CN105504454A - Anti-sunshine machine protection cover plastic and preparation method thereof - Google Patents
Anti-sunshine machine protection cover plastic and preparation method thereof Download PDFInfo
- Publication number
- CN105504454A CN105504454A CN201610013815.2A CN201610013815A CN105504454A CN 105504454 A CN105504454 A CN 105504454A CN 201610013815 A CN201610013815 A CN 201610013815A CN 105504454 A CN105504454 A CN 105504454A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- parts
- stirred
- plastic
- minute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses anti-sunshine machine protection cover plastic. The plastic is prepared from, by weight, 0.1-0.2 part of ultraviolet absorber UV-329, 1-2 parts of benzotriazole, 140-200 parts of high density polyethylene, 2-3 parts of didecyl dimethyl ammonium bromide, 1-2 parts of citrus residues, 0.6-1 part of aluminum ammonium sulfate, 3-4 parts of phytic acid, 10-12 parts of polybutylene terephthalate, 4-5 parts of tackifier, 10-14 parts of illite powder, 2-3 parts of oyster shell powder and 1-2 parts of sodium dodecyl sulfate. The ultraviolet absorber UV-329, the benzotriazole and the like are added into the plastic, so the anti-ultraviolet intensity of the plastic can be obviously improved, and the anti-sunshine performance is improved. The plastic is particularly suitable for an external-use machine protection cover and good in heat resistance, water resistance and acid-base resistance. Pentaerythritol and polyvinylpyrrolidone are used as main materials of the tackifier added into the plastic, so that dispersity of filler in the plastic is effectively improved, and stability and strength of a finished plastic product are improved.
Description
Technical field
The present invention relates to plastics arts, particularly relate to a kind of machinery Sun-proof protecting jacket plastics and preparation method thereof.
Background technology
Plastics take monomer as raw material, by the macromolecular compound of addition polymerization or polycondensation polymerized, be commonly called as plastics or resin, can freely change composition and body styles, be made up of additives such as synthetic resins and filler, softening agent, stablizer, lubricant, colorants, most of plastics light weight, chemical stabilization, can not corrosion; Shock-resistance is good; There is the transparency and wear resistant preferably; Good insulating, thermal conductivity is low; General formability, tint permanence are good, and tooling cost is low; But the plastic prod shortcoming that also ubiquity is much common at present: most of plastics poor heat resistance, coefficient of thermal expansion is large, easy firing; Poor dimensional stability, is easily out of shape; Most plastics lower temperature resistance is poor, becomes fragile under low temperature, easily aging; Plastics different performance determines it in life purposes in the industry, along with the progress of technology, never stops research to modifying plastics.In order to improve constantly the performance of plastic product, making plastics have different characteristics in different fields, meeting different Working environments, modification is targetedly carried out to plastics and just seems particularly necessary.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of machinery Sun-proof protecting jacket plastics and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of machinery Sun-proof protecting jacket plastics, it is made up of the raw material of following weight parts:
UV light absorber UV-3290.1-0.2, phenylpropyl alcohol triazole 1-2, high density polyethylene(HDPE) 140-200, two decyl dimethyl brometo de amonio 2-3, citrus pulp 1-2, exsiccated ammonium alum 0.6-1, phytinic acid 3-4, polybutylene terephthalate 10-12, tackifier 4-5, Erie stone flour 10-14, oyster shell powder 2-3, sodium lauryl sulphate 1-2.
Described one machinery Sun-proof protecting jacket plastics, described tackifier are made up of the raw material of following weight parts:
Aluminium dihydrogen phosphate 0.7-1, polyvinylpyrrolidone 3-5, sodium bicarbonate 1.5-2, tetramethylolmethane 2-3, silane coupling agent KH5600.1-0.2;
Joined by above-mentioned polyvinylpyrrolidone in its weight 6-8 times deionized water, stirring and dissolving, adds sodium bicarbonate, and raised temperature is 70-75 DEG C, insulated and stirred 3-5 minute, adds aluminium dihydrogen phosphate, is stirred to normal temperature, is material a;
Join in tetramethylolmethane by above-mentioned silane coupling agent KH560, insulated and stirred 10-20 minute at 50-60 DEG C, mix with above-mentioned material a, 700-1000 rev/min is stirred 4-10 minute, to obtain final product.
