CN105239253A - Durable flame-retardant cloth and preparation method thereof - Google Patents

Durable flame-retardant cloth and preparation method thereof Download PDF

Info

Publication number
CN105239253A
CN105239253A CN201510770451.8A CN201510770451A CN105239253A CN 105239253 A CN105239253 A CN 105239253A CN 201510770451 A CN201510770451 A CN 201510770451A CN 105239253 A CN105239253 A CN 105239253A
Authority
CN
China
Prior art keywords
retardant
fiber
preparation
cloth
ammonium salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510770451.8A
Other languages
Chinese (zh)
Other versions
CN105239253B (en
Inventor
庄银江
庄津
丁功胜
何济琛
李苑育
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Meilenstein Shenzhen Garments Co ltd
Original Assignee
Meilenstein Shenzhen Garments Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meilenstein Shenzhen Garments Co ltd filed Critical Meilenstein Shenzhen Garments Co ltd
Priority to CN201510770451.8A priority Critical patent/CN105239253B/en
Publication of CN105239253A publication Critical patent/CN105239253A/en
Application granted granted Critical
Publication of CN105239253B publication Critical patent/CN105239253B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention relates to a durable flame-retardant cloth and a preparation method thereof, and belongs to the fields of textile materials and flame-retardant materials. The durable flame-retardant cloth is prepared from, by weight, 10%-50% of long-stapled cotton fiber, 20%-70% of nylon 6 fibers and 20%-70% of polyphosphamide fibers. The method comprises the steps that 1, the raw materials of the long-stapled cotton fiber, the nylon 6 fibers and the polyphosphamide fibers are taken to be soaked in an ammonium salt solution of nano-montmorillonite for 6-24 hours; 2, the soaked long-stapled cotton fiber, nylon 6 fibers and polyphosphamide fibers are put into a combing machine to be combed, evenly mixed through a mixing machine and then spun into warp yarns and weft yarns with the count ranging from 20 to 110; 3, a cloth material obtained in the step 2 is soaked in a polyphosphamide solution to be soaked, dried and washed until no residue exists. According to the method, the nano-montmorillonite is permeated into the interior of the fibers, and polyphosphamide coagulated on the cloth surface under the high-temperature condition forms a stable flame-retardant protecting layer.

