CN105332001B - Half barrier film hypochlorite generator - Google Patents

Half barrier film hypochlorite generator Download PDF

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Publication number
CN105332001B
CN105332001B CN201510830635.9A CN201510830635A CN105332001B CN 105332001 B CN105332001 B CN 105332001B CN 201510830635 A CN201510830635 A CN 201510830635A CN 105332001 B CN105332001 B CN 105332001B
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China
Prior art keywords
housing
barrier film
hypochlorite generator
electrode plate
liquid outlet
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Application number
CN201510830635.9A
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CN105332001A (en
Inventor
艾昊波
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Changsha Taozi Health Information Technology Co., Ltd
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Chengdu Baioufeida Biotechnology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention provides a kind of half barrier film hypochlorite generator, belong to sterilizing equipment decontaminating apparatus technical field, it includes housing and battery lead plate, housing has inlet and liquid outlet, battery lead plate includes first electrode plate and second electrode plate, second electrode plate upper end connects shell top wall and electrically connected with power cathode, lower end and housing lower wall formation passage;First electrode plate lower end connects housing lower wall and electrically connected with positive source, upper end and shell top wall formation passage.Two electrode plates that the half barrier film hypochlorite generator that the present invention is provided passes through half diaphragm type of setting, the flowing for making saline solution reciprocal in electrolytic cell, and the pH value of solution also changes therewith, so that the pH value of the thimerosal outwards overflowed at liquid outlet is in convenient scope, and contain enough hypochlorites in thimerosal, more traditional hypochlorite generating means, the thimerosal Disinfection Effect of its output is more preferable.

