CN105440921A - Paint with good light transmission and preparation method of paint - Google Patents

Paint with good light transmission and preparation method of paint Download PDF

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Publication number
CN105440921A
CN105440921A CN 201511009201 CN201511009201A CN105440921A CN 105440921 A CN105440921 A CN 105440921A CN 201511009201 CN201511009201 CN 201511009201 CN 201511009201 A CN201511009201 A CN 201511009201A CN 105440921 A CN105440921 A CN 105440921A
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parts
paint
titanium dioxide
polyoxyethylene
polyoxyethylene ether
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CN 201511009201
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Chinese (zh)
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曲少春
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曲少春
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; MISCELLANEOUS COMPOSITIONS; MISCELLANEOUS APPLICATIONS OF MATERIALS
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses paint with good light transmission. The paint is prepared from raw materials in parts by weight as follows: 0.7-1.5 parts of 2-phenylethyl xenol polyoxyethylene ether, 3.5-5 parts of aluminium-carbon based refractory brick powder, 2.3-4.4 parts of polyol polyoxyethylene ether carboxylic ester, 2-5 parts of bis-phenethyl phenol polyoxyethylene ether, 3.4-6.6 parts of titanium dioxide, 2.6-3.8 parts of 3,5-tert-butyl-4-hydroxyphenyl thioether, 1.5-2.5 parts of trilinolein, 5.8-7.8 parts of deionized water and 0.12-0.55 parts of a surfactant. The paint with the good light transmission is good UV (ultraviolet)-curable anti-scratch paint for window films and protecting films, sources of raw materials are convenient, the raw materials and a finished paint product have excellent stability, industrial popularization and application are facilitated, besides, the paint has the characteristics of high curing speed, simple preparation technology and the like, and the production cost can be greatly reduced; a coating prepared from the paint has the characteristics of moderate hardness, good light transmission and the like.

Description

[0001] 一种透光性好的涂料及其制备方法 [0001] A transparent coating and preparation method good

技术领域 FIELD

[0002] 本发明涉及一种涂料,尤其是涉及一种透光性好的涂料及其制备方法,属于涂料领域。 [0002] The present invention relates to a coating, in particular to a light-transmitting coating material and a preparation method good belongs coatings.

背景技术 Background technique

[0003] 耐刮涂层是一种薄膜涂层,具有硬度高、耐磨、透光性好等特点,其制作方法是将耐刮涂料涂布于基体膜上,通过热固化或紫外线固化等方法,进行成膜操作。 [0003] The scratch-resistant coating is a film coating having a high hardness, wear resistance, and good light transmitting characteristics, its production method is to scratch the coating film applied onto the substrate, by thermal curing or ultraviolet curing method, the film formation operation. 其中,紫外线光固化方法有环保、节能、效率高等优点。 Wherein the ultraviolet light curing method has environmental protection, energy saving and high efficiency. 耐刮涂层广泛应用于汽车太阳膜、汽车防爆膜、 LCD显示器保护膜、照相机镜头保护膜等。 Scratch-resistant coatings widely used in automotive solar film, car explosion-proof membrane, LCD display, a protective film, a protective film camera lens. 但是目前市面上现有的耐刮涂料的硬度一般低于2H。 However, conventional scratch coatings currently on the market is generally lower than the hardness of 2H. 有些耐刮涂料的硬度高于2H,但是其透明度不高,而且不具有防紫外线的功能,不适合窗膜及光学显示产品用的保护膜的要求。 Some paint scratch hardness than 2H, but transparency is not high, but does not have the function of UV, the optical film and the display window is not suitable for the protective film of the product was required. 因此,开发一种能够用于制备既具有较高的硬度,又具有较高的透明度和防紫外线的耐刮涂层的耐刮涂料是本领域亟待解决的问题。 Accordingly, development of a preparation can be used for both a high hardness, and scratch-resistant coatings having a high transparency and scratch-resistant coatings are UV art problems to be solved.

