CN105130392B - Iron-red fancy glazed porcelain prepared from josephinite tailing slag - Google Patents

Iron-red fancy glazed porcelain prepared from josephinite tailing slag Download PDF

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CN105130392B
CN105130392B CN201510452602.5A CN201510452602A CN105130392B CN 105130392 B CN105130392 B CN 105130392B CN 201510452602 A CN201510452602 A CN 201510452602A CN 105130392 B CN105130392 B CN 105130392B
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glaze
ferronickel
clay
iron
josephinite
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CN105130392A (en
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毛录贵
郑金鼎
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QUANZHOU YANGGUANG CHUANGYI CERAMIC CO., LTD.
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Quanzhou Sunshine Creative Ceramics Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention relates to the technical field of ceramic and concretely relates to an iron-red fancy glazed porcelain prepared from josephinite tailing slag. The iron-red fancy glazed porcelain prepared from josephinite tailing slag has a blank formula comprising josephinite tailings, clay, pyrophillite, quartz, alkalifeldspar and limestone and has a glaze formula comprising josephinite tailings, potassium feldspar, clay, quartz, iron oxide and phosphoric pentoxide. The iron-red fancy glazed porcelain comprises a lot of dispersed small liquid drops. The glaze is brown. Bean-shaped spots and blocks are distributed on the glaze and are orange. Iron oxide in the josephinite tailings is not melt at a high temperature and can individually adhere to the glaze surface in a liquid drop form, and after cooling, large red flower-shaped iron crystals are formed so that iron-red fancy glaze is formed. The waste josephinite tailings are recycled so that solid waste discharge is reduced, a porcelain clay raw ore use amount is reduced and ore product resource development is reduced.