Description

Half barrier film hypochlorite generator
Technical field
The present invention relates to sterilizing equipment decontaminating apparatus technical field, in particular to a kind of half barrier film hypochlorite generator.
Background technology
On engineering of water treatment, sterilizing technology almost mostly relies on salt prime system disinfectant.Particularly in Shang Shui Sterilizing more than 90% in road processing engineering is all chlorine, sodium hypochlorite, calcium hypochlorite for being sterilized using salt prime system etc..
Sodium hypochlorite efficiently, increasingly paid attention to and popularized by wide spectrum, safe thimerosal, and electrolytic sodium hypochlorite is sent out Raw device is wide using field because it is easy to use, and is rapidly developed and promoted.
But electrolytic hypochlorite generator of the prior art is raw material using sodium chloride, the vinegar sodium chlorate being electrolysed out is dense Degree is inadequate, and Disinfection Effect is poor, in view of this, is badly in need of a kind of electrolytic sodium hypochlorite hair that can improve sodium hypochlorite electrolyte concentrations Raw device.
The content of the invention
The invention provides a kind of half barrier film hypochlorite generator, it is intended to improves above-mentioned technical problem.
What the present invention was realized in:
Half barrier film hypochlorite generator, including housing and battery lead plate, the housing has inlet and liquid outlet, described Inlet and the liquid outlet are located at the left and right ends of the housing respectively, and the battery lead plate is included from inlet to liquid outlet side To the first electrode plate and second electrode plate set gradually, the battery lead plate is made up of chlorion semipermeable membrane material;
The upper end of the second electrode plate is connected to the upper inside walls of the housing and electrically connected with the negative pole of extraneous power supply, The passage circulated for liquid is formed between lower end and the downside inwall of the housing;The lower end of the first electrode plate is connected to institute State the downside inwall of housing and electrically connected with the positive pole of extraneous power supply, feed flow is formed between the upper inside walls of upper end and the housing The passage of body circulation.
Battery lead plate of the prior art is the battery lead plate in the technical program to be set in the form of electrolytic cell groove mostly Using semi-transparent setting form, by setting 2 pieces of semi-transparent battery lead plates, wherein the battery lead plate connection power supply close to liquid outlet is born Pole, close to the battery lead plate connection positive source of inlet, the benefit so set is:
(1) in electrolytic process, from inlet enters electrolytic cell in first electrode plate oxidation reaction occurs for saline solution, and A large amount of hydrogen ions are produced, local solution ph is reduced into acidity rapidly, solution is through the passage between the first electrolytic zinc-coated steel sheet and housing Flowed to second electrode plate direction, second electrode plate reduction reaction, the pH value of topical solutions is alkalescence, inlet raw material not It is disconnected pour in the case of, the solution near first electrode plate can flow towards liquid outlet direction, and near second electrode plate Solution mutually neutralize so that the pH value of the final thimerosal overflowed from liquid outlet is in appropriate level.
(2) because battery lead plate and housing have passage, housing is not separated completely, and battery lead plate be use chlorine from What sub- semipermeable membrane material was made, this, which allows for the ion containing chlorine element in solution, to be flowed out of passage, and such solution is from entering During liquid mouth flows to liquid outlet, flowed in the passage back and forth set, substantially prolongs its flow path, make in solution The reaction time for having abundance produces enough sodium hypochlorite, improves the Disinfection Effect of the thimerosal overflowed from liquid outlet.
(3) salting liquid generates NaClO, pH value about 6.5 ± 0.5 after the electrolysis of first electrode plate and second electrode plate.
Also, by regulating and controlling the electric current and voltage of battery lead plate, the electrolysis amount at each battery lead plate can be accurately controlled, makes electricity The more sodium hypochlorite of generation in Xie Chi.
Further, the inlet is connected with input duct, the input duct and is provided with measuring pump.
Liquid inlet volume and feed speed are accurately controlled by measuring pump, and mutually tied with the control of each battery lead plate electricity Close, it is possible to achieve the accurate control of the sodium hypochlorite concentration produced by whole hypochlorite generator.
Further, half of the width of the passage no more than the upper and lower ends inwall spacing of the housing.
The width of passage is the spacing between one end of the unclosed housing of battery lead plate and housing, and the size of the width is determined The path length of Chlorine in Solution ion flow.Specifically, the width of passage is bigger, and the flow path of chlorion is shorter, on the contrary It is then longer.
It is highly preferred that being summarized through inventor's many experiments, when the width of the passage is in the upper and lower ends of the housing Wall spacing 1/3rd when, the electrolysis effectiveness in whole hypochlorite generator is best.
Further, in addition to PLC control system and the surveymeter for detecting pH value, the surveymeter is arranged on out liquid At mouthful, the surveymeter is electrically connected with the PLC control system, and institute's PLC control system is used to control power supply to the battery lead plate The electric current and voltage of power supply.
PLC control system is connected with all battery lead plates formation circuit, and the electricity of each circuit board is accurately controlled by plug-in Amount, realizes the accurate control to electrolytic process.In addition, PLC control system can also be attached control with measuring pump.