发明内容 SUMMARY

[0004] 针对现有技术的不足,本发明所要解决的技术问题是,提供一种透光性好的涂料及其制备方法,具有较高的稳定性,制备工艺简单,利用该涂料制成的耐刮涂层既具有很强的防紫外线功能,又具有较高的透光性。 [0004] for the deficiencies of the prior art, the present invention is to solve the technical problem, to provide a good light-transmitting coating material and its preparation method, high stability, simple preparation process, the coating prepared using scratch coating both have strong anti-ultraviolet function, but also has high light transmission.

[0005] 为解决上述技术问题,本发明采取的技术方案是,一种透光性好的涂料,其由以下重量份数的原料制成: 二苯乙基联苯酚聚氧乙烯醚0.7-1.5份,铝碳质耐火砖粉3.5-5份,多元醇聚氧乙烯醚羧酸酯2.3-4.4份,双苯乙基酚聚氧乙烯醚2-5份,钛白粉3.4-6.6份,3,5-三级丁基-4-羟基苯基硫醚2.6-3.8份,三亚油酸甘油酯1.5-2.5份,去离子水5.8-7.8份,表面活性剂0.12-0.55 份。 [0005] To solve the above problems, the present invention takes technical solution a good light-transmitting coating material made of the following parts by weight: diphenylethyl biphenol polyoxyethylene ethers 0.7-1.5 parts of aluminum powder, 3.5-5 parts carbonaceous bricks, 2.3-4.4 parts of polyhydric alcohol polyoxyethylene ether carboxylates, phenethyl bis phenol polyoxyethylene ether 2-5 parts, 3.4-6.6 parts of titanium dioxide, 3, 5- tert.butyl-4-hydroxyphenyl sulfide 2.6-3.8 parts, three parts of glyceryl linoleate 1.5-2.5, 5.8-7.8 parts of deionized water, 0.12-0.55 parts surfactant.

[0006] 优化的,上述透光性好的涂料,其由以下重量份数的原料制成: 二苯乙基联苯酚聚氧乙烯醚0.7份,铝碳质耐火砖粉3.5份,多元醇聚氧乙烯醚羧酸酯2.3份,双苯乙基酚聚氧乙烯醚2份,钛白粉3.4份,3,5-三级丁基-4-羟基苯基硫醚2.6份,三亚油酸甘油酯1.5份,去离子水5.8份,表面活性剂0.12份。 [0006] Optimization of the good light-transmitting coating material made of the following parts by weight: diphenylethyl biphenol 0.7 parts of polyoxyethylene ethers, aluminum powder, 3.5 parts of carbonaceous bricks, polyol poly polyoxyethylene ether carboxylate, 2.3 parts of bis phenethyl phenol polyoxyethylene ether 2 parts, 3.4 parts of titanium dioxide, 3,5-tert.butyl-4-hydroxyphenyl sulfide 2.6 parts of glyceryl trilinoleate 1.5 parts, 5.8 parts of deionized water, 0.12 parts of a surfactant.

[0007] 优化的,上述透光性好的涂料,其钛白粉为金红石型钛白粉,粒度为2000目。 [0007] Optimization of the good light-transmitting coating, the titanium dioxide is rutile titanium dioxide particle size of 2000 mesh.

