CN105503138A - Jade-carving imitating art and preparing method thereof - Google Patents

Jade-carving imitating art and preparing method thereof Download PDF

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Publication number
CN105503138A
CN105503138A CN201510930974.4A CN201510930974A CN105503138A CN 105503138 A CN105503138 A CN 105503138A CN 201510930974 A CN201510930974 A CN 201510930974A CN 105503138 A CN105503138 A CN 105503138A
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CN
China
Prior art keywords
jade
step
jade carving
handicraft article
product
Prior art date
Application number
CN201510930974.4A
Other languages
Chinese (zh)
Inventor
杨卓舒
蒋云辉
陈常文
徐军
李石明
黄宝山
许永剑
林道略
师迎坤
韦佳洪
高兰英
林江元
Original Assignee
卓达新材料科技集团有限公司
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Priority to CN201510930974.4A priority Critical patent/CN105503138A/en
Publication of CN105503138A publication Critical patent/CN105503138A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00956Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses jade-carving imitating art and a preparing method thereof. The jade-carving imitating art is prepared from magnesium oxide, magnesium chloride, water, silica fume, quartz powder, quartz sand, agricultural waste, glass fibers and additive. The product has the health-preserving effects of being nontoxic, odourless, free of harmful gas and the like, and the environment can not be polluted by the waste of the jade-carving imitating art; compared with a natural jade art, the jade-carving imitating art has higher artistry and the higher ornamental value, and the value is higher.

Description

A kind of jade carving handicraft article and preparation method thereof

Technical field

The invention belongs to field of artware, particularly relate to a kind of jade carving handicraft article and preparation method thereof.

Background technology

The starting material of tradition jade carving arts are natural beautiful ores, by mining of cutting into a mountain, chisel and carve polishing, retrofit is made into product.Natural beautiful ore resource is rare, and cause soil erosion in making processes, destroy ecotope, therefore cost of manufacture is high, product is expensive.

And some imitation jade process product mainly organic polymer material such as unsaturated polyester resin, urethane resin, the jade stoneware glossiness that these materials make is relatively good, can mix the spurious with the genuine, but unsaturated polyester resin, polyurethanes product easily produce the material harmful to the person, the waste of organic polymer material can cause environmental pollution, texture is bad, and its product itself does not reach the effect of jade handicraft yet.

The plasticity-such as cement, gypsum of similar inorganic materials is strong and frangible, intensity, the performance such as wear-resisting and glossiness are not high.

Summary of the invention

Technical assignment of the present invention is mainly for above-mentioned the deficiencies in the prior art, and the present invention utilizes fabrication of new materials to go out " jade carving handicraft article ", product have nontoxic, tasteless, without health-preserving functions such as obnoxious flavoures, its waste can not cause any pollution to environment; Have more artistry and sight than natural jade artwork, its value is higher.

The invention provides a kind of jade carving handicraft article, with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:

Magnesium oxide: 30% ~ 40%

Magnesium chloride: 15% ~ 20%

Water: 15% ~ 20%

Silicon ash: 10% ~ 15%

Silica powder: 5% ~ 15%

Quartz sand: 5% ~ 15%

Agricultural wastes: 5% ~ 10%

Glass fibre: 1% ~ 3%

Additive: 0.5% ~ 2%.

As preferably, described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150 one or more.

As preferably, described agricultural wastes are sawdust.

The present invention also provides the preparation method of above-mentioned jade carving handicraft article, comprises the steps:

Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add silicon ash, silica powder, quartz sand, agricultural wastes, glass fibre and additive, stir, obtain fabric;

Step 2: by the fabric filling molding in product mold be stirred, remove mould product shaping after certain hour;

Step 3: polished finish is carried out, test package to the product after removing mould.

As preferably, in step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.

As preferably, in step 2, certain hour is 4-8 hours.

As preferably, in step 1, the weight of silicon ash, silica powder, quartz sand and agricultural wastes accounts for 25% ~ 40% of jade carving handicraft article raw material gross weight.

Advantageous Effects of the present invention is as follows:

(1) the present invention utilizes New Inorganic Materials to be made through scientific formula, and appearance design is unique, adds its practicality and artistry, formed at normal temp solidifies, and does not need through calcining and other complicated technology, energy-conserving and environment-protective, fire prevention combustion, high-strength light, health care absolutely, manufacture craft is simple, cost is low, and product strength is high, lightweight, non-friable, nontoxic, tasteless, produce without obnoxious flavour, the shaping defect such as product pore-free, trachoma, simultaneously glossiness will be got well.