Further, the liquid outlet is provided with magnetic valve, and the magnetic valve is electrically connected with the PLC control system.When There is a situation where that the thimerosal in electrolytic cell is not up to use requirement, PLC control system control closed electromagnetic valve, during extension electrolysis Between.
Further, the inlet is located at the lower end of side wall on the left of the housing.
Further, the liquid outlet is located at the upper end of the housing right sidewall.
Inlet and liquid outlet are separately positioned on the lower end of side wall and the upper end of right sidewall on the left of housing, so do same Sample can extend the flow path of the solution entered from inlet in electrolytic cell.
Specifically, inlet is close to the lower end of first electrode plate, and then remote passage between first electrode plate and housing; And liquid outlet is then close to the upper end of the 4th battery lead plate, and then away from the passage between first electrode plate and housing.
Further, the housing is made up of insulating materials, and the inwall of the housing is provided with corrosion-resistant coating.
, locally can be in acid or alkalescence during cell operation.Violent corrosion can be produced to housing, corrosion-resistant coating Setting is to strengthen the corrosivity of the acid-proof, alkali, salt of whole housing, extend its service life.
Further, the corrosion-resistant coating thickness is not less than 3mm.
The beneficial effects of the invention are as follows:The new half barrier film hypochlorite generator that the present invention is provided is by setting half barrier film The pH value of four electrode plates of formula, the flowing for making saline solution reciprocal in electrolytic cell, and solution also changes therewith, directly raw Outwards overflowed into sodium hypochlorite, and at liquid outlet, and the pH value of the thimerosal generated is in convenient scope, thimerosal In contain enough sodium hypochlorite, the plain generating means of more traditional hypochlorite, the thimerosal Disinfection Effect of its output is more preferable.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be attached to what is used required in embodiment Figure is briefly described, it will be appreciated that the following drawings illustrate only certain embodiments of the present invention, therefore is not construed as pair The restriction of scope, for those of ordinary skill in the art, on the premise of not paying creative work, can also be according to this A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is the structural representation of half barrier film hypochlorite generator provided in an embodiment of the present invention;
Fig. 2 is the workflow diagram for the half barrier film hypochlorite generator that the present invention is provided.
Scheming acceptance of the bid note is respectively:
Saline solution storage pool 101;Measuring pump 102;Housing 103;Inlet 104;Liquid outlet 105;First electrode plate 111;The Two battery lead plates 112.
Embodiment
On engineering of water treatment, sterilizing technology almost mostly relies on salt prime system disinfectant.Particularly in Shang Shui Sterilizing more than 90% in road processing engineering is all chlorine, sodium hypochlorite, calcium hypochlorite for being sterilized using salt prime system etc..
Sodium hypochlorite efficiently, increasingly paid attention to and popularized by wide spectrum, safe thimerosal, and electrolytic sodium hypochlorite is sent out Raw device is wide using field because it is easy to use, and is rapidly developed and promoted.
But electrolytic hypochlorite generator of the prior art is raw material using sodium chloride, the vinegar sodium chlorate being electrolysed out is dense Degree is inadequate, and Disinfection Effect is poor, in view of this, is badly in need of a kind of electrolytic sodium hypochlorite hair that can improve sodium hypochlorite electrolyte concentrations Raw device.
In view of this, those skilled in the art are seeking the instrument or method of a kind of improvement problem always for a long time.
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is A part of embodiment of the present invention, rather than whole embodiments.Therefore, embodiments of the invention below to providing in the accompanying drawings Detailed description be not intended to limit the scope of claimed invention, but be merely representative of the present invention selected embodiment. Based on the embodiment in the present invention, it is all that those of ordinary skill in the art are obtained under the premise of creative work is not made Other embodiment, belongs to the scope of protection of the invention.
It should be noted that:Similar label and letter represents similar terms in following accompanying drawing, therefore, once a certain Xiang Yi It is defined in individual accompanying drawing, then it further need not be defined and explained in subsequent accompanying drawing.
In the description of the invention, it is necessary to explanation, term " " center ", " on ", " under ", "left", "right", " vertical ", The orientation or position relationship of the instruction such as " level ", " interior ", " outer " be based on orientation shown in the drawings or position relationship, or should Orientation or position relationship that invention product is usually put when using, are for only for ease of the description present invention and simplify description, without It is that instruction or the signified device of hint or element must have specific orientation, with specific azimuth configuration and operation, therefore not It is understood that as limitation of the present invention.In addition, term " first ", " second ", " the 3rd " etc. are only used for distinguishing description, and it can not manage Solve to indicate or imply relative importance.
