CN105131494A - Waterproof acid and alkali-resistant flame-retardant insulating power cable material for marine ships - Google Patents
Waterproof acid and alkali-resistant flame-retardant insulating power cable material for marine ships Download PDFInfo
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Abstract
The invention relates to a waterproof acid and alkali-resistant flame-retardant insulating power cable material for marine ships. The power cable material is prepared from the following components in parts by mass: 52 to 56 parts of chlorinated polyethylene rubber, 54 to 58 parts of maleic anhydride grafted polyethylene, 50 to 54 parts of modified acrylonitrile-butadiene rubber, 54 to 58 parts of triphenyl phosphate, 50 to 54 parts of trioctyl trimellitate, 54 to 58 parts of ground limestone, 50 to 54 parts of polydimethylsiloxane, 56 to 60 parts of EPDM rubber, 50 to 54 parts of dipentaerythritol hexaacrylate, 54 to 58 parts of toluene diisocynate, 50 to 54 parts of chlorinated paraffin, 54 to 58 parts of polyurethane, 50 to 54 parts of polystyrene, 54 to 58 parts of butadiene-styrene rubber, 50 to 54 parts of molybdenum disulfide, 54 to 58 parts of polyether ester amide, 50 to 54 parts of sodium alkyl benzene sulfonate, 50 to 54 parts of sodium antimonate, 54 to 58 parts of phenyl petroleum sulfonate, 50 to 54 parts of dibutyltin dilaurate and 54 to 58 parts of poly carbazolyl acrylic ester. The product has better corrosion resistance, flame retardance, waterproofness and insulating property, and is suitable for being used in many fields.
Description
Technical field
The present invention relates to a kind of marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, belong to cable material formula technique field.
Background technology
According to the development of several years domestic and international shipping industrys, estimate that following market of ship demand presents based on large-tonnage, there is the feature such as high technology content and high added value.The fast development of China's shipping industry, will pull the market requirement of shipboard cable further.Shipboard cable also known as marine power cables, be a kind of electric power for sea, the river aquatic building such as various boats and ships and offshore oil platform, illumination and general control electric wire.In order to make cable adapt to marine Working environment, needing to add various raw material in cable raw material, making cable have waterproof, acid and alkali-resistance, fire-retardant and insulating property.
Summary of the invention
The object of the present invention is to provide a kind of marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, to realize the waterproof acid and alkali-resistance fire retardant insulating function of marine ship electric power cable material better.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 52 ~ 56 parts, maleic anhydride grafted polyethylene 54 ~ 58 parts, modified butadiene acrylonitrile rubber 50 ~ 54 parts, triphenylphosphate 54 ~ 58 parts, trioctyl trimellitate 50 ~ 54 parts, water-ground limestone 54 ~ 58 parts, polydimethylsiloxane 50 ~ 54 parts, terpolymer EP rubber 56 ~ 60 parts, double pentaerythritol methacrylate 50 ~ 54 parts, tolylene diisocyanate 54 ~ 58 parts, clorafin 50 ~ 54 parts, urethane 54 ~ 58 parts, polystyrene 50 ~ 54 parts, butadiene-styrene rubber 54 ~ 58 parts, molybdenumdisulphide 50 ~ 54 parts, polyether ester amides 54 ~ 58 parts, sodium alkyl benzene sulfonate 50 ~ 54 parts, sodium antimonate 50 ~ 54 parts, phenyl alkylsulfonate 54 ~ 58 parts, dibutyl tin laurate 50 ~ 54 parts, polycarbazole base acrylate 54 ~ 58 parts.
Further, above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 52 parts, maleic anhydride grafted polyethylene 54 parts, modified butadiene acrylonitrile rubber 50 parts, triphenylphosphate 54 parts, trioctyl trimellitate 50 parts, water-ground limestone 54 parts, polydimethylsiloxane 50 parts, terpolymer EP rubber 56 parts, double pentaerythritol methacrylate 50 parts, tolylene diisocyanate 54 parts, clorafin 50 parts, urethane 54 parts, polystyrene 50 parts, butadiene-styrene rubber 54 parts, molybdenumdisulphide 50 parts, polyether ester amides 54 parts, sodium alkyl benzene sulfonate 50 parts, sodium antimonate 50 parts, phenyl alkylsulfonate 54 parts, dibutyl tin laurate 50 parts, polycarbazole base acrylate 54 parts.
