CN105191970A - Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium - Google Patents
Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium Download PDFInfo
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- CN105191970A CN105191970A CN201510655639.8A CN201510655639A CN105191970A CN 105191970 A CN105191970 A CN 105191970A CN 201510655639 A CN201510655639 A CN 201510655639A CN 105191970 A CN105191970 A CN 105191970A
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- clodinafop
- propargyl
- flucarbazone
- grand
- thiophene ketone
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Abstract
The invention discloses a pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium. The effective ingredients of the pesticide composition comprise the thiencarbazone-methyl, the clodinafop-propargyl and the flucarbazone-sodium, wherein the weight percent of the thiencarbazone-methyl in the pesticide composition is 1%-20%; the weight percent of the clodinafop-propargyl in the pesticide composition is 1%-20%; the weight percent of the flucarbazone-sodium in the pesticide composition is 1%-20%; and the rest is the pesticide auxiliaries. After the thiencarbazone-methyl, the clodinafop-propargyl and the flucarbazone-sodium are compounded, the obvious synergism is achieved; compared with the dosage of the singly used effective ingredients, the dosage of the effective ingredients of the compound medicament is obviously lowered; the pesticide composition is fit for preventing and killing the annual weeds in a wheat paddock.
Description
Technical field
The composition pesticide that the present invention relates to, be, clodinafop-propargyl grand with thiophene ketone sulphur and flucarbazone for active ingredient, for preventing and treating farmland weed, be particularly useful for preventing and kill off wheat paddock annual weed.
Background technology
Chemical method weeding is agriculturally one of Main Means controlling weeds.In recent years, because some weed killer herbicide kind large area are used alone, a lot of weeds have been caused to develop immunity to drugs.Simultaneously, grass when weeds occur is mutually complicated, not only annual and perennial weed is mixed raw, draft, liana and shrub have concurrently, and weeds emerge uneven, seed, low age, the staggered generation of weeds at advanced age, so when weed killer herbicide kind is used alone, defect in a certain respect and limitation all can be shown.
Thiophene ketone sulphur is grand is sulfonyl-amino-carbnyl triazolinone class weed killer herbicide, is inhibitor of acetolactate synthetase.Thiophene ketone sulphur is grand is can effectively prevent and kill off wheat paddock grassy weed and broad leaved weed, and this active ingredient effectively can prevent and kill off piemarker and many Caryophyllaceae weeds, all can use in early days before bud and after bud.Safener accelerates the degraded of this weed killer herbicide in cereal, improves the tolerance of crop.
Flucarbazone is sulfonylurea herbicide, main chirp is absorbed by the cauline leaf of plant, through phloem and xylem conduction, pass through soil absorption on a small quantity, suppress the activity of the acetolactate synthestase in sensitive plant body, cause the biosynthesis block of the numerous acid of side chain ammonia, thus T suppression cell division, cause sensitive plant dead.Generally, dispenser is after 2 ~ 4 hours, and the absorptive amount of susceptible weeds peaks, and stops growing after 2 days, and within 4 ~ 7 days, rear blade starts yellow, occurs withered spot subsequently, dead after 2 ~ 4 weeks.The safener contained in this product, can promote that it is doing to decompose rapidly in object, and does not affect its degraded in target weeds body, thus reaches the object of killing weeds, cover crop.Be applicable to use in soft and semi-rigid type winter wheat variety.Amur foxtail, wild oat, caput grass, annual bluegrass, hard grass, alkali thatch, Annual Ryegrass, lolium temulentum, bromegrass, candle grass, Triticum tauschii, Tong grass, wheatgrass, shepherd's purse, amur foxtail, green foxtail, spontaneous rape etc. can be prevented and kill off.
Clodinafop-propargyl belongs to neophyl pyrazolines weed killer herbicide, and the mechanism of action is acetyl-CoA carboxylase (ACC) inhibitor.Cause fatty acid biosynthesis block, make cell division stop cell membrane destructurized containing fat, cause weeds dead.Have Uptake and translocation to be mainly used in barley field and to prevent and kill off annual gramineous weed, through toxicity test and field control effectiveness test, result shows barley field annual gramineous weed as wild oat, green foxtail, barnyard grass etc. have good preventive effect.
Thiophene ketone sulphur is grand, clodinafop-propargyl and flucarbazone single use time, all have certain defect and limitation.
The present inventor conducts in-depth research grand, clodinafop-propargyl, flucarbazone the mixture of thiophene ketone sulphur, on the basis of a large amount of formula indoor screening tests and field medicine effect test, find that thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone carry out mixture, within the scope of certain mixed ratio, obvious synergistic effect is shown to weeds of wheat, after further study, the present invention is completed.
Thiophene ketone sulphur is grand, the mixture of clodinafop-propargyl, flucarbazone and application there is no report at present.
