CN105332001A - Semi-membrane sodium hypochlorite generator - Google Patents
Semi-membrane sodium hypochlorite generator Download PDFInfo
- Publication number
- CN105332001A CN105332001A CN201510830635.9A CN201510830635A CN105332001A CN 105332001 A CN105332001 A CN 105332001A CN 201510830635 A CN201510830635 A CN 201510830635A CN 105332001 A CN105332001 A CN 105332001A
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- CN
- China
- Prior art keywords
- hypochlorite generator
- battery lead
- lead plate
- barrier film
- housing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 11
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 title abstract description 19
- 239000005708 Sodium hypochlorite Substances 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 claims abstract description 41
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 58
- 239000012530 fluid Substances 0.000 claims description 24
- 230000004888 barrier function Effects 0.000 claims description 19
- 238000005260 corrosion Methods 0.000 claims description 11
- 230000007797 corrosion Effects 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 241000370738 Chlorion Species 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 239000011810 insulating material Substances 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 13
- 150000003839 salts Chemical class 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000008859 change Effects 0.000 abstract description 3
- 239000000645 desinfectant Substances 0.000 abstract 3
- 230000000249 desinfective effect Effects 0.000 abstract 1
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 14
- 229940033663 thimerosal Drugs 0.000 description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 238000005868 electrolysis reaction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000010327 methods by industry Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- 230000000699 topical effect Effects 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention provides a semi-membrane sodium hypochlorite generator, and belongs to the technical field of disinfecting equipment. The semi-membrane sodium hypochlorite generator comprises a shell and plate electrodes. The shell is provided with a liquid inlet and a liquid outlet. The plate electrodes comprise the first plate electrode and the second plate electrode, the upper end of the second plate electrode is connected with the upper wall of the shell and is electrically connected with the negative electrode of a power source, the lower end of the second plate electrode and the lower wall of the shell form a channel, the lower end of the first plate electrode is connected with the lower wall of the shell and is electrically connected with the positive electrode of the power source, and the upper end of the first plate electrode and the upper wall of the shell form a channel. According to the semi-membrane sodium hypochlorite generator, the two semi-membrane type plate electrodes are arranged, salt liquid flows in an electrolytic tank in a reciprocating mode, the pH values of solutions change accordingly, the pH value of disinfectant overflowing outwards from the liquid outlet is within an appropriate range, and the disinfectant contains enough pypocholoride. Compared with traditional pypocholoride generators, the semi-membrane sodium hypochlorite generator has the advantage that the disinfection effect of the produced disinfectant is better.
Description
Technical field
The present invention relates to sterilization equipment technical field, in particular to a kind of half barrier film hypochlorite generator.
Background technology
On engineering of water treatment, sterilization and disinfection technology almost major part depends on salt prime system sterilizing agent.Sterilization and disinfection more than 90% particularly in water-supply line process engineering is all the chlorine, clorox, Losantin etc. that use the sterilization of salt prime system.
Clorox is efficient, wide spectrum, and the thimerosal of safety is more and more paid attention to and popularizes, and electrolyzing hypochlorite generator is because it is easy to use, uses field wide, and is developed rapidly and promote.
But electrolyzing hypochlorite generator of the prior art uses sodium-chlor to be raw material, the vinegar density of sodium chlorate that electrolysis goes out is inadequate, and sterilisation effect is poor, in view of this, is badly in need of a kind of electrolyzing hypochlorite generator that can improve clorox electrolyte concentrations.
Summary of the invention
The invention provides a kind of half barrier film hypochlorite generator, be intended to improve above-mentioned technical problem.
The present invention is achieved in that
Half barrier film hypochlorite generator, comprise housing and battery lead plate, described housing has fluid inlet and liquid outlet, described fluid inlet and described liquid outlet lay respectively at the two ends, left and right of described housing, described battery lead plate comprises the first battery lead plate and the second battery lead plate that set gradually to liquid outlet direction from fluid inlet, and described battery lead plate is made up of chlorion semipermeable membrane material;
The upper end of described second battery lead plate is connected to the upper inside walls of described housing and is connected with the negative electricity of extraneous power supply, forms the passage circulated for liquid between the downside inwall of lower end and described housing; The lower end of described first battery lead plate is connected to the downside inwall of described housing and is electrically connected with the positive pole of extraneous power supply, forms the passage circulated for liquid between the upper inside walls of upper end and described housing.