In the description of the invention, in addition it is also necessary to explanation, unless otherwise clearly defined and limited, term " setting ", " installation ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or one Connect body;Can be mechanical connection or electrical connection;Can be joined directly together, can also be indirect by intermediary It is connected, can is the connection of two element internals.For the ordinary skill in the art, on being understood with concrete condition State the concrete meaning of term in the present invention.
Embodiment
As depicted in figs. 1 and 2, a kind of half barrier film hypochlorite generator, including housing 103, PLC are present embodiments provided Control system and saline solution storage pool 101.In the present embodiment, housing 103 is rectangular-shaped, and housing 103, which is adopted, to be made from an insulative material, The inwall of the housing 103 is provided with corrosion-resistant coating, the setting of corrosion-resistant coating be in order to strengthen the acid-proof of whole housing 103, alkali, The corrosivity of salt, extends its service life.
Specifically, the thickness of corrosion-resistant coating should be not less than in 3mm, the present embodiment, and corrosion-resistant coating is by high molecule plastic PVDF is made, and the thickness of corrosion-resistant coating is 4mm.
As shown in figure 1, the housing 103 have inlet 104 and liquid outlet 105, the inlet 104 and it is described go out liquid Mouth 105 is located at the left and right ends of the housing 103 respectively.Saline solution storage pool 101 is connected by input duct with inlet 104, And be provided with measuring pump 102 in input duct, measuring pump 102 can accurately control the flow that saline solution enters in housing 103 and Flow velocity.Measuring pump 102 is electrically connected with PLC control system, and PLC control system controls measuring pump 102 by plug-in Open, close and flow.
PH value surveymeter is provided with liquid outlet 105, pH value surveymeter is used for the pH value for detecting solution at liquid outlet 105, And magnetic valve is additionally provided with liquid outlet 105, pH value surveymeter and magnetic valve are electrically connected with PLC control system, PLC controls The opening and closing for the output control magnetic valve that system is detected according to pH value surveymeter, it is ensured that the pH of the thimerosal overflowed from liquid outlet 105 Value can be up to standard.
Cavity inside housing 103 constitutes and is provided with opening on electrolytic cell, the top and bottom sidewall of housing 103.Set in electrolytic cell Two electrode plates are equipped with, battery lead plate is to be stretched into by the opening set on top and bottom sidewall inside electrolytic cell.
Battery lead plate is made up of chlorion semipermeable membrane material, and this chlorion semipermeable membrane material can prevent chloride elemental substance Pass through.
In the present embodiment, the battery lead plate includes the first electrode set gradually from inlet 104 to the direction of liquid outlet 105 Plate 111 and second electrode plate 112.
Specifically, the upper end of second electrode plate 112 be both connected to the housing 103 upper inside walls and with extraneous power supply Negative pole electrical connection, form the passage circulated for liquid between lower end and the downside inwall of the housing 103;The first electrode The lower end of plate 111 is both connected to the downside inwall of the housing 103 and electrically connected with the positive pole of extraneous power supply, upper end and the shell The passage circulated for liquid is formed between the upper inside walls of body 103.
First electrode plate 111, second electrode plate 112 and extraneous power supply are electrically connected with PLC control system, PLC controls System can control the instantaneous input voltage and electric current of first electrode plate 111, second electrode plate 112.
In actual use, saline solution is aoxidized from inlet 104 enters electrolytic cell on first electrode plate 111 Reaction, and a large amount of hydrogen ions are produced, local solution ph is reduced into acidity rapidly, solution is through first electrode plate 111 and shell Passage between body 103 flows to the direction of second electrode plate 112, and reduction reaction, the pH value of topical solutions occur for second electrode plate 112 For alkalescence, in the case where the raw material of inlet 104 is constantly poured in, the solution near first electrode plate 111 can be towards liquid outlet 105 directions are flowed, and are neutralized first with the solution near second electrode plate 112, are in faintly acid after neutralization, finally from liquid outlet The pH value of 105 thimerosals overflowed is in appropriate level.
The present embodiment provides a kind of preferred electrolytic cell pH value control program, specifically, near first electrode plate 111 Solution ph is that the solution ph near 2.5 ± 0.2, second electrode plate 112 is 6 ± 0.5, is so overflowed from liquid outlet 105 The pH value of thimerosal is faintly acid, and suitably sterilization is used.
The width of passage between battery lead plate and housing 103 is weighed very much for path length of the control solution in electrolytic cell Will, in the present embodiment, the width of the passage is 1/3rd of the upper and lower ends inwall spacing of the housing 103.
Passage is under the width, and the path that solution flows through electrolytic cell is more suitable, the operating efficiency highest of electrolytic cell.
The new half barrier film hypochlorite generator that the present embodiment is provided is made by two electrode plates of half diaphragm type of setting Saline solution flowing reciprocal in electrolytic cell, and the pH value of solution also changes therewith, directly generates sodium hypochlorite, and from going out Outwards overflowed at liquid mouthful 105, and the pH value of the thimerosal generated is in convenient scope, thimerosal containing enough times Sodium chlorate, the plain generating means of more traditional hypochlorite, the thimerosal Disinfection Effect of its output is more preferable.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should be included in the scope of the protection.