Summary of the invention
The object of the invention is to solve in prior art to farmland weed develop immunity to drugs problem and actual control efficiency poor, provide a kind of efficient, low toxicity, quick-acting are good and the lasting period is long, are conducive to the composition pesticide of the farmland weed comprehensive regulation.
Another object of the present invention is used for preventing and kill off farmland weed by this composition pesticide, is particularly useful for preventing and kill off wheat paddock annual weed etc.
Technical solution of the present invention: a kind of composition pesticide containing the grand and clodinafop-propargyl of thiophene ketone sulphur and flucarbazone, active ingredient is that thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone; The grand percentage by weight in the composition of thiophene ketone sulphur is 1% ~ 20%, and clodinafop-propargyl percentage by weight is in the composition 1% ~ 20%, and flucarbazone percentage by weight is in the composition 1% ~ 20%, and all the other are insecticides adjuvant.
Composition pesticide of the present invention is prepared into any one formulation being applicable to agriculturally using by known method, reasonable formulation is wetting powder, suspending agent or water dispersible granules.
The auxiliary agent used in composition pesticide of the present invention comprise solvent, dispersant, stabilizing agent, emulsifier, antifreezing agent, thickener etc. and other to be of value to active ingredient stable and play the known substance of drug effect in the formulation, all various compositions that are conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by simple test according to recipe requirements.
Product described in the invention can the form of finished product preparation provide, and namely in composition, each material mixes, and the composition of composition also can the form of single dose provide, and directly mixes in tank or bucket, be then diluted to required concentration before using.The frequency of administration of the present composition and amount of application change with weather condition and crop condition change, can by the object using suitable formulation to reach control.
Composition pesticide of the present invention is applicable to prevent and treat farmland weed, especially wheat paddock annual weed.
Compared with prior art, beneficial effect of the present invention is, composite have obvious synergistic effect, improves control efficiency; Expand control spectrum; Two kinds of active ingredients are composite, reduce Pesticide use amount, thus reduce cost and decrease the pollution to environment.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Embodiment one: joint toxicity measuring embodiment
Test method:
Adopt potted plant cauline leaf spray-on process (NY/T1155.4-2006): at high 6cm, the in-built quantitative soil of porcelain alms bowl of diameter 9cm, will for 15 ~ 20 sowings of examination target weed seed in porcelain alms bowl, be placed in greenhouse after the fine earth of lid 0.5 ~ 1cm and cultivate, treat that amur foxtail grew to for 2 ~ 4 leaf phases, carry out cauline leaf spraying process, every porcelain alms bowl quantitatively sprays 1ml, often process and repeat for 4 times, and set the process not containing medicament as contrasting, after process, examination material is placed in greenhouse and cultivates, the growing state of routine observation target weeds, target damage symptoms and growth inhibition situation is estimated after 15d, and claim acrial part fresh weight, medicament is evaluated to the toxicity action of target weeds with target fresh weight inhibition.
Data survey and statistical analysis estimate target damage symptoms and growth inhibition situation after testing and processing 15d, and claim acrial part fresh weight, calculate fresh weight inhibition (%).
Synergy evaluation method, evaluate weed killer herbicide associated form (NY/T1155.7-2006) according to Gowing method, its formula is as follows:
E
0﹦X×Y×Z/100
2
In formula, X be thiophene ketone sulphur grand alone with certain dosage time fresh weight inhibition to target weeds; Y be clodinafop-propargyl alone with certain dosage time fresh weight inhibition to target weeds; Z be flucarbazone alone with certain dosage time fresh weight inhibition to target weeds.E
0for thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone three kinds of pharmacy mix time theoretical value to target weeds fresh weight inhibition; E is that thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone three kinds of pharmacy mix time measured value to target weeds fresh weight inhibition.
Evaluation criterion: as E – E
0during > 10%, be expressed as synergistic effect; As ﹣ 10%≤E – E
0when≤10%, show as summation action; As E – E
0during < ﹣ 10%, show as antagonism.
Table 1, thiophene ketone sulphur are grand, clodinafop-propargyl, flucarbazone different proportion be to the indoor synergy of bromegrass.
Embodiment two: 35% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone wetting powder
Mix entering in blender after above-mentioned formula in proportion coarse crushing, more namely obtain 35% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone wetting powder after air-flow crushing.
This embodiment is used for preventing and kill off wheat paddock annual weed, and 35% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone wettable powder formulation mu is with 15 grams, and the weeds 2-3 leaf phase sprays process, and after medicine, 10 days preventive effects are 95.1%; 15% clodinafop-propargyl wettable powder formulation mu is with 15 grams, and spraying processes, and after medicine, 10 days preventive effects are 80.7%; The 20 grams of spraying process of the grand aqueous suspension formulations mu of 10% thiophene ketone sulphur, after medicine, 10 days broad leaved weed preventive effect 88.7%, 3% flucarbazone aqueous suspension formulations mu is with 15 grams, and after medicine, 10 days preventive effects are 77.1%.Thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone composite after can effectively prevent and kill off wheat paddock annual weed, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, and reduces drug cost, delays the generation of disease drug resistance, decrease environmental pollution.