[0008] 优化的,上述透光性好的涂料,其表面活性剂为脂肪酸酯硫酸脂盐。 [0008] Optimization of the good light-transmitting coating, the surfactant is a lipid fatty acid ester sulfate salts. 一种透光性好的涂料的制备方法,包括以下步骤: 1) 按照配方称量,将二苯乙基联苯酚聚氧乙烯醚、去离子水和铝碳质耐火砖粉加入分散罐中,以400-500r/min进行分散搅拌15-20min; 2) 然后加入多元醇聚氧乙烯醚羧酸酯和双苯乙基酚聚氧乙烯醚,以1000-1200r/min高速分散20-35min ; 3) 再将钛白粉和3,5-三级丁基-4-羟基苯基硫醚按配方比例加入,将混合物加热到SO-gOt , 并在该温度下保温2 小时; 4) 将混合物冷却到室温后,加入三亚油酸甘油酯和表面活性剂,继续升温到60°C,该温度下保温45-50分钟,同时施加真空到0.09~0.095MPa,然后冷却即为成品。 A method of preparing a translucent good paint, comprising the following steps: 1) in accordance with the Formulation, ethyl diphenyl biphenol polyoxyethylene ethers, deionized water and carbonaceous refractory aluminum powder added to the dispersion tank, in 400-500r / min dispersing stirring 15-20min; 2) was then added polyhydric alcohol polyoxyethylene ether carboxylate, and bis phenethyl phenol polyoxyethylene ether, to 1000-1200r / min high speed disperser 20-35min; 3 ) then titanium dioxide and 3,5-tert.butyl-4-hydroxyphenyl sulfide was added according to the formula proportion, the mixture was heated to SO-gOt, and maintained at this temperature for 2 hours; 4) cooling the mixture to after room temperature, glyceryl trilinoleate, and a surfactant, continue to heat to 60 ° C, holding at this temperature for 45-50 minutes, while applying a vacuum to 0.09 ~ 0.095MPa, and then cooling is finished.

[0009] 本发明提供的透光性好的涂料是一种良好的窗膜及保护膜用紫外线光固化耐刮涂料,不仅原料来源方便,而且无论原材料本身还是涂料成品均具有优秀的稳定性,便于工业化推广和应用,并且该涂料具有固化速度快、制备工艺简单等特点,能够大大降低生产成本;由该涂料制成的涂层具有硬度适中、透光性好等特点。 [0009] The present invention provides coatings having good light-transmissive window is a good film and a protective film coating with ultraviolet light curing scratch, not only convenient source of raw materials, and the raw material itself or whether the finished product has excellent coating stability, convenient for industrial promotion and application, and the coating having a high curing speed, simple preparation process and the like, and can greatly reduce production costs; coating made of the coating material having a moderate hardness, good light transmission characteristics.

具体实施方式 detailed description

[0010] 下面结合其实施例对发明进一步详细说明。 [0010] Next, the invention will be described in more detail in connection with embodiments.

[0011] 实施例1 本发明为一种透光性好的涂料,其由以下重量份数的原料制成:二苯乙基联苯酚聚氧乙烯醚0.7份,铝碳质耐火砖粉3.5份,多元醇聚氧乙烯醚羧酸酯2.3份,双苯乙基酚聚氧乙烯醚2份,钛白粉3.4份,3,5-三级丁基-4-羟基苯基硫醚2.6份,三亚油酸甘油酯1.5份,去离子水5.8份,表面活性剂即脂肪酸酯硫酸脂盐0.12份。 [0011] Example 1 invention embodiment as a good light transmitting coating material made of the following parts by weight: diphenylethyl biphenol 0.7 parts of polyoxyethylene ethers, aluminum powder, 3.5 parts carbonaceous refractory , polyoxyethylene polyhydric alcohol ether 2.3 parts of a carboxylic acid ester, phenethyl bis phenol polyoxyethylene ether 2 parts, 3.4 parts of titanium dioxide, 3,5-tert.butyl-4-hydroxyphenyl 2.6 parts sulfide, trimethylene glyceryl oleate 1.5 parts, 5.8 parts of deionized water, a surfactant, i.e. fatty acid ester sulfate ester salts 0.12 parts. 钛白粉为金红石型钛白粉,粒度为2000 目。 Titanium dioxide is a rutile titanium dioxide particle size of 2000 mesh.

