CN105500182B - A kind of environment-friendly and energy-efficient high-performance multiple grinding piece - Google Patents
A kind of environment-friendly and energy-efficient high-performance multiple grinding piece Download PDFInfo
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- CN105500182B CN105500182B CN201510832861.0A CN201510832861A CN105500182B CN 105500182 B CN105500182 B CN 105500182B CN 201510832861 A CN201510832861 A CN 201510832861A CN 105500182 B CN105500182 B CN 105500182B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/12—Lapping plates for working plane surfaces
- B24B37/14—Lapping plates for working plane surfaces characterised by the composition or properties of the plate materials
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, and the abrasive material is attached in substrate by adhesive, and adhesive is mixed by weight than the composition A and 35 43% composition B for 57 65%;Composition A includes phenolic resin, trimethylolpropane trimethacrylate, filler, surfactant, diluent, coupling agent, fire retardant, ethylene-vinyl acetate copolymer, LLDPE, high density polyethylene (HDPE);Composition B includes:Phenolic resin, polyphenylene oxide resin powder, sodium carbonate, epoxy resin, methyl methacrylate, butyl acrylate, filler, coupling agent, diluent, antistatic additive, catalyst;Sharp quick, the service life length of abrasive sheet in the present invention, polishing high heat resistance, splendid moisture resistance, its preparation method can effectively prevent deformation, and product tensile strength is big, and adhesive property is good, and grinding performance is strong.
Description
Technical field
The invention belongs to coated abrasive tool field, it is related to a kind of environment-friendly and energy-efficient high-performance multiple grinding piece.
Background technology
Abrasive sheet refers to utilize ultraprecise coating technique, by selected micron or nanoscale abrasive micropowder(Diamond, carbonization
Silicon, aluminum oxide, silica, cerium oxide etc.)With high performance adhesive it is dispersed after, substrate surface is coated on, then through too high
Precision cuts technique and processed.Abrasive sheet with field widely, such as lead by optical communication field, micromachine field, hard disk
Domain etc..Such as vulcan fibre emery disc that uses on the market at present, vulcan fibre emery disc is also known as vulcanized paper sanding discs, at a high speed grinding, abrasive disk, it be with
Vulcan fibre is base material, a kind of plate-like coated abrasive tool being made by binding agent of synthetic resin.Its tensile strength is big, wearability extra-heavy,
Can be arranged on electronic or pneumatic electric angle grinder metal and the various type faces of nonmetallic materials are derusted, deburring, coating removal,
Polishing welding seams, are the ideal tools that are ground, polish, polish in Furniture manufacture and repair of machine work, are widely used in timber, family
Tool, shipbuilding, metallurgy, automobile, machinery, instrument, bridge and building trade.
The domestic emery disc used is generally red steel paper emery disc, i.e. base material for red steel paper at present, but red steel paper emery disc
When in use particularly in the summer meeting moisture absorption so that the emery disc toughness reduction of red steel paper ultimately results in emery disc cracking, thus a lot
The toughness of emery disc improves in the form of glass fiber mesh is added in centre in producer, and such as patent CN201420209Y proposes one kind
New waterleaf paper for velcanized fiber, has been mainly in vulcan fibre surface even spread the strong fibrous layer that one layer is made up of cotton fiber so that body paper
Water imbibition is strong, and patent CN201276524Y proposes a kind of resin laminated board grinding sheet, the mainly ring by setting tool to be of five storeys
On oxygen tree fat glass fiber laminate, improve the performances such as deformation, mechanical strength, impact strength, toughness with this, but it is this
Increased glass fiber mesh can produce many dusts during polishing, simultaneously because the increase of hardness easily flies in polishing
The red steel paper splashed can cause the injury of staff.
In addition, the problem of people are directed in emery disc is corresponding to propose a specific solution, such as CN201419364Y is carried
Go out a kind of high strength steel cardboard, with zinc chloride gel layer mainly in vulcanized fiber board basic unit so that its use time is longer,
Grinding effect is more preferably.CN101180159A is by effectively being handled vulcan fibre backing, it will be apparent that improve vulcan fibre emery disc
Deformation condition, while improving service life.CN200939582Y proposes a kind of enhancing silencing steel-paper sand disk, mainly passes through
Increase well-regulated open-work and curved grooves on emery disc, improve aerodynamic profile when being ground application, reach obvious reduction
It is ground the effect of noise.CN101235261A proposes a kind of preparation method of aerodux, is bonded using this phenolic aldehyde
The vulcan fibre emery disc of agent manufacture, significantly improves adhesive property, shear strength and moisture resistance energy.
