CN105293703B - A kind of multifunctional combination filler for the novel aeration chinampa of eutrophication water in-situ immobilization - Google Patents
A kind of multifunctional combination filler for the novel aeration chinampa of eutrophication water in-situ immobilization Download PDFInfo
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- CN105293703B CN105293703B CN201510868422.5A CN201510868422A CN105293703B CN 105293703 B CN105293703 B CN 105293703B CN 201510868422 A CN201510868422 A CN 201510868422A CN 105293703 B CN105293703 B CN 105293703B
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Abstract
The invention discloses a kind of multifunctional combination fillers for the novel aeration chinampa of eutrophication water in-situ immobilization, have both pollutant and intercept, adsorb enrichment and biomembrane purification effect, substantially increase purification efficiency.Novel compositions filler includes outer shell and inside stuffing.Outer shell is made of polyethylene or polypropylene, is the hollow cubic bodily form of six face hollow outs, including main body and two squares.The inner cavity of plastic casing is divided into space at upper and lower two, the inorganic filtrate of lower space loaded particles by movable plastic wire, and upper space has loaded the particle organic filler of biofilm carrier effect and played the hollow float ball of floating.The invention avoids the blockings of the stacking of filler, water passing rate is high, it is combined using organic filler with inorganic filtrate, and different environment uses the inorganic filler of different formulations, microbial activity and detergent power are improved, and the filler keeps chinampa convenient for management using concealed floating body is dispersed, using flexible, it is handsome in appearance.
Description
Technical field
The present invention relates to the granular pattern multifunctional combination fillers of a kind of organic filler and inorganic filtrate, fill out for novel aeration
In the water purification technology for expecting chinampa, belong to restoration of the ecosystem field.
Background technique
As a large amount of nitrogen phosphorus enter water body, leads to the eutrophication of water field of big area, seriously affected expanding economy
With the life of resident.For the water body of eutrophication, every country and area using different physics, chemistry, biological method into
Row is administered, and has repaired the water body of eutrophication to a certain extent.It largely practices and studies have shown that ecological restoring method obtains
The universal approval of researcher.Artificial floating island is as one of water body in-situ recovery technique, compared to more other biological prosthetic
Technology has the advantages that significant.Water body environment is repaired using the absorption of plant and the catharsis of microorganism in chinampa, seeks to richness
Feedingization water quality has preferable catharsis;It is flexible in application, various water bodys are applicable to, and can be made various sizes, just
In transport;Chinampa can also beautify water environment, so, floating island technique is increasingly valued by people.
With the continuous development of floating island technique, researcher has found some disadvantages on traditional chinampa, such as plant type chinampa
It is seasonal obvious, and mainly by the pollutant in the harvesting removal water body of plant, not manageability, and the plant gathered in mostly at
For solid refuse, it is difficult to handle.In order to solve this problem, researcher has developed novel aerating filling chinampa, this kind floating
Island relies primarily on the biomembrane purification of filler, does not depend on plant, convenient for management, and has combined absorption interception function, strengthens and exposes
The technologies such as gas and plug-flow, effectively raise the clean-up effect on chinampa.
Currently used for the filler of floating island technique, there are two main classes, and one kind is organic filler, including fiber filler beam (soft,
Semi-soft and compounded mix) and granular pattern floating stuffing it is (annular packing, column filler, polyhedron empty ball homogeneous filler, built-in
Filler and porous rotation ball-shaped filling material);The inorganic filler of another kind of predominantly light granules type, such as steel slag, zeolite etc..Comparison
Corpuscular filler, fiber bundle-like filler greatly reduce filler using conglomeration, clogging is easy to happen after a period of time
Available specific surface area influences its clean-up effect.
