CN105315983A - Drag reducing agent of aqueous fracturing fluid, preparation method and application thereof - Google Patents
Drag reducing agent of aqueous fracturing fluid, preparation method and application thereof Download PDFInfo
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- CN105315983A CN105315983A CN201410314297.9A CN201410314297A CN105315983A CN 105315983 A CN105315983 A CN 105315983A CN 201410314297 A CN201410314297 A CN 201410314297A CN 105315983 A CN105315983 A CN 105315983A
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- fracturing fluid
- fluid flow
- flow improver
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- acid salt
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Abstract
The invention relates to a drag reducing agent of an aqueous fracturing fluid, a preparation method and an application thereof and mainly solves the problems of a low drag reducing rate of a surfactant drag reducing agent in the prior art. In the invention, a cationic surfactant represented as the formula (I) and an organic acid salt are employed, wherein the R is a saturated or unsaturated aliphatic group being 8-24 in carbon atom number; R1, R2 and R6 are independently selected from alkyl groups having 1-4 carbon atoms or hydroxyalkyl groups having 2-4 carbon atoms; R3, R4 and R5 are independently selected from alkylene groups having 1-6 carbon atom number; and D is one selected from halogen ions. The weight ratio of the cationic surfactant to the organic acid salt is 1:(1-50). The organic acid salt is selected from at least one of aliphatic carboxylates, aliphatic sulfonates and aromatic salts. The technical scheme solves the technical problems well. The drag reducing agent can be used for fracturing exploitation of shale gas.
Description
Technical field
The present invention relates to a kind of aqueous fracturing fluid flow improver and its preparation method and application.
Background technology
Shale gas reservoir generally belongs to super low-porosity and low-permeability reservoir, and the rate of permeation of permeability ratio Clastic Rock Gas Reservoirs also will a low 2-3 order of magnitude, and for this type of gas reservoir, fracturing reform is the important means of exploratory development.The fracturing technique being applicable to exploit hypotonic, low hole unconventional reservoir obtains increasing application in shale gas reservoir exploitation.But inject water and be subject to pipeline and RKB and flow the obstruction of shear-stress, fluid displacement can reduce greatly.The frictional resistance of effective reduction liquid can reduce the demand to equipment, reduces construction cost to a certain extent.Therefore, in order to lower frictional resistance, generally need in slippery water fracturing liquid to add flow improver additive.
Water-based drag reducer is the earliest polymkeric substance, but the viscosity of solution polymer product own is large, and polymer content is low, and dissolution time is long, unstable chemcial property, brings constant greatly therefore to transport and use.It is crucial that polymer drag reducer polymer drag reducing agent is generally linear molecule, and molecular weight is greater than 500,000, but under the effect of the factors such as Strong shear power, high temperature, backbone will be destroyed, and cannot repair.Pay close attention to widely therefore, it is possible to the tensio-active agent flow improver forming vermiculate glues causes.And tensio-active agent effectively can reduce and injects contact angle between fluid and reservoir fluid, rock and surface tension, reduce the capillary force that drag reduction water flows in shale reservoir, and then improve fracturing effect.
Tensio-active agent vermiculate glues (is less than 10 under low Reynolds number
4) be present in the aqueous solution in a kind of mode of lack of alignment, flowing is sheared and does not almost act on.(10 are greater than under high Reynolds number
4), aligning of micella result in obviously drag-reduction effect.And (10 are greater than under higher Reynolds number
5), shearing force destroys vermiculate glues, and drag-reduction effect reduces fast.The Reynolds number scope that surfactant system has obvious drag-reduction effect depends on several factors, such as: total concn, proportioning, surfactant hydrophobic chain length etc.