Further, above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 54 parts, maleic anhydride grafted polyethylene 56 parts, modified butadiene acrylonitrile rubber 52 parts, triphenylphosphate 56 parts, trioctyl trimellitate 52 parts, water-ground limestone 56 parts, polydimethylsiloxane 52 parts, terpolymer EP rubber 58 parts, double pentaerythritol methacrylate 52 parts, tolylene diisocyanate 56 parts, clorafin 52 parts, urethane 56 parts, polystyrene 52 parts, butadiene-styrene rubber 56 parts, molybdenumdisulphide 52 parts, polyether ester amides 56 parts, sodium alkyl benzene sulfonate 52 parts, sodium antimonate 52 parts, phenyl alkylsulfonate 56 parts, dibutyl tin laurate 52 parts, polycarbazole base acrylate 56 parts.
Further, above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 56 parts, maleic anhydride grafted polyethylene 58 parts, modified butadiene acrylonitrile rubber 54 parts, triphenylphosphate 58 parts, trioctyl trimellitate 54 parts, water-ground limestone 58 parts, polydimethylsiloxane 54 parts, terpolymer EP rubber 60 parts, double pentaerythritol methacrylate 54 parts, tolylene diisocyanate 58 parts, clorafin 54 parts, urethane 58 parts, polystyrene 54 parts, butadiene-styrene rubber 58 parts, molybdenumdisulphide 54 parts, polyether ester amides 58 parts, sodium alkyl benzene sulfonate 54 parts, sodium antimonate 54 parts, phenyl alkylsulfonate 58 parts, dibutyl tin laurate 54 parts, polycarbazole base acrylate 58 parts.
Further, above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material preparation method step is as follows:
(1) by the chlorinated polyethylene rubber of described mass fraction, maleic anhydride grafted polyethylene, modified butadiene acrylonitrile rubber, triphenylphosphate, trioctyl trimellitate, water-ground limestone, terpolymer EP rubber, double pentaerythritol methacrylate, tolylene diisocyanate, clorafin, urethane, polystyrene, butadiene-styrene rubber, molybdenumdisulphide, polyether ester amides, sodium alkyl benzene sulfonate, sodium antimonate, phenyl alkylsulfonate, polycarbazole base acrylate is mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min,
(2) add the polydimethylsiloxane of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the dibutyl tin laurate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
Above-mentioned each component function is as follows:
(1) chlorinated polyethylene rubber: saturated macromolecular material, outward appearance is white powder, nonpoisonous and tasteless, has excellent weather resisteant, resistance to ozone, chemical-resistant resistance and ageing-resistant performance, has good oil-proofness, flame retardant resistance and tinctorial property.Be mainly used in electric wire, hydralic hose, automobile-used sebific duct, adhesive tape, offset plate, the modification of PVC type tubing, magneticsubstance, ABS modification etc.
(2) maleic anhydride grafted polyethylene: connect the several maleic anhydride molecule of skill by the means of chemical reaction on polyethylene molecular chain, product is made both to have had poly good workability and other excellent properties, what have again a maleic anhydride polar molecule can reactive and strong polarity again, be beneficial to as coupling agent and reaction modifier use again, have been widely used at plastic applications tool.May be used for polypropylene, the filling of high density polyethylene(HDPE), the coupling agent of fiberglass reinforced, the vector resin of Masterbatch, the antifog phase properties-correcting agent of prolongation etc. of the plasticized modifier of engineering plastics, the expanding material of inorganic filler plastic blending material, antifog mulch film.
(3) modified butadiene acrylonitrile rubber: there is excellent elongation, wear resistance, oil-proofness and intensity, and migration of plasticizer and volatilization can be reduced, extend the work-ing life of goods.For industrial low, middle piezoelectricity arc welding concentric cable telephone wire cover, oil resistant cable.
(4) triphenylphosphate: colourless slightly phenol is smelly, water insoluble to micro-yellow transparent liquid, and wet gas facile hydrolysis generates free phenol, can be dissolved in alcohol, ether, benzene and acetone and other organic solvent, has sorption to ultraviolet.As the camphor uninflammability surrogate in the softening agent of the flame-retardant plasticizer of nitrocotton, cellulose acetate film, polyvinyl chloride, viscose fiber.