Although the problem of existing from different perspectives to vulcan fibre emery disc above proposes specific solution, vulcan fibre emery disc
Inherently one comprehensive problem of use, it is still necessary to those skilled in the art continue to research and develop to play vulcan fibre emery disc at it
The maximum use value of application field.
The content of the invention
The technical problems to be solved by the invention are that the shortcoming existed for above prior art proposes a kind of environmental protection section
Energy type high-performance multiple grinding piece, can effectively prevent deformation, and tensile strength is big, and adhesive property is good, and grinding performance is strong, produces
Sharp quick, the service life length of abrasive sheet, polishing high heat resistance, splendid moisture resistance.
The present invention solve above technical problem technical scheme be:
A kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, the abrasive material passes through gluing
Agent is attached in substrate;
Composition B of the adhesive by weight than composition A and 35-43% for 57-65% is mixed;
Composition A includes following components by weight:Phenolic resin:36-40 parts, trimethylolpropane trimethacrylate:
11-25 parts, filler:15-17 parts, surfactant:3-5 parts, diluent:10-13 parts, coupling agent:4-6 parts, fire retardant:2-8
Part, ethylene-vinyl acetate copolymer:5-7 parts, LLDPE:2-5 parts, high density polyethylene (HDPE):5-7 parts;
Composition B includes following components by weight:Phenolic resin:57-60 parts, polyphenylene oxide resin powder:23-25 parts, carbon
Sour sodium 5-7 parts, epoxy resin:5-7 parts, methyl methacrylate:11-13 parts, butyl acrylate:15-17 parts, filler:20-23
Part, coupling agent:5-7 parts, diluent:10-13 parts, antistatic additive:5-7 parts, catalyst:13-15 parts;
Catalyst includes following components by weight:Epoxy resin:31-36 parts, polyphenylene oxide resin powder:20-24 parts, butylbenzene
Rubber:10-14 parts, toluene:5-8 parts, ammonium phosphate:4-7 parts.
The technical scheme that further limits of the present invention is:
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein, filler be coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or
At least one of wollastonite powder;Surfactant is aliphatic sulfonic compound, alkyl aryl sulphonic acid compound, Span
At least one of or polyoxyethylene sorbitan fatty acid ester;Diluent is methanol, acetone, ethyl acetate, ethylene glycol list
At least one of ether, diethylene glycol ether or water;Coupling agent is at least one of silane coupler or zirconium class coupling agent;
The fire retardant is phosphotriester;Antistatic additive is anionic antistatic agent, cationic antistatic agent or non-ionic anti-
At least one of electrostatic agent.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 57% and
43% composition B is mixed;Composition A includes following components by weight:Phenolic resin:36 parts, trimethylolpropane tris
Acrylate:11 parts, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant:2 parts, second
Alkene-acetate ethylene copolymer:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;Composition B is wrapped by weight
Include following components:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, 5 parts of sodium carbonate, epoxy resin:5 parts, methacrylic acid
Methyl esters:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, diluent:10 parts, antistatic additive:5 parts, catalysis
Agent:13 parts;Catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, butadiene-styrene rubber:
10 parts, toluene:5 parts, ammonium phosphate:4 parts.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 60% and
40% composition B is mixed;Composition A includes following components by weight:Phenolic resin:38 parts, trimethylolpropane tris
Acrylate:20 parts, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant:5 parts, second
Alkene-acetate ethylene copolymer:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;Composition B is wrapped by weight
Include following components:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, 6 parts of sodium carbonate, epoxy resin:6 parts, methacrylic acid
Methyl esters:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, diluent:12 parts, antistatic additive:6 parts, catalysis
Agent:14 parts;Catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, butadiene-styrene rubber:
13 parts, toluene:7 parts, ammonium phosphate:5 parts.
Foregoing environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the composition A for 65% and
35% composition B is mixed;Composition A includes following components by weight:Phenolic resin:40 parts, trimethylolpropane tris
Acrylate:25 parts, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant:8 parts, second
Alkene-acetate ethylene copolymer:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;Composition B is wrapped by weight
Include following components:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, 7 parts of sodium carbonate, epoxy resin:7 parts, methacrylic acid
Methyl esters:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, diluent:13 parts, antistatic additive:7 parts, catalysis
Agent:15 parts;Catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, butadiene-styrene rubber:
14 parts, toluene:8 parts, ammonium phosphate:7 parts.
The beneficial effects of the invention are as follows:
The present invention adds trimethylolpropane trimethacrylate, polyphenylene oxide resin powder, carbonic acid by the mixing of each composition
Sodium, epoxy resin, methyl methacrylate, butyl acrylate makes product have adhesion strength high, water-fast, antiacid, good weatherability etc.
Advantage, and cause the more soft folding of sand paper product.
