CN105158048B - A kind of drawing-in type solid-liquid separator - Google Patents
A kind of drawing-in type solid-liquid separator Download PDFInfo
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- 239000007788 liquid Substances 0.000 title claims abstract description 56
- 238000007789 sealing Methods 0.000 claims abstract description 41
- 238000000605 extraction Methods 0.000 claims abstract description 30
- 239000002699 waste material Substances 0.000 claims abstract description 18
- 238000005086 pumping Methods 0.000 claims abstract description 8
- 238000004064 recycling Methods 0.000 claims abstract 8
- 238000006243 chemical reaction Methods 0.000 claims description 31
- 230000006835 compression Effects 0.000 claims description 9
- 238000007906 compression Methods 0.000 claims description 9
- 238000009434 installation Methods 0.000 claims description 9
- 230000003044 adaptive effect Effects 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 238000002203 pretreatment Methods 0.000 abstract 1
- 238000002414 normal-phase solid-phase extraction Methods 0.000 description 21
- 238000011084 recovery Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 10
- 238000004891 communication Methods 0.000 description 8
- 238000003780 insertion Methods 0.000 description 8
- 230000037431 insertion Effects 0.000 description 8
- 230000002452 interceptive effect Effects 0.000 description 7
- 239000012491 analyte Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 238000001172 liquid--solid extraction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
Description
技术领域technical field
本发明涉及一种水质分析测试的前处理装置,具体涉及一种水质分析测试用的抽吸式固液分离器。The invention relates to a pretreatment device for water quality analysis and testing, in particular to a suction type solid-liquid separator for water quality analysis and testing.
背景技术Background technique
固相萃取是近年发展起来一种样品预处理技术,由液固萃取和柱液相色谱技术相结合发展而来,主要用于样品的分离、纯化和浓缩,可以提高分析物的回收率,更有效的将分析物与干扰组分分离,减少样品预处理过程,操作简单、省时、省力。广泛的应用在医药、食品、环境、商检、化工等领域。Solid phase extraction is a sample pretreatment technology developed in recent years. It is developed from the combination of liquid-solid extraction and column liquid chromatography. It is mainly used for the separation, purification and concentration of samples, which can improve the recovery rate of analytes and make it more Effectively separate analytes from interfering components , reduce sample pretreatment process, simple operation, save time and effort. Widely used in medicine, food, environment, commodity inspection, chemical industry and other fields.
在水质分析测试的前处理过程中固相萃取主要是利用固相萃取小柱内的填料来分离、纯化和浓缩水样品,将水样品内的干扰组分分离;目前的具体操作通常如下:In the pretreatment process of water quality analysis and testing, solid phase extraction mainly uses the packing in the solid phase extraction column to separate, purify and concentrate the water sample, and separate the interfering components in the water sample; the current specific operation is usually as follows:
首先,将水样品加入固相萃取小柱内,并通过抽真空的方式使水样品内的干扰组 分过滤分离,并通过收集容器收集分离出的干扰组分(水及其他组分),从而将水样品中的分析物留在固相萃取小柱内;接着,将关闭抽真空装置,将收集干扰组分的容器取出,并放入一个新的收集容器用于收集分析物;再接着,向固相萃取小柱内加入有机溶剂来溶解留在固相萃取小柱内的分析物,并通过抽真空的方式使分析物及有机溶剂由固相萃取小柱内流出到收集容器内,从而完成对水样品分析测试的前处理。First, add the water sample into the solid phase extraction column, and filter and separate the interfering components in the water sample by vacuuming, and collect the separated interfering components (water and other components) through the collection container, so that The analyte in the water sample is left in the solid phase extraction cartridge; then, the vacuum device will be turned off, the container for collecting the interfering components will be removed, and a new collection container will be used to collect the analyte; and then, An organic solvent is added to the solid phase extraction column to dissolve the analyte remaining in the solid phase extraction column, and the analyte and the organic solvent flow out from the solid phase extraction column into the collection container by vacuuming, thereby Complete the pretreatment of the water sample analysis test.
目前的水质分析测试的前处理装置存在以下不足:There are following deficiencies in the pretreatment device of current water quality analysis test:
其一,在水样品前处理过程中需要关闭抽真空装置,并更换收集容器,其操作过程比较繁琐、费时费力。其二,通常一次前处理过程只能对一个样品管进行操作,这导致在实际检测中大批量的样品往往会花费大量的时间。First, during the pretreatment process of water samples, it is necessary to close the vacuum device and replace the collection container. The operation process is cumbersome, time-consuming and labor-intensive. Second, usually only one sample tube can be operated in one pretreatment process, which leads to a large amount of time spent in the actual detection of a large number of samples.