[0012] 上述透光性好的涂料的制备方法,包括以下步骤: 1) 按照配方称量,将二苯乙基联苯酚聚氧乙烯醚、去离子水和铝碳质耐火砖粉加入分散罐中,以400r/min进行分散搅拌15min; 2) 然后加入多元醇聚氧乙烯醚羧酸酯和双苯乙基酚聚氧乙烯醚,以1000r/min高速分散20min ; 3) 再将钛白粉和3,5-三级丁基-4-羟基苯基硫醚按配方比例加入,将混合物加热到80 °C,并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入三亚油酸甘油酯和表面活性剂,继续升温到60°C,该温度下保温45分钟,同时施加真空到0.09MPa,然后冷却即为成品。 [0012] preparation method for the coating of good light transmission, comprising the following steps: 1) in accordance with the Formulation, ethyl diphenyl biphenol polyoxyethylene ethers, and deionized water was added aluminum carbonaceous refractory powder dispersion tank in order to 400r / min dispersing stirred 15min; 2) was then added polyhydric alcohol polyoxyethylene ether carboxylate, and bis phenethyl phenol polyoxyethylene ether, at 1000r / min high speed disperser 20min; 3) titanium dioxide, and then 3,5-tert.butyl-4-hydroxyphenyl sulfide was added according to the formula proportion, the mixture was heated to 80 ° C, and maintained at this temperature for 2 hours; 4) the mixture was cooled to room temperature, trimethylene oil triglycerides and a surfactant, continue to heat to 60 ° C, holding at this temperature for 45 minutes while vacuum is applied to 0.09MPa, and then cooling is finished. 实施例2 本发明为一种透光性好的涂料,其由以下重量份数的原料制成:二苯乙基联苯酚聚氧乙烯醚1.5份,铝碳质耐火砖粉5份,多元醇聚氧乙烯醚羧酸酯4.4份,双苯乙基酚聚氧乙烯醚5份,钛白粉6.6份,3,5-三级丁基-4-羟基苯基硫醚3.8份,三亚油酸甘油酯2.5份,去离子水7.8份,表面活性剂即脂肪酸酯硫酸脂盐0.55份。 Example 2 embodiment of the present invention as a good light-transmitting coating material made of the following parts by weight: diphenylethyl biphenol 1.5 parts of polyoxyethylene ethers, carbonaceous refractory aluminum powder, 5 parts polyol polyoxyethylene ether carboxylate 4.4 parts, phenethyl bis phenol polyoxyethylene ether 5 parts, 6.6 parts of titanium dioxide, 3,5-tert.butyl-4-hydroxyphenyl sulfide 3.8 parts glycerol trilinoleate ester 2.5 parts, 7.8 parts of deionized water, i.e., fatty acid ester surfactant 0.55 parts of sulfuric acid ester salt. 钛白粉为金红石型钛白粉,粒度为2000 目。 Titanium dioxide is a rutile titanium dioxide particle size of 2000 mesh.

[0013] 上述透光性好的涂料的制备方法,包括以下步骤: 1) 按照配方称量,将二苯乙基联苯酚聚氧乙烯醚、去离子水和铝碳质耐火砖粉加入分散罐中,以500r/min进行分散搅拌20min; 2) 然后加入多元醇聚氧乙烯醚羧酸酯和双苯乙基酚聚氧乙烯醚,以1200r/min高速分散35min ; 3) 再将钛白粉和3,5-三级丁基-4-羟基苯基硫醚按配方比例加入,将混合物加热到90 °C,并在该温度下保温2小时; 4)将混合物冷却到室温后,加入三亚油酸甘油酯和表面活性剂,继续升温到60°C,该温度下保温50分钟,同时施加真空到0.095MPa,然后冷却即为成品。 [0013] The preparation method of the light transmissive good paint, comprising the following steps: 1) in accordance with the Formulation, ethyl diphenyl biphenol polyoxyethylene ethers, and deionized water was added aluminum carbonaceous refractory powder dispersion tank in order to 500r / min dispersing stirred 20min; 2) was then added polyhydric alcohol polyoxyethylene ether carboxylate, and bis phenethyl phenol polyoxyethylene ether, at 1200r / min high speed disperser 35min; 3) titanium dioxide, and then 3,5-tert.butyl-4-hydroxyphenyl sulfide was added according to the formula proportion, the mixture was heated to 90 ° C, and maintained at this temperature for 2 hours; 4) the mixture was cooled to room temperature, trimethylene oil triglycerides and a surfactant, continue to heat to 60 ° C, holding at this temperature for 50 minutes while vacuum is applied to 0.095MPa, and then cooling is finished.