Description

A kind of Durable fire-retardant cloth and preparation method thereof
Technical field
The present invention relates to a kind of Durable fire-retardant cloth and preparation method thereof, belong to textile material and fire proofing field.
Project background
Workers In Hot Environment operating environment is severe, is necessary for it and provides fire retardant protective clothing.Fire retardant protective clothing, due to its Long-Time Service, not only requires higher lasting fire resistance, also will have good snugness of fit.Du pont company successfully have developed aromatic polyamide " Nomex " fiber in early days, and its heat resistance is very good, and limited oxygen index reaches 29, although its limited oxygen index is not very high, after it leaves burning things which may cause a fire disaster, and can self-extinguish and do not produce molten drop; Aromatic polyamide " Apyil " fiber that " Terjinconex " of Di Ren company of Japan, You Nijika company successfully develop, its limited oxygen index can reach 29% ~ 32%; Amoco Corp. of the U.S. disclosed a kind of daiamid composition in 1999, can flame retardant effect be reached and there is good anti-performance and the incoagulable patent of invention of dripping, Solutia Corp also discloses fiber prepared by the flame-retardant polymer about polymer-bound non-halogen, fabric has anti-flammability.Other is as spandex fibre cloth, acrylic fiber cloth, polyacrylic and polyester fiber cloth, fire resistant viscose acetal fibre cloth, flame-resistant terylene cloth etc., and this fibrid all also exists meets fiery melting drippage, causes skin scald, can not reach the effect of fire safety.Adopt the cloth that flame-retarding blended fibre is woven into, realize flame resistant woven processing method, high-performance fiber and cotton carry out blending or to carry out blending with fire-retardant chemical fibre and prepare fire retardant with cotton and mainly contain through flame-retardant after-finishing process series products: acrylic fibers/Nomex, cotton/Nomex, cotton/Kevlar/Nomex, spandex/fire-retardant viscose, dacron cotton/terylene/nylon cloth prepares flame retardant fabric through Final finishing; Having Tetrakis hydroxymethyl phosphonium chloride to soak to cotton fiber is fire-retardant a long time ago, make cotton fiber have certain anti-flaming function, but feel is poor, water-wash resistance is poor, all loses anti-flaming function after generally washing 5 ~ 8 times; Fire retardant is normally added surface by the fire-retardant of chemical fibre, and this technology only can realize coming to the surface fire-retardant, and its product is a lot; For making nylon 6 fire-retardant, a kind of phosphonium flame retardant adds in PA6 by Beijing Institute of Technology Liu Ji equality, adopts melt spinning method, its addition is 2% ~ 6%, and PA6 can be made fire-retardant, and it is water-fastness to permanent, but the fibrous mechanical property that this method obtains is poor, there is serious melting drippage; Studied again a kind of polymeric phosphorus-containing flame retardant afterwards to mix with nano imvite, add in monomer, polymerization obtains flame-retardant anti-dropping PA6 fiber, melt spinning obtains the fiber of 3.1d and 3.5CN/tex, can reach permanent fire-retardant, the cloth char length be prepared into thus is 155.2mm, substantially remains unchanged after washing 50 times, substantially not melting drippage; In addition, professor Xia Yanzhi also studies the fire resistant viscose acetal fibre of hand feel performance excellence, at home industrialization; Professor Wang Yuzhong has also carried out extensive research to chemical fibre is fire-retardant, also has some to achieve industrialization.By cotton and polyster fibre, aramid fiber by blending, can practical function variation, not only can reduce product price, the diversity of snugness of fit and color can also be improved.Along with the development of textile technology, the development of flame retardant textiles develops to blending field gradually.Cotton/blend polyester Final finishing and cotton/aramid fiber blending become the main method preparing flame retardant textiles.But traditional blending hindlimb unload uses fire retardant mostly to be low molecular compound, in Long-Time Service poor durability, the shortcomings such as fire resistance significantly declines, service life is short, resistance to elevated temperatures is poor and intensity is low after ubiquity washing, are difficult to use as high-grade flame retardant products.Therefore, the aggretion type flame retardant treating agent that useful life longevity is good, good with cloth compatibility effectively can improve the quality of flame retardant fabric.
Low for flame retardant fabric heating temperature, the highest refractory temperature can only reach 260 DEG C, and produces the difficult problems such as melting drippage.The present invention is then completely different from these technical methods above-mentioned, both original single fire-retardant deficiency had been overcome, reach and drip without melting, achieve again the characteristic of heatproof, also unusual on the weaving method of cloth, adopt the T-shaped weave of 3 × 3, be woven into the fire-resistance cloth of ability 260 ~ 280 DEG C of high temperature, density reaches 200 ~ 360g/m 2, cloth char length is 92.6mm ~ 135.7mm (after washing for 50 times), and intensity is high-comfort good.