Lot of documents shows, cats product and organic salt mixed system easily form vermiculate glues.Some of them system effectively applies to (U.S. Patent number: 4705860 in the heat exchange applications of pipeline, title, quaternaryammoniumsaltsandtheiruseasdragreductionagents), but most of cats product/organic salt system, such as cetyl trimethylammonium bromide/sodium salicylate system easily from vermiculate glues englobement micella, loses resistance reducing performance under high Reynolds number.In order to there is resistance reducing performance under high Reynolds number, needing tensio-active agent flow improver to have higher concentration, generally reaching 2000ppmw.We have synthesized oligomerization cats product now, find that the tensio-active agent of the type and the composite of organic salt effectively can reduce the concentration of flow improver formula, achieve good drag-reduction effect.Oligomerization tensio-active agent is the surfactant molecule be connected by chemical bond by two or more strand surfactant structure by linking group.According to head base in surfactant molecule and hydrophobic chain quantity, oligomerization tensio-active agent can be divided into dimerization, trimerization, four poly-and even more types such as high-polymerization degree usually.Present invention employs the complex composition of four polycation tensio-active agents and organic salt.
Summary of the invention
One of technical problem to be solved by this invention is the problem that the tensio-active agent flow improver resistance-reducing yield that exists in prior art is low, there is provided a kind of new aqueous fracturing fluid flow improver, this flow improver is used for having the advantage that resistance-reducing yield is high, working concentration is low in aqueous fracturing fluid.
Two of technical problem to be solved by this invention is preparation methods of the described aqueous fracturing fluid flow improver of one of above-mentioned technical problem.
Three of technical problem to be solved by this invention is the application in fracturing liquid of the described aqueous fracturing fluid flow improver of one of above-mentioned technical problem.
In order to one of solve the problems of the technologies described above, technical scheme of the present invention is as follows: aqueous fracturing fluid drag reducing agent composition, comprises the cats product described in formula (I) and organic acid salt; Wherein, R is the saturated or unsaturated aliphatic base containing 8 ~ 24 carbon atoms, R
1, R
2and R
6independently be selected from the alkyl of 1 ~ 4 carbon atom or the hydroxyalkyl of 2 ~ 4 carbon atoms, R
3, R
4and R
5be the alkylidene group of 1 ~ 6 carbon atom, D is the one in halide-ions;
Wherein, the weight ratio of described cats product and described organic acid salt is 1:(1 ~ 50); Described organic acid salt is selected from least one in fat carboxylate, Fatty sulphonates, fragrant hydrochlorate.
In technique scheme, R
1, R
2and R
6independent preferable methyl, ethyl or propyl group.
In technique scheme, R
3, R
4and R
5the alkylidene group of independent preferably 2 ~ 3 carbon atoms, R
3, R
4and R
5the alkylidene group of 2 ~ 3 more preferably identical carbon atoms.
In technique scheme, described fat carboxylate is preferably at least one in aliphatic alcohol polyethenoxy ether carboxylate, Fatty amine polyoxyethylene ether carboxylate; Be more preferably at least one in hydrocarbon alcohol polyethenoxy ether carboxylate, alkylamine polyethenoxy ether carboxylate; More preferably C
12~ C
18hydrocarbon alcohol polyethenoxy ether carboxylate, C
12~ C
18at least one in alkylamine polyethenoxy ether carboxylate, wherein EO segment add and number be preferably 1 ~ 20; Most preferably be C
12~ C
18hydrocarbon alcohol Soxylat A 25-7 carboxylic acid potassium, C
12~ C
18at least one in alkylamine Soxylat A 25-7 carboxylic acid potassium, wherein EO segment add and number be preferably 2 ~ 10.Described Fatty sulphonates is preferably at least one in aliphatic alcohol polyoxyethylene sulfonate, aliphatic amine polyoxyethylene ether sulfonate; Be more preferably at least one in hydrocarbon alcohol polyethenoxy ether sulphonate, alkylamine polyethenoxy ether sulphonate; More preferably C
12~ C
18hydrocarbon alcohol polyethenoxy ether sulphonate, C
12~ C
18at least one in alkylamine polyethenoxy ether sulphonate, wherein EO segment add and number be preferably 1 ~ 20; Most preferably be C
12~ C
18hydrocarbon alcohol Soxylat A 25-7 potassium sulfonate, C
12~ C
18at least one in alkylamine Soxylat A 25-7 potassium sulfonate, wherein EO segment add and number be preferably 2 ~ 10.