Battery lead plate of the prior art be mostly with the form running through electrolyzer groove arrange, what the battery lead plate employing in the technical program was semi-transparent arranges form, by arranging 2 pieces of semi-transparent battery lead plates, battery lead plate wherein near liquid outlet is communicated with power cathode, battery lead plate near fluid inlet is communicated with positive source, and the benefit arranged like this is:
(1) in electrolytic process, saline solution enters electrolyzer from fluid inlet, in the first battery lead plate generation oxidizing reaction, and produce a large amount of hydrogen ion, the solution ph of local is made to be lowered into acidity rapidly, solution flows to the second battery lead plate direction through the passage between the first electrolytic zinc-coated steel sheet and housing, second battery lead plate reduction reaction, the pH value of topical solutions is alkalescence, when the raw material of fluid inlet constantly pours in, solution near first battery lead plate can flow towards liquid outlet direction, and mutually neutralize with the solution near the second battery lead plate, make the pH value of the thimerosal finally overflowed from liquid outlet in more suitable level.
(2) because battery lead plate and housing all exist passage, completely housing is not separated, and battery lead plate adopts chlorion semipermeable membrane material to make, this just makes the ion of chloride element in solution can only flow in passage, the process that such solution flows from fluid inlet to liquid outlet, flow in the passage back and forth arranged, substantially prolongs its flowing-path, make in solution, have the sufficient reaction times to produce enough clorox, improve the sterilisation effect of the thimerosal overflowed from liquid outlet.
(3) namely salts solution generates NaClO, pH value about 6.5 ± 0.5 after the electrolysis of the first battery lead plate and the second battery lead plate.
Further, by regulating and controlling electric current and the voltage of battery lead plate, the electrolysis amount of each battery lead plate place can be controlled accurately, making to generate more clorox in electrolyzer.
Further, described fluid inlet is connected with input duct, and described input duct is provided with volume pump.
By volume pump, liquid inlet volume and feed liquor speed are controlled accurately, and combine with each battery lead plate electric energy control, the accurate control of the clorox concentration that whole hypochlorite generator produces can be realized.
Further, the width of described passage is no more than the half of the inwall spacing of two ends up and down of described housing.
Namely the width of passage is the spacing between one end of the non-closure casing of battery lead plate and housing, and the size of this width determines the path length of Chlorine in Solution ion flow.Specifically, the width of passage is larger, and the flowing-path of chlorion is shorter, otherwise then longer.
More preferably, sum up through contriver's many experiments, when the width of described passage be the inwall spacing of two ends up and down of described housing three/for the moment, the electrolysis effectiveness in whole hypochlorite generator is best.
Further, also comprise PLC control system and the surveymeter for detecting pH value, described surveymeter is arranged on liquid outlet place, and described surveymeter is electrically connected with described PLC control system, and institute's PLC control system is for the electric current that controls power supply and power to described battery lead plate and voltage.
PLC control system and all battery lead plates form circuit and are connected, and are accurately controlled the electricity of each circuit card by plug-in, realize the accurate control to electrolytic process.In addition, PLC control system can also carry out connection control with volume pump.
Further, described discharge port is provided with magnetic valve, and described magnetic valve is electrically connected with described PLC control system.When there is the thimerosal in electrolyzer and do not reach the situation of service requirements, PLC control system Controlling solenoid valve is closed, and extends electrolysis time.
Further, described fluid inlet is positioned at the lower end of sidewall on the left of described housing.
Further, described liquid outlet is positioned at the upper end of described housing right sidewall.
Fluid inlet and liquid outlet are separately positioned on the lower end of sidewall and the upper end of right sidewall on the left of housing, do the flowing-path that can extend equally and enter the solution in electrolyzer from fluid inlet like this.
Specifically, fluid inlet near the lower end of the first battery lead plate, and then away from the passage between the first battery lead plate and housing; Liquid outlet then near the upper end of the 4th battery lead plate, and then away from the passage between the first battery lead plate and housing.
Further, described housing is made up of insulating material, and the inwall of described housing is provided with corrosion-resistant coating.
In cell operation process, local can in acid or alkaline.Can produce violent corrosion to housing, the setting of corrosion-resistant coating is the corrodibility of acid-proof in order to strengthen whole housing, alkali, salt, extends its work-ing life.
Further, described corrosion-resistant coating thickness is not less than 3mm.