Summary of the invention
The object of the invention is can only reach 260 DEG C to solve low, the highest refractory temperature of flame retardant fabric heating temperature existed in traditional blending fire retardant and after-finishing flame resistant technique, and produce the difficult problems such as melting drippage, propose a kind of Durable fire-retardant cloth and preparation method thereof.
Core content of the present invention selects long-staple cotton fiber and nylon fiber to soak post-drying in nano imvite, the raw material after immersion and poly-phosphamide fibers mixture evenly spinned, then be made into cloth; The poly-phosphamide solution impregnation of cloth, dry after being washed to noresidue, reach the effect of permanent fire retardant.
The object of the invention is to be achieved through the following technical solutions.
A kind of Durable fire-retardant cloth, its mass percent composition is as follows:
Long-staple cotton fiber 10 ~ 50%;
Nylon 6 fiber 20 ~ 70%;
Poly-phosphamide fiber 20 ~ 70%;
A preparation method for Durable fire-retardant cloth, comprises the following steps:
Step one, get long-staple cotton fiber and nylon 6 fiber, take out after soaking 6 ~ 24 hours with the ammonium salt solution of nano imvite, dry for standby;
Step 2, by long-staple cotton fiber, nylon 6 fiber and the poly-phosphamide fiber after soaking, drop in breaker beater and discongest and through confusing after machine mixes, be spun into warp thread and the weft yarn of 20 ~ 110;
Step 3, with 4 ~ 12 warp yarn be spun into and 3 ~ 9 weft yarns, be made into high-temperature-resistant cloth;
Step 4, to soak weaving the cloth that obtains 6 ~ 24 hours in the dimethyl carbonate composition soak with 10% ~ 30% poly-phosphamide and 70% ~ 90%, taking out post-drying; Durable fire-retardant cloth is obtained after washing.
Ammonium salt solution described in step one consists of quaternary ammonium salt 20% ~ 30%, nano organic montmorillonite 10% ~ 20%, ethanol 10% ~ 20%, water 30% ~ 60%; Described quaternary ammonium salt is one or both in epoxy silicones quaternary ammonium salt, amido organosilicon quaternary ammonium salt; Soaking conditions is soak 6 ~ 24h at 10 ~ 40 DEG C.
Warp thread described in step 2 is made up of 4 ~ 6 bursts of spun yarn doublings, and ultimate strength is 175.6cN ~ 279.3cN, and fracture strength is 11.7cN/tex ~ 21.2cN/tex; Weft yarn is made up of 3 ~ 7 bursts of spun yarn doublings, and ultimate strength is 126.3cN ~ 187.4cN, and fracture strength is 7.9cN/tex ~ 13.5cN/tex;
Beneficial effect
1, a Durable fire-retardant cloth, specification 200 ~ 360g/m 2,, its mechanical property is cross-breaking strength is 39.7cN/tex ~ 55.63cN/tex, and elongation at break is 41.6% ~ 61.2%, and longitudinal fracture intensity is 36.6cN/tex ~ 52.2cN/tex; Quality is soft, and comfortableness is good, antistatic property, and tinctorial yield is excellent;
2, a Durable fire-retardant cloth, keeps 60min without drippage at the temperature of 260 ~ 280 DEG C; Vertical combustion test after flame time: do not wash 0mm, wash rear 0mm 5 ~ 10 times; Ignitor firing time: do not wash 0mm, wash rear 0mm 30 ~ 50 times; Char length: do not wash 159mm ~ 210mm, washes rear 161mm ~ 212mm 30 ~ 50 times, can to prevent fires dress ornament Long-Time Service as top grade;
3, a Durable fire-retardant cloth preparation method, production method is simple, automated production, and be easy to operation, cost is low, can realize large-scale industrial production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is elaborated.
Embodiment 1
Get 40kg long-staple cotton fiber and 60kg nylon fiber, drop in HXF-1 type reciprocating breaker beater and to discongest and through confusing after machine mixes, drop in the immersion cylinder of 500L, soak in cylinder and 300kg soak is housed, soak consists of: by adding the industrial alcohol of 45kg95% in 66kg epoxy organosilicon butyl ammonium and 39kg nano organic montmorillonite, add 350kg running water after being uniformly dispersed; The cellulose mixed is dropped in soak, 12 hours are soaked 30 DEG C time, elimination soak in filter press, after dry and 230kg gather phosphamide fibers mixture, feed intake and to discongest in the reciprocating breaker beater of HXF-1 type and to mix through confusing in machine, enter people's spinning machine, spin by normal spinning process, the yarn obtained carries out doubling, forms warp yarn by 4 bursts of 90 yarn doublings, be 196.2cN through the ultimate strength of yarn after doubling, fracture strength is 13.2cN/tex; Form weft yarn by 3 bursts of 75 yarn doublings, after doubling, the ultimate strength of weft yarn is 131.7cN, and fracture strength is 8.6cN/tex; With 6 warp thread be spun into and 3 weft yarns, on WF-II type loom, the T-shaped weave of 3 × 3 is