In order to improve dirt-removing power, researcher has done a large amount of research and innovation to filler, in the direction for improving filler
Constantly break through.Inorganic filler has preferable absorption property, can intercept the pollutant in water, and researcher is by some light-weight inorganics
It is used in chinampa after modification of filtration medium, achieves certain clean-up effect.It thanks to long blood et al. and has invented a kind of hanging for biological film process
Floating filler, is fabricated by volcanic rock powder, rubber powder and adhesive, is suitble to the Absorption Growth of microorganism, is easy to fluidize, mention
High treatment effeciency (application number 200910077129.1).Wen Baozhong et al. has invented a kind of active composite biological packing, by carrying
Body base-material and functional auxiliary material form porous carrier, and one layer of porous active powder substance is bonded on through-hole ball external surface
Layer, preferably improves the absorption property of filler, enhances the treatment effeciency (application number of COD and ammonia nitrogen
201210040598.8).Land rings et al. less has invented a kind of Suspension ceramsite filter material, is crushed using shale, powder processed, firing, sieve
Floating haydite is obtained after choosing, effectively raises specific surface area and mechanical strength, is suitble to the processing (application number of micro polluted source
201310239044.5).Although this kind of filler, by being modified, its essence is still inorganic filler, and there is no fundamentally change
The shortcomings that detergent power is lost after the disadvantage and adsorption saturation of carrier surface forming biofilm property difference.
The shortcomings that in order to overcome inorganic filler, the stability of filler detergent power is maintained, researcher fills out organic granular
Material has done numerous studies as floating stuffing.Han Hongjun has invented a kind of floating stuffing for sewage treatment, using soft or
Various shape is made in semi-soft resistant material, and vertical fin is arranged on surface, is effectively increased the specific surface area of filler
(application number 200410013528.9).Wangkai et al. has invented a kind of suspension water treatment filler, and helical structure greatly improved
The effective surface area of filler, and toxicity bioassay is not easily caused, there is excellent water treatmenting performance (application number
201010511103.6).This kind of filler, which mainly passes through, changes shape, structure to increase specific surface area, and then increases microbial biomass,
But its specific surface area amplification is limited, so the effect is unsatisfactory.Zhourong is rich et al. to have invented a kind of Wedge and plug-in combined suspending filling material,
The various fillers of plastic casing and internal attached microbial including outer layer, by effectively being further increased using space
The specific surface area (application 200610117939.1) of filler.It has invented a kind of efficient hollow grid shape spherical suspending and has filled out in Wuchuan et al.
Material, soft coarse fiber filament is wound on spherical structure, not only increases the specific surface area of filler, and will not cause fibre
It ties up silk conglomeration and causes waste (application number 200810200621.9).This kind of filler is intended to increase specific surface area by a larger margin,
But still without the inertia for fundamentally changing filler itself and increase biomembrane activity.
In order to further strengthen the detergent power of filler, researcher has also been made relevant from the modified angle of organic filler
Research.Tian Shuanhong et al. has invented a kind of suspended biological filler of porous surface, porous polymer materials bonding is coated to poly-
On olefin plastics skeleton, the hydraulic characteristic of filler is increased, can effectively retain the activated sludge of inoculation, promotes microorganism
Increment and metabolism (application number 201010154425.X).A kind of improved plastic filler of concrete has been invented by Wang Xiao army et al.,
It is attached to a layer concrete in frosting, improves the hydrophily of frosting, can effectively be improved micro- in water treatment system
The biofilm speed and biofilm intensity of biology.This kind of filler overcomes the inertia of filler itself by being modified to a certain extent, but
Its coat can reduce the specific surface area of script filler instead, cause the waste of material, and its production process is complicated, undoubtedly compared with
Big increases cost, it is difficult to promote.In order to overcome this disadvantage, Sui Jun et al. from change the angle of material composition to filler into
Row is modified, and has invented a kind of active filler, promotes the growth of microorganism by the way that biodegradable substance (such as starch) is added.
But the cruising ability of this kind of filler is poor, and organic matter is difficult to support the growth of excess microorganisms after decomposing completely, and can breed
Pathogenic microorganism, and the hole left also has an impact to the firmness of filler.Zhang Peng et al. has invented a kind of suspended biological
The hydrophily that magnetic powder, zeolite powder etc. improve filler is added in high density polyethylene (HDPE), increases biomembrane adsorption strength for filler.But
The characteristics of being due to production method, the functional component of this kind of filler is wrapped in the inside of plastic material more, and functional component adds
It is few to enter amount, plays a role faint, the waste of material but will be caused.