In technique scheme, at least one in described fragrant hydrochlorate preferred formula (II) or the fragrant hydrochlorate shown in formula (III);
Wherein, R
7preferably from-SO
3m or-COOW, M and W independent preferably H, basic metal or NH
4; X is selected from H or C
1~ C
4alkyl; Y and Z is independent preferably takes from H, fluorine, chlorine, bromine, iodine, OH; R
7more preferably-COOW.
In technique scheme, at least one in the preferred benzoate of described fragrant hydrochlorate, benzene sulfonate, halogenated benzoic acid salt, halogenated benzoic acid salt, hydroxyl-substituted formate or hydroxyl-substituted sulfonate.
In technique scheme, optimum technical scheme is: aqueous fracturing fluid flow improver, comprises the cats product described in formula (I) and fragrant hydrochlorate; Described fragrant hydrochlorate is selected from least one in formula (II) or the fragrant hydrochlorate shown in formula (III); Wherein, R is the saturated or unsaturated aliphatic base containing 12 ~ 24 carbon atoms, is more preferably the aliphatic group of 12 ~ 24 carbon atoms, more preferably the alkyl of 12 ~ 24 carbon atoms or alkylene; R
1, R
2and R
6independently be selected from the alkyl of 1 ~ 4 carbon atom or the hydroxyalkyl of 2 ~ 4 carbon atoms, R
3, R
4and R
5be the alkylidene group of 2 ~ 3 carbon atoms, D is chlorion, bromide anion or iodide ion; R
7for-COOW, W are selected from H, basic metal or NH
4; X is selected from H or C
1~ C
4alkyl; In Y and Z only one be that in OH, Y and Z, another one takes from H, fluorine, chlorine, bromine, iodine.Now the highest drag reducing efficiency can maintain more than 80%.
In technique scheme, described aqueous fracturing fluid flow improver can also comprise water, and the mass body volume concentrations of wherein said cats product and organic acid salt (as fragrant hydrochlorate) is preferably 0.1 ~ 10kg/m
3.
Aqueous fracturing fluid flow improver of the present invention can be supplied respectively in solid form for ease of accumulating, and scene is added in fracturing liquid respectively and used; Also with the supply of solid mixture form after can first mixing, scene joins in fracturing liquid and uses; Also can supply in form of an aqueous solutions for ease of onsite application.Aqueous fracturing fluid flow improver of the present invention can also comprise other conventional component of this area, such as clay stabilizer, sterilant, Scale inhibitors, pH adjusting agent, anti-fluid loss agents, emulsion splitter etc.
When the present invention adopts aqueous solution form, the form of strong solution can be adopted, dilute when deployed, or be preferably directly made into the concentration of onsite application, the preferred described cats product of concentration of onsite application and fragrant hydrochlorate amount to and account for described of the fracturing fluid 0.1 ~ 10kg/m
3.
In order to solve the problems of the technologies described above two, technical scheme of the present invention is as follows: the preparation method of aqueous fracturing fluid flow improver described in arbitrary technical scheme in the described technical scheme of one of above-mentioned technical problem, comprises the following steps:
A) preparation of described cats product
Be the compound of R-D and structural formula by the chemical formula of 4 ~ 8 times of mole numbers be (R
1r
2) NR
3n (R
1) R
4n (R
1) R
5n (R
1r
6) four reactive tertiary amines obtain described cats product;
B) described aqueous fracturing fluid flow improver preparation by step a) in obtained cats product mix in described ratio with described organic acid salt, obtain described aqueous fracturing fluid flow improver.