发明内容Contents of the invention
本发明的目的是为了克服现有技术中的不足,提供一种操作方便,工作效率高,并能够同时对多个水样品进行前处理操作的抽吸式固液分离器。The purpose of the present invention is to overcome the deficiencies in the prior art and provide a suction type solid-liquid separator which is easy to operate, has high working efficiency, and can perform pretreatment operations on multiple water samples at the same time.
本发明的技术方案是:Technical scheme of the present invention is:
一种抽吸式固液分离器,包括具有密闭内腔的箱体及抽真空设备,所述抽真空设备通过抽真空管道与箱体的内腔连通,还包括设置在箱体上的萃取液收集装置,所述箱体顶面上设有若干连接通孔,箱体的内腔底面上设有上端开口的废液回收桶,且各连接通孔位于废液回收桶的上端口的内侧;所述萃取液收集装置位于废液回收桶上方,萃取液收集装置包括设置在箱体内且设置在回收桶上方的安装板,设置在安装板上并与各连接通孔一一对应的萃取液收集管,设置在箱体侧面上并与箱体的内腔相连通的水平导套及可滑动设置在水平导套内的导杆,所述水平导套内侧面上设有第一密封圈,所述导杆的内端与安装板相连接。A suction type solid-liquid separator, comprising a box body with a sealed inner cavity and a vacuum pumping device, the vacuum pumping device communicates with the inner cavity of the box body through a vacuum pumping pipeline, and also includes an extracting liquid arranged on the box body A collection device, the top surface of the box body is provided with a number of connection through holes, and the bottom surface of the inner cavity of the box body is provided with a waste liquid recovery bucket with an upper end opening, and each connection through hole is located inside the upper port of the waste liquid recovery bucket; The extraction liquid collection device is located above the waste liquid recovery bucket, and the extraction liquid collection device includes a mounting plate arranged in the box and above the recovery bucket, and the extraction liquid collection plate is arranged on the mounting plate and corresponds to each connecting through hole one-to-one. tube, a horizontal guide sleeve arranged on the side of the box body and communicated with the inner cavity of the box body, and a guide rod slidably arranged in the horizontal guide sleeve, the inner side of the horizontal guide sleeve is provided with a first sealing ring, so The inner end of the guide rod is connected with the mounting plate.
本方案抽吸式固液分离器的操作方便,工作效率高,并能够同时对多个水样品进行前处理操作获得前处理样品。The suction type solid-liquid separator of this scheme is easy to operate, has high working efficiency, and can perform pretreatment operations on multiple water samples at the same time to obtain pretreated samples.
作为优选,还包括自适应气密装置,所述箱体包括上端开口的箱体本体及用于封遮箱体本体及的上端开口的箱盖,所述箱盖边缘设有一圈往下延伸的环形侧缘板,且环形侧缘板套设在箱体本体上;Preferably, it also includes an adaptive airtight device, the box body includes a box body with an upper end opening and a box cover for sealing the box body and the upper end opening, and the edge of the box cover is provided with a circle of downward extending An annular side edge plate, and the annular side edge plate is sleeved on the box body;
所述自适应气密装置包括设置在环形侧缘板内侧面上的安装槽,设置在安装槽内的充气式密封圈及压力转换缸体;The self-adaptive airtight device includes an installation groove arranged on the inner side of the annular side edge plate, an inflatable sealing ring and a pressure conversion cylinder arranged in the installation groove;
所述压力转换缸体的内腔由相互连通的第一腔体及第二腔体构成,且第一腔体的内径大于第二腔体的内径;所述第一腔体内设有第一活塞体,第二腔体内设有第二活塞体,且第一活塞体与第二活塞体之间通过第一连接杆相连接,所述压力转换缸体上靠近第一活塞体的一端开口,靠近第二活塞体的一端封闭;The inner cavity of the pressure conversion cylinder is composed of a first cavity and a second cavity which communicate with each other, and the inner diameter of the first cavity is larger than the inner diameter of the second cavity; the first cavity is provided with a first piston body, the second cavity is provided with a second piston body, and the first piston body and the second piston body are connected through a first connecting rod, and the pressure conversion cylinder is opened at one end close to the first piston body, close to One end of the second piston body is closed;
所述第一腔体内侧面上设有第一限位块,且第一限位块与第二活塞体位于第一活塞体相对两侧,所述第二腔体设有可使第一活塞体抵靠在第一限位块上的第一预紧压缩弹簧,且第一预紧压缩弹簧与第一活塞体位于第二活塞体相对两侧;A first limit block is provided on the inner side of the first cavity, and the first limit block and the second piston body are located on the opposite sides of the first piston body, and the second cavity is provided to make the first piston body leaning against the first preloaded compression spring on the first limit block, and the first preloaded compression spring and the first piston body are located on opposite sides of the second piston body;
所述压力转换缸体外侧面上设有第一连接口及第二连接口,第一连接口与第一腔体相连通,且第一连接口位于第一活塞体与第二活塞体之间;第二连接口与第二腔体相连通,且第二连接口与第一活塞体位于第二活塞体相对两侧;所述箱体本体外侧面上设有第三连接口,所述充气式密封圈上设有充排气嘴,所述第一连接口与第三连接口之间通过第一连通管道相连接,所述第二连接口与充排气嘴之间通过第二连通管道相连接。A first connection port and a second connection port are provided on the outer side of the pressure conversion cylinder, the first connection port communicates with the first cavity, and the first connection port is located between the first piston body and the second piston body ; the second connection port communicates with the second cavity, and the second connection port and the first piston body are located on opposite sides of the second piston body; the outer surface of the box body is provided with a third connection port, and the inflation A filling and exhausting nozzle is provided on the sealing ring, the first connecting port and the third connecting port are connected through a first communication pipe, and the second connecting port and the charging and discharging nozzle are connected through a second communicating pipe connected.