The invention has the beneficial effects as follows: novel half barrier film hypochlorite generator provided by the invention is by arranging four electrode plate of half diaphragm type, make the flowing that saline solution is reciprocal in electrolyzer, and also there is change in the pH value of solution thereupon, direct generation clorox, and outwards overflow from liquid outlet, and the pH value of the thimerosal generated is in comparatively suitable scope, containing enough clorox in thimerosal, more traditional hypochlorite element generating unit, the thimerosal sterilisation effect of its output is better.
Accompanying drawing explanation
In order to be illustrated more clearly in the technical scheme of the embodiment of the present invention, be briefly described to the accompanying drawing used required in embodiment below, be to be understood that, the following drawings illustrate only some embodiment of the present invention, therefore the restriction to scope should be counted as, for those of ordinary skill in the art, under the prerequisite not paying creative work, other relevant accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the structural representation of the half barrier film hypochlorite generator that the embodiment of the present invention provides;
Fig. 2 is the workflow diagram of half barrier film hypochlorite generator provided by the invention.
Figure acceptance of the bid note is respectively:
Saline solution storage pool 101; Volume pump 102; Housing 103; Fluid inlet 104; Liquid outlet 105; First battery lead plate 111; Second battery lead plate 112.
Embodiment
On engineering of water treatment, sterilization and disinfection technology almost major part depends on salt prime system sterilizing agent.Sterilization and disinfection more than 90% particularly in water-supply line process engineering is all the chlorine, clorox, Losantin etc. that use the sterilization of salt prime system.
Clorox is efficient, wide spectrum, and the thimerosal of safety is more and more paid attention to and popularizes, and electrolyzing hypochlorite generator is because it is easy to use, uses field wide, and is developed rapidly and promote.
But electrolyzing hypochlorite generator of the prior art uses sodium-chlor to be raw material, the vinegar density of sodium chlorate that electrolysis goes out is inadequate, and sterilisation effect is poor, in view of this, is badly in need of a kind of electrolyzing hypochlorite generator that can improve clorox electrolyte concentrations.
In view of this, those skilled in the art are seeking a kind of instrument or the method for improving this problem for a long time always.
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Therefore, below to the detailed description of the embodiments of the invention provided in the accompanying drawings and the claimed scope of the present invention of not intended to be limiting, but selected embodiment of the present invention is only represented.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
It should be noted that: represent similar terms in similar label and letter accompanying drawing below, therefore, once be defined in an a certain Xiang Yi accompanying drawing, then do not need to define further it and explain in accompanying drawing subsequently.
In describing the invention, it should be noted that, term " " center ", " on ", D score, " left side ", " right side ", " vertically ", " level ", " interior ", orientation or the position relationship of the instruction such as " outward " are based on orientation shown in the drawings or position relationship, or this invention product orientation of usually putting or position relationship when using, only the present invention for convenience of description and simplified characterization, instead of indicate or imply that the device of indication or element must have specific orientation, with specific azimuth configuration and operation, therefore limitation of the present invention can not be interpreted as.In addition, term " first ", " second ", " the 3rd " etc. only for distinguishing description, and can not be interpreted as instruction or hint relative importance.
In describing the invention, also it should be noted that, unless otherwise clearly defined and limited, term " setting ", " installation ", " being connected ", " connection " should be interpreted broadly, and such as, can be fixedly connected with, also can be removably connect, or connect integratedly; Can be mechanical connection, also can be electrical connection; Can be directly be connected, also indirectly can be connected by intermediary, can be the connection of two element internals.For the ordinary skill in the art, particular case above-mentioned term concrete meaning in the present invention can be understood.
Embodiment
As depicted in figs. 1 and 2, present embodiments provide a kind of half barrier film hypochlorite generator, comprise housing 103, PLC control system and saline solution storage pool 101.In the present embodiment, housing 103 is rectangular-shaped, and housing 103 adopts insulating material to make, and the inwall of described housing 103 is provided with corrosion-resistant coating, and the setting of corrosion-resistant coating is the corrodibility of acid-proof in order to strengthen whole housing 103, alkali, salt, extends its work-ing life.
Specifically, the thickness of corrosion-resistant coating should be not less than 3mm, and in the present embodiment, corrosion-resistant coating is made up of high molecule plastic PVDF, and the thickness of corrosion-resistant coating is 4mm.
As shown in Figure 1, described housing 103 has fluid inlet 104 and liquid outlet 105, and described fluid inlet 104 and described liquid outlet 105 lay respectively at the two ends, left and right of described housing 103.Saline solution storage pool 101 is communicated with fluid inlet 104 by input duct, and input duct is provided with volume pump 102, and volume pump 102 accurately can control saline solution and enter flow in housing 103 and flow velocity.Volume pump 102 is electrically connected with PLC control system, and PLC control system controls the unlatching of volume pump 102, closedown and flow by plug-in.