Fire retardant is added with the adhesive components of the present invention, because aluminum oxide flame retardant effect is poor, in polishing, grinding
The heat-resisting quantity of piece directly affects its performance, increases phosphotriester fire retardant, improves heat-resisting quantity while enhancing mill
Cut performance.
Catalyst is added in invention adhesive, preferably improves the water resistance and adhesive property of grinding tool, it is possible to make
Abrasive surface is kept as more smooth, rationally can effectively control internal stresses release, reduce product deformation;Simultaneously as urging
The presence of agent, can improve the rate of drying of grinding tool production process, so as to greatly improve production efficiency, serve imaginary
Less than technique effect.
Sharp quick, the service life length of abrasive sheet in the present invention, polishing high heat resistance, splendid moisture resistance, are being manufactured
In can effectively prevent deformation, product tensile strength is big, and adhesive property is good, and grinding performance is strong.
Embodiment
Embodiment 1
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 57%
Compound A and 43% composition B is mixed;Composition A includes following components by weight:Phenolic resin:36 parts, three hydroxyl first
Base propane triacrylate:11 parts, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant:
2 parts, ethylene-vinyl acetate copolymer:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;Composition B is by weight
Measuring part includes following components:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, 5 parts of sodium carbonate, epoxy resin:5 parts, methyl
Methyl acrylate:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, diluent:10 parts, antistatic additive:5
Part, catalyst:13 parts;Catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, fourth
Benzene rubber:10 parts, toluene:5 parts, ammonium phosphate:4 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat
In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester
It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water
Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is
At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
Embodiment 2
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 60%
Compound A and 40% composition B is mixed;Composition A includes following components by weight:Phenolic resin:38 parts, three hydroxyl first
Base propane triacrylate:20 parts, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant:
5 parts, ethylene-vinyl acetate copolymer:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;Composition B is by weight
Measuring part includes following components:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, 6 parts of sodium carbonate, epoxy resin:6 parts, methyl
Methyl acrylate:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, diluent:12 parts, antistatic additive:6
Part, catalyst:14 parts;Catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, fourth
Benzene rubber:13 parts, toluene:7 parts, ammonium phosphate:5 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat
In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester
It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water
Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is
At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
Embodiment 3
The present embodiment is a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, wherein adhesive by weight than the group for 65%
Compound A and 35% composition B is mixed;Composition A includes following components by weight:Phenolic resin:40 parts, three hydroxyl first
Base propane triacrylate:25 parts, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant:
8 parts, ethylene-vinyl acetate copolymer:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;Composition B is by weight
Measuring part includes following components:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, 7 parts of sodium carbonate, epoxy resin:7 parts, methyl
Methyl acrylate:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, diluent:13 parts, antistatic additive:7
Part, catalyst:15 parts;Catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, fourth
Benzene rubber:14 parts, toluene:8 parts, ammonium phosphate:7 parts.
Wherein, filler is at least one of coarse whiting, fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;Surfactant is fat
In fat race azochlorosulfonate acid compound, alkyl aryl sulphonic acid compound, Span or polyoxyethylene sorbitan fatty acid ester
It is at least one;Diluent is at least one in methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water
Kind;Coupling agent is at least one of silane coupler or zirconium class coupling agent;The fire retardant is phosphotriester;Antistatic additive is
At least one of anionic antistatic agent, cationic antistatic agent or non-ionic antistatic agent.
In addition to the implementation, the present invention can also have other embodiment.All use equivalent substitution or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (5)
1. a kind of environment-friendly and energy-efficient high-performance multiple grinding piece, including substrate, adhesive and abrasive material, the abrasive material pass through adhesive
It is attached in substrate, it is characterised in that:
Composition B of the adhesive by weight than composition A and 35-43% for 57-65% is mixed;
The composition A includes following components by weight:Phenolic resin:36-40 parts, trimethylolpropane trimethacrylate:
11-25 parts, filler:15-17 parts, surfactant:3-5 parts, diluent:10-13 parts, coupling agent:4-6 parts, fire retardant:2-8
Part, ethylene-vinyl acetate copolymer:5-7 parts, LLDPE:2-5 parts, high density polyethylene (HDPE):5-7 parts;
The composition B includes following components by weight:Phenolic resin:57-60 parts, polyphenylene oxide resin powder:23-25 parts, carbon
Sour sodium 5-7 parts, epoxy resin:5-7 parts, methyl methacrylate:11-13 parts, butyl acrylate:15-17 parts, filler:20-23
Part, coupling agent:5-7 parts, diluent:10-13 parts, antistatic additive:5-7 parts, catalyst:13-15 parts;
The catalyst includes following components by weight:Epoxy resin:31-36 parts, polyphenylene oxide resin powder:20-24 parts, butylbenzene
Rubber:10-14 parts, toluene:5-8 parts, ammonium phosphate:4-7 parts.
2. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1, it is characterised in that:The filler be coarse whiting,
At least one of fine particle calcium carbonate, chalky soil, diatomite or wollastonite powder;The surfactant is aliphatic sulfonic compound, alkyl virtue
At least one of base azochlorosulfonate acid compound, Span or polyoxyethylene sorbitan fatty acid ester;The diluent
It is at least one of methanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water;The coupling agent is silicon
At least one of alkane coupling agent or zirconium class coupling agent;The fire retardant is phosphotriester;The antistatic additive is anionic
At least one of antistatic additive, cationic antistatic agent or non-ionic antistatic agent.
3. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by
Weight is mixed than the composition B of the composition A and 43% for 57%;
The composition A includes following components by weight:Phenolic resin:36 parts, trimethylolpropane trimethacrylate:11
Part, filler:15 parts, surfactant:3 parts, diluent:10 parts, coupling agent:4 parts, fire retardant:2 parts, ethene-vinyl acetate is common
Polymers:5 parts, LLDPE:2 parts, high density polyethylene (HDPE):5 parts;
The composition B includes following components by weight:Phenolic resin:57 parts, polyphenylene oxide resin powder:23 parts, sodium carbonate 5
Part, epoxy resin:5 parts, methyl methacrylate:11 parts, butyl acrylate:15 parts, filler:20 parts, coupling agent:5 parts, dilution
Agent:10 parts, antistatic additive:5 parts, catalyst:13 parts;
The catalyst includes following components by weight:Epoxy resin:31 parts, polyphenylene oxide resin powder:20 parts, butadiene-styrene rubber:
10 parts, toluene:5 parts, ammonium phosphate:4 parts.
4. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by
Weight is mixed than the composition B of the composition A and 40% for 60%;
The composition A includes following components by weight:Phenolic resin:38 parts, trimethylolpropane trimethacrylate:20
Part, filler:16 parts, surfactant:4 parts, diluent:12 parts, coupling agent:5 parts, fire retardant:5 parts, ethene-vinyl acetate is common
Polymers:6 parts, LLDPE:3 parts, high density polyethylene (HDPE):6 parts;
The composition B includes following components by weight:Phenolic resin:58 parts, polyphenylene oxide resin powder:24 parts, sodium carbonate 6
Part, epoxy resin:6 parts, methyl methacrylate:12 parts, butyl acrylate:16 parts, filler:22 parts, coupling agent:6 parts, dilution
Agent:12 parts, antistatic additive:6 parts, catalyst:14 parts;
The catalyst includes following components by weight:Epoxy resin:33 parts, polyphenylene oxide resin powder:22 parts, butadiene-styrene rubber:
13 parts, toluene:7 parts, ammonium phosphate:5 parts.
5. environment-friendly and energy-efficient high-performance multiple grinding piece as claimed in claim 1 or 2, it is characterised in that:The adhesive by
Weight is mixed than the composition B of the composition A and 35% for 65%;
The composition A includes following components by weight:Phenolic resin:40 parts, trimethylolpropane trimethacrylate:25
Part, filler:17 parts, surfactant:5 parts, diluent:13 parts, coupling agent:6 parts, fire retardant:8 parts, ethene-vinyl acetate is common
Polymers:7 parts, LLDPE:5 parts, high density polyethylene (HDPE):7 parts;
The composition B includes following components by weight:Phenolic resin:60 parts, polyphenylene oxide resin powder:25 parts, sodium carbonate 7
Part, epoxy resin:7 parts, methyl methacrylate:13 parts, butyl acrylate:17 parts, filler:23 parts, coupling agent:7 parts, dilution
Agent:13 parts, antistatic additive:7 parts, catalyst:15 parts;
The catalyst includes following components by weight:Epoxy resin:36 parts, polyphenylene oxide resin powder:24 parts, butadiene-styrene rubber:
14 parts, toluene:8 parts, ammonium phosphate:7 parts.
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CN107538361A (en) * | 2017-05-26 | 2018-01-05 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | One kind back of the body suede abrasive disk and its preparation technology |
CN107127686A (en) * | 2017-05-31 | 2017-09-05 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | A kind of environment-friendly and energy-efficient multiple grinding piece of high service life |
CN107236341A (en) * | 2017-06-09 | 2017-10-10 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | A kind of antistatic adhesive of high bond strength for coated abrasive tool |
CN107418457A (en) * | 2017-06-09 | 2017-12-01 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | A kind of high bond strength high-temperature resistance adhesive for coated abrasive tool |
CN113231919A (en) * | 2021-05-10 | 2021-08-10 | 南通瑞景光电科技有限公司 | Environment-friendly grinding process for optical element |
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