made into cloth, and weaving process adopts conputer controlled; The cloth be made into is immersed in poly-phosphamide solution, poly-phosphamide soaking solution composition: 15% poly-phosphamide and 85% dimethyl carbonate, take out hot-rolling after soaking 8h and press dry; Wash 3 times, make its noresidue, obtain 291.6g/m 2fire resistant cloth 1026.5m 2, at the temperature of 281 DEG C, keep 60min without drippage.Its mechanical property is cross-breaking strength is 41.3cN/tex, and elongation at break is 44.2%, and longitudinal fracture intensity is 40.1cN/tex; Oxygen index (OI) 36.1% before washing, oxygen index (OI) 35.5% after washing 50 times; Vertical combustion test after flame time: do not wash 0mm, wash rear 0mm 10 times; Ignitor firing time: do not wash 0mm, wash rear 0mm 50 times; Char length: do not wash 159mm, washes rear 161mm 50 times.
Embodiment 2
Get 20kg long-staple cotton fiber and 80kg nylon fiber, drop in HXF-1 type reciprocating breaker beater and to discongest and through confusing after machine mixes, drop in the immersion cylinder of 800L, soak in cylinder and 350kg soak is housed, soak consists of: by adding the industrial alcohol of 50kg95% in 40kg amido organosilicon tertiary amine and 30kg cetyl modified montmorillonoid, add 400kg running water after being uniformly dispersed; The cellulose mixed is dropped in soak, 20 hours are soaked 30 DEG C time, elimination soak in filter press, after dry and 200kg gather phosphamide fibers mixture, feed intake and to discongest in the reciprocating breaker beater of HXF-1 type and to mix through confusing in machine, enter people's spinning machine, spin by normal spinning process, the yarn obtained carries out doubling, forms warp yarn by 6 strand of 110 yarn doubling, be 206.7cN through the ultimate strength of yarn after doubling, fracture strength is 14.4cN/tex; Form weft yarn by 5 bursts of 95 yarn doublings, after doubling, the ultimate strength of weft yarn is 136.3cN, and fracture strength is 9.2cN/tex; With 8 warp thread be spun into and 5 weft yarns, on WF-II type loom, the T-shaped weave of 3 × 3 is made into cloth, and weaving process adopts conputer controlled; The cloth be made into is immersed in poly-phosphamide solution, poly-phosphamide soaking solution composition: 12% poly-phosphamide and 88% dimethyl carbonate, take out hot-rolling after soaking 16h and press dry; Wash 5 times, make its noresidue, obtain 283.1g/m 2fire resistant cloth 997m 2, at the temperature of 273 DEG C, keep 60min without drippage.Its mechanical property is cross-breaking strength is 43.2cN/tex, and elongation at break is 57.3%, and longitudinal fracture intensity is 43.3cN/tex; Oxygen index (OI) 37.0% before washing, oxygen index (OI) 36.2% after washing 30 times; Vertical combustion test after flame time: do not wash 0mm, wash rear 0mm 10 times; Ignitor firing time: do not wash 0mm, wash rear 0mm 50 times; Char length: do not wash 160mm, washes rear 161mm 30 times.
Embodiment 3
Get 10kg long-staple cotton fiber and 90kg nylon fiber, drop in HXF-1 type reciprocating breaker beater and to discongest and through confusing after machine mixes, drop in the immersion cylinder of 800L, soak in cylinder and 350kg soak is housed, soak consists of: by adding the industrial alcohol of 60kg95% in 35kg amido organosilicon tertiary amine and 35kg cetyl modified montmorillonoid, add 470kg running water after being uniformly dispersed; The cellulose mixed is dropped in soak, 24 hours are soaked 30 DEG C time, elimination soak in filter press, after dry and 220kg gather phosphamide fibers mixture, feed intake and to discongest in the reciprocating breaker beater of HXF-1 type and to mix through confusing in machine, enter people's spinning machine, spin by normal spinning process, the yarn obtained carries out doubling, forms warp yarn by 4 strands of 95 yarns and 1 burst of 110 yarn doubling, be 193.6cN through the ultimate strength of yarn after doubling, fracture strength is 13.7cN/tex; Form weft yarn by 2 strands of 85 yarns and 1 strand of 20 yarn and 1 burst of 60 yarn doubling, after doubling, the ultimate strength of weft yarn is 131.1cN, and fracture strength is 8.7cN/tex; With 8 warp thread be spun into and 5 weft yarns, on WF-II type loom, the T-shaped weave of 3 × 3 is made into cloth, and weaving process adopts conputer controlled; The cloth be made into is immersed in poly-phosphamide solution, poly-phosphamide soaking solution composition: 10% poly-phosphamide and 90% dimethyl carbonate, take out hot-rolling after soaking 24h and press dry; Wash 4 times, make its noresidue, obtain 271.5g/m 2fire resistant cloth 1039.2m 2, at the temperature of 280 DEG C, keep 60min without drippage.Its mechanical property is cross-breaking strength is 41.7cN/tex, and elongation at break is 63.7%, and longitudinal fracture intensity is 40.6cN/tex; Oxygen index (OI) 35.9% before washing, oxygen index (OI) 35.3% after washing 30 times; Vertical combustion test after flame time: do not wash 0mm, wash rear 0mm 10 times; Ignitor firing time: do not wash 0mm, wash rear 0mm 50 times; Char length: do not wash 179mm, washes rear 177mm 30 times.