(5) trioctyl trimellitate: there is good thermotolerance, low volatility, oil-proofness and workability, be widely used as the softening agent of the heat-resisting softening agent of PVC, solvent resistant crosslinkable vinyl chloride resin, the primary plasticizer of 90 DEG C and 105 DEG C of level heat-resisting cables formula and the supporting softening agent be used as needed for high-tension cable.
(6) water-ground limestone: conventional powdery inorganic filler, have that chemical purity is high, inertia greatly, not easily chemical reaction, Heat stability is good, can not decompose below 400 DEG C, the advantage such as whiteness is high, oil absorbency is low, refractive index is low, matter is soft, dry, little, nontoxic, tasteless containing crystal water, the low wear(ing)value of hardness, odorless, good dispersity.Be filled among rubber, tensile strength, tear strength and the wear resistance higher than gum sulfide can be obtained, and save expensive natural rubber, thus greatly reduce costs.
(7) polydimethylsiloxane: a kind of organosilicon material of hydrophobic class.Colourless or light yellow liquid, tasteless, transparency is high, there is thermotolerance, winter hardiness, viscosity vary with temperature little, water-repellancy, surface tension are little, electrical insulating property and weathering resistance, can be directly used in moisture-proof insulation, damping, damping, froth breaking, lubrication, the aspects such as polishing, are widely used as insulation lubrication, shockproof, grease proofing dirt, dielectric liquid and thermal barrier.And be used as froth breaking, releasing agent, paint and daily use chemicals product additive.
(8) terpolymer EP rubber: the multipolymer of ethene, propylene and a small amount of non-conjugated diene hydrocarbon, because its main chain is made up of chemically stable stable hydrocarbon, only in side chain, contain unsaturated double-bond, therefore its resistance to ozone, the ageing-resistant performance such as heat-resisting, weather-proof are excellent, can be widely used in the fields such as trolley part, building water-proof material, electric wire and cable jacket, heat-resistant rubber hose, adhesive tape, automotive sealant.
(9) double pentaerythritol methacrylate: be applicable to hard coat cable material, ink, solder mask, and can urethane synthesis material be used as.Major advantage is that curing speed is fast, and high rigidity, resistance to emulsifying property is good, prevents crystallization.
(10) tolylene diisocyanate: water white or weak yellow liquid, has strong impulse smell.Miscible with ether, glycol ether, acetone, tetracol phenixin, benzene, chlorobenzene, kerosene, sweet oil.Mainly as the raw materials for production of urethane resin, smear plastics, cable material, rubber, tackiness agent, sealing agent etc. for the production of polyurethane bubble.Also can be used as vulcanizer, protein cross agent etc.
(11) clorafin: the chlorinated derivatives of paraffinic hydrocarbon, advantages such as having low volatility, fire-retardant, electrical insulating property is good, be inexpensive, can be used as fire retardant and polyvinyl chloride extender plasticizer.Be widely used in production CABLE MATERIALS, the goods such as plate, flexible pipe, leatheroid, rubber.And be applied to cable material, plastic cement race track, lubricating oil, the additive waited.
(12) urethane: formed by organic diisocyanate or polyisocyanates and dihydroxyl or polyol addition polymerization.There is the excellent properties such as wear-resisting, heatproof, sealing, sound insulation, good processability, degradable.Purposes is very wide, can replace rubber, plastics, nylon etc., for airport, and hotel, building materials, automobile factory, colliery factory, cement mill, condo, villa, landscaping, colored stone art, park etc.
(13) polystyrene: the polymkeric substance synthesized through free radical polymerization by styrene monomer, easy machine-shaping, and there is the advantages such as transparent, cheap, rigidity, insulation, printing be good.Market for manufactured goods turned out by light industry can be widely used in, daily decoration, the aspects such as illumination instruction and packaging.Insulating material good especially and heat-insulating heat-preserving material in electric, can make various meter case, lampshade, optical chemical instrument part, transparent film, capacitor dielectric layer etc.
(14) butadiene-styrene rubber: the multipolymer of vinylbenzene and divinyl, compares with natural rubber, uniform quality, few foreign, and has excellent mechanical stability, can use with natural rubber fusion.For the manufacture of rubber sponge, impregnation of fibers and fabric, also directly tackiness agent, cable material etc. can be used as.