为了方便将箱体内的废液回收桶及萃取液收集管取出,通常箱体都设有一个箱盖;但这样一来箱盖与箱体本体之间就需要设置密封结构,防止抽真空过程中外界气体由箱盖与箱体本体之间进入箱体内腔。目前箱盖与箱体本体之间的密封结构通常就是一个密封圈,而由于箱盖与箱体本体的配合精度问题,普通的密封圈往往难以形成赖好的密封。另一方面,由于箱盖需要经常开启/关闭,这使得箱盖与箱体本体之间的密封圈容易松动、产生间隙,导致箱体内腔抽真空过程中外界气体进入箱体内腔,影响样品提取液的过滤。另外,由于箱盖需要经常开启/关闭,若采用普通的充气密封圈会导致箱盖无法顺利的开启/关闭。本方案针对这一问题进行改进,其能够在不影响抽吸式固液分离器正常使用的前提下,有效解决因箱盖与箱体本体之间的密封不良,而导致抽箱体内的腔体的负压不足,影响样品分离、提取处理的问题。In order to facilitate the removal of the waste liquid recovery barrel and extraction liquid collection tube in the box, the box is usually equipped with a box cover; but in this way, a sealing structure needs to be set between the box cover and the box body to prevent The outside air enters the inner cavity of the box from between the box cover and the box body. At present, the sealing structure between the box cover and the box body is usually a sealing ring, and due to the problem of the matching accuracy of the box cover and the box body, it is often difficult for ordinary sealing rings to form a good seal. On the other hand, since the box cover needs to be opened/closed frequently, the sealing ring between the box cover and the box body is easy to loosen and a gap is formed, resulting in the outside gas entering the box cavity during the vacuuming process of the box cavity, which affects sample extraction liquid filtration. In addition, since the box cover needs to be opened/closed frequently, if a common inflatable sealing ring is used, the box cover cannot be opened/closed smoothly. This solution improves on this problem. It can effectively solve the problem of the cavity in the pumping tank caused by poor sealing between the tank cover and the tank body without affecting the normal use of the suction solid-liquid separator. Insufficient negative pressure affects the separation and extraction of samples.