Claims (8)

1. a Durable fire-retardant cloth, is characterized in that, the raw material composition mass percent of employing is:
Long-staple cotton fiber 10 ~ 50%;
Nylon 6 fiber 20 ~ 70%;
Poly-phosphamide fiber 20 ~ 70%.
2. a preparation method for Durable fire-retardant cloth as claimed in claim 1, is characterized in that, comprises the following steps:
Step one, get long-staple cotton fiber and nylon 6 fiber, take out after soaking with the ammonium salt solution of nano imvite, dry for standby;
Step 2, by long-staple cotton fiber, nylon 6 fiber and the poly-phosphamide fiber after soaking, drop in breaker beater and discongest and through confusing after machine mixes, be spun into warp thread and the weft yarn of 20 ~ 110;
Step 3, with 4 ~ 12 warp thread be spun into and 3 ~ 9 weft yarns, loom is made into high-temperature-resistant cloth;
Step 4, by weave the cloth that obtains with poly-phosphamide and dimethyl carbonate composition soak in soak after take out post-drying; Durable fire-retardant cloth is obtained after washing.
3. the preparation method of a kind of Durable fire-retardant cloth according to claim 2, is characterized in that: ammonium salt solution described in step one consists of quaternary ammonium salt 20% ~ 30%, nano organic montmorillonite 10% ~ 20%, ethanol 10% ~ 20%, water 30% ~ 60%.
4. the preparation method of a kind of Durable fire-retardant cloth according to claim 2, is characterized in that: warp thread described in step 2 is made up of 4 ~ 6 bursts of spun yarn doublings, and ultimate strength is 175.6cN ~ 279.3cN, and fracture strength is 11.7cN/tex ~ 21.2cN/tex; Weft yarn is made up of 3 ~ 7 bursts of spun yarn doublings, and ultimate strength is 126.3cN ~ 187.4cN, and fracture strength is 7.9cN/tex ~ 13.5cN/tex.
5. the preparation method of a kind of Durable fire-retardant cloth according to claim 2, is characterized in that: forming poly-phosphamide in soak in step 4 is 10% ~ 30%; Dimethyl carbonate is 70% ~ 90%.
6. the preparation method of a kind of Durable fire-retardant cloth according to claim 2, is characterized in that: the described soak time in step 4 is generally 6 ~ 24 hours.
7. the preparation method of a kind of Durable fire-retardant cloth according to claim 3, is characterized in that: described quaternary ammonium salt is one or both in epoxy silicones quaternary ammonium salt, amido organosilicon quaternary ammonium salt.
8. the preparation method of a kind of Durable fire-retardant cloth according to claim 2, is characterized in that: be generally 6 ~ 24 hours by the ammonium salt solution soak time of nano imvite described in step one.
CN201510770451.8A 2015-11-13 2015-11-13 Durable flame-retardant cloth and preparation method thereof Active CN105239253B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510770451.8A CN105239253B (en) 2015-11-13 2015-11-13 Durable flame-retardant cloth and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510770451.8A CN105239253B (en) 2015-11-13 2015-11-13 Durable flame-retardant cloth and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105239253A true CN105239253A (en) 2016-01-13
CN105239253B CN105239253B (en) 2017-05-10