In conclusion can only improve biofilm biomass to the change of organic filler shape, structure, there is no fundamentally solved
The inertia of filler itself.Though and improving the biofilm speed of filler to a certain extent to the modification of organic filler and inorganic filler
Degree, biofilm intensity etc., but the ingredient being added is difficult to play preferable effect, and the effect is unsatisfactory, and production is complicated mostly.
Applicant early period studies have shown that a large amount of pollutants can be adsorbed to packing area by the absorption property of inorganic filler,
The pollutant of high concentration can stimulate the mass transfer to the inside of biomembrane, keep biomembrane thicker, and the combination of organic and inorganic particle
Space can be preferably utilized, the activity of biomembrane not only can be improved, but also the growth of biomembrane can be promoted, increases unit
The biofilm biomass of volume filler promotes purification of the filler to water quality.In addition, inorganic filler and organic filler will not be to ecological rings
Cause secondary hazards in border.So being a kind of higher mode of cost performance by the direct combination of organic filler and inorganic filler particle.
Scientific research personnel has done a large amount of research to this.
Zhourong is rich et al. to have invented a kind of functional suspended stuffing, and main body is that plastic plate grips particle material for water treatment
The compound wing plate being made into makes microorganism be easier to attachment and breeds (application number 03115913.3) thereon by the combination of filler.But by
Keep the utilization rate in space lower in its special structure, the density of microorganism is not high, and it is limited to improve purification of water quality ability.Tian Binghui
Et al. invented a kind of dual chamber suspended biological carrier, different environment more than general carrier, by adjusting carrier material,
Design vector chamber structure etc. forms the chamber of different purification functions, improves the efficiency (application number of biological treatment
201110102088.4).But this kind of filler is difficult to cope with the water quality of different parameters and form dual chamber environment, for example, processing is different
When the sewage of dissolved oxygen concentration, the size for needing to redesign carrier and each chamber just can guarantee different aerobic-anoxic environment,
There are higher specific aim, specificity, it is difficult to a wide range of to promote.Pan Yongzhang has invented a kind of microorganism suspended carrier of water process,
Float stone is packed into the plastics global shell of surface aperture (application number 200610132379.7), the coarse surface of carrier is suitble to micro- life
Object apposition growth substantially increases the removal efficiency of water pollutant.But its filler density is smaller, so that this kind of filler is answered
When for being aerated chinampa, the biomembrane of inner face can be fallen off due to shock and largely, the reduction effective specific surface area of filler, and its
40% filling rate is even more to have aggravated this phenomenon.
Granular pattern organic filler and inorganic filler do not easily cause secondary pollution, unlike plant chinampa due to its performance stabilization
It needs periodically to gather in, lasts a long time, be widely used in floating island technique.But the existing suspension that can be used for chinampa is filled out
Material, clean-up effect is unsatisfactory, and is easily delaminated using particle composite filling, reduced water and crosses gas rate.So for chinampa
Filler is improving detergent power, and reducing management difficulty etc., there is still a need for continue to develop and perfect.
Summary of the invention
The purpose of the invention is to overcome in the development trend of existing floating island technique, increasingly emphasis biomembrane is net
The various effects such as change, enhanced aeration, interception absorption, plant absorption are used in combination to improve the detergent power on chinampa, but existing
The effect that floating stuffing is applied to this kind of novel aerating filling chinampa is not ideal enough.And multifunctional combination filler provided by the invention
Applied in floating island technique, there is improvement in terms of detergent power, management difficulty, chinampa flexibility ratio, air water, can push away
The development of dynamic packing type floating island technique.
The technical solution of the invention is as follows provides a kind of multifunctional combination filler having following structure, overall configuration category
In one kind of granular pattern filler, including outer layer plastic shell and internal fill.
The outer shell is made of materials such as high-strength polyethylene or polypropylene, including main body and square two parts.
