CN105295140A - Elastic antiskid shoe material and preparation method thereof - Google Patents

Elastic antiskid shoe material and preparation method thereof Download PDF

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Publication number
CN105295140A
CN105295140A CN201510862338.2A CN201510862338A CN105295140A CN 105295140 A CN105295140 A CN 105295140A CN 201510862338 A CN201510862338 A CN 201510862338A CN 105295140 A CN105295140 A CN 105295140A
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China
Prior art keywords
weight
parts
preventing shoes
resilient slip
stir
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Pending
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CN201510862338.2A
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Chinese (zh)
Inventor
陈卫江
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Wujiang Fengshang Shoe Factory
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Wujiang Fengshang Shoe Factory
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Priority to CN201510862338.2A priority Critical patent/CN105295140A/en
Publication of CN105295140A publication Critical patent/CN105295140A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an elastic antiskid shoe material and a preparation method thereof. The elastic antiskid shoe material is prepared from the following components in parts by weight: 75 to 80 parts of butadiene styrene rubber elastomer, 20 to 30 parts of polyvinyl chloride (PVC), 8 to 13 parts of PET (polyethylene terephthalate), 8 to 11 parts of polyamide fiber, 4 to 7 parts of chlorinated paraffin, 3 to 6 parts of barium oxide, 1 to 2 parts of sodium tripolyphosphate, 1 to 2 parts of trimethylolpropane triacrylate, 0.5 to 3 parts of diphenylmethane diisocyanate, 0.5 to 1 part of triallyl isocyanurate and 0.5 to 1 part of ammonium molybdate. The invention also provides the preparation method of the elastic antiskid shoe material.