Family

ID=55037062

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510770451.8A Active CN105239253B (en) 2015-11-13 2015-11-13 Durable flame-retardant cloth and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105239253B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723896A (en) * 2017-10-31 2018-02-23 张家港市华阳针纺织品有限公司 A kind of fabric for improving fire resistance
CN108823972A (en) * 2018-07-11 2018-11-16 合肥铭佑高温技术有限公司 A kind of preparation method of fireproof facing material
CN108842258A (en) * 2018-07-05 2018-11-20 惠州市恒吉纺织品有限公司 Flame retardant fabric with comfort
CN109082879A (en) * 2018-07-05 2018-12-25 惠州市恒吉纺织品有限公司 Flame retardant fabric and its processing technology with comfort

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108491A (en) * 1985-12-10 1987-10-28 坦卡特全纤维公司 The improvement of textile materials
CN1050059A (en) * 1989-09-08 1991-03-20 纳幕尔杜邦公司 The blended yarn of cotton, nylon and heat resistance fiber
CN102391643A (en) * 2011-09-07 2012-03-28 上海日之升新技术发展有限公司 High temperate-resistant nanometer fire resistance-enhanced PA6 composite material and preparation method thereof
CN102926200A (en) * 2012-09-25 2013-02-13 台州学院 Flame-retardant cotton fiber and preparation method thereof
CN103255521A (en) * 2013-04-19 2013-08-21 晋江市闽高纺织科技有限公司 Fire-retardant fiber blended yarn, preparation method of fire-retardant fiber blended yarn and fabrics of fire-retardant fiber blended yarn
CN103352293A (en) * 2013-04-19 2013-10-16 晋江市闽高纺织科技有限公司 Flame-retardant and fireproof fabric, and processing technology and textile thereof
CN103361987A (en) * 2013-07-16 2013-10-23 徐州亿盈纺织科技有限公司 Multi-layer anti-flaming textile cloth and manufacturing method thereof
CN103789999A (en) * 2013-11-30 2014-05-14 常熟市亚欧进出口贸易有限公司 Flame-retardant finishing method for polyester fabric
CN104047092A (en) * 2014-06-27 2014-09-17 江苏金宏针纺织有限公司 Flame-retardant knitted fabric
CN104711861A (en) * 2015-02-13 2015-06-17 南通奥斯特鞋业有限公司 Flame resistant textile fabric and manufacturing method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108491A (en) * 1985-12-10 1987-10-28 坦卡特全纤维公司 The improvement of textile materials
CN1050059A (en) * 1989-09-08 1991-03-20 纳幕尔杜邦公司 The blended yarn of cotton, nylon and heat resistance fiber
CN102391643A (en) * 2011-09-07 2012-03-28 上海日之升新技术发展有限公司 High temperate-resistant nanometer fire resistance-enhanced PA6 composite material and preparation method thereof
CN102926200A (en) * 2012-09-25 2013-02-13 台州学院 Flame-retardant cotton fiber and preparation method thereof
CN103255521A (en) * 2013-04-19 2013-08-21 晋江市闽高纺织科技有限公司 Fire-retardant fiber blended yarn, preparation method of fire-retardant fiber blended yarn and fabrics of fire-retardant fiber blended yarn
CN103352293A (en) * 2013-04-19 2013-10-16 晋江市闽高纺织科技有限公司 Flame-retardant and fireproof fabric, and processing technology and textile thereof
CN103361987A (en) * 2013-07-16 2013-10-23 徐州亿盈纺织科技有限公司 Multi-layer anti-flaming textile cloth and manufacturing method thereof
CN103789999A (en) * 2013-11-30 2014-05-14 常熟市亚欧进出口贸易有限公司 Flame-retardant finishing method for polyester fabric
CN104047092A (en) * 2014-06-27 2014-09-17 江苏金宏针纺织有限公司 Flame-retardant knitted fabric
CN104711861A (en) * 2015-02-13 2015-06-17 南通奥斯特鞋业有限公司 Flame resistant textile fabric and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723896A (en) * 2017-10-31 2018-02-23 张家港市华阳针纺织品有限公司 A kind of fabric for improving fire resistance
CN108842258A (en) * 2018-07-05 2018-11-20 惠州市恒吉纺织品有限公司 Flame retardant fabric with comfort
CN109082879A (en) * 2018-07-05 2018-12-25 惠州市恒吉纺织品有限公司 Flame retardant fabric and its processing technology with comfort
CN108823972A (en) * 2018-07-11 2018-11-16 合肥铭佑高温技术有限公司 A kind of preparation method of fireproof facing material