In technique scheme, described chemical formula is the compound of R-D and structural formula is (R
1r
2) NR
3n (R
1) R
4n (R
1) R
5n (R
1r
6) the reaction preferably back flow reaction in anhydrous ethanol medium of four tertiary amines, obtained cats product preferably in anhydrous ethanol medium recrystallization obtain; Four described tertiary amines can be such as N, N, N ', N ", N " ', N " '-hexamethyl triethylene tetramine, N, N, N ', N ", N " ', N " '-hexamethyl three propylene tetramine, N, N, N ', N ", N " ', N " '-hexamethyl three hexene tetramine etc.; Cats product can preferably further mix with water in described ratio with described organic acid salt by described mixing, and can mix with water further as paste or aqueous solution form.
In order to solve the problems of the technologies described above three, technical scheme of the present invention is as follows: the application of aqueous fracturing fluid flow improver in fracturing liquid according to any one of the described technical scheme of one of above-mentioned technical problem.
In technique scheme, preferred version is: described fracturing liquid is preferably aqueous fracturing fluid; The use temperature of described application is preferably 10 ~ 85 DEG C; The concentration that described cats product and organic acid salt amount in fracturing liquid is preferably 0.1 ~ 10kg/m
3, the fragrant hydrochlorate that described organic acid salt is preferably above-mentioned.
Fracturing liquid flow improver of the present invention is used for, in fracturing liquid, not specially requiring, can make the water quality well-known to those skilled in the art such as deionized water, clear water, river, sewage, salinity water, local water to of the fracturing fluid water quality.
The measuring method of the resistance-reducing yield of the present composition is as follows: the drag reducing efficiency of fracturing liquid flow improver uses flowing loop friction drag test macro to carry out test and obtains.Experiment test group water solution in length to be 3 meters of internal diameters the be stainless pipe of 1/2 inch along with the pressure reduction of change in flow changes.Carry out turbulent flow drag reduction flowing research time, record turbulent flow drag reduction flowing Fanning friction factor with after the result of variations of Reynolds number, by comparing with the Fanning friction factor of the water under identical Reynolds number the size obtaining drag reducing efficiency.Drag reducing efficiency DR formula is as follows, is obtained by pressure difference data:
In formula: Δ P is the pressure reduction that the flow improver fluid prepared passes through when testing pipeline, KPa;
Δ P
sfor clear water is by pressure reduction during testing conduit, KPa.
Reynolds number Re is the parameter-definition by streaming fluid:
μ is solvent viscosity, and ρ is the density of fluid, and Q is fluid flow rate, and D is internal diameter of the pipeline, therefore Reynolds number and flow proportional.The data finally obtained are the relation curve between drag reducing efficiency DR and Reynolds number.
Drag reducing efficiency size when to get fixing Reynolds number Re in the present invention be 20000 is the drag reducing efficiency of this aqueous fracturing fluid flow improver.
Key problem in technology of the present invention is the oligomerization cats product synthesized with four hydrophobic chains and four cation groups, combine with organic acid salt, especially combine with fragrant hydrochlorate, prepare efficient fracturing liquid flow improver, adopt aqueous fracturing fluid flow improver of the present invention for fracturing liquid, especially in aqueous fracturing fluid, use temperature 10 ~ 85 DEG C, working concentration 0.1 ~ 10kg/m
3condition under, resistance-reducing yield can reach 80%, obtains good technique effect.
Below by specification drawings and specific embodiments, the present invention is described in detail.
Accompanying drawing explanation
Fig. 1 is the drag reducing efficiency curve tested at 25 DEG C for embodiment 3.
Embodiment
In mass-spectrometric data in embodiment, M-Br and M-Cl represents that target molecule removes bromine atoms or target molecule removes chlorine atom respectively.
[comparative example 1]
The quality such as cetyl trimethylammonium bromide and sodium salicylate is composite, is dissolved into the friction reducer aqueous solution of obtained 2000ppmw in water, precipitates at 15 DEG C of temperature.Drag reducing efficiency under test differing temps, the highest drag reducing efficiency can remain on 65%.