(15) molybdenumdisulphide: this product look black is slightly with silver gray, has metalluster, that touches has soapy feeling, water insoluble.Product has good dispersity, inadherent advantage, can be added in various grease, forms exhausted inadherent colloidal state, can increase oilness and the extreme pressure property of grease.Also the machine work state of high temperature, high pressure, high rotating speed high loading is applicable to, the extension device life-span.
(16) polyether ester amides: a class tensio-active agent, has special structure, contains the alkyl of different surfaces activity, hydroxyl, ether and amide functional group in its structure.Can play washing, emulsification, moistening, soak into and the multiple effect such as dispersion.
(17) sodium alkyl benzene sulfonate: aniorfic surfactant.Because production cost is low, performance is good, thus of many uses, be the maximum synthetic surfactant of household detergent consumption, also produce the organic amine salts such as inorganic salt and trolamine such as a part of magnesium, calcium.
(18) sodium antimonate: granular crystal and the white powder waiting axle crystallization.Be dissolved in tartrate, sodium sulfide solution, the vitriol oil, be slightly soluble in alcohol, ammonium salt, be insoluble to acetic acid, diluted alkaline and diluted mineral acid.As the finings of picture tube, opticglass and various high glass, the fire retardant of textiles, plastics, enamel opacifier, manufacture foundry goods paint opaque filler and iron sheet, steel plate acid-proof varniss composition.
(19) phenyl alkylsulfonate: this product is plasticizer for polyvinyl chloride, electrical property and good mechanical property, and volatility is low, good weatherability, and winter hardiness is poor.Be mainly used in polyvinyl chloride film, enter fabricate-leather, CABLE MATERIALS, sole, plastic shoes etc.
(20) dibutyl tin laurate: have the excellent transparency, oilness, weather resisteant, is used in PVC soft transparent goods, and finished surface gloss and excellent transparency after processing, without sulfide staining.Be mainly used in soft and half soft polrvinyl chloride product, as transparent film, pipe, leatheroid etc., also can make catalysts for polyurethanes.
(21) polycarbazole base acrylate: oil resistant, heat-resisting, water tolerance are better is the monomer manufacturing tackiness agent, synthetic resins, specialty elastomer and plastics.
This beneficial effect of the invention is: this marine ship is simple by waterproof acid and alkali-resistance fire retardant insulating power cable material preparation process method, and prepared product has good corrosion-resistant fire-resistant waterproof insulating property, is adapted at multiple fields and uses.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1
Marine ship in the present embodiment waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 52 parts, maleic anhydride grafted polyethylene 54 parts, modified butadiene acrylonitrile rubber 50 parts, triphenylphosphate 54 parts, trioctyl trimellitate 50 parts, water-ground limestone 54 parts, polydimethylsiloxane 50 parts, terpolymer EP rubber 56 parts, double pentaerythritol methacrylate 50 parts, tolylene diisocyanate 54 parts, clorafin 50 parts, urethane 54 parts, polystyrene 50 parts, butadiene-styrene rubber 54 parts, molybdenumdisulphide 50 parts, polyether ester amides 54 parts, sodium alkyl benzene sulfonate 50 parts, sodium antimonate 50 parts, phenyl alkylsulfonate 54 parts, dibutyl tin laurate 50 parts, polycarbazole base acrylate 54 parts.
Above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material preparation method step is as follows:
(1) by the chlorinated polyethylene rubber of described mass fraction, maleic anhydride grafted polyethylene, modified butadiene acrylonitrile rubber, triphenylphosphate, trioctyl trimellitate, water-ground limestone, terpolymer EP rubber, double pentaerythritol methacrylate, tolylene diisocyanate, clorafin, urethane, polystyrene, butadiene-styrene rubber, molybdenumdisulphide, polyether ester amides, sodium alkyl benzene sulfonate, sodium antimonate, phenyl alkylsulfonate, polycarbazole base acrylate is mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5400r/min, jitter time is 60min,
(2) add the polydimethylsiloxane of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5200r/min, and jitter time is 50min;
(3) add the dibutyl tin laurate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 4800r/min, and jitter time is 40min; Mix rear obtained this product.