Liquid outlet 105 place is provided with pH value surveymeter, pH value surveymeter is for detecting the pH value of liquid outlet 105 place solution, and liquid outlet 105 place is also provided with magnetic valve, pH value surveymeter and magnetic valve are all electrically connected with PLC control system, the opening and closing of the output control magnetic valve that PLC control system detects according to pH value surveymeter, ensures that the pH value of the thimerosal overflowed from liquid outlet 105 all can be up to standard.
The cavity of housing 103 inside forms electrolyzer, and the top and bottom sidewall of housing 103 is provided with opening.Be provided with two electrode plate in electrolyzer, battery lead plate is that the opening by top and bottom sidewall is arranged stretches into electrolyzer inside.
Battery lead plate is made up of chlorion semipermeable membrane material, and this chlorion semipermeable membrane material can stop chloride elemental substance to pass through.
In the present embodiment, described battery lead plate comprises the first battery lead plate 111 and the second battery lead plate 112 set gradually to liquid outlet 105 direction from fluid inlet 104.
Specifically, the upper end of the second battery lead plate 112 is all connected to the upper inside walls of described housing 103 and is connected with the negative electricity of extraneous power supply, forms the passage circulated for liquid between the downside inwall of lower end and described housing 103; The lower end of described first battery lead plate 111 is all connected to the downside inwall of described housing 103 and is electrically connected with the positive pole of extraneous power supply, forms the passage circulated for liquid between the upper inside walls of upper end and described housing 103.
First battery lead plate 111, second battery lead plate 112 and extraneous power supply are all electrically connected with PLC control system, and PLC control system can control instantaneous input voltage and the electric current of the first battery lead plate 111, second battery lead plate 112.
In actual use procedure, saline solution enters electrolyzer from fluid inlet 104, there is oxidizing reaction in the first battery lead plate 111, and produce a large amount of hydrogen ion, the solution ph of local is made to be lowered into acidity rapidly, solution flows to the second battery lead plate 112 direction through the passage between the first battery lead plate 111 and housing 103, there is reduction reaction in the second battery lead plate 112, the pH value of topical solutions is alkalescence, when the raw material of fluid inlet 104 constantly pours in, solution near first battery lead plate 111 can flow towards liquid outlet 105 direction, and first with the second battery lead plate 112 near solution neutralize, in slightly acidic after neutralization, the pH value of the final thimerosal from liquid outlet 105 spilling is in more suitable level.
The present embodiment provides a kind of preferred electrolyzer pH value control program, specifically, solution ph near first battery lead plate 111 is 2.5 ± 0.2, solution ph near second battery lead plate 112 is 6 ± 0.5, the pH value of thimerosal of overflowing from liquid outlet 105 is like this slightly acidic, is suitable for use of sterilizing.
The width of the passage between battery lead plate and housing 103 is extremely important for controlling the path length of solution in electrolyzer, and in the present embodiment, the width of described passage is 1/3rd of the inwall spacing of two ends up and down of described housing 103.
Passage is under this width, and solution stream is comparatively suitable through the path of electrolyzer, and the working efficiency of electrolyzer is the highest.
The novel half barrier film hypochlorite generator that the present embodiment provides is by arranging two electrode plate of half diaphragm type, make the flowing that saline solution is reciprocal in electrolyzer, and also there is change in the pH value of solution thereupon, direct generation clorox, and outwards overflow from liquid outlet 105, and the pH value of the thimerosal generated is in comparatively suitable scope, containing enough clorox in thimerosal, more traditional hypochlorite element generating unit, the thimerosal sterilisation effect of its output is better.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. half barrier film hypochlorite generator, it is characterized in that, comprise housing and battery lead plate, described housing has fluid inlet and liquid outlet, described fluid inlet and described liquid outlet lay respectively at the two ends, left and right of described housing, described battery lead plate comprises the first battery lead plate and the second battery lead plate that set gradually to liquid outlet direction from fluid inlet, and described battery lead plate is made up of chlorion semipermeable membrane material;
The upper end of described second battery lead plate is connected to the upper inside walls of described housing and is connected with the negative electricity of extraneous power supply, forms the passage circulated for liquid between the downside inwall of lower end and described housing; The lower end of described first battery lead plate is connected to the downside inwall of described housing and is electrically connected with the positive pole of extraneous power supply, forms the passage circulated for liquid between the upper inside walls of upper end and described housing.