Description

A kind of resilient slip-preventing shoes material and preparation method thereof
Technical field
The invention belongs to on-slip shoes material field, particularly a kind of resilient slip-preventing shoes material and preparation method thereof.
Background technology
Footwear are that people go on a journey requisite articles for use, the of a great variety of footwear is selected for various people, people are not identical to the requirement of footwear yet, but non-skid property is people institute common prescription, because in the road surface of snow and ice cover and rainy day easy ways section, the not anti-skidding footwear of dress are easy to fall down, some meetings therefore tumble injury, particularly old man and child Geng Yi tumble injury.
The quality of material for sole of shoe is except non-skid property, and its elasticity and wear resistance are also the very large influence factors determining shoes comfort levels, meanwhile, sole in use between longer rear easy jaundice, tell frost, compressive property can reduce.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of resilient slip-preventing shoes material and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of resilient slip-preventing shoes material, be made up of the component comprising following weight part:
Styrene-butadiene rubber(SBR) elastomerics 75-80 part,
Polyvinyl chloride 20-30 part,
Polyethylene terephthalate 8-13 part,
Tynex 8-11 part,
Clorafin 4-7 part,
Barium oxide 3-6 part,
Tripoly phosphate sodium STPP 1-2 part,
Viscoat 295 1-2 part,
Diphenylmethanediisocyanate 0.5-3 part,
Cyamelide triallyl 0.5-1 part,
Ammonium molybdate 0.5-1 part.
Described component also comprises metasilicic acid trimethyl 0-2 weight part.
Described component also comprises toner 0-1 weight part.
Described barium oxide is nano oxidized barium, and the particle diameter of described nano oxidized barium is 20-30 nanometer.
A preparation method for resilient slip-preventing shoes material, the method comprises the following steps:
(1) take styrene-butadiene rubber(SBR) elastomerics 75-80 weight part, polyvinyl chloride 20-30 weight part, polyethylene terephthalate 8-13 weight part, tynex 8-11 weight part, clorafin 4-7 weight part, Viscoat 295 1-2 weight part, diphenylmethanediisocyanate 0.5-3 weight part, ammonium molybdate 0.5-1 weight part, metasilicic acid trimethyl 0-2 weight part and toner 0-1 weight part, stir at 40-60 DEG C;
(2) in reactor, add barium oxide 3-6 weight part, cyamelide triallyl 0.5-1 weight part, stir 5-10 minute, add tripoly phosphate sodium STPP 1-2 weight part, 10-15 minute is stirred at 60-75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 180-190 DEG C, and the time is 3-5 minute.
Compared with prior art, its beneficial effect is in the present invention:
(1) the resilient slip-preventing shoes material that obtains of the present invention, by adding styrene-butadiene rubber(SBR) elastomerics, polyvinyl chloride, polyethylene terephthalate, tynex, clorafin, barium oxide, tripoly phosphate sodium STPP, Viscoat 295, diphenylmethanediisocyanate, cyamelide triallyl and ammonium molybdate, obtained resilient slip-preventing shoes material has good elasticity and non-skid property, and has good processability.
(2) the resilient slip-preventing shoes material treatment process that obtains of the present invention is simple, has good water-repellancy and ageing resistance, after longer duration of service, color still can be kept constant, there will not be yellowing phenomenon.
(3) resilient slip-preventing shoes material of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) take styrene-butadiene rubber(SBR) elastomerics 75kg, polyvinyl chloride 20kg, polyethylene terephthalate 8kg, tynex 8kg, clorafin 4kg, Viscoat 295 1kg, diphenylmethanediisocyanate 0.5kg and ammonium molybdate 0.5kg, stir at 40 DEG C;
(2) in reactor, add barium oxide 3kg, the cyamelide triallyl 0.5kg that particle diameter is 20 nanometers, stir 5 minutes, add tripoly phosphate sodium STPP 1kg, stir 15 minutes at 60 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 180 DEG C, and the time is 3 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Embodiment 2
(1) take styrene-butadiene rubber(SBR) elastomerics 75kg, polyvinyl chloride 20kg, polyethylene terephthalate 8kg, tynex 8kg, clorafin 4kg, Viscoat 295 1kg, diphenylmethanediisocyanate 0.5kg, ammonium molybdate 0.5kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 40 DEG C;
(2) in reactor, add barium oxide 3kg, the cyamelide triallyl 0.5kg that particle diameter is 20 nanometers, stir 5 minutes, add tripoly phosphate sodium STPP 1kg, stir 15 minutes at 60 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 180 DEG C, and the time is 3 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Embodiment 3
(1) take styrene-butadiene rubber(SBR) elastomerics 80kg, polyvinyl chloride 30kg, polyethylene terephthalate 13kg, tynex 11kg, clorafin 7kg, Viscoat 295 2kg, diphenylmethanediisocyanate 3kg, ammonium molybdate 1kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 60 DEG C;
(2) in reactor, add barium oxide 6kg, the cyamelide triallyl 1kg that particle diameter is 30 nanometers, stir 10 minutes, add tripoly phosphate sodium STPP 2kg, stir 10 minutes at 75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 190 DEG C, and the time is 5 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Embodiment 4
(1) take styrene-butadiene rubber(SBR) elastomerics 80kg, polyvinyl chloride 30kg, polyethylene terephthalate 13kg, tynex 11kg, clorafin 4kg, Viscoat 295 1kg, diphenylmethanediisocyanate 0.5kg, ammonium molybdate 0.5kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 60 DEG C;
(2) in reactor, add barium oxide 6kg, the cyamelide triallyl 1kg that particle diameter is 30 nanometers, stir 10 minutes, add tripoly phosphate sodium STPP 2kg, stir 10 minutes at 75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 190 DEG C, and the time is 5 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Embodiment 5
(1) take styrene-butadiene rubber(SBR) elastomerics 78kg, polyvinyl chloride 25kg, polyethylene terephthalate 10kg, tynex 9kg, clorafin 5kg, Viscoat 295 1.5kg, diphenylmethanediisocyanate 2kg, ammonium molybdate 0.8kg, metasilicic acid trimethyl 1kg and toner 0.5kg, stir at 50 DEG C;
(2) in reactor, add barium oxide 4kg, the cyamelide triallyl 0.8kg that particle diameter is 25 nanometers, stir 8 minutes, add tripoly phosphate sodium STPP 1.5kg, stir 12 minutes at 65 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 185 DEG C, and the time is 4 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Comparative example 1
(1) take styrene-butadiene rubber(SBR) elastomerics 80kg, polyvinyl chloride 30kg, polyethylene terephthalate 13kg, tynex 11kg, diphenylmethanediisocyanate 3kg, ammonium molybdate 1kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 60 DEG C;
(2) in reactor, add barium oxide 6kg, the cyamelide triallyl 1kg that particle diameter is 30 nanometers, stir 10 minutes, add tripoly phosphate sodium STPP 2kg, stir 10 minutes at 75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 190 DEG C, and the time is 5 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Comparative example 2
(1) take styrene-butadiene rubber(SBR) elastomerics 80kg, polyvinyl chloride 30kg, polyethylene terephthalate 13kg, tynex 11kg, clorafin 7kg, Viscoat 295 2kg, diphenylmethanediisocyanate 3kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 60 DEG C;
(2) in reactor, add barium oxide 6kg, the cyamelide triallyl 1kg that particle diameter is 30 nanometers, stir 10 minutes, add tripoly phosphate sodium STPP 2kg, stir 10 minutes at 75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 190 DEG C, and the time is 5 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Comparative example 3
(1) take styrene-butadiene rubber(SBR) elastomerics 80kg, polyvinyl chloride 30kg, polyethylene terephthalate 13kg, tynex 11kg, clorafin 7kg, Viscoat 295 2kg, ammonium molybdate 1kg, metasilicic acid trimethyl 2kg and toner 1kg, stir at 60 DEG C;
(2) in reactor, add barium oxide 6kg, the cyamelide triallyl 1kg that particle diameter is 30 nanometers, stir 10 minutes, add tripoly phosphate sodium STPP 2kg, stir 10 minutes at 75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
The temperature of a described ejection formation is 190 DEG C, and the time is 5 minutes.
The performance test results of obtained resilient slip-preventing shoes material is as shown in table 1.
Table 1
Test event Tearing toughness (KN/m) Extensibility (%)
Embodiment 1 29 145
Embodiment 2 28 143
Embodiment 3 38 155
Embodiment 4 37 141
Embodiment 5 35 149
Comparative example 1 16 87
Comparative example 2 14 84
Comparative example 3 15 88
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.