(2) the present invention utilizes magnesium oxide to combine with magnesium chloride, after fully reacting, produce the gelling material of high strength, solve product weight, flimsy problem, the present invention only needs 4-8 hours at shaping time, shaping making is fast, and traditional jade carving arts manufacture craft is very complicated, operation is loaded down with trivial details, and the invention solves problems.

(3) the application is in auxiliary material, have selected agricultural wastes and trade waste, glass fibre and additive.With the trade waste that silicon ash, silica powder, quartz sand are representative, its wear resistance for product and intensity play important enhancement; And agricultural wastes can play cohesive action on the one hand, also greatly reduce the weight of product simultaneously; Glass fibre is also the material of important enhancing product strength; In order to better promote mixing and the condensation of raw material, the present invention selects the additive of one or more comprising phosphoric acid, ferrous sulfate, Tai-Ace S 150.Therefore, the material energy-saving environmental protection of the application, fire prevention combustion, high-strength light, health care absolutely; Product have lightweight, intensity high, non-friable, nontoxic, tasteless, produce without obnoxious flavour, ambient cure, make simple, low cost and other advantages.

(4) the present invention also has energy-saving and emission-reduction, economizes on resources, lightweight, intensity good, nontoxic, without obnoxious flavour, nonpollution environment, making is simple, cost is low, production efficiency advantages of higher; And the permanent releasing negative oxygen ion of product that the present invention produces, has anti-radiation effect, meets the requirement of green, environmental protection, health care, turn waste into wealth, solve in making processes and cause waste ecological resources, cause soil erosion, destroys the problems such as ecotope.

Other features and advantages of the present invention are described in detail in embodiment part subsequently.

Embodiment

Carry out clear, complete description by the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.

The invention provides a kind of jade carving handicraft article, with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:

Magnesium oxide: 30% ~ 40%

Magnesium chloride: 15% ~ 20%

Water: 15% ~ 20%

Silicon ash: 10% ~ 15%

Silica powder: 5% ~ 15%

Quartz sand: 5% ~ 15%

Agricultural wastes: 5% ~ 10%

Glass fibre: 1% ~ 3%

Additive: 0.5% ~ 2%.

As preferably, described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150 one or more.

As preferably, described agricultural wastes are sawdust.

The present invention also provides the preparation method of above-mentioned jade carving handicraft article, comprises the steps:

Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add silicon ash, silica powder, quartz sand, agricultural wastes, glass fibre and additive, stir, obtain fabric;

Step 2: by the fabric filling molding in product mold be stirred, remove mould product shaping after certain hour;

Step 3: polished finish is carried out, test package to the product after removing mould.

As preferably, in step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.

As preferably, in step 2, certain hour is 4-8 hours.

As preferably, in step 1, the weight of silicon ash, silica powder, quartz sand and agricultural wastes accounts for 25% ~ 40% of jade carving handicraft article raw material gross weight.

The present invention carries out test result according to regulation in magnesite art general technical specifications GB/T17657-1999:

(1) surface halide accumulation resistance

Being stood up by test specimen or hang into relative humidity is 90%-95%, and temperature is in the thermostat container of 40 DEG C ± 2 DEG C.Enough intervals should be had, to ensure the circulation of air between test specimen.Take out after 72h and observe each surface of product.

(2) apparent density

According in GB/T17657-1999 4.2 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1g/cm3.

(3) water-intake rate

Should under test conditions, according in GB/T17657-1999 4.6 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1%.

(4) water ratio

Should under test conditions, according in GB/T17657-1999 4.3 regulation carry out, using the arithmetical av of 3 test specimens as measurement result, be accurately 0.1%.

(5) chlorion stripping quantity

The method that should specify by JG/T301 free chlorine ion content is carried out.

(6) film adhesive

With sharp blade and scale steel ruler, cut in the direction in length and breadth of test specimen the cut channel that 11 stripe pitch are 1mm, cut channel intersects 100 pros in length and breadth.During cutting, blade face must be vertical with base plate, blade becomes 10 ° of-20 ° of angles with bottom surface, firmly will will penetrate the surface of film to base material by evenly all otch, each sharp mouth of blade can only do single test to keep the sharp of blade, and the different sites of same test specimen does three tests.After cutting with banister brush gently along foursquare two diagonal lines each brush 5 times back and forth, and observe with 4 times of magnifying glasses and come off with or without grid, with the test-results that secondary is close, as final test-results.