[comparative example 2]
By 2.0mol bromododecane, 0.5molN, N, N ', N ", N " ', " '-hexamethyl triethylene tetramine, 300g dehydrated alcohol join in the 2000ml reaction flask being furnished with sealing machine stirring, thermometer, condenser west tube, receiving flask N in the lump; oil bath temperature 100 DEG C, reaction backflow 72h.The product the obtained recrystallization in dehydrated alcohol that cools down obtains white solid, confirms as target product four polycation tensio-active agent 12-2-12-2-12-2-12 [MS-ESI (m/z): theoretical value, 1226 by mass spectrum; Actual value, 226.5 (M/4 – Br)].The quality such as 12-2-12-2-12-2-12 and sodium lauryl sulphate is composite, and the aqueous solution of obtained 1000ppmw, does not have drag-reduction effect.
[embodiment 1]
The mass ratio mixing such as the product four polycation tensio-active agent 12-2-12-2-12-2-12 that comparative example 2 is obtained and benzene sulfonic acid sodium salt.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 60%.
[embodiment 2]
The mass ratio mixing such as the product four polycation tensio-active agent 12-2-12-2-12-2-12 that comparative example 2 is obtained and Sodium Benzoate.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 75%.
[embodiment 3]
The mass ratio mixing such as the product four polycation tensio-active agent 12-2-12-2-12-2-12 that comparative example 2 is obtained and sodium salicylate.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 80%.
[embodiment 4]
By 2.0mol bromododecane, 0.5molN, N, N ', N ", N " ', " '-hexamethyl three propylene tetramine, 300g dehydrated alcohol join in the 2000ml reaction flask being furnished with sealing machine stirring, thermometer, condenser west tube, receiving flask N in the lump; oil bath temperature 100 DEG C, reaction backflow 72h.The product the obtained recrystallization in dehydrated alcohol that cools down obtains white solid, confirms as target product four polycation tensio-active agent 12-3-12-3-12-3-12 [MS-ESI (m/z): theoretical value, 1268 by mass spectrum; Actual value, 237 (M/4 – Br)].The mass ratio such as 12-3-12-3-12-3-12 and sodium salicylate mixes.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 80%.
[embodiment 5]
By 2.0mol bromotetradecane, 0.5molN, N, N ', N ", N " ', " '-hexamethyl three propylene tetramine, 300g dehydrated alcohol join in the 2000ml reaction flask being furnished with sealing machine stirring, thermometer, condenser west tube, receiving flask N in the lump; oil bath temperature 100 DEG C, reaction backflow 72h.The product the obtained recrystallization in dehydrated alcohol that cools down obtains white solid, confirms as target product four polycation tensio-active agent 14-3-14-3-14-3-14 [MS-ESI (m/z): theoretical value, 1380 by mass spectrum; Actual value, 265 (M/4 – Br)].The mass ratio such as 14-3-14-3-14-3-14 and sodium salicylate mixes.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 80%.
[embodiment 6]
By 2.0mol bromohexadecane, 0.5molN, N, N ', N ", N " ', " '-hexamethyl three propylene tetramine, 300g dehydrated alcohol join in the 2000ml reaction flask being furnished with sealing machine stirring, thermometer, condenser west tube, receiving flask N in the lump; oil bath temperature 100 DEG C, reaction backflow 72h.The product the obtained recrystallization in dehydrated alcohol that cools down obtains white solid, confirms as target product four polycation tensio-active agent 16-3-16-3-16-3-16 [MS-ESI (m/z): theoretical value, 1492 by mass spectrum; Actual value, 293 (M/4 – Br)].The mass ratio such as 16-3-16-3-16-3-16 and sodium salicylate mixes.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 80%.