A preparation method for described machinery Sun-proof protecting jacket plastics, comprises the following steps:
(1) above-mentioned exsiccated ammonium alum is joined in its weight 10-13 deionized water doubly, insulated and stirred 10-20 minute at 80-90 DEG C;
(2) join in phytinic acid by above-mentioned citrus pulp, be uniformly mixed 20-30 minute, the exsiccated ammonium alum aqueous solution obtained with above-mentioned steps (1), 100-120 rev/min is stirred 30-40 minute, obtains modified solution;
(3) above-mentioned sodium lauryl sulphate joined in its weight 20-30 deionized water doubly, stir, add oyster shell powder, raised temperature is 60-70 DEG C, adds above-mentioned modified solution, tackifier, and 800-1000 rev/min is stirred 4-6 minute, is material a;
(4) above-mentioned Erie stone flour is sent in the sodium hydroxide solution of 10-17mol/l and soak 2-3 hour, filter discharging, wash 3-4 time, drying, mixes with two decyl dimethyl brometo de amonio, joins in compound weight 2-3 deionized water doubly, stir, mix with above-mentioned material a, add UV light absorber UV-329, phenylpropyl alcohol triazole, insulated and stirred 4-5 minute in the water-bath of 80-90 DEG C, discharging cools, suction filtration, by filter cake dry 1-2 hour at 60-70 DEG C, obtains Preblend;
(5) above-mentioned Preblend mixed with each raw material of residue, stir, send into twin screw extruder and melt extrude, cooling, to obtain final product.
Advantage of the present invention is
Plastics of the present invention add UV light absorber UV-329, phenylpropyl alcohol triazole etc., significantly can improve the uvioresistant intensity of plastics, improve Sun-proof performance, plastics of the present invention are particularly suitable as mechanical external protection cover, heat-resisting, water-fast, resistance to acids and bases is good, the tackifier that plastics of the present invention add for major ingredient with tetramethylolmethane, polyvinylpyrrolidone, effectively raise filler dispersiveness in the plastic, improve the stability_intensity of plastic product.
Embodiment
A kind of machinery Sun-proof protecting jacket plastics, it is made up of the raw material of following weight parts:
UV light absorber UV-329, phenylpropyl alcohol triazole 1, high density polyethylene(HDPE) 140, two decyl dimethyl brometo de amonio 2, citrus pulp 1, exsiccated ammonium alum 0.6, phytinic acid 3, polybutylene terephthalate 10, tackifier 4, Erie's stone flour 10, oyster shell powder 2, sodium lauryl sulphate 1.
Described one machinery Sun-proof protecting jacket plastics, described tackifier are made up of the raw material of following weight parts:
Aluminium dihydrogen phosphate 0.7, polyvinylpyrrolidone 3, sodium bicarbonate 1.5, tetramethylolmethane 2, silane coupling agent KH5600.1;
Joined by above-mentioned polyvinylpyrrolidone in its weight 6 times of deionized waters, stirring and dissolving, adds sodium bicarbonate, and raised temperature is 70 DEG C, and insulated and stirred 3 minutes, adds aluminium dihydrogen phosphate, be stirred to normal temperature, is material a;
Join in tetramethylolmethane by above-mentioned silane coupling agent KH560, insulated and stirred 10 minutes at 50 DEG C, mixes with above-mentioned material a, and 700 revs/min are stirred 4 minutes, to obtain final product.
A preparation method for described machinery Sun-proof protecting jacket plastics, comprises the following steps:
(1) above-mentioned exsiccated ammonium alum is joined in the deionized water of its weight 10 times, insulated and stirred 10 minutes at 80 DEG C;
(2) join in phytinic acid by above-mentioned citrus pulp, be uniformly mixed 20 minutes, the exsiccated ammonium alum aqueous solution obtained with above-mentioned steps (1), 100 revs/min are stirred 30 minutes, obtain modified solution;
(3) above-mentioned sodium lauryl sulphate joined in the deionized water of its weight 20 times, stir, add oyster shell powder, raised temperature is 60 DEG C, adds above-mentioned modified solution, tackifier, and 800 revs/min are stirred 4 minutes, is material a;
(4) above-mentioned Erie stone flour is sent in the sodium hydroxide solution of 10mol/l and soak 2 hours, filter discharging, wash 3 times, drying, mixes with two decyl dimethyl brometo de amonio, joins in the deionized water of compound weight 2 times, stir, mix with above-mentioned material a, add UV light absorber UV, phenylpropyl alcohol triazole, insulated and stirred 4 minutes in the water-bath of 80 DEG C, discharging cools, suction filtration, by filter cake at 60 DEG C dry 1 hour, obtains Preblend;
(5) above-mentioned Preblend mixed with each raw material of residue, stir, send into twin screw extruder and melt extrude, cooling, to obtain final product.