Description

The iron oxide red fancy glaze porcelain prepared using ferronickel mine tailings
Technical field
The present invention relates to ceramic technology field, is specifically related to iron oxide red fancy glaze porcelain prepared by a kind of utilization ferronickel mine tailings Device.
Background technology
With the high speed development of economic society, the quality of life of people increasingly improves, and consumption idea also constantly changes, Ask ceramic there be practicality, have artistry and sight again.Existing glaze colours by firing temperature be divided into high-temperature glaze and Low temperature glaze;Clear frit, opaque glaze can be divided, coloured glaze, had light glaze, mat glaze, crack glaze (hacking), crystalline glaze by barment tag Deng.
Mineral Resources in China is enriched, and greatly, after exploitation purification, its mine tailings is not utilized reserves, and mine tailing is piled up such as Mountain, not only around severe contamination, while waste substantial amounts of resource.Mine tailing takes a large amount of soils, cause soil erosion and The problems such as environmental pollution, the in recent years comprehensive utilization to mine tailing, are also valued by the people, and such as Chinese patent CN103145449B is public " a kind of method that iron tailings is prepared into into preparing ceramic clinker glaze " has been opened, utilization ways and the preparation of iron tailings has been this method provided Black glaze, coffee color glaze, the method for brown glaze, and for example Chinese patent CN 104529549A disclose " with iron tailings prepare tea Leaf end glaze and preparation method " this method provides method of the utilization ways of iron tailings to prepare Folium Camelliae sinensis glaze, and said method is all It is that ceramic glaze is prepared by iron tailings, due to the restriction of raw material and formulation composition, the ferrum for being prepared by ferronickel mine tailings at present The technology of the porcelain of Flos Carthami glaze, has not seen the record of pertinent literature.
The content of the invention
To overcome deficiency of the prior art, the present invention to provide iron oxide red fancy glaze porcelain prepared by a kind of utilization ferronickel mine tailings And its hack method.
For achieving the above object, the technical solution used in the present invention is as follows:
9th, the iron oxide red fancy glaze porcelain prepared using ferronickel mine tailings, it is characterised in that
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 40-50, clay 20-30, pyrophillite 5-10, Quartzy 5-10, potassium albite 10-15, limestone 5-10;
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 25-35, potassium feldspar 20-30, clay 20-30, Quartzy 5-10, ferrum oxide 5-10, phosphorus pentoxide 2-7.
10th, iron oxide red fancy glaze porcelain prepared by utilization ferronickel mine tailings according to claim 1, it is characterised in that:
The chemical constituent content of the body recipe is as follows:SiO2 50-60、AL2O3 12-18、MgO 7-10、CaO 4- 8、K2O 4-7、Na2O 3-5、Fe2O3 5-10、MnO2 1-2、TiO20-3 loss on ignitions 2-3;
The chemical constituent content of the glaze formula is as follows:SiO2 40-50、AL2O3 14-18、MgO 5-10 CaO 5- 10、K2O 5-8、Na2O 1-2、Fe2O3 8-14、P2O5 1-2。
Optimization, its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 45, clay 25, pyrophillite 6, stone English 6, potassium albite 11, limestone 7;Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 31, potassium feldspar 25, Clay 23, quartz 9, ferrum oxide 7, phosphorus pentoxide 5.
Optimization, the chemical constituent content of body recipe is as follows:SiO2 56、AL2O3 13、MgO 8、CaO 4、K2O 5、 Na2O 4, Fe2O3 6, MnO2 1, TiO2 1, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 48、AL2O3 17、MgO 7、CaO 8、K2O 6、Na2O 1、Fe2O3 12、P2O5 1。
Optimization, its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 48, clay 21, pyrophillite 8, stone English 9, potassium albite 11, limestone 6;Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 28, potassium feldspar 29, Clay 20, quartz 7, ferrum oxide 10, phosphorus pentoxide 6.
Optimization, the chemical constituent content of body recipe is as follows:SiO253、AL2O313、MgO 7、CaO5、K2O 6、Na2O 3、Fe2O3 9、MnO22nd, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 43、AL2O3 17、MgO 9、CaO 8、K2O 8、Na2O 2、Fe2O3 12、P2O5 1。
Optimization, body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 42, clay 20, pyrophillite 6, quartz 10th, potassium albite 14, limestone 8;Its glaze formula is mixed to prepare by following parts by weight:It is ferronickel mine tailing 25, potassium feldspar 28, viscous Soil 24, quartz 7, ferrum oxide 9, phosphorus pentoxide 7.
Optimization, the chemical constituent content of body recipe is as follows:SiO2 57、AL2O3 13、MgO 9、CaO 4、K2O 4、 Na2O 4、Fe2O3 6、MnO21st, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 49、AL2O3 15、MgO 6、CaO 8、K2O 8、Na2O 1、Fe2O3 12、P2O5 1。
The iron oxide red fancy glaze porcelain prepared from the above-mentioned description of this invention, the utilization ferronickel mine tailings that the present invention is provided Device, is main base glaze raw material using the ferronickel mine tailings discarded in tailing dam, and iron oxide red flower is made by adding corresponding material Glaze artistic porcelain and its processing technology;