Embodiment three: 24% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone suspending agent
Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 24% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone suspending agent of allotment after high shear mixing.
This embodiment is used for preventing and kill off wheat paddock annual weed, and 24% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone aqueous suspension formulations mu is with 20 grams, and the weeds 2-3 leaf phase sprays process, and after medicine, 10 days preventive effects are 95.6%; The 20 grams of spraying process of 15% clodinafop-propargyl cream preparation mu, after medicine, 10 days preventive effects are 77.1%; 8% thiophene ketone sulphur grand aqueous suspension formulations mu consumption 20 grams spraying process, 10 days broad leaved weed preventive effects 83.3% after medicine.Can effectively prevent and kill off wheat paddock annual weed after clodinafop-propargyl, flucarbazone are composite, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, and reduces drug cost, delays the generation of disease drug resistance, decrease environmental pollution.
Embodiment four: 48% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone water dispersible granules
By above-mentioned formula dry pulverization process, granulation, drying, the obtained 48% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone water-dispersible granules of screening preparation in proportion.
This embodiment is used for preventing and kill off wheat paddock annual weed, and 48% thiophene ketone sulphur grand clodinafop-propargyl flucarbazone water-dispersible grain agent formulation mu is with 10 grams, and the weeds 2-3 leaf phase sprays process, and after medicine, 10 days preventive effects are 93.2%; 20 grams, the preparation spraying process of 15% Clodinafop-propargyl microemulsion mu, after medicine, 10 days preventive effects are 81.8%; 20 grams, the preparation spraying process of 10% flucarbazone suspending agent mu, 10 days broad leaved weed preventive effects 75.4% after medicine.Thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone composite after can effectively prevent and kill off wheat paddock annual weed, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, and reduces drug cost, delays the generation of disease drug resistance, decrease environmental pollution.
Claims (4)
1. the composition pesticide containing the grand and clodinafop-propargyl of thiophene ketone sulphur and flucarbazone, is characterized in that: active ingredient is that thiophene ketone sulphur is grand, clodinafop-propargyl, flucarbazone; The grand percentage by weight in the composition of thiophene ketone sulphur is 1% ~ 20%, and clodinafop-propargyl percentage by weight is in the composition 1% ~ 20%, and flucarbazone percentage by weight is in the composition 1% ~ 20%, and all the other are insecticides adjuvant.
2. a kind of composition pesticide containing the grand and clodinafop-propargyl of thiophene ketone sulphur and flucarbazone according to claim 1, is characterized in that: also containing pesticidal preparations auxiliary element in described composition pesticide, to make the application forms being applicable to agriculturally using.
3. a kind of composition pesticide containing the grand and clodinafop-propargyl of thiophene ketone sulphur and flucarbazone according to claim 2, is characterized in that: the formulation of described composition pesticide is the one in suspending agent, wetting powder or dosage form of water dispersible granule.
4. a kind of grand containing thiophene ketone sulphur and clodinafop-propargyl and flucarbazone the composition pesticide according to any one of a claim 1-3 is preventing and kill off the application on wheat paddock annual weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510655639.8A CN105191970A (en) | 2015-10-10 | 2015-10-10 | Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510655639.8A CN105191970A (en) | 2015-10-10 | 2015-10-10 | Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium |
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| CN105191970A true CN105191970A (en) | 2015-12-30 |
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| CN201510655639.8A Pending CN105191970A (en) | 2015-10-10 | 2015-10-10 | Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857623A (en) * | 2017-03-17 | 2017-06-20 | 佛山市盈辉作物科学有限公司 | A kind of herbicidal composition containing clodinafop-propargyl, flucarbazone and mesosulfuron |
| CN107873724A (en) * | 2017-12-25 | 2018-04-06 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of thifensulfuron methyl and its application |
| CN107897200A (en) * | 2017-11-30 | 2018-04-13 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of Fluoropyrimidinesulfuron and its application |
| CN108077301A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with nicosulfuron of sulphur of ketone containing thiophene |
| CN108077300A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with thifensulfuronmethyl of sulphur of ketone containing thiophene |
-
2015
- 2015-10-10 CN CN201510655639.8A patent/CN105191970A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857623A (en) * | 2017-03-17 | 2017-06-20 | 佛山市盈辉作物科学有限公司 | A kind of herbicidal composition containing clodinafop-propargyl, flucarbazone and mesosulfuron |
| CN107897200A (en) * | 2017-11-30 | 2018-04-13 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of Fluoropyrimidinesulfuron and its application |
| CN107873724A (en) * | 2017-12-25 | 2018-04-06 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of thifensulfuron methyl and its application |
| CN108077301A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with nicosulfuron of sulphur of ketone containing thiophene |
| CN108077300A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with thifensulfuronmethyl of sulphur of ketone containing thiophene |
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