene-styrene copolymer 70kg, batyl alcohol 10kg, polyhydroxybutyrate valeric acid copolyesters 8kg, butyl benzyl phthalate 5kg, de-acetyl rubichloric acid acid methyl esters 3kg, 3 is taken, 7-dimethyl-7-octenal 1.8kg, 5,7,8,4 '-tetramethoxy flavones 1.6kg, N-isobutyl-14 carbon tetraene acid amides 0.4kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 16kg, diatomite 12kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 190 DEG C, two district's temperature 220 DEG C, three district's temperature 230 DEG C, four district's temperature 210 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Comparative example 3
(1) acrylonitrile-butadiene-styrene copolymer 70kg, batyl alcohol 10kg, polyhydroxybutyrate valeric acid copolyesters 8kg, butyl benzyl phthalate 5kg, de-acetyl rubichloric acid acid methyl esters 3kg, 3 is taken, 7-dimethyl-7-octenal 1.8kg, 5,7,8,4 '-tetramethoxy flavones 1.6kg, pyridine-2,6-dicarboxylic acid 0.8kg, polyacrylamide sodium salt 1kg and toner 1kg;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 16kg, diatomite 12kg at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
The each zone temperatures of described twin screw extruder is: district's temperature 190 DEG C, two district's temperature 220 DEG C, three district's temperature 230 DEG C, four district's temperature 210 DEG C.
The performance test results of obtained dielectric plastic material is as shown in table 1.
Table 1
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (5)
1. a dielectric plastic material, is characterized in that, is made up of the component comprising following weight part:
Acrylonitrile-butadiene-styrene copolymer: 65-70 part, polyisobutene: 11-16 part,
Diatomite: 10-12 part, batyl alcohol: 8-10 part,
Polyhydroxybutyrate valeric acid copolyesters: 5-8 part, butyl benzyl phthalate: 2-5 part,
De-acetyl rubichloric acid acid methyl esters: 1-3 part,
3,7-dimethyl-7-octenal: 0.8-1.8 part,
5,7,8,4 '-tetramethoxy flavones: 0.8-1.6 part,
Pyridine-2,6-dicarboxylic acid: 0.5-0.8 part,
N-isobutyl-14 carbon tetraene acid amides: 0.2-0.4 part.
2. dielectric plastic material according to claim 1, it is characterized in that, described component also comprises polyacrylamide sodium salt 0-1 weight part.
3. dielectric plastic material according to claim 1, it is characterized in that, described component also comprises toner 0-1 weight part.
4. a preparation method for dielectric plastic material, is characterized in that, the method comprises the following steps:
(1) acrylonitrile-butadiene-styrene copolymer 65-70 weight part, batyl alcohol 8-10 weight part, polyhydroxybutyrate valeric acid copolyesters 5-8 weight part, butyl benzyl phthalate 2-5 weight part, de-acetyl rubichloric acid acid methyl esters 1-3 weight part, 3 is taken, 7-dimethyl-7-octenal 0.8-1.8 weight part, 5,7,8,4 '-tetramethoxy flavones 0.8-1.6 weight part, pyridine-2,6-dicarboxylic acid 0.5-0.8 weight part, N-isobutyl-14 carbon tetraene acid amides 0.2-0.4 weight part, polyacrylamide sodium salt 0-1 weight part and toner 0-1 weight part;
(2) said components ball mill is carried out ground and mixed, adds polyisobutene 11-16 weight part, diatomite 10-12 weight part at the side loading mouth of twin screw extruder, melting, extrude, dry, pelletizing, obtain dielectric plastic material.
5. the preparation method of dielectric plastic material according to claim 4, is characterized in that, each zone temperatures of described twin screw extruder is: a district temperature 170-190 DEG C, two district temperature 200-220 DEG C, three district temperature 220-230 DEG C, four district temperature 200-210 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610052490.9A CN105504660A (en) | 2016-01-26 | 2016-01-26 | Insulated plastic material and preparation method thereof |
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| CN201610052490.9A CN105504660A (en) | 2016-01-26 | 2016-01-26 | Insulated plastic material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106188904A (en) * | 2016-09-07 | 2016-12-07 | 芜湖德鑫汽车部件有限公司 | PIB air conditioning for automobiles protects solar or lunar halo and preparation method thereof |
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| CN102482463A (en) * | 2009-08-27 | 2012-05-30 | 埃克森美孚化学专利公司 | Elastomeric compositions and their use in articles |
| CN103540089A (en) * | 2013-09-28 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Modified ABS (acrylonitrile butadiene styrene) abrasion-resistance polymer material |
| CN104072839A (en) * | 2014-06-24 | 2014-10-01 | 安徽宁国尚鼎橡塑制品有限公司 | Flame retardant and heat resistant rubber material |
| CN104109336A (en) * | 2014-07-18 | 2014-10-22 | 滁州诺恩金塑制品有限公司 | High-gloss ABS plastic for domestic appliances |
| CN104877242A (en) * | 2015-04-29 | 2015-09-02 | 安徽欧耐橡塑工业有限公司 | Heatproof rubber material for conveying belt |
-
2016
- 2016-01-26 CN CN201610052490.9A patent/CN105504660A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102482463A (en) * | 2009-08-27 | 2012-05-30 | 埃克森美孚化学专利公司 | Elastomeric compositions and their use in articles |
| CN103540089A (en) * | 2013-09-28 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Modified ABS (acrylonitrile butadiene styrene) abrasion-resistance polymer material |
| CN104072839A (en) * | 2014-06-24 | 2014-10-01 | 安徽宁国尚鼎橡塑制品有限公司 | Flame retardant and heat resistant rubber material |
| CN104109336A (en) * | 2014-07-18 | 2014-10-22 | 滁州诺恩金塑制品有限公司 | High-gloss ABS plastic for domestic appliances |
| CN104877242A (en) * | 2015-04-29 | 2015-09-02 | 安徽欧耐橡塑工业有限公司 | Heatproof rubber material for conveying belt |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106188904A (en) * | 2016-09-07 | 2016-12-07 | 芜湖德鑫汽车部件有限公司 | PIB air conditioning for automobiles protects solar or lunar halo and preparation method thereof |
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Application publication date: 20160420 |