embodiment 2
Marine ship in the present embodiment waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 54 parts, maleic anhydride grafted polyethylene 56 parts, modified butadiene acrylonitrile rubber 52 parts, triphenylphosphate 56 parts, trioctyl trimellitate 52 parts, water-ground limestone 56 parts, polydimethylsiloxane 52 parts, terpolymer EP rubber 58 parts, double pentaerythritol methacrylate 52 parts, tolylene diisocyanate 56 parts, clorafin 52 parts, urethane 56 parts, polystyrene 52 parts, butadiene-styrene rubber 56 parts, molybdenumdisulphide 52 parts, polyether ester amides 56 parts, sodium alkyl benzene sulfonate 52 parts, sodium antimonate 52 parts, phenyl alkylsulfonate 56 parts, dibutyl tin laurate 52 parts, polycarbazole base acrylate 56 parts.
Above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material preparation method step is as follows:
(1) by the chlorinated polyethylene rubber of described mass fraction, maleic anhydride grafted polyethylene, modified butadiene acrylonitrile rubber, triphenylphosphate, trioctyl trimellitate, water-ground limestone, terpolymer EP rubber, double pentaerythritol methacrylate, tolylene diisocyanate, clorafin, urethane, polystyrene, butadiene-styrene rubber, molybdenumdisulphide, polyether ester amides, sodium alkyl benzene sulfonate, sodium antimonate, phenyl alkylsulfonate, polycarbazole base acrylate is mixed, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 5200r/min, jitter time is 45min,
(2) add the polydimethylsiloxane of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion about 5000r/min, and jitter time is 40min;
(3) add the dibutyl tin laurate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion about 4700r/min, and jitter time is 30min; Mix rear obtained this product.
embodiment 3
Marine ship in the present embodiment waterproof acid and alkali-resistance fire retardant insulating power cable material, be made up of the component of following mass fraction: chlorinated polyethylene rubber 56 parts, maleic anhydride grafted polyethylene 58 parts, modified butadiene acrylonitrile rubber 54 parts, triphenylphosphate 58 parts, trioctyl trimellitate 54 parts, water-ground limestone 58 parts, polydimethylsiloxane 54 parts, terpolymer EP rubber 60 parts, double pentaerythritol methacrylate 54 parts, tolylene diisocyanate 58 parts, clorafin 54 parts, urethane 58 parts, polystyrene 54 parts, butadiene-styrene rubber 58 parts, molybdenumdisulphide 54 parts, polyether ester amides 58 parts, sodium alkyl benzene sulfonate 54 parts, sodium antimonate 54 parts, phenyl alkylsulfonate 58 parts, dibutyl tin laurate 54 parts, polycarbazole base acrylate 58 parts.
Above-mentioned marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material preparation method step is as follows:
(1) by the chlorinated polyethylene rubber of described mass fraction, maleic anhydride grafted polyethylene, modified butadiene acrylonitrile rubber, triphenylphosphate, trioctyl trimellitate, water-ground limestone, terpolymer EP rubber, double pentaerythritol methacrylate, tolylene diisocyanate, clorafin, urethane, polystyrene, butadiene-styrene rubber, molybdenumdisulphide, polyether ester amides, sodium alkyl benzene sulfonate, sodium antimonate, phenyl alkylsulfonate, polycarbazole base acrylate is mixed, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, jitter time is 30min,
(2) add the polydimethylsiloxane of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) add the dibutyl tin laurate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 4600r/min, and jitter time is 20min; Mix rear obtained this product.
Carry out performance measurement for the cable material in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available cable material, measured data are as shown in table 1.Fire protection flame retarding level estimate adopts UL94 standard.