由于第一活塞体与第二活塞体之间的压力转换缸体内腔通过第一连通管道与箱体的内腔相连通,并且第一活塞体的横截面积大于第二活塞体的横截面积;因而在抽真空过程中第一活塞体与第二活塞体之间的气压减小,使第二活塞体往第二限位块方向移动,从而将压力转换缸体内的气体通过第二连通管道压入充气式密封圈的内腔内,使充气式密封圈膨胀,进而保证充气式密封圈在箱盖与箱体本体之间形成可靠的密封;并且随着箱体内腔的负压增大,充气式密封圈的环形充气内腔内的气压也随之增大,从而进一步保证充气式密封圈在箱盖与箱体本体之间形成可靠的密封,有效解决因箱盖与箱体本体之间的密封不良,而导致抽真空腔体的负压不足,影响样品分离、提取处理的问题。另一方面,当样品分离、提取处理完成后,抽真空设备关闭,此时箱体内腔压力恢复,从而使第一活塞体及第二活塞体在第一预紧压缩弹簧的作用下复位,此时充气式密封圈收缩,从而使箱盖能够顺利的开启/关闭,保证设备正常工作。Since the pressure conversion cylinder cavity between the first piston body and the second piston body communicates with the inner cavity of the box body through the first communication pipe, and the cross-sectional area of the first piston body is greater than that of the second piston body Therefore, the air pressure between the first piston body and the second piston body decreases during the vacuuming process, which makes the second piston body move toward the second limit block, so that the gas in the pressure conversion cylinder passes through the second The connecting pipe is pressed into the inner cavity of the inflatable sealing ring to expand the inflatable sealing ring, thereby ensuring that the inflatable sealing ring forms a reliable seal between the box cover and the box body; and as the negative pressure in the box inner cavity increases Large, the air pressure in the annular inflatable inner chamber of the inflatable sealing ring will also increase accordingly, thereby further ensuring that the inflatable sealing ring forms a reliable seal between the box cover and the box body, effectively solving the problem of problems caused by the box cover and the box body. The poor seal between them leads to insufficient negative pressure in the vacuum chamber, which affects the separation and extraction of samples. On the other hand, when the sample separation and extraction process is completed, the vacuuming equipment is closed, and the pressure in the inner cavity of the box is restored at this time, so that the first piston body and the second piston body are reset under the action of the first pre-tightened compression spring. When the inflatable sealing ring shrinks, the lid can be opened/closed smoothly to ensure the normal operation of the equipment.
作为优选,压力转换缸体外侧面上设有与第一腔体相连通的第四连接口,且第四连接口位于第一活塞体与第二活塞体之间,所述第四连接口处设有电磁开关阀;压力转换缸体外侧面上设有与第二腔体相连通的第五连接口,且第五连接口与第一活塞体位于第二活塞体相对两侧,所述第五连接口处设有电磁开关阀;所述箱体本体外侧面上设有第六连接口,所述第六连接口处设有电磁开关阀。Preferably, a fourth connection port communicating with the first cavity is provided on the outer side of the pressure conversion cylinder, and the fourth connection port is located between the first piston body and the second piston body, and the fourth connection port is An electromagnetic switch valve is provided; a fifth connection port communicating with the second cavity is provided on the outer side of the pressure conversion cylinder, and the fifth connection port and the first piston body are located on opposite sides of the second piston body. An electromagnetic switch valve is provided at the fifth connection port; a sixth connection port is provided on the outer surface of the box body, and an electromagnetic switch valve is provided at the sixth connection port.
作为优选,第二腔体内侧面上设有第二限位块,且第二限位块位于第二活塞体与第二连接口之间。Preferably, a second limiting block is provided on the inner side of the second cavity, and the second limiting block is located between the second piston body and the second connection port.
作为优选,连接通孔竖直设置,各连接通孔内分别插设有可取出的转换接头,转换接头的外侧面上设有第二密封圈,且第二密封圈位于转换接头与连接通孔之间;所述转换接头上端面设有竖直插接通孔,且竖直插接通孔内侧面上设有第三密封圈。本方案通过转换接头与固相萃取小柱连接,因而可以通过更换转换接头来适应不同型号的固相萃取小柱。Preferably, the connecting through-holes are arranged vertically, each connecting through-hole is respectively inserted with a removable adapter, the outer surface of the adapter is provided with a second sealing ring, and the second sealing ring is located between the adapter and the connecting through-hole. Between; the upper end surface of the conversion joint is provided with a vertical insertion through hole, and a third sealing ring is provided on the inner side of the vertical insertion through hole. This solution is connected to the solid-phase extraction column through an adapter, so it can adapt to different types of solid-phase extraction columns by changing the adapter.
作为优选,转换接头外侧面上并位于连接通孔上方设有第三限位块,且第三限位块位于第二密封圈上方。Preferably, a third limiting block is provided on the outer surface of the conversion joint above the connection through hole, and the third limiting block is located above the second sealing ring.
作为优选,导杆外侧面上并位于箱体的内腔内设有内限位凸块,并且当内限位凸块抵靠在水平导套时,所述安装板移动至废液回收桶的上端口的外侧。As a preference, an inner limit projection is provided on the outer surface of the guide rod and in the inner cavity of the box body, and when the inner limit projection abuts against the horizontal guide sleeve, the mounting plate moves to the waste liquid recovery bucket. on the outside of the port.
作为优选,导杆外侧面上并位于箱体外侧设有外限位凸块,并且当外限位凸块抵靠在水平导套时,各萃取液收集管位于对应的连接通孔的正下方。Preferably, an outer limiting protrusion is provided on the outer surface of the guide rod and outside the box, and when the outer limiting protrusion abuts against the horizontal guide sleeve, each extraction liquid collection tube is located directly below the corresponding connecting through hole .