(7) intensity

Adopt the actual slip of craft articles, cast, vibratory compaction 40mm × 40mm × 160mm prism test specimen 2 groups totally 6 pieces.It is 20 DEG C ± 5 DEG C in temperature, form removal after maintenance 1d in the indoor environment of relative humidity (60 ± 10) %, continue maintenance with this understanding afterwards to 28d, wherein 1 group for measuring ultimate compression strength and folding strength, and measuring method carries out according to the regulation of GB/T17657.

(8) coefficient of softening

Test specimen should temperature 20 DEG C ± 5 DEG C, maintenance 28d in the indoor environment of relative humidity (60 ± 10) %, test specimen is immersed in the water that temperature is (20 ± 5) DEG C, spacing between test specimen is not less than 20mm, the submerged depth of upper surface and the water surface is not less than 20mm, take out after soaking 24h, wipe the moisture of surface of test piece with towel away.According to the folding strength after the regulation immersion of GB/T17671, the ratio of folding strength before what the folding strength and 6.10 calculated after water inlet measured do not soak is test-results, is accurately 0.1.

(9) freezing and thawing test

At room temperature soak test specimen 24h, takes out and wipe swimming of surface, put into the Hanging Basket of the cryogenic freezing case being cooled to-20 DEG C ± 2 DEG C in advance, freezing 4h, takes out the clear water putting into 20 DEG C ± 5 DEG C, melts 4h, for once circulating.Multigelation 28 times, needs to dry before putting into cryogenic freezing case at every turn, observes the surface of test specimen with or without damaged, cracking phenomena.

Advantageous Effects of the present invention is as follows:

(1) the present invention utilizes New Inorganic Materials to be made through scientific formula, and appearance design is unique, adds its practicality and artistry, formed at normal temp solidifies, and does not need through calcining and other complicated technology, energy-conserving and environment-protective, fire prevention combustion, high-strength light, health care absolutely, manufacture craft is simple, cost is low, and product strength is high, lightweight, non-friable, nontoxic, tasteless, produce without obnoxious flavour, the shaping defect such as product pore-free, trachoma, simultaneously glossiness will be got well.

(2) the present invention utilizes magnesium oxide to combine with magnesium chloride, after fully reacting, produce the gelling material of high strength, solve product weight, flimsy problem, the present invention only needs 4-8 hours at shaping time, shaping making is fast, traditional jade carving arts manufacture craft also very complicated, operation is loaded down with trivial details, and the invention solves problems.

(3) the application is in auxiliary material, have selected agricultural wastes and trade waste, glass fibre and additive.With the trade waste that silicon ash, silica powder, quartz sand are representative, its wear resistance for product and intensity play important enhancement; And agricultural wastes can play cohesive action on the one hand, also greatly reduce the weight of product simultaneously; Glass fibre is also the material of important enhancing product strength; In order to better promote mixing and the condensation of raw material, the present invention selects the additive of one or more comprising phosphoric acid, ferrous sulfate, Tai-Ace S 150.Therefore, the material energy-saving environmental protection of the application, fire prevention combustion, high-strength light, health care absolutely; Product have lightweight, intensity high, non-friable, nontoxic, tasteless, produce without obnoxious flavour, ambient cure, make simple, low cost and other advantages.

(4) the present invention also has energy-saving and emission-reduction, economizes on resources, lightweight, intensity good, nontoxic, without obnoxious flavour, nonpollution environment, making is simple, cost is low, production efficiency advantages of higher; And the permanent releasing negative oxygen ion of product that the present invention produces, has anti-radiation effect, meets the requirement of green, environmental protection, health care, turn waste into wealth, solve in making processes and cause waste ecological resources, cause soil erosion, destroys the problems such as ecotope.

Below will be described the present invention by embodiment.

Embodiment 1:

A kind of jade carving handicraft article, with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:

Magnesium oxide: 30%

Magnesium chloride: 15%

Water: 15%

Silicon ash: 10%

Silica powder: 10.5%

Quartz sand: 8%

Sawdust: 10%

Glass fibre: 1%

Phosphoric acid: 0.5%.

A preparation method for above-mentioned jade carving handicraft article, comprises the steps:

Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add silicon ash, silica powder, quartz sand, sawdust, glass fibre and phosphoric acid according to said ratio, stir, obtain fabric;

Step 2: by the fabric filling molding in product mold be stirred, removes mould product in 6 hours shaping;

Step 3: polished finish is carried out, test package to the product after removing mould.

The product integrated performance index of embodiment 1

Embodiment 2:

A kind of jade carving handicraft article, with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:

Magnesium oxide: 35%

Magnesium chloride: 17.5%

Water: 17.5%

Silicon ash: 10%

Silica powder: 5%

Quartz sand: 5%

Sawdust: 5%

Glass fibre: 3%

Ferrous sulfate: 2%.