Table 1 the performance test results
Visible, material of the present invention has corrosion-resistant, fire-retardant, waterproof, insulating property preferably.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. a marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material, it is characterized in that: be made up of the component of following mass fraction: chlorinated polyethylene rubber 52 ~ 56 parts, maleic anhydride grafted polyethylene 54 ~ 58 parts, modified butadiene acrylonitrile rubber 50 ~ 54 parts, triphenylphosphate 54 ~ 58 parts, trioctyl trimellitate 50 ~ 54 parts, water-ground limestone 54 ~ 58 parts, polydimethylsiloxane 50 ~ 54 parts, terpolymer EP rubber 56 ~ 60 parts, double pentaerythritol methacrylate 50 ~ 54 parts, tolylene diisocyanate 54 ~ 58 parts, clorafin 50 ~ 54 parts, urethane 54 ~ 58 parts, polystyrene 50 ~ 54 parts, butadiene-styrene rubber 54 ~ 58 parts, molybdenumdisulphide 50 ~ 54 parts, polyether ester amides 54 ~ 58 parts, sodium alkyl benzene sulfonate 50 ~ 54 parts, sodium antimonate 50 ~ 54 parts, phenyl alkylsulfonate 54 ~ 58 parts, dibutyl tin laurate 50 ~ 54 parts, polycarbazole base acrylate 54 ~ 58 parts.
2. marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material according to claim 1, it is characterized in that: described marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material is made up of the component of following mass fraction: chlorinated polyethylene rubber 52 parts, maleic anhydride grafted polyethylene 54 parts, modified butadiene acrylonitrile rubber 50 parts, triphenylphosphate 54 parts, trioctyl trimellitate 50 parts, water-ground limestone 54 parts, polydimethylsiloxane 50 parts, terpolymer EP rubber 56 parts, double pentaerythritol methacrylate 50 parts, tolylene diisocyanate 54 parts, clorafin 50 parts, urethane 54 parts, polystyrene 50 parts, butadiene-styrene rubber 54 parts, molybdenumdisulphide 50 parts, polyether ester amides 54 parts, sodium alkyl benzene sulfonate 50 parts, sodium antimonate 50 parts, phenyl alkylsulfonate 54 parts, dibutyl tin laurate 50 parts, polycarbazole base acrylate 54 parts.
3. according to the waterproof acid and alkali-resistance fire retardant insulating power cable material of the marine ship described in claim 1 to 2, it is characterized in that: described marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material is made up of the component of following mass fraction: chlorinated polyethylene rubber 54 parts, maleic anhydride grafted polyethylene 56 parts, modified butadiene acrylonitrile rubber 52 parts, triphenylphosphate 56 parts, trioctyl trimellitate 52 parts, water-ground limestone 56 parts, polydimethylsiloxane 52 parts, terpolymer EP rubber 58 parts, double pentaerythritol methacrylate 52 parts, tolylene diisocyanate 56 parts, clorafin 52 parts, urethane 56 parts, polystyrene 52 parts, butadiene-styrene rubber 56 parts, molybdenumdisulphide 52 parts, polyether ester amides 56 parts, sodium alkyl benzene sulfonate 52 parts, sodium antimonate 52 parts, phenyl alkylsulfonate 56 parts, dibutyl tin laurate 52 parts, polycarbazole base acrylate 56 parts.
4. the waterproof acid and alkali-resistance fire retardant insulating power cable material of the marine ship according to claims 1 to 3, it is characterized in that: described marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material is made up of the component of following mass fraction: chlorinated polyethylene rubber 56 parts, maleic anhydride grafted polyethylene 58 parts, modified butadiene acrylonitrile rubber 54 parts, triphenylphosphate 58 parts, trioctyl trimellitate 54 parts, water-ground limestone 58 parts, polydimethylsiloxane 54 parts, terpolymer EP rubber 60 parts, double pentaerythritol methacrylate 54 parts, tolylene diisocyanate 58 parts, clorafin 54 parts, urethane 58 parts, polystyrene 54 parts, butadiene-styrene rubber 58 parts, molybdenumdisulphide 54 parts, polyether ester amides 58 parts, sodium alkyl benzene sulfonate 54 parts, sodium antimonate 54 parts, phenyl alkylsulfonate 58 parts, dibutyl tin laurate 54 parts, polycarbazole base acrylate 58 parts.