[0014] 实施例3 本发明为一种透光性好的涂料,其由以下重量份数的原料制成:二苯乙基联苯酚聚氧乙烯醚0.9份,铝碳质耐火砖粉4.5份,多元醇聚氧乙烯醚羧酸酯3.6份,双苯乙基酚聚氧乙烯醚3.6份,钛白粉5.2份,3,5-三级丁基-4-羟基苯基硫醚3.3份,三亚油酸甘油酯1.8份,去离子水6.1份,表面活性剂即脂肪酸酯硫酸脂盐0.33份。 [0014] Example 3 invention embodiment as a good light transmitting coating material made of the following parts by weight: diphenylethyl biphenol 0.9 parts of polyoxyethylene ethers, aluminum powder, 4.5 parts carbonaceous refractory , polyoxyethylene polyhydric alcohol ether 3.6 parts of a carboxylic acid ester, phenethyl bis phenol polyoxyethylene ether 3.6 parts, 5.2 parts of titanium dioxide, 3,5-tert.butyl-4-hydroxyphenyl 3.3 parts of sulfide, trimethylene 1.8 parts of glycerol oleate, 6.1 parts of deionized water, i.e., fatty acid ester surfactant 0.33 parts of sulfuric acid ester salt. 钛白粉为金红石型钛白粉,粒度为2000 目。 Titanium dioxide is a rutile titanium dioxide particle size of 2000 mesh.

[0015] 上述透光性好的涂料的制备方法,包括以下步骤: 1) 按照配方称量,将二苯乙基联苯酚聚氧乙烯醚、去离子水和铝碳质耐火砖粉加入分散罐中,以450r/min进行分散搅拌18min; 2) 然后加入多元醇聚氧乙烯醚羧酸酯和双苯乙基酚聚氧乙烯醚,以1100r/min高速分散28min ; 3) 再将钛白粉和3,5-三级丁基-4-羟基苯基硫醚按配方比例加入,将混合物加热到85 °C,并在该温度下保温2小时; 4) 将混合物冷却到室温后,加入三亚油酸甘油酯和表面活性剂,继续升温到60°C,该温度下保温48分钟,同时施加真空到0.092MPa,然后冷却即为成品。 [0015] The preparation method of the light transmissive good paint, comprising the following steps: 1) in accordance with the Formulation, ethyl diphenyl biphenol polyoxyethylene ethers, and deionized water was added aluminum carbonaceous refractory powder dispersion tank in order to 450r / min dispersing stirred 18min; 2) was then added polyhydric alcohol polyoxyethylene ether carboxylate, and bis phenethyl phenol polyoxyethylene ether, at 1100r / min high speed disperser 28min; 3) titanium dioxide, and then 3,5-tert.butyl-4-hydroxyphenyl sulfide was added according to the formula proportion, the mixture was heated to 85 ° C, and maintained at this temperature for 2 hours; 4) the mixture was cooled to room temperature, trimethylene oil triglycerides and a surfactant, continue to heat to 60 ° C, holding at this temperature for 48 minutes while vacuum is applied to 0.092MPa, and then cooling is finished.