Prepared iron oxide red fancy glaze porcelain is made up of many scattered fine droplets, glaze for brown, be distributed with glaze The speckle and bulk of bean shape, in Chinese red, does not melt in high temperature by using the ferrum oxide in ferronickel mine tailing, individually with drop Form be attached to glaze layer surface, bright red flower-shaped ferrum crystallization is formed after cooling, iron-red glaze is formed;
Replace expensive china clay as one of primary raw material of the production iron-red glaze art work by the use of ferronickel mine tailing, energetically will be useless The resource of tailings resource abandoned is recycled, and is reduced solid waste discharge, is reduced ceramic clay raw ore consumption, is saved mineral resources and is opened Send out.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
The iron oxide red fancy glaze porcelain prepared using ferronickel mine tailings, it is characterised in that
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 40-50, clay 20-30, pyrophillite 5-10, Quartzy 5-10, potassium albite 10-15, limestone 5-10;The chemical constituent content of body recipe is as follows:SiO2 50-60、AL2O3 12-18、MgO 7-10、CaO 4-8、K2O 4-7、Na2O 3-5、Fe2O35-10、MnO2 1-2、TiO20-3 loss on ignitions 2-3.
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 25-35, potassium feldspar 20-30, clay 20-30, Quartzy 5-10, ferrum oxide 5-10, phosphorus pentoxide 2-7;The chemical constituent content of glaze formula is as follows:SiO2 40-50、AL2O3 14-18、MgO 5-10CaO 5-10、K2O 5-8、Na2O 1-2、Fe2O3 8-14、P2O5 1-2。
Specific embodiment one:
Iron oxide red fancy glaze porcelain prepared by a kind of utilization ferronickel mine tailings,
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 45, clay 25, pyrophillite 6, quartz 6, potassium sodium Anhydrite 11, limestone 7;The chemical constituent content of body recipe is as follows:SiO2 56、AL2O3 13、MgO 8、CaO 4、K2O 5、 Na2O 4, Fe2O3 6, MnO2 1, TiO2 1, loss on ignition 2.
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 31, potassium feldspar 25, clay 23, quartz 9, oxygen Change ferrum 7, phosphorus pentoxide 5;The chemical constituent content of glaze formula is as follows:SiO2 48、AL2O3 17、MgO 7、CaO 8、K2O 6、Na2O 1、Fe2O3 12、P2O5 1。
Specific embodiment two:
Iron oxide red fancy glaze porcelain prepared by a kind of utilization ferronickel mine tailings,
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 48, clay 21, pyrophillite 8, quartz 9, potassium sodium Anhydrite 11, limestone 6;The chemical constituent content of body recipe is as follows:SiO2 53、AL2O3 13、MgO 7、CaO5、K2O 6、 Na2O 3、Fe2O3 9、MnO22nd, loss on ignition 2.
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 28, potassium feldspar 29, clay 20, quartz 7, oxygen Change ferrum 10, phosphorus pentoxide 6;The chemical constituent content of glaze formula is as follows:SiO2 43、AL2O3 17、MgO 9、CaO 8、K2O 8、Na2O 2、Fe2O3 12、P2O5 1。
Specific embodiment three,
Iron oxide red fancy glaze porcelain prepared by a kind of utilization ferronickel mine tailings,
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 42, clay 20, pyrophillite 6, quartz 10, potassium Albite 14, limestone 8;The chemical constituent content of body recipe is as follows:SiO2 57、AL2O3 13、MgO 9、CaO 4、K2O 4、Na2O 4、Fe2O3 6、MnO21st, loss on ignition 2.
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 25, potassium feldspar 28, clay 24, quartz 7, oxygen Change ferrum 9, phosphorus pentoxide 7;The chemical constituent content of glaze formula is as follows:SiO2 49、AL2O3 15、MgO 6、CaO 8、K2O 8、Na2O 1、Fe2O3 12、P2O5 1。
Iron oxide red fancy glaze porcelain and its preparation technology prepared by the utilization ferronickel mine tailings that the present invention is provided, using discarding in tail The ferronickel mine tailings on ore deposit dam are main base glaze raw material, make iron oxide red fancy glaze artistic porcelain and its system by adding corresponding material Make technique;Prepared iron oxide red fancy glaze porcelain is made up of many scattered fine droplets, glaze for brown, bean is distributed with glaze The speckle and bulk of shape, in Chinese red, does not melt in high temperature by using the ferrum oxide in ferronickel mine tailing, individually with drop Form is attached to glaze layer surface, forms bright red flower-shaped ferrum crystallization, form iron-red glaze after cooling;Replace high using ferronickel mine tailing Discarded resource of tailings resource is recycled energetically by expensive china clay as one of primary raw material for producing the iron-red glaze art work, Solid waste discharge is reduced, ceramic clay raw ore consumption is reduced, exploitation of mineral resources is saved.
Some specific embodiments of the present invention are above are only, but the design concept of the present invention is not limited thereto, all profits The change of unsubstantiality is carried out to the present invention with this design, the behavior for invading the scope of the present invention all should be belonged to.