5. the waterproof acid and alkali-resistance fire retardant insulating power cable material of the marine ship according to claim 1 or 4, is characterized in that: described marine ship waterproof acid and alkali-resistance fire retardant insulating power cable material preparation method step is as follows:
(1) by the chlorinated polyethylene rubber of described mass fraction, maleic anhydride grafted polyethylene, modified butadiene acrylonitrile rubber, triphenylphosphate, trioctyl trimellitate, water-ground limestone, terpolymer EP rubber, double pentaerythritol methacrylate, tolylene diisocyanate, clorafin, urethane, polystyrene, butadiene-styrene rubber, molybdenumdisulphide, polyether ester amides, sodium alkyl benzene sulfonate, sodium antimonate, phenyl alkylsulfonate, polycarbazole base acrylate is mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min,
(2) add the polydimethylsiloxane of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the dibutyl tin laurate of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
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| CN107342130A (en) * | 2017-05-16 | 2017-11-10 | 安徽瑞鑫自动化仪表有限公司 | A kind of instrument cable |
| CN108546402A (en) * | 2018-04-04 | 2018-09-18 | 苏州耐思特塑胶有限公司 | A kind of preparation method of flame retardant type sealing element rubber material |
| CN108690272A (en) * | 2018-06-13 | 2018-10-23 | 合肥浦尔菲电线科技有限公司 | A kind of water-fast corrosion proof cable material of marine settings pressure resistance |
| CN109206692A (en) * | 2018-07-26 | 2019-01-15 | 合肥安力电力工程有限公司 | A kind of high fire-retardance heat proof cable sheath and preparation method thereof |
| CN110845800A (en) * | 2018-08-20 | 2020-02-28 | 南京浩宁达电气有限公司 | Preparation method of insulating material for cable insulating layer |
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| CN102775689A (en) * | 2011-05-13 | 2012-11-14 | 远东电缆有限公司 | Torsion and cold resistant flame-retardant sheath rubber for wind power generation flexible cable |
| CN103467971A (en) * | 2013-09-27 | 2013-12-25 | 广东中德电缆有限公司 | Modified high-flame-retardation weather-resistant polyurethane cable material and preparing method thereof |
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| CN105440460A (en) * | 2015-12-30 | 2016-03-30 | 合肥星辰电线电缆股份有限公司 | Preparation process of rubber cable sheath |
| CN105575468A (en) * | 2016-02-02 | 2016-05-11 | 安徽复兴电缆集团有限公司 | Low-smoke halogen-free cable for computers |
| CN105694249A (en) * | 2016-03-19 | 2016-06-22 | 孟根森 | Multifunctional cable for high-speed rail construction and installation |
| CN105860171A (en) * | 2016-05-20 | 2016-08-17 | 安徽新科电缆集团股份有限公司 | Formula and preparation method of ultraviolet-proof cable sheath |
| CN105801946A (en) * | 2016-05-23 | 2016-07-27 | 国网山东省电力公司蓬莱市供电公司 | Acid-and-alkali-resistant power cable protective layer material |
| CN106189162A (en) * | 2016-07-29 | 2016-12-07 | 华蓥伟创立电子科技有限公司 | A kind of communication insulation acid and alkali-resistance flame retardant cable |
| CN106832876A (en) * | 2016-12-21 | 2017-06-13 | 柳州市昌泉贸易有限公司 | A kind of preparation method of oil resistant fire-resistant cable material |
| CN106832798A (en) * | 2016-12-30 | 2017-06-13 | 安徽远征电缆科技有限公司 | A kind of cable insulating barrier |
| CN107342130A (en) * | 2017-05-16 | 2017-11-10 | 安徽瑞鑫自动化仪表有限公司 | A kind of instrument cable |
| CN107342130B (en) * | 2017-05-16 | 2019-07-02 | 安徽瑞鑫自动化仪表有限公司 | A kind of instrument cable |
| CN107312320A (en) * | 2017-07-31 | 2017-11-03 | 铜陵市铜都特种线缆有限公司 | A kind of jacket layer material for underground power cable |
| CN108546402A (en) * | 2018-04-04 | 2018-09-18 | 苏州耐思特塑胶有限公司 | A kind of preparation method of flame retardant type sealing element rubber material |
| CN108690272A (en) * | 2018-06-13 | 2018-10-23 | 合肥浦尔菲电线科技有限公司 | A kind of water-fast corrosion proof cable material of marine settings pressure resistance |
| CN109206692A (en) * | 2018-07-26 | 2019-01-15 | 合肥安力电力工程有限公司 | A kind of high fire-retardance heat proof cable sheath and preparation method thereof |
| CN110845800A (en) * | 2018-08-20 | 2020-02-28 | 南京浩宁达电气有限公司 | Preparation method of insulating material for cable insulating layer |
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Application publication date: 20151209 |