Claims (6)

1. a resilient slip-preventing shoes material, is characterized in that, is made up of the component comprising following weight part:
Styrene-butadiene rubber(SBR) elastomerics 75-80 part,
Polyvinyl chloride 20-30 part,
Polyethylene terephthalate 8-13 part,
Tynex 8-11 part,
Clorafin 4-7 part,
Barium oxide 3-6 part,
Tripoly phosphate sodium STPP 1-2 part,
Viscoat 295 1-2 part,
Diphenylmethanediisocyanate 0.5-3 part,
Cyamelide triallyl 0.5-1 part,
Ammonium molybdate 0.5-1 part.
2. resilient slip-preventing shoes material according to claim 1, it is characterized in that, described component also comprises metasilicic acid trimethyl 0-2 weight part.
3. resilient slip-preventing shoes material according to claim 1, it is characterized in that, described component also comprises toner 0-1 weight part.
4. resilient slip-preventing shoes material according to claim 1, it is characterized in that, described barium oxide is nano oxidized barium, and the particle diameter of described nano oxidized barium is 20-30 nanometer.
5. a preparation method for resilient slip-preventing shoes material, is characterized in that, the method comprises the following steps:
(1) take styrene-butadiene rubber(SBR) elastomerics 75-80 weight part, polyvinyl chloride 20-30 weight part, polyethylene terephthalate 8-13 weight part, tynex 8-11 weight part, clorafin 4-7 weight part, Viscoat 295 1-2 weight part, diphenylmethanediisocyanate 0.5-3 weight part, ammonium molybdate 0.5-1 weight part, metasilicic acid trimethyl 0-2 weight part and toner 0-1 weight part, stir at 40-60 DEG C;
(2) in reactor, add barium oxide 3-6 weight part, cyamelide triallyl 0.5-1 weight part, stir 5-10 minute, add tripoly phosphate sodium STPP 1-2 weight part, 10-15 minute is stirred at 60-75 DEG C, banburying, an ejection formation, obtains resilient slip-preventing shoes material.
6. the preparation method of resilient slip-preventing shoes material as claimed in claim 5, it is characterized in that, the temperature of a described ejection formation is 180-190 DEG C, and the time is 3-5 minute.
CN201510862338.2A 2015-12-01 2015-12-01 Elastic antiskid shoe material and preparation method thereof Pending CN105295140A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1159460A (en) * 1996-03-12 1997-09-17 韩国鞋和皮革研究所 Thermoplastic PVC foam composition
CN101709127A (en) * 2009-12-07 2010-05-19 陆颂裕 PVC elastomer material
CN101921491A (en) * 2010-08-23 2010-12-22 东莞市启原实业有限公司 Wood plastic composite material
CN103589016A (en) * 2013-10-18 2014-02-19 青岛科技大学 Composite material for anti-slip soles and preparation method of composite material
CN104017288A (en) * 2013-02-28 2014-09-03 章磊 Heat-resistant, wear-resistant and aging-resistant PVC (Polyvinyl Chloride) elastomer material
CN104292543A (en) * 2014-09-22 2015-01-21 刘丽 Antiskid rubber shoe sole
CN104672515A (en) * 2013-12-01 2015-06-03 朱伟萍 Antiskid wear-resistant sole material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1159460A (en) * 1996-03-12 1997-09-17 韩国鞋和皮革研究所 Thermoplastic PVC foam composition
CN101709127A (en) * 2009-12-07 2010-05-19 陆颂裕 PVC elastomer material
CN101921491A (en) * 2010-08-23 2010-12-22 东莞市启原实业有限公司 Wood plastic composite material
CN104017288A (en) * 2013-02-28 2014-09-03 章磊 Heat-resistant, wear-resistant and aging-resistant PVC (Polyvinyl Chloride) elastomer material
CN103589016A (en) * 2013-10-18 2014-02-19 青岛科技大学 Composite material for anti-slip soles and preparation method of composite material
CN104672515A (en) * 2013-12-01 2015-06-03 朱伟萍 Antiskid wear-resistant sole material and preparation method thereof
CN104292543A (en) * 2014-09-22 2015-01-21 刘丽 Antiskid rubber shoe sole

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吕常钦: "《丙烯酸及酯生产与管理》", 31 July 2009, 北京:中国石化出版社 *
李和平: "《含氯精细化学品》", 30 June 2010, 北京:化学工业出版社 *

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Application publication date: 20160203