[embodiment 7]
1mol oleyl alcohol, 0.02molN, dinethylformamide adds in 1000ml reaction flask in the lump, oil bath temperature 40 DEG C, and 1.1mol146g thionyl chloride adds gradually, and 1.5h drips off, and continues backflow 2h afterwards, and intensification oil bath temperature 80 DEG C continues backflow 2h.Oil pump revolves steaming and obtains sterling chloro octadecylene hydrocarbon 0.95mol.Reactant oleyl alcohol is not had in infrared display product.By 2.0mol chloro octadecylene hydrocarbon, 0.5molN, N, N ', N ", N " ', " '-hexamethyl three propylene tetramine, 300g dehydrated alcohol join in the 2000ml reaction flask being furnished with sealing machine stirring, thermometer, condenser west tube, receiving flask N in the lump; oil bath temperature 100 DEG C, reaction backflow 72h.The colod-application n-hexane of the product obtained, obtains white solid precipitation, confirms as target product four polycation tensio-active agent 18-3-18-3-18-3-18 [MS-ESI (m/z): theoretical value, 1418 by mass spectrum; Actual value, 319 (M/4 – Cl)].The mass ratio such as 18-3-18-3-18-3-18 and sodium salicylate mixes.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 25 DEG C, drag reducing efficiency remains on 80%.
[embodiment 8]
The mass ratio mixing such as the product four polycation tensio-active agent 12-2-12-2-12-2-12 that comparative example 2 is obtained and sodium salicylate.Be dissolved into the settled solution of obtained 1000ppmw in water, the drag reducing efficiency at testing 10 DEG C, drag reducing efficiency remains on 80%.
[embodiment 9]
The mass ratio mixing such as the product four polycation tensio-active agent 12-2-12-2-12-2-12 that comparative example 2 is obtained and sodium salicylate.Be dissolved into the settled solution of obtained 5000ppmw in water, the drag reducing efficiency at testing 85 DEG C, drag reducing efficiency remains on 50%.
Table 1
| Composition | The highest drag reducing efficiency | |
| Comparative example 1 | Cetyl trimethylammonium bromide, sodium salicylate | 65％(25℃) |
| Comparative example 2 | 12-2-12-2-12-2-12, sodium lauryl sulphate | 0(25℃) |
| Embodiment 1 | 12-2-12-2-12-2-12 and benzene sulfonic acid sodium salt | 66％(25℃) |
| Embodiment 2 | 12-2-12-2-12-2-12 and Sodium Benzoate | 76％(25℃) |
| Embodiment 3 | 12-2-12-2-12-2-12 and sodium salicylate | 81％(25℃) |
| Embodiment 4 | 12-3-12-3-12-3-12 and sodium salicylate | 82％(25℃) |
| Embodiment 5 | 14-3-14-3-14-3-14 and sodium salicylate | 82％(25℃) |
| Embodiment 6 | 16-3-16-3-16-3-16 and sodium salicylate | 83％(25℃) |
| Embodiment 7 | 18-3-18-3-18-3-18 and sodium salicylate | 83％(25℃) |
| Embodiment 8 | 12-2-12-2-12-2-12 and sodium salicylate | 81％(10℃) |
| Embodiment 9 | 12-2-12-2-12-2-12 and sodium salicylate | 65％(85℃) |
Claims (10)
1. aqueous fracturing fluid flow improver, comprises the cats product described in formula (I) and organic acid salt; Wherein, R is the saturated or unsaturated aliphatic base containing 8 ~ 24 carbon atoms, R
1, R
2and R
6independently be selected from the alkyl of 1 ~ 4 carbon atom or the hydroxyalkyl of 2 ~ 4 carbon atoms, R
3, R
4and R
5independently be selected from the alkylidene group of 1 ~ 6 carbon atom, D is the one in halide-ions;
Wherein, the weight ratio of described cats product and described organic acid salt is 1:(1 ~ 50); Described organic acid salt is selected from least one in fat carboxylate, Fatty sulphonates, fragrant hydrochlorate.