[0016] 将上述实施例1-3中生产的涂料成品与现有技术中涂料成品对比,检测结果如下: 施工性的评价以肉眼观察发生厚涂时明显下垂和薄涂时难以抹平的涂覆厚度为标准; 透去离子水性评价参照JIS A6909进行试验;耐去离子水性评价在50°C的温去离子水中浸泡,以出现明显的白化时间为标准;耐冻融性评价是将涂层在_20°C环境下冻结2h后在10°C去离子水中浸泡1小时,如此反复,以出现明显的开裂回数为标准;硬化收缩率是在涂层静置干燥30天后测量的。 [0016] The finished coating with the above-described prior art produced in Examples 1-3 in comparison paint finished, the detection results are as follows: when the hard smooth coating and thin coating significantly sagging when thick coating workability evaluation was visually observed to occur coating thickness standard; deionized water permeability evaluation test conducted with reference to JIS A6909; deionized water resistance evaluation was immersed in warm deionized water at 50 ° C to apparent whitening time standard; freeze-thaw durability evaluation coating after 2h frozen at _20 ° C ambient 10 ° C and soaked in deionized water for 1 hour and so forth, in order to return the number of significant cracking standard; curing shrinkage ratio measured is left to dry for 30 days in the coating. 本发明涂料的各项指标远远超过国标,具有较高的抗压强度和粘结强度,耐去离子水性好。 Indicators of the present invention, the coating is far more than the national standard, having a high compressive strength and bond strength, good resistance to deionized water. 本发明提供的透光性好的涂料是一种良好的窗膜及保护膜用紫外线光固化耐刮涂料,不仅原料来源方便,而且无论原材料本身还是涂料成品均具有优秀的稳定性,便于工业化推广和应用,并且该涂料具有固化速度快、制备工艺简单等特点,能够大大降低生产成本;由该涂料制成的涂层具有硬度适中、透光性好等特点。 The present invention provides coatings having good light transmitting window is a good film and a protective film coating with ultraviolet light curing scratch, not only convenient source of raw materials, and the raw material itself or whether the finished product has excellent coating stability, facilitate promotion of industrialization and application, and the coating having a high curing speed, simple preparation process and the like, and can greatly reduce production costs; coating made of the coating material having a moderate hardness, good light transmission characteristics.

[0017] 对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。 [0017] The above description of the disclosed embodiments enables those skilled in the art to make or use the present invention. 对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。 Various modifications to these professionals skilled in the art of the present embodiments will be apparent, and the generic principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. 因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。 Accordingly, the present invention will not be limited to the embodiments shown herein but is to be accorded herein consistent with the principles and novel features disclosed widest scope.

Claims (5)