Main body is the hollow square bodily form of uncovered up and down of 8~10cm of side length, and there be one layer of movable plastic wire in centre, with a thickness of 1~
1.5mm.Square is mating with main body, can be buckled in main body.Six faces of the good outer shell of snapping are netted hollow out, gap
Width depending on intensity needed for the particle size of internal loaded particles and filler.Plastic wire divides the inner cavity of outer shell
For the two parts to differ in size.
The inside fill is loaded in two spaces respectively, and wherein granular pattern inorganic filler is loaded on lesser sky
Between in, hollow float ball and particle organic filler are loaded in biggish space.
The raw material of the granular pattern inorganic filler are as follows: zeolite, steel slag, haydite, cement and foaming agent.The weight of its each component
Measure percentage are as follows: zeolite accounts for about 30%~40%, and steel slag accounts for about 15%~20%, and haydite accounts for about 20%~30%, and cement is about
5%~10% is accounted for, foaming agent accounts for about 1%.The filler is ball-type or ellipsoidal particle.
The granular pattern inorganic filler the preparation method is as follows:
Bulky grain zeolite, steel slag, haydite are sieved after crushing, make its partial size no more than 80 mesh;By after sieving zeolite,
Steel slag, haydite and foaming agent are uniformly mixed according to a certain percentage, and are added water and stirred agglomerating;Partial size, which is made, in the slurry being stirred is
The ball-type or ellipsoidal particle of 10-15mm or so;Filler after being made is air-dried under field conditions (factors).
The averag density of the multifunctional combination filler are as follows: aerobic condition 1.2g/cm3, anoxia condition 1.0g/
cm3, density, one inorganic filler of each filler self-contained are adjusted according to plastic casing, organic filler and the loading of inorganic filler
With the combined system of organic filler.
The hollow float ball is bead made of polyethylene or polypropylene material, and diameter is 3~5cm, is loaded on outer
In one space of layer shell, irregular movement is done in space under the action of water flow or aeration.
Compared with prior art, the invention has the following advantages that
Multifunctional combination filler of the invention is combined using inorganic filler with organic filler, and the adsorption energy of inorganic filler is utilized
The good feature of power, pollutant is adsorbed in packing area, to improve the rate of film build on organic filler surface, it is living to increase microorganism
Property, effectively raise the purification efficiency of filler.
The filler uses loading type, and queueing discipline takes full advantage of space, improves the density of microorganism, to mentioning
The clean-up effect on high chinampa also has certain effect.
In composite filling of the invention, special type of feed fixes inorganic filler portion, avoids in water flow and exposure
Under conditions of gas, collides shell and cause the biofilm detachment of case inside.Hollow float ball and particle in another space
Organic filler then at fluidised form, effectively raises disturbance of the water body in packing area, improves coefficient of oxygen utilization, promotes pollutant to life
Mass transfer in object film.
In packing type chinampa, general packing area is an entirety, though various types of filler can be sufficiently mixed in an installation,
But be possible to during aeration can due to density difference and be gradually layered, lose the meaning of composite filling, and compared with
The inorganic particle of weight is gradually reduced, and is become closeer inorganic filler layer, can also be hindered to be aerated to a certain extent.And it is of the invention
Composite filling, each equal self-organizing system of filler, avoids filler from being layered, keeps biofilm uniform.
By adjusting organic ratio with inorganic filler under the conditions of composite filling aerobic-anoxic of the invention, reach most
Excellent proportion can further improve the denitrification effect on chinampa.
Composite filling of the invention uses concealed floating body, i.e., floats filler itself in an intracavitary filling hollow plastic ball
It floats or additional buoyancy is provided, so that chinampa is not required to peripheral hardware floating body, moulding is more attractive.
Detailed description of the invention
Fig. 1 is the plastic case structure schematic diagram of multifunctional combination filler of the invention.
Fig. 2 is the sectional side elevation of multifunctional combination filler main view of the invention.
Fig. 3 is the sectional view of multifunctional combination filler hollow float ball of the invention.
Specific embodiment
Multifunctional combination filler of the invention is described further in conjunction with attached drawing.As depicted in figs. 1 and 2, of the invention
Composite filling include outer shell 1, be set to one layer of movable plastic wire 2 of appropriate position in shell, plastic wire is by shell
The inner cavity of body is divided into space at upper and lower two, is organic filler charge space 3 and inorganic filler charge space 4, loads respectively hollow
Float ball 6, particle organic filler 7 and particulate inorganic filler 5.