作为优选,安装板水平设置,安装板上设有若干贯穿安装板上、下表面的安装通孔,所述萃取液收集管插设在对应的安装通孔内,且萃取液收集管外侧面上并位于安装板上方设有第四限位块。As a preference, the mounting plate is arranged horizontally, and the mounting plate is provided with several mounting through-holes passing through the mounting plate and the lower surface, and the extraction liquid collection pipe is inserted into the corresponding mounting through-hole, and the outer surface of the extraction liquid collection pipe is And a fourth limit block is arranged above the mounting plate.
作为优选,连接通孔的下端口设有横截面自上而下逐渐减小的导流套。Preferably, the lower port of the connection through hole is provided with a diversion sleeve whose cross-section gradually decreases from top to bottom.
本发明的有益效果是:具有操作方便,工作效率高,并能够同时对多个水样品进行前处理操作的特点。The invention has the advantages of convenient operation, high work efficiency, and the ability to perform pretreatment operations on multiple water samples at the same time.
附图说明Description of drawings
图1是本发明的抽吸式固液分离器的一种结构示意图。Fig. 1 is a schematic structural view of the suction solid-liquid separator of the present invention.
图2是本发明的自适应气密装置的一种结构示意图。Fig. 2 is a schematic structural view of the self-adaptive airtight device of the present invention.
图3是本发明的抽吸式固液分离器在工作过程中的另一种结构示意图。Fig. 3 is another structural schematic view of the suction solid-liquid separator of the present invention during operation.
图中:箱体1、箱体本体1a、箱盖1b、环形侧缘板1b1,连接通孔2,转换接头3、竖直插接通孔31,导流套4,自适应气密装置5、充气式密封圈51、第三连接口52、第一连通管道53、第二连通管道54、压力转换缸体55、第一连接口56、第二连接口57、第五连接口58、In the figure: box body 1, box body 1a, box cover 1b, annular side edge plate 1b1, connecting through hole 2, conversion joint 3, vertical insertion through hole 31, diversion sleeve 4, self-adaptive airtight device 5 , Inflatable sealing ring 51, third connection port 52, first communication pipe 53, second communication pipe 54, pressure conversion cylinder 55, first connection port 56, second connection port 57, fifth connection port 58,
第一预紧压缩弹簧59、第二腔体510、第二限位块511、第二活塞体512、第四连接口513、第一腔体514、第一活塞体515、第一限位块516,萃取液收集装置6、安装板61、萃取液收集管62、第四限位块63、内限位凸块64、水平导套65、导杆66、外限位凸块67,废液回收桶7,抽吸口8,第六连接口9,固相萃取小柱10。The first pre-tightening compression spring 59, the second cavity 510, the second limit block 511, the second piston body 512, the fourth connection port 513, the first cavity 514, the first piston body 515, the first limit block 516, extraction liquid collection device 6, mounting plate 61, extraction liquid collection pipe 62, fourth limit block 63, inner limit bump 64, horizontal guide sleeve 65, guide rod 66, outer limit bump 67, waste liquid Recovery barrel 7, suction port 8, sixth connection port 9, solid phase extraction column 10.
具体实施方式detailed description
下面结合附图与具体实施方式对本发明作进一步详细描述:Below in conjunction with accompanying drawing and specific embodiment the present invention is described in further detail:
如图1所示,一种抽吸式固液分离器包括具有密闭内腔的箱体1,抽真空设备,自适应气密装置5及设置在箱体上的萃取液收集装置6。箱体包括上端开口的箱体本体1a及用于封遮箱体本体及的上端开口的箱盖1b。箱盖边缘设有一圈往下延伸的环形侧缘板1b1,且环形侧缘板套设在箱体本体上。抽真空设备通过抽真空管道与箱体的内腔连通,具体说是,箱体本体外侧面上设有抽吸口8,抽真空设备通过抽真空管道与抽吸口相连接。As shown in FIG. 1 , a suction type solid-liquid separator includes a box body 1 with a sealed inner cavity, vacuum equipment, an adaptive airtight device 5 and an extraction liquid collecting device 6 arranged on the box body. The box body includes a box body 1a with an open upper end and a box cover 1b for covering the box body and the upper end opening. An annular side edge plate 1b1 extending downward is provided on the edge of the box cover, and the annular side edge plate is sheathed on the box body. The vacuuming equipment communicates with the inner cavity of the box body through a vacuuming pipeline, specifically, a suction port 8 is provided on the outer surface of the box body, and the vacuuming equipment is connected with the suction port through a vacuuming pipeline.