A preparation method for above-mentioned jade carving handicraft article, comprises the steps:

Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add silicon ash, silica powder, quartz sand, sawdust, glass fibre and ferrous sulfate according to said ratio, stir, obtain fabric;

Step 2: by the fabric filling molding in product mold be stirred, removes mould product in 8 hours shaping;

Step 3: polished finish is carried out, test package to the product after removing mould.

The product integrated performance index of embodiment 2

Embodiment 3:

A kind of jade carving handicraft article, with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:

Magnesium oxide: 40%

Magnesium chloride: 15%

Water: 15%

Silicon ash: 10%

Silica powder: 5%

Quartz sand: 5%

Sawdust: 7%

Glass fibre: 1.5%

Tai-Ace S 150: 1.5%.

A preparation method for above-mentioned jade carving handicraft article, comprises the steps:

Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to said ratio, then add silicon ash, silica powder, quartz sand, sawdust, glass fibre and Tai-Ace S 150 according to said ratio, stir, obtain fabric;

Step 2: by the fabric filling molding in product mold be stirred, removes mould product in 4 hours shaping;

Step 3: polished finish is carried out, test package to the product after removing mould.

The product integrated performance index of embodiment 3

Those skilled in the art, at consideration specification sheets and after putting into practice invention disclosed herein, will easily expect other embodiment of the present invention.The application is intended to contain any modification of the present invention, purposes or adaptations, and these modification, purposes or adaptations are followed general principle of the present invention and comprised the undocumented common practise in the art of the disclosure or conventional techniques means.Specification sheets and embodiment are only regarded as exemplary, and true scope of the present invention and spirit are pointed out by claim.

Should be understood that, the present invention can carry out various amendment and change not departing from its scope.Scope of the present invention is only limited by appended claim.

Claims (7)

1. a jade carving handicraft article, is characterized in that: with jade carving handicraft article raw material total weight, this jade carving handicraft article is made up of following weight percent raw material:
2. jade carving handicraft article as claimed in claim 1, is characterized in that: described additive comprise phosphoric acid, ferrous sulfate, Tai-Ace S 150 one or more.
3. jade carving handicraft article as claimed in claim 1 or 2, is characterized in that: described agricultural wastes are sawdust.
4. the preparation method of the jade carving handicraft article described in claim 1-3, is characterized in that: comprise the steps:
Step 1: magnesium oxide and magnesium chloride and water are uniformly mixed according to a certain percentage, then add silicon ash, silica powder, quartz sand, agricultural wastes, glass fibre and additive, stir, obtain fabric;
Step 2: by the fabric filling molding in product mold be stirred, remove mould product shaping after certain hour;
Step 3: polished finish is carried out, test package to the product after removing mould.
5. preparation method as claimed in claim 4, is characterized in that:
In step 1, magnesium oxide and magnesium chloride and water are uniformly mixed with 1:0.5:0.5 according to weight.
6. preparation method as claimed in claim 4, is characterized in that:
In step 2, certain hour is 4-8 hours.
7. preparation method as claimed in claim 4, is characterized in that:
In step 1, the weight of silicon ash, silica powder, quartz sand and agricultural wastes accounts for 25% ~ 40% of jade carving handicraft article raw material gross weight.
CN201510930974.4A 2015-12-11 2015-12-11 Jade-carving imitating art and preparing method thereof CN105503138A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1145342A (en) * 1996-07-02 1997-03-19 丁佑民 Magnesia cement furniture and its prodn. method
WO2011111032A1 (en) * 2010-03-10 2011-09-15 Boaz Harpaz Composition for construction elements and improved tiles
CN103274664A (en) * 2013-07-01 2013-09-04 长沙铭泰建材有限公司 Artware and fabrication method thereof
CN104926268A (en) * 2015-07-01 2015-09-23 卓达新材料科技集团有限公司 Marble-imitated furniture material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1145342A (en) * 1996-07-02 1997-03-19 丁佑民 Magnesia cement furniture and its prodn. method
WO2011111032A1 (en) * 2010-03-10 2011-09-15 Boaz Harpaz Composition for construction elements and improved tiles
CN103274664A (en) * 2013-07-01 2013-09-04 长沙铭泰建材有限公司 Artware and fabrication method thereof
CN104926268A (en) * 2015-07-01 2015-09-23 卓达新材料科技集团有限公司 Marble-imitated furniture material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
涂平涛: "《氯氧镁材料技术与应用》", 31 December 2009, 化学工业出版社 *

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Application publication date: 20160420

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