Claims (8)

1. the iron oxide red fancy glaze porcelain for being prepared using ferronickel mine tailings, it is characterised in that
Its body recipe is mixed to prepare by following parts by weight:Ferronickel mine tailing 40-50, clay 20-30, pyrophillite 5-10, quartz 5-10, potassium albite 10-15, limestone 5-10;
Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 25-35, potassium feldspar 20-30, clay 20-30, quartz 5-10, ferrum oxide 5-10, phosphorus pentoxide 2-7.
2. the iron oxide red fancy glaze porcelain that prepared by utilization ferronickel mine tailings according to claim 1, it is characterised in that:
The chemical constituent content of the body recipe is as follows:SiO2 50-60、Al2O3 12-18、MgO 7-10、CaO 4-8、K2O 4-7、Na2O 3-5、Fe2O3 5-10、MnO2 1-2、TiO20-3 loss on ignitions 2-3;
The chemical constituent content of the glaze formula is as follows:SiO2 40-50、Al2O3 14-18、MgO 5-10CaO 5-10、K2O 5-8、Na2O 1-2、Fe2O3 8-14、P2O5 1-2。
3. the iron oxide red fancy glaze porcelain that prepared by utilization ferronickel mine tailings according to claim 1 or claim 2, it is characterised in that its base substrate Formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 45, clay 25, pyrophillite 6, quartz 6, potassium albite 11, limestone 7;Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 31, potassium feldspar 25, clay 23, quartz 9, ferrum oxide 7, Phosphorus pentoxide 5.
4. the iron oxide red fancy glaze porcelain for being prepared using ferronickel mine tailings according to claim 3, it is characterised in that body recipe Chemical constituent content is as follows:SiO2 56、Al2O3 13、MgO 8、CaO 4、K2O 5、Na2O 4、Fe2O3 6、MnO2 1、TiO2 1st, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 48、Al2O3 17、MgO 7、CaO 8、K2O 6、Na2O 1、 Fe2O3 12、P2O5 1。
5. the iron oxide red fancy glaze porcelain that prepared by utilization ferronickel mine tailings according to claim 1 or claim 2, it is characterised in that its base substrate Formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 48, clay 21, pyrophillite 8, quartz 9, potassium albite 11, limestone 6;Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 28, potassium feldspar 29, clay 20, quartz 7, ferrum oxide 10, Phosphorus pentoxide 6.
6. the iron oxide red fancy glaze porcelain for being prepared using ferronickel mine tailings according to claim 5, it is characterised in that body recipe Chemical constituent content is as follows:SiO2 53、Al2O3 13、MgO 7、CaO5、K2O 6、Na2O 3、Fe2O3 9、MnO22nd, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 43、Al2O3 17、MgO 9、CaO 8、K2O 8、Na2O 2、Fe2O3 12、P2O5 1。
7. the iron oxide red fancy glaze porcelain that prepared by utilization ferronickel mine tailings according to claim 1 or claim 2, it is characterised in that its base substrate Formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 42, clay 20, pyrophillite 6, quartz 10, potassium albite 14, limestone 8;Its glaze formula is mixed to prepare by following parts by weight:Ferronickel mine tailing 25, potassium feldspar 28, clay 24, quartz 7, ferrum oxide 9, Phosphorus pentoxide 7.
8. the iron oxide red fancy glaze porcelain for being prepared using ferronickel mine tailings according to claim 7, it is characterised in that body recipe Chemical constituent content is as follows:SiO2 57、Al2O3 13、MgO 9、CaO 4、K2O 4、Na2O 4、Fe2O3 6、MnO21st, loss on ignition 2;The chemical constituent content of glaze formula is as follows:SiO2 49、Al2O3 15、MgO 6、CaO 8、K2O 8、Na2O 1、Fe2O3 12、P2O5 1。
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CN104591695A (en) * 2015-02-03 2015-05-06 朱立民 Manufacturing method of large-sized regenerated ceramic
CN107266033B (en) * 2017-08-06 2020-11-27 福建省德化世盛陶瓷有限公司 Iron rust red glaze ceramic prepared from Dehua Yangshan magnetite tailings and process thereof
CN110526579B (en) * 2019-08-02 2022-02-11 东北大学 Method for preparing glaze by adopting gold ore associated altered rock
CN111087172B (en) * 2019-12-22 2022-05-31 南宁师范大学 Preparation method and application of plant ash glaze special for Nanning red pottery
CN114315312A (en) * 2021-12-17 2022-04-12 邱小平 Aurous ceramic adopting lithium battery waste and preparation method thereof

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* Cited by examiner, † Cited by third party
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CN103145449B (en) * 2012-12-28 2014-05-28 北京科技大学 Method for preparing iron tailing into ceramic frit glaze
CN104211444B (en) * 2014-09-03 2015-08-12 江苏省宜兴彩陶工艺厂 The preparation method of transmutation Sorghum pigment fancy glaze
CN104446660B (en) * 2014-12-04 2016-03-09 王占一 Recrystallized ceramic color glaze
CN104591790A (en) * 2014-12-25 2015-05-06 醴陵陶润实业发展有限公司 High-temperature iron-red glaze and preparation method thereof
CN104529549B (en) * 2015-02-02 2016-03-09 王占一 The tea-dust glaze prepared with iron tailings and preparation method

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