箱体顶面上设有若干连接通孔2,具体说是,箱盖顶面上设有若干连接通孔。连接通孔竖直设置。连接通孔的下端口设有横截面自上而下逐渐减小的导流套4。连接通孔为圆孔。各连接通孔内分别插设有可取出的转换接头3。转换接头的外侧面上设有第二密封圈,且第二密封圈位于转换接头与连接通孔之间。转换接头外侧面上并位于连接通孔上方设有第三限位块,且第三限位块位于第二密封圈上方。转换接头上端面设有竖直插接通孔31,且竖直插接通孔内侧面上设有第三密封圈。箱体的内腔底面上设有上端开口的废液回收桶7,且各连接通孔位于废液回收桶的上端口的内侧。A plurality of connection through holes 2 are provided on the top surface of the box body, specifically, a plurality of connection through holes are provided on the top surface of the case cover. The connection vias are arranged vertically. The lower port connecting the through hole is provided with a diversion sleeve 4 whose cross-section gradually decreases from top to bottom. The connecting through hole is a round hole. Removable conversion joints 3 are respectively inserted in each connection through hole. A second sealing ring is provided on the outer surface of the conversion joint, and the second sealing ring is located between the conversion joint and the connection through hole. A third limiting block is arranged on the outer surface of the conversion joint and above the connecting through hole, and the third limiting block is located above the second sealing ring. The upper end surface of the conversion joint is provided with a vertical insertion through hole 31, and a third sealing ring is provided on the inner side of the vertical insertion through hole. A waste liquid recovery barrel 7 with an open upper end is provided on the bottom surface of the inner cavity of the box body, and each connecting through hole is located inside the upper port of the waste liquid recovery barrel.
萃取液收集装置位于废液回收桶上方。萃取液收集装置包括设置在箱体内且设置在回收桶上方的安装板61,设置在安装板上并与各连接通孔一一对应的萃取液收集管62,设置在箱体侧面上并与箱体的内腔相连通的水平导套65及可滑动设置在水平导套内的导杆66。安装板水平设置。安装板上设有若干贯穿安装板上、下表面的安装通孔。萃取液收集管的上端开口,下端封闭。萃取液收集管插设在对应的安装通孔内,且萃取液收集管外侧面上并位于安装板上方设有第四限位块63。水平导套内侧面上设有第一密封圈。导杆的内端与安装板相连接。The extraction liquid collection device is located above the waste liquid recovery barrel. The extraction liquid collecting device comprises the installation plate 61 that is arranged in the casing and is arranged on the top of the recovery barrel, the extraction liquid collection pipe 62 that is arranged on the installation plate and corresponds to each connecting through hole one by one, is arranged on the side of the casing and is connected with the casing. The horizontal guide sleeve 65 connected with the inner cavity of the body and the guide rod 66 slidably arranged in the horizontal guide sleeve. The mounting plate is set horizontally. The mounting plate is provided with a plurality of mounting through holes penetrating through the mounting plate and the lower surface. The upper end of the extraction solution collection tube is open and the lower end is closed. The extraction liquid collection tube is inserted into the corresponding installation through hole, and a fourth limiting block 63 is provided on the outer surface of the extraction liquid collection tube and above the mounting plate. A first sealing ring is arranged on the inner surface of the horizontal guide sleeve. The inner end of the guide rod is connected with the mounting plate.
如图1所示,导杆外侧面上并位于箱体的内腔内设有内限位凸块64,并且当内限位凸块抵靠在水平导套时,所述安装板移动至废液回收桶的上端口的外侧。如图3所示,导杆外侧面上并位于箱体外侧设有外限位凸块67,并且当外限位凸块抵靠在水平导套时,各萃取液收集管位于对应的连接通孔的正下方。As shown in Figure 1, an inner limit projection 64 is provided on the outer surface of the guide rod and in the inner cavity of the box body, and when the inner limit projection abuts against the horizontal guide sleeve, the mounting plate moves to the waste the outside of the upper port of the liquid recovery bucket. As shown in Figure 3, an outer limit bump 67 is provided on the outer surface of the guide rod and outside the box, and when the outer limit bump abuts against the horizontal guide sleeve, each extraction liquid collection tube is located in the corresponding connection channel. directly below the hole.