  1. 1. 一种透光性好的涂料,其特征在于: 由以下重量份数的原料制成:二苯乙基联苯酚聚氧乙烯醚0.7-1.5份,铝碳质耐火砖粉3.5-5份,多元醇聚氧乙烯醚羧酸酯2.3-4.4份,双苯乙基酚聚氧乙烯醚2-5份,钛白粉3.4-6.6份,3,5-三级丁基-4-羟基苯基硫醚2.6-3.8份,三亚油酸甘油酯1.5-2.5份,去离子水5 · 8-7 · 8份,表面活性剂0 · 12-0 · 55份。 A good paint translucent, characterized in that: the raw material is made of the following parts by weight: diphenylethyl biphenol polyoxyethylene ethers 0.7-1.5 parts aluminum powder, 3.5-5 parts carbonaceous refractory , polyoxyethylene polyhydric alcohol ether carboxylates 2.3-4.4 parts, bis phenethyl 2-5 parts of polyoxyethylene ether, 3.4-6.6 parts of titanium dioxide, 3,5-tert.butyl-4-hydroxyphenyl 2.6 to 3.8 parts of sulfide, glyceryl trilinoleate 1.5-2.5 parts of deionized water · 8-7 · 8 5 parts surfactant 0 · 12-0 · 55 parts.
  2. 2. 根据权利要求1所述的透光性好的涂料,其特征在于: 由以下重量份数的原料制成:二苯乙基联苯酚聚氧乙烯醚〇. 7份,铝碳质耐火砖粉3.5 份,多元醇聚氧乙烯醚羧酸酯2.3份,双苯乙基酚聚氧乙烯醚2份,钛白粉3.4份,3,5_三级丁基-4-羟基苯基硫醚2.6份,三亚油酸甘油酯1.5份,去离子水5.8份,表面活性剂0.12份。 2. translucent good paint according to claim 1, wherein: the raw material is made of the following parts by weight: diphenylethyl biphenol polyoxyethylene ethers billion parts 7, alumina carbon refractory brick powder, 3.5 parts, 2.3 parts of a polyoxyethylene polyhydric alcohol ether carboxylates, phenethyl bis phenol polyoxyethylene ether 2 parts, 3.4 parts of titanium dioxide, 3,5_-tert.butyl-4-hydroxyphenyl sulfide 2.6 parts, three glyceryl linoleate 1.5 parts, 5.8 parts of deionized water, 0.12 parts of a surfactant.
  3. 3. 根据权利要求2所述的透光性好的涂料,其特征在于:所述钛白粉为金红石型钛白粉,粒度为2000目。 3. The optically-clear coating according to claim 2, wherein: said titanium dioxide is rutile type titanium dioxide, a particle size of 2000 mesh.
  4. 4. 根据权利要求3所述的透光性好的涂料,其特征在于:所述表面活性剂为脂肪酸酯硫酸脂盐。 4. The optically-clear coating according to claim 3, wherein: the surfactant is a tallow fatty acid ester sulfate.
  5. 5. 根据权利要求1-4任一项所述的透光性好的涂料的制备方法,包括以下步骤: 1) 按照配方称量,将二苯乙基联苯酚聚氧乙烯醚、去离子水和铝碳质耐火砖粉加入分散罐中,以400-500r/min进行分散搅拌15-20min; 2) 然后加入多元醇聚氧乙烯醚羧酸酯和双苯乙基酚聚氧乙烯醚,以1000-1200r/min高速分散20-35min; 3) 再将钛白粉和3,5-三级丁基-4-羟基苯基硫醚按配方比例加入,将混合物加热到SO-gOt, 并在该温度下保温2 小时; 4) 将混合物冷却到室温后,加入三亚油酸甘油酯和表面活性剂,继续升温到60°C,该温度下保温45-50分钟,同时施加真空到0.09~0.095MPa,然后冷却即为成品。 The preparation method according to any optically-clear coating according to claims 1-4, comprising the following steps: 1) in accordance with the Formulation, ethyl diphenyl biphenol polyoxyethylene ethers, deionized water carbonaceous refractory bricks and aluminum powder added to the dispersion tank at 400-500r / min dispersing stirring 15-20min; 2) was then added polyhydric alcohol polyoxyethylene ether carboxylate, and bis phenethyl phenol polyoxyethylene ether, to 1000-1200r / min high speed disperser 20-35min; 3) then titanium dioxide and 3,5-tert.butyl-4-hydroxyphenyl sulfide was added according to the formula proportion, the mixture was heated to SO-gOt, and the holding at temperature for 2 hours; 4) the mixture was cooled to room temperature, tris linoleic glycerides and surfactants, continue to heat to 60 ° C, holding at this temperature for 45-50 minutes, while applying a vacuum to 0.09 ~ 0.095MPa and then cooling is finished.
CN 201511009201 2015-12-30 2015-12-30 Paint with good light transmission and preparation method of paint CN105440921A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1891306A (en) * 2005-07-07 2007-01-10 贺利氏古萨有限公司 Dyed polymethyl methacrylate bone cement and process for its production
CN102704330A (en) * 2012-06-01 2012-10-03 安徽省金盾涂料有限责任公司 Waterproof coating of carton
CN103965707A (en) * 2014-05-16 2014-08-06 湖州百胜涂料有限公司 Improved anti-aging waterproof coating
JP5826171B2 (en) * 2010-05-27 2015-12-02 花王株式会社 Oil-in-water emulsion composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1891306A (en) * 2005-07-07 2007-01-10 贺利氏古萨有限公司 Dyed polymethyl methacrylate bone cement and process for its production
JP5826171B2 (en) * 2010-05-27 2015-12-02 花王株式会社 Oil-in-water emulsion composition
CN102704330A (en) * 2012-06-01 2012-10-03 安徽省金盾涂料有限责任公司 Waterproof coating of carton
CN103965707A (en) * 2014-05-16 2014-08-06 湖州百胜涂料有限公司 Improved anti-aging waterproof coating

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