2. aqueous fracturing fluid flow improver according to claim 1, is characterized in that described fragrant hydrochlorate is selected from least one in formula (II) or the fragrant hydrochlorate shown in formula (III);
Wherein, R
7be selected from-SO
3m or-COOW, M and W are independently selected from H, basic metal or NH
4; X is selected from H or C
1~ C
4alkyl; Y and Z independently takes from H, fluorine, chlorine, bromine, iodine, OH.
3. aqueous fracturing fluid flow improver according to claim 1, is characterized in that R
1, R
2and R
6independently be selected from methyl, ethyl or propyl group.
4. aqueous fracturing fluid flow improver according to claim 1, is characterized in that R
3, R
4and R
5independently be selected from the alkylidene group of 2 ~ 6 carbon atoms.
5. aqueous fracturing fluid flow improver according to claim 1, is characterized in that described fragrant hydrochlorate is selected from least one in benzoate, benzene sulfonate, halogenated benzoic acid salt, halogenated benzoic acid salt, hydroxyl-substituted formate or hydroxyl-substituted sulfonate.
6. aqueous fracturing fluid flow improver according to claim 2, is characterized in that R
7be selected from-COOW.
7. the preparation method of the aqueous fracturing fluid flow improver described in claim 1 ~ 6, comprises the following steps:
A) preparation of described cats product
Be the compound of R-D and structural formula by the chemical formula of 4 ~ 8 times of mole numbers be (R
1r
2) NR
3n (R
1) R
4n (R
1) R
5n (R
1r
6) four reactive tertiary amines obtain described cats product;
B) preparation of described aqueous fracturing fluid flow improver
By step a) in obtained cats product mix in described ratio with described organic acid salt, obtain described aqueous fracturing fluid flow improver.
8. the application of aqueous fracturing fluid flow improver in fracturing liquid according to any one of claim 1 to 6.
9. according to Claim 8 described in the application of aqueous fracturing fluid flow improver in fracturing liquid, it is characterized in that described fracturing liquid comprises water, wherein said cats product and organic acid salt amount to and account for described of the fracturing fluid concentration is 0.1 ~ 10kg/m
3.
10. the application of aqueous fracturing fluid flow improver according to claim 8 in fracturing liquid, is characterized in that the temperature of described application is 10 ~ 85 DEG C.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590610A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Water-based fracturing fluid drag reducer and applications thereof |
| CN108192587A (en) * | 2017-12-19 | 2018-06-22 | 北京捷贝通石油技术有限公司 | A kind of shale gas pressure break multifunctional cleaning drag reducer and preparation method thereof |
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| WO2001018147A1 (en) * | 1999-09-07 | 2001-03-15 | Crompton Corporation | Quaternary ammonium salts as thickening agents for aqueous systems |
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2014
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2001018147A1 (en) * | 1999-09-07 | 2001-03-15 | Crompton Corporation | Quaternary ammonium salts as thickening agents for aqueous systems |
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| 张海龙: "清洁压裂液研制与应用", 《中国优秀硕士论文全文数据库 工程科技I辑》 * |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590610A (en) * | 2015-10-20 | 2017-04-26 | 中国石油化工股份有限公司 | Water-based fracturing fluid drag reducer and applications thereof |
| CN106590610B (en) * | 2015-10-20 | 2022-04-01 | 中国石油化工股份有限公司 | Water-based fracturing fluid drag reducer and application thereof |
| CN108192587A (en) * | 2017-12-19 | 2018-06-22 | 北京捷贝通石油技术有限公司 | A kind of shale gas pressure break multifunctional cleaning drag reducer and preparation method thereof |
| CN108192587B (en) * | 2017-12-19 | 2020-05-01 | 北京捷贝通石油技术有限公司 | Multifunctional clean drag reducer for shale gas fracturing and preparation method thereof |
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|---|---|
| CN105315983B (en) | 2018-06-08 |
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