如图1、图2所示,自适应气密装置5包括设置在环形侧缘板内侧面上的安装槽,设置在安装槽内的充气式密封圈51及压力转换缸体55。压力转换缸体的内腔呈阶梯状。压力转换缸体的内腔由相互连通的第一腔体514及第二腔体510构成,且第一腔体的内径大于第二腔体的内径。第一腔体内设有第一活塞体515。第二腔体内设有第二活塞体512,且第一活塞体与第二活塞体之间通过第一连接杆相连接。压力转换缸体上靠近第一活塞体的一端开口,靠近第二活塞体的一端封闭。第一腔体内侧面上设有第一限位块516,且第一限位块与第二活塞体位于第一活塞体相对两侧。第二腔体内侧面上设有第二限位块511,且第二限位块位于第二活塞体与第二连接口之间。第二腔体设有可使第一活塞体抵靠在第一限位块上的第一预紧压缩弹簧59,且第一预紧压缩弹簧与第一活塞体位于第二活塞体相对两侧。As shown in Fig. 1 and Fig. 2, the self-adaptive airtight device 5 includes a mounting groove disposed on the inner side of the annular side edge plate, an inflatable sealing ring 51 and a pressure conversion cylinder 55 disposed in the mounting groove. The inner cavity of the pressure conversion cylinder is stepped. The inner cavity of the pressure conversion cylinder is composed of a first cavity 514 and a second cavity 510 which communicate with each other, and the inner diameter of the first cavity is larger than the inner diameter of the second cavity. A first piston body 515 is disposed in the first cavity. A second piston body 512 is disposed in the second cavity, and the first piston body and the second piston body are connected through a first connecting rod. One end close to the first piston body is open on the pressure conversion cylinder body, and one end close to the second piston body is closed. A first limiting block 516 is disposed on the inner side of the first cavity, and the first limiting block and the second piston body are located on opposite sides of the first piston body. A second limiting block 511 is disposed on the inner side of the second cavity, and the second limiting block is located between the second piston body and the second connection port. The second cavity is provided with a first pre-tightened compression spring 59 that can make the first piston body lean against the first limit block, and the first pre-tightened compression spring and the first piston body are located on opposite sides of the second piston body .
压力转换缸体外侧面上设有第一连接口56及第二连接口57。第一连接口与第一腔体相连通,且第一连接口位于第一活塞体与第二活塞体之间。第二连接口与第二腔体相连通,且第二连接口与第一活塞体位于第二活塞体相对两侧。箱体本体外侧面上设有第三连接口52。压力转换缸体外侧面上设有与第一腔体相连通的第四连接口513,且第四连接口位于第一活塞体与第二活塞体之间。第四连接口处设有电磁开关阀。压力转换缸体外侧面上设有与第二腔体相连通的第五连接口58,且第五连接口与第一活塞体位于第二活塞体相对两侧。第五连接口处设有电磁开关阀。箱体本体外侧面上设有与主箱体内腔相连通的第六连接口9。第六连接口处设有电磁开关阀。充气式密封圈上设有充排气嘴。第一连接口与第三连接口之间通过第一连通管道53相连接。第二连接口与充排气嘴之间通过第二连通管道54相连接。A first connection port 56 and a second connection port 57 are provided on the outer side of the pressure conversion cylinder. The first connection port communicates with the first cavity, and the first connection port is located between the first piston body and the second piston body. The second connection port communicates with the second cavity, and the second connection port and the first piston body are located on opposite sides of the second piston body. A third connecting port 52 is provided on the outer surface of the box body. A fourth connection port 513 communicating with the first cavity is provided on the outer side of the pressure conversion cylinder, and the fourth connection port is located between the first piston body and the second piston body. The fourth connecting port is provided with an electromagnetic switch valve. A fifth connection port 58 communicating with the second cavity is provided on the outer side of the pressure conversion cylinder, and the fifth connection port and the first piston body are located on opposite sides of the second piston body. The fifth connecting port is provided with an electromagnetic switch valve. The outer surface of the box body is provided with a sixth connection port 9 communicating with the inner cavity of the main box. The sixth connection port is provided with an electromagnetic switch valve. The inflatable sealing ring is provided with an inflatable exhaust nozzle. The first connection port is connected with the third connection port through a first communication pipe 53 . The second connecting port is connected with the charging and exhausting nozzle through the second communication pipe 54 .
本发明的抽吸式固液分离器的具体工作过程如下:The specific working process of suction type solid-liquid separator of the present invention is as follows:
第一,通过导杆带动安装板及萃取液收集管移动,直至内限位凸块抵靠在水平导套上,此时安装板移动至废液回收桶的上端口的外侧,如图1所示。First, drive the installation plate and the extraction liquid collection tube to move through the guide rod until the inner limit projection abuts against the horizontal guide sleeve, at this time the installation plate moves to the outside of the upper port of the waste liquid recovery bucket, as shown in Figure 1 Show.