Also Published As

Publication number Publication date
CN105239253B (en) 2017-05-10

Similar Documents

Publication Publication Date Title
CN102191609B (en) Arc-protection antiflaming blending fabric
CN104611806B (en) Flame-retardant yarn comprising the aromatic polymer fiber containing sulfuryl and by its obtained fabric and preparation method
CN1834314B (en) Blend fabric and shuttled fabric from the same and manufacturing thereof
CN100343426C (en) Thermal resistant fire resistant fibric and preparation process thereof
CN105239253A (en) Durable flame-retardant cloth and preparation method thereof
CN104630958B (en) Fabric made from the flame-retardant yarn of polymer blend fiber comprising aromatic polyamide and polyarylsulfone (PAS) and and preparation method
CN201074263Y (en) High-strength compound structural protective fabric
CN101397710A (en) Industrial flame-retardant protection suit fabric, production method thereof and flame-retardant protection suit thereof
CN105581409A (en) High-comfort protective garment fabric, protective garment and manufacturing method of high-comfort protective garment fabric
CN104120536B (en) A kind of fire-retardant comfort fabrics and preparation method thereof
CN103284368A (en) Blended flame-retardant fabric and flame-retardant protecting clothes
CN106400266A (en) Multi-component low-cost permanent inflaming retarding fabric and preparation method for same
CN109706572B (en) Flame-retardant anti-dripping anti-static core-spun yarn and preparation method thereof
CN110512336A (en) Fast-drying type is without molten drop fabric
CN102634896A (en) Flame retardant anti-dripping blended fabric and preparation method thereof
CN105220314B (en) A kind of resistance to 320~340 DEG C of fire- resistance cloths and preparation method thereof
CN108166119A (en) The fire-retardant blend of comfort arc protection
CN108754786A (en) A kind of multifunctional flame-proof blanket and preparation method thereof
JP6975531B2 (en) Fabrics and textiles
CN109629060B (en) High-strength flame-retardant anti-dripping wear-resistant anti-static blending wrapping core-spun yarn and preparation method thereof
CN104611804B (en) Yarn and fabric and preparation method made of aromatic polymer fiber and heat-resistance and flame-retardant fiber containing sulfuryl
CN103361870B (en) The BLENDED FABRIC of Ju Fang oxadiazole and anti-flaming viscose
CN108166118A (en) The fire-retardant blend of economical material
CN104372497A (en) Indigo blue jean fabric
CN105350109B (en) A kind of poly- phosphamide fiber and its fusion method preparation method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Durable flame-retardant cloth and preparation method thereof

Effective date of registration: 20190709

Granted publication date: 20170510

Pledgee: Shanwei Branch of China Construction Bank Co., Ltd.

Pledgor: MEILENSTEIN SHENZHEN GARMENTS CO., LTD.

Registration number: 2019990000697