Wherein, outer shell 1 is that high-strength polyethylene or polypropylene material are made, and be side length is standing for 8~10cm
Cube shape can regard concrete condition and make different size of composite filling, and wall thickness is about 1~1.5mm, the wide 3mm of grid item, if
It is higher using intensity of the water body to composite filling, can appropriate adjustment, the center spacing of adjacent two net items is no more than 1cm.Outer layer
There is the movable plastic wire 2 of layer in the inner cavity of shell 1, thickness 1mm, since its intensity requirement is lower, net width can suitably subtract
Small, inner cavity is divided into space at upper and lower two by plastic wire 2, and superposed space is larger, is organic filler charge space 3, is located at
The space of lower part is smaller, is inorganic filler space 4, depending on density of the volume in two spaces to load filler 5, final control combination
The averag density of filler is, is 1.2g/cm under aerobic condition3Or so, it is 1.0g/cm under anoxia condition3Left and right.The filler 5 of filling
For by granular filler made of the formula, partial size is 1~1.5cm.One float 6 is set in organic filler space 3, for poly- second
Alkene or polypropylene hollow bead, diameter are 3~5cm, and irregular movement can be done under the action of water flow and aeration, strengthens filler
Aqueous vapor disturbs in area.
By this kind of multifunctional combination applying filler when novel aeration chinampa, inorganic filler and hollow plastic ball are filled first
Two for being filled into shell are intracavitary, then by upper and lower two grid snappings, are loaded into the filler safeguard measure on chinampa.
Claims (4)
1. a kind of multifunctional combination filler for eutrophication water in-situ immobilization aeration chinampa, it is characterised in that: including outer
Layer shell and inside stuffing, wherein the inner cavity of outer shell is separated into space at upper and lower two by movable plastic wire;Described
Filler is loaded in the two spaces of housing cavity, and upper space loads hollow float ball and particle organic filler, and lower part is empty
Between the inorganic filtrate of loaded particles;The inorganic filtrate mainly presses following weight hundred by zeolite, steel slag, haydite, cement and foaming agent
Divide than composition: zeolite accounts for 30%~40%, and steel slag accounts for 15%~20%, and haydite accounts for 20%~30%, and cement accounts for 5%~10%,
Foaming agent accounts for 1%;The composite filling averag density is respectively 1.2g/cm under aerobic condition3;1.0g/ under anoxia condition
cm3。
2. a kind of multifunctional combination for eutrophication water in-situ immobilization aeration chinampa according to claim 1 is filled out
Material, it is characterised in that: the outer shell is made of main body and square, is all made of polyethylene or polypropylene material is made, main
Body is to have the square of plastic wire in upper and lower uncovered, and square side length is 8~10cm, square be can snapping it is latticed, inside is filled out
It fills object filling and is buckled in main body after the completion, there is hollow out in six faces of composite filling, the width view inside stuffing in gap
Depending on intensity needed for partial size and composite filling.
3. a kind of multifunctional combination for eutrophication water in-situ immobilization aeration chinampa according to claim 1 is filled out
Material, it is characterised in that: the production method is as follows break zeolite, steel slag and haydite into pieces sieving, make its partial size not the inorganic filtrate
Greater than 80 mesh;Zeolite, steel slag, haydite after cement, foaming agent and sieving is uniformly mixed according to a certain percentage, and added water and stirred
It is agglomerating;The ball-type or ellipsoidal particle that partial size is 10~15mm is made in the slurry being stirred, by manufactured filtrate in natural item
It is air-dried under part.
4. a kind of multifunctional combination for eutrophication water in-situ immobilization aeration chinampa according to claim 1 is filled out
Material, it is characterised in that: the hollow float ball is the bead that diameter made of polyethylene or polypropylene material is 3~5cm, dress
The upper space for filling in inner cavity does irregular movement under the disturbance of water flow and aeration.
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