Performance test:
Tensile strength: 22.0MPa;
Low temperature brittleness impact temperature (DEG C) :-30 DEG C are passed through;
Fire-retardant rank: V-0.
Claims (3)
1. machinery Sun-proof protecting jacket plastics, is characterized in that: it is made up of the raw material of following weight parts:
UV light absorber UV-3290.1-0.2, phenylpropyl alcohol triazole 1-2, high density polyethylene(HDPE) 140-200, two decyl dimethyl brometo de amonio 2-3, citrus pulp 1-2, exsiccated ammonium alum 0.6-1, phytinic acid 3-4, polybutylene terephthalate 10-12, tackifier 4-5, Erie stone flour 10-14, oyster shell powder 2-3, sodium lauryl sulphate 1-2.
2. a kind of machinery Sun-proof protecting jacket plastics according to claim 1, is characterized in that: described tackifier are made up of the raw material of following weight parts:
Aluminium dihydrogen phosphate 0.7-1, polyvinylpyrrolidone 3-5, sodium bicarbonate 1.5-2, tetramethylolmethane 2-3, silane coupling agent KH5600.1-0.2;
Joined by above-mentioned polyvinylpyrrolidone in its weight 6-8 times deionized water, stirring and dissolving, adds sodium bicarbonate, and raised temperature is 70-75 DEG C, insulated and stirred 3-5 minute, adds aluminium dihydrogen phosphate, is stirred to normal temperature, is material a;
Join in tetramethylolmethane by above-mentioned silane coupling agent KH560, insulated and stirred 10-20 minute at 50-60 DEG C, mix with above-mentioned material a, 700-1000 rev/min is stirred 4-10 minute, to obtain final product.
3. a machinery preparation method for Sun-proof protecting jacket plastics as claimed in claim 1, is characterized in that, comprise the following steps:
(1) above-mentioned exsiccated ammonium alum is joined in its weight 10-13 deionized water doubly, insulated and stirred 10-20 minute at 80-90 DEG C;
(2) join in phytinic acid by above-mentioned citrus pulp, be uniformly mixed 20-30 minute, the exsiccated ammonium alum aqueous solution obtained with above-mentioned steps (1), 100-120 rev/min is stirred 30-40 minute, obtains modified solution;
(3) above-mentioned sodium lauryl sulphate joined in its weight 20-30 deionized water doubly, stir, add oyster shell powder, raised temperature is 60-70 DEG C, adds above-mentioned modified solution, tackifier, and 800-1000 rev/min is stirred 4-6 minute, is material a;
(4) above-mentioned Erie stone flour is sent in the sodium hydroxide solution of 10-17mol/l and soak 2-3 hour, filter discharging, wash 3-4 time, drying, mixes with two decyl dimethyl brometo de amonio, joins in compound weight 2-3 deionized water doubly, stir, mix with above-mentioned material a, add UV light absorber UV-329, phenylpropyl alcohol triazole, insulated and stirred 4-5 minute in the water-bath of 80-90 DEG C, discharging cools, suction filtration, by filter cake dry 1-2 hour at 60-70 DEG C, obtains Preblend;
(5) above-mentioned Preblend mixed with each raw material of residue, stir, send into twin screw extruder and melt extrude, cooling, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610013815.2A CN105504454A (en) | 2016-01-11 | 2016-01-11 | Anti-sunshine machine protection cover plastic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610013815.2A CN105504454A (en) | 2016-01-11 | 2016-01-11 | Anti-sunshine machine protection cover plastic and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504454A true CN105504454A (en) | 2016-04-20 |
Family
ID=55712791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610013815.2A Pending CN105504454A (en) | 2016-01-11 | 2016-01-11 | Anti-sunshine machine protection cover plastic and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504454A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101517005A (en) * | 2006-09-25 | 2009-08-26 | 科聚亚公司 | Flame resistance natural fiber-filled thermoplastics with improved properties |
| CN102276896A (en) * | 2011-06-24 | 2011-12-14 | 合肥工业大学 | Bamboo shoot shell fiber/PE degradable composite material and preparation method thereof |
| CN102516634A (en) * | 2011-12-14 | 2012-06-27 | 吴江明峰聚氨酯制品有限公司 | Halogen-free flame-retardant polyethylene plastic |
| CN102690525A (en) * | 2012-05-29 | 2012-09-26 | 北京化工大学 | Wood-plastic composite material using sweet sorghum slag as enhanced phase and preparation method for wood-plastic composite material |