同时,如图3所示,将固相萃取小柱10的下端插入转换接头的竖直插接通孔内,并通过竖直插接通孔内的第三密封圈在固相萃取小柱与转换接头之间形成密封(各竖直插接通孔内分别插设固相萃取小柱);然后,将待处理水样品加入对应的固相萃取小柱内(各固相萃取小柱内内可以加入不同的待处理水样品)。Simultaneously, as shown in Figure 3, insert the lower end of the solid phase extraction small column 10 in the vertical insertion through hole of the adapter, and through the third sealing ring in the vertical insertion through hole, connect the solid phase extraction small column and the A seal is formed between the conversion joints (the solid-phase extraction cartridges are respectively inserted in each vertical insertion hole); then, the water sample to be treated is added to the corresponding solid-phase extraction cartridge (the inside of each solid-phase extraction cartridge is Different water samples to be treated can be added).
第二,关闭第四、第五及第六连接口处的电磁开关阀,并开启抽真空设备对箱体的内腔进行抽真空,使水样品中的干扰组分(水及其他组分)由固相萃取小柱的下端口滴落到废液回收桶内,并使水样品中的分析物留在固相萃取小柱内。Second, close the electromagnetic switching valves at the fourth, fifth and sixth connection ports, and turn on the vacuum equipment to vacuum the inner cavity of the box, so that the interfering components (water and other components) in the water sample The lower port of the solid-phase extraction cartridge drips into the waste liquid recovery bucket, and the analytes in the water sample remain in the solid-phase extraction cartridge.
如图1、图2所示,在抽真空设备对箱体的内腔进行抽真空的过程中,由于第一活塞体与第二活塞体之间的连通式缸体内腔通过第一连通管道与主箱体的内腔相连通,并且第一活塞体的横截面积大于第二活塞体的横截面积;因而在抽真空过程中第一活塞体与第二活塞体之间的气压减小,使第二活塞体往第二限位块方向移动,从而将连通式缸体内的气体通过第二连通管道压入充气式密封圈的环形充气内腔内,使充气式密封圈膨胀,进而保证充气式密封圈在箱盖与箱体本体之间形成可靠的密封。As shown in Figure 1 and Figure 2, during the process of vacuuming the inner cavity of the box body by the vacuum equipment, due to the communication cylinder inner cavity between the first piston body and the second piston body through the first communication pipe It communicates with the inner cavity of the main box body, and the cross-sectional area of the first piston body is larger than that of the second piston body; thus, the air pressure between the first piston body and the second piston body decreases during vacuuming , so that the second piston body moves toward the second limit block, so that the gas in the communicating cylinder is pressed into the annular inflatable inner cavity of the inflatable sealing ring through the second communicating pipe, so that the inflatable sealing ring expands, and then Ensure that the inflatable sealing ring forms a reliable seal between the box cover and the box body.
第三,当水样品内的干扰组分分离后,通过导杆带动安装板及萃取液收集管移动,直至外限位凸块抵靠在水平导套上,此时各萃取液收集管位于对应的连接通孔的正下方,如图3所示;Third, after the interfering components in the water sample are separated, the guide rod drives the mounting plate and the extraction liquid collection tube to move until the outer limit bumps abut against the horizontal guide sleeve. At this time, each extraction liquid collection tube is located at the corresponding directly below the connecting through hole, as shown in Figure 3;
接着,向固相萃取小柱内加入有机溶剂来溶解留在固相萃取小柱内的分析物,溶解在有机溶剂内的分析物将由固相萃取小柱的下端口滴落到对应的萃取液收集管内,从而完成对水样品分析测试的前处理。Next, add an organic solvent to the solid phase extraction column to dissolve the analyte remaining in the solid phase extraction column, and the analyte dissolved in the organic solvent will drop from the lower port of the solid phase extraction column to the corresponding extract In the collection tube, the pretreatment of the water sample analysis test is completed.
第四,将抽真空设备关闭,同时将第四、第五及第六连接口处的电磁开关阀开启,从而使第一活塞体及第二活塞体在预紧压缩弹簧的作用下复位,此时充气式密封圈收缩(使箱盖能够顺利的开启/关闭);接着,开启箱盖将萃取液收集管取出即可。Fourth, turn off the vacuuming equipment, and at the same time open the electromagnetic switch valves at the fourth, fifth and sixth connection ports, so that the first piston body and the second piston body are reset under the action of the pre-tightened compression spring. When the inflatable sealing ring shrinks (so that the box cover can be opened/closed smoothly); then, open the box cover and take out the extraction liquid collection tube.
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