Claims (10)

1. half barrier film hypochlorite generator, it is characterised in that including housing and battery lead plate, the housing has inlet and gone out Liquid mouthful, the inlet and the liquid outlet are located at the left and right ends of the housing respectively, and the battery lead plate is included from inlet The first electrode plate and second electrode plate set gradually to liquid outlet direction, the battery lead plate is by chlorion semipermeable membrane material system Into;
The upper end of the second electrode plate is connected to the upper inside walls of the housing and electrically connected with the negative pole of extraneous power supply, lower end The passage circulated for liquid is formed between the downside inwall of the housing;The lower end of the first electrode plate is connected to the shell The downside inwall of body is simultaneously electrically connected with the positive pole of extraneous power supply, is formed and flowed for liquid between the upper inside walls of upper end and the housing Logical passage.
2. half barrier film hypochlorite generator according to claim 1, it is characterised in that the inlet is connected with feed liquor Measuring pump is provided with pipeline, the input duct.
3. half barrier film hypochlorite generator according to claim 1, it is characterised in that the width of the passage is no more than The half of the upper and lower ends inwall spacing of the housing.
4. half barrier film hypochlorite generator according to claim 3, it is characterised in that the width of the passage is described / 3rd of the upper and lower ends inwall spacing of housing.
5. half barrier film hypochlorite generator according to claim 1, it is characterised in that also including PLC control system and Surveymeter for detecting pH value, the surveymeter is arranged at liquid outlet, and the surveymeter is electrically connected with the PLC control system Connect, the PLC control system is used to control the electric current and voltage that power supply is powered to the battery lead plate.
6. half barrier film hypochlorite generator according to claim 5, it is characterised in that the liquid outlet is provided with electromagnetism Valve, the magnetic valve is electrically connected with the PLC control system.
7. half barrier film hypochlorite generator according to claim 1, it is characterised in that the inlet is located at the shell The lower end of side wall on the left of body.
8. half barrier film hypochlorite generator according to claim 1, it is characterised in that the liquid outlet is located at the shell The upper end of body right sidewall.
9. half barrier film hypochlorite generator according to claim 1, it is characterised in that the housing is by insulating materials system Into the inwall of the housing is provided with corrosion-resistant coating.
10. half barrier film hypochlorite generator according to claim 9, it is characterised in that the corrosion-resistant coating thickness is not Less than 3mm.
CN201510830635.9A 2015-11-24 2015-11-24 Half barrier film hypochlorite generator Active CN105332001B (en)

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CN105332001B true CN105332001B (en) 2017-10-27

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6887940B2 (en) * 2017-12-06 2021-06-16 ホシザキ株式会社 Tank vault
CN110158116A (en) * 2019-05-31 2019-08-23 凯莱英医药集团(天津)股份有限公司 Electrolysis unit and electrolysis system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU429020A1 (en) * 1972-03-06 1974-05-25 Л. М. Якименко BIPOLAR ELECTROLIZER FOR PRODUCING A HYPOCHLORATE ALKALINE METAL SOLUTION
GB2022616B (en) * 1978-06-06 1983-02-02 Finnish Chemicals Oy Electrode assembly
CN2097839U (en) * 1991-03-13 1992-03-04 于兆骅 Seal multi-layer plate type no-diaphragm electrolysis generator
CN102021602A (en) * 2010-07-19 2011-04-20 江苏泽宇环境工程有限公司 Sodium hypochlorite generator
CN205275710U (en) * 2015-11-24 2016-06-01 成都百鸥飞达生物科技有限公司 Half unfamiliar hypochlorite generator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU429020A1 (en) * 1972-03-06 1974-05-25 Л. М. Якименко BIPOLAR ELECTROLIZER FOR PRODUCING A HYPOCHLORATE ALKALINE METAL SOLUTION
GB2022616B (en) * 1978-06-06 1983-02-02 Finnish Chemicals Oy Electrode assembly
CN2097839U (en) * 1991-03-13 1992-03-04 于兆骅 Seal multi-layer plate type no-diaphragm electrolysis generator
CN102021602A (en) * 2010-07-19 2011-04-20 江苏泽宇环境工程有限公司 Sodium hypochlorite generator
CN205275710U (en) * 2015-11-24 2016-06-01 成都百鸥飞达生物科技有限公司 Half unfamiliar hypochlorite generator

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Address after: Room 2709, Kuanyu building, No. 139, Wanjiali Middle Road, dongtundu street, Furong district, Changsha City, Hunan Province

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Address before: 1, No. 23, No. 610000, 3 floor, 1480 North Tianfu Road, Chengdu hi tech Zone, Sichuan

Patentee before: CHENGDU BAIOUFEIDA BIOTECHNOLOGY Co.,Ltd.