| CN102993538A (en) * | 2011-09-09 | 2013-03-27 | 滁州格美特科技有限公司 | Modified plastic, and making method and use thereof |
| CN103554601A (en) * | 2013-10-30 | 2014-02-05 | 安徽国通高新管业股份有限公司 | High-density polyethylene double-wall corrugated tube |
| CN104861267A (en) * | 2015-05-09 | 2015-08-26 | 安徽宜佳日用品有限公司 | High density polyethylene plastic container |
-
2016
- 2016-01-11 CN CN201610013815.2A patent/CN105504454A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101517005A (en) * | 2006-09-25 | 2009-08-26 | 科聚亚公司 | Flame resistance natural fiber-filled thermoplastics with improved properties |
| CN102276896A (en) * | 2011-06-24 | 2011-12-14 | 合肥工业大学 | Bamboo shoot shell fiber/PE degradable composite material and preparation method thereof |
| CN102993538A (en) * | 2011-09-09 | 2013-03-27 | 滁州格美特科技有限公司 | Modified plastic, and making method and use thereof |
| CN102516634A (en) * | 2011-12-14 | 2012-06-27 | 吴江明峰聚氨酯制品有限公司 | Halogen-free flame-retardant polyethylene plastic |
| CN102690525A (en) * | 2012-05-29 | 2012-09-26 | 北京化工大学 | Wood-plastic composite material using sweet sorghum slag as enhanced phase and preparation method for wood-plastic composite material |
| CN103554601A (en) * | 2013-10-30 | 2014-02-05 | 安徽国通高新管业股份有限公司 | High-density polyethylene double-wall corrugated tube |
| CN104861267A (en) * | 2015-05-09 | 2015-08-26 | 安徽宜佳日用品有限公司 | High density polyethylene plastic container |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106589650A (en) | Fine-performance plastic material and preparation method thereof | |
| CN105462110A (en) | Antistatic screen radiation modified polyvinyl chloride cable material and preparation method thereof | |
| CN105821520A (en) | Efficient environment-friendly inflaming-retarding brush wire production technology | |
| CN105504455A (en) | Heat preservation and insulation plastic for building material and preparation method of heat preservation and insulation plastic | |
| CN104292647A (en) | Antibacterial anti-corrosion polypropylene sheet | |
| CN105504514A (en) | Environment-friendly plastic toughened through fibers and preparation method thereof | |
| CN105504454A (en) | Anti-sunshine machine protection cover plastic and preparation method thereof | |
| CN105504513A (en) | Energy-saving abrasion-resistant sheath plastic for apparatus handle and preparing method of energy-saving abrasion-resistant sheath plastic | |
| CN103665401A (en) | Preparation method of halogen-free flame-retardant glass fiber reinforced polyphenyl ether alloy material | |
| CN106543523A (en) | It is a kind of to carry the enhanced CABLE MATERIALS of silver-colored CNT collaboration lauric ester of pentachlorophenol antibacterial and mouldproof | |
| CN103087399B (en) | A kind of high-toughness high-strength halogen-free polypropylene flame redardant | |
| CN104448572A (en) | Plastic packaging material for low-temperature dairy product | |
| CN105001547A (en) | Modified polyvinyl chloride cable sheath material capable of resisting ultraviolet radiation aging | |
| CN104109339A (en) | ABS (acrylonitrile-butadiene-styrene) plastic for air conditioner shells | |
| CN104109333A (en) | Fluoride whisker ABS (acrylonitrile-butadiene-styrene) plastic material | |
| CN103756302B (en) | A kind of Nano fluorescent material composite material for nylon gasket | |
| CN107446256B (en) | Toughened polystyrene filling master batch and preparation method thereof | |
| CN105440417A (en) | High-density polyethylene anti-impact plastic and preparation method of high-density polyethylene anti-impact plastic | |
| CN105860344A (en) | Heat resistant modified plastic granule | |
| CN111057275A (en) | Constant-viscosity adhesive and preparation method thereof | |
| CN105504592A (en) | Machine protection cover plastic and preparation method thereof | |
| CN105754221A (en) | Novel macromolecular fireproofing flame retardant material and preparing method thereof | |
| CN105462041A (en) | Polymer heat-resisting plastic and preparation method thereof | |
| CN105837897A (en) | Modified polyethylene plastic | |
| CN111961293B (en) | Stretch-proof PVC gloves and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160420 |
|
| RJ01 | Rejection of invention patent application after publication |