2. half barrier film hypochlorite generator according to claim 1, it is characterized in that, described fluid inlet is connected with input duct, and described input duct is provided with volume pump.
3. half barrier film hypochlorite generator according to claim 1, is characterized in that, the width of described passage is no more than the half of the inwall spacing of two ends up and down of described housing.
4. half barrier film hypochlorite generator according to claim 3, is characterized in that, the width of described passage is 1/3rd of the inwall spacing of two ends up and down of described housing.
5. half barrier film hypochlorite generator according to claim 1, it is characterized in that, also comprise PLC control system and the surveymeter for detecting pH value, described surveymeter is arranged on liquid outlet place, described surveymeter is electrically connected with described PLC control system, and institute's PLC control system is for the electric current that controls power supply and power to described battery lead plate and voltage.
6. half barrier film hypochlorite generator according to claim 5, it is characterized in that, described discharge port is provided with magnetic valve, and described magnetic valve is electrically connected with described PLC control system.
7. half barrier film hypochlorite generator according to claim 1, it is characterized in that, described fluid inlet is positioned at the lower end of sidewall on the left of described housing.
8. half barrier film hypochlorite generator according to claim 1, is characterized in that, described liquid outlet is positioned at the upper end of described housing right sidewall.
9. half barrier film hypochlorite generator according to claim 1, it is characterized in that, described housing is made up of insulating material, and the inwall of described housing is provided with corrosion-resistant coating.
10. half barrier film hypochlorite generator according to claim 9, is characterized in that, described corrosion-resistant coating thickness is not less than 3mm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510830635.9A CN105332001B (en) | 2015-11-24 | 2015-11-24 | Half barrier film hypochlorite generator |
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| CN201510830635.9A CN105332001B (en) | 2015-11-24 | 2015-11-24 | Half barrier film hypochlorite generator |
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| CN105332001B CN105332001B (en) | 2017-10-27 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019098286A (en) * | 2017-12-06 | 2019-06-24 | ホシザキ株式会社 | Tank storage |
| CN110158116A (en) * | 2019-05-31 | 2019-08-23 | 凯莱英医药集团（天津）股份有限公司 | Electrolysis unit and electrolysis system |
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|---|---|---|---|---|
| SU429020A1 (en) * | 1972-03-06 | 1974-05-25 | Л. М. Якименко | BIPOLAR ELECTROLIZER FOR PRODUCING A HYPOCHLORATE ALKALINE METAL SOLUTION |
| GB2022616B (en) * | 1978-06-06 | 1983-02-02 | Finnish Chemicals Oy | Electrode assembly |
| CN2097839U (en) * | 1991-03-13 | 1992-03-04 | 于兆骅 | Seal multi-layer plate type no-diaphragm electrolysis generator |
| CN102021602A (en) * | 2010-07-19 | 2011-04-20 | 江苏泽宇环境工程有限公司 | Sodium hypochlorite generator |
| CN205275710U (en) * | 2015-11-24 | 2016-06-01 | 成都百鸥飞达生物科技有限公司 | Half unfamiliar hypochlorite generator |
-
2015
- 2015-11-24 CN CN201510830635.9A patent/CN105332001B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU429020A1 (en) * | 1972-03-06 | 1974-05-25 | Л. М. Якименко | BIPOLAR ELECTROLIZER FOR PRODUCING A HYPOCHLORATE ALKALINE METAL SOLUTION |
| GB2022616B (en) * | 1978-06-06 | 1983-02-02 | Finnish Chemicals Oy | Electrode assembly |
| CN2097839U (en) * | 1991-03-13 | 1992-03-04 | 于兆骅 | Seal multi-layer plate type no-diaphragm electrolysis generator |
| CN102021602A (en) * | 2010-07-19 | 2011-04-20 | 江苏泽宇环境工程有限公司 | Sodium hypochlorite generator |
| CN205275710U (en) * | 2015-11-24 | 2016-06-01 | 成都百鸥飞达生物科技有限公司 | Half unfamiliar hypochlorite generator |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019098286A (en) * | 2017-12-06 | 2019-06-24 | ホシザキ株式会社 | Tank storage |
| CN110158116A (en) * | 2019-05-31 | 2019-08-23 | 凯莱英医药集团（天津）股份有限公司 | Electrolysis unit and electrolysis system |
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| CN105332001B (en) | 2017-10-27 |
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