CN105086125A - Anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material for outer sheaths of outdoor overhead laid power lines and method for manufacturing anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material - Google Patents
Anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material for outer sheaths of outdoor overhead laid power lines and method for manufacturing anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material Download PDFInfo
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- -1 ethylene-chlorotrifluoroethylene Chemical group 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 title claims abstract description 33
- 230000003712 anti-aging effect Effects 0.000 title claims abstract description 18
- 229920001780 ECTFE Polymers 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001153 Polydicyclopentadiene Polymers 0.000 claims abstract description 8
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 8
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 8
- QWDBCIAVABMJPP-UHFFFAOYSA-N Diisopropyl phthalate Chemical compound CC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)C QWDBCIAVABMJPP-UHFFFAOYSA-N 0.000 claims abstract description 7
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims abstract description 7
- MQHNKCZKNAJROC-UHFFFAOYSA-N phthalic acid dipropyl ester Natural products CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 claims abstract description 7
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001038 ethylene copolymer Polymers 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 16
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 14
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 claims description 14
- 230000007797 corrosion Effects 0.000 claims description 12
- 238000005260 corrosion Methods 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229920002125 Sokalan® Polymers 0.000 claims description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 7
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 7
- 229910001593 boehmite Inorganic materials 0.000 claims description 7
- 229910052599 brucite Inorganic materials 0.000 claims description 7
- 229910021540 colemanite Inorganic materials 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 7
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 7
- 239000004584 polyacrylic acid Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000004575 stone Substances 0.000 claims description 7
- UYJHFNNLKCQMOX-UHFFFAOYSA-L 1,1'-biphenyl dichlorotin Chemical compound Cl[Sn]Cl.C1=CC=CC=C1C1=CC=CC=C1 UYJHFNNLKCQMOX-UHFFFAOYSA-L 0.000 claims description 6
- VZPHSJLSYGMBGE-UHFFFAOYSA-N C(=O)(O)C1=CC=C(C=C1)P(C1=CC=CC=C1)=O Chemical compound C(=O)(O)C1=CC=C(C=C1)P(C1=CC=CC=C1)=O VZPHSJLSYGMBGE-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 229940087654 iron carbonyl Drugs 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- UVTXHAOLTBFLDL-UHFFFAOYSA-N 4-[(4-carboxyphenyl)-phenylphosphoryl]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1P(=O)(C=1C=CC(=CC=1)C(O)=O)C1=CC=CC=C1 UVTXHAOLTBFLDL-UHFFFAOYSA-N 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- 229940083916 aluminum distearate Drugs 0.000 abstract 1
- RDIVANOKKPKCTO-UHFFFAOYSA-K aluminum;octadecanoate;hydroxide Chemical compound [OH-].[Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O RDIVANOKKPKCTO-UHFFFAOYSA-K 0.000 abstract 1
- ISXUHJXWYNONDI-UHFFFAOYSA-L dichloro(diphenyl)stannane Chemical compound C=1C=CC=CC=1[Sn](Cl)(Cl)C1=CC=CC=C1 ISXUHJXWYNONDI-UHFFFAOYSA-L 0.000 abstract 1
- 229910052666 hauyne Inorganic materials 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 5
- 241000272165 Charadriidae Species 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with monomers containing atoms other than carbon, hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material for outer sheaths of outdoor overhead laid power lines and a method for manufacturing the anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material. The anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material comprises, by weight, 27-39 parts of ethylene-chlorotrifluoroethylene copolymers, 16-28 parts of polydiallylphthalate, 10-15 parts of polydicyclopentadiene, 2-4 parts of diphenyltin dichloride, 3-5 parts of tributylamine, 10-15 parts of bis (4-carboxyphenyl) phenylphosphine oxide, 4-8 parts of carbonyl iron, 3-6 parts of ethylene bis stearamide, 8-13 parts of nano titanium nitride, 12-17 parts of diisopropyl phthalate, 5-10 parts of nano molybdenum trioxide, 10-15 parts of zirconium phosphate, 4-6 parts of aluminum distearate, 5-7 parts of Fischer-Tropsch wax, 15-20 parts of hauynite powder and 17-22 parts of flame-retardant particles. The anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material and the method have the advantage that the material is excellent in anti-aging and anticorrosion properties.
Description
Technical field
The present invention relates to a kind of outdoor making somebody a mere figurehead and lay supply lead oversheath anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material and preparation method thereof, belong to processing of high molecular material technical field.
Background technology
Supply lead is the electric wire of transmission current, and it is primarily of oversheath, inner sheath, conductor composition.Oversheath is referred to as again to protect sheath, and be the outmost one deck sheath of supply lead, this layer of oversheath plays a part protection power source line.Oversheath need have powerful characteristic, the characteristics such as good in the interference of high temperature resistant, low temperature resistant, against natural light, winding degree performance, high life, material environment friendly.Along with the fast development of science and technology, family expenses on existing market outdoor is built on stilts lays the demand that the resistance to deterioration of supply lead jacket material and erosion resistance more and more cannot meet market.
Summary of the invention
The object of the invention is to for prior art not enough, provide the outdoor of a kind of resistance to deterioration and excellent corrosion resistance to make somebody a mere figurehead and lay supply lead oversheath anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of outdoor making somebody a mere figurehead lays the anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material of supply lead oversheath, be made up of the raw material of following weight part: ethylene-chlorotrifluoro-ethylene copolymer 27-39, polydiallyl phthalate 16-28, polydicyclopentadiene 10-15, phenylbenzene tindichloride 2-4, tri-n-butylamine 3-5, two (4-carboxyl phenyl) phenyl phosphine oxide 10-15, iron carbonyl 4-8, ethylene bis stearamide 3-6, Nano titanium nitride 8-13, diisopropyl phthalate 12-17, nano-sized molybdenum oxide 5-10, zirconium phosphate 10-15, double stearic acid aluminium 4-6, Fischer-Tropsch wax 5-7, blue party stone flour 15-20, fire-retardant particle 17-22,
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight part: colemanite 24-36, brucite 16-28, boehmite 12-24, expanded graphite 10-15, Sodium Aluminium Carbonate Basic 6-12, basic magnesium chloride 5-10, brominated bisphenol-A epoxy resin 24-32, polyacrylic acid pentabromo-benzyl ester 25-35, hexaphenoxycyclotriphosphazene 10-15, dipentaerythritol diphosphites 5-10, chlorinatedpolyethylene 35-45; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 100-150 mesh sieve, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 70-80 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 90-100 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
Above-mentioned fire-retardant particle adopts colemanite, brucite, boehmite, expanded graphite, Sodium Aluminium Carbonate Basic, the inorganic combustion inhibitor compound uses such as basic magnesium chloride, and adopt brominated bisphenol-A epoxy resin, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene, dipentaerythritol diphosphites, the high molecular weight flame retardants such as chlorinatedpolyethylene are to its blending and modifying, the two is synergy mutually, not only significantly can improve the interface performance of inorganic combustion inhibitor, improve the consistency of itself and supply lead macromolecule matrix, the flame retardant effect of high molecular weight flame retardant can also be improved, in a word, this fire-retardant particle has excellent flame retardant properties, applied widely, most of Polymer Systems can be applied to.
Outdoor is maked somebody a mere figurehead and is laid the preparation method of supply lead oversheath with anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material, comprises the following steps:
(1) ethylene-chlorotrifluoro-ethylene copolymer, two (4-carboxyl phenyl) phenyl phosphine oxide, Nano titanium nitride, iron carbonyl, double stearic acid aluminium are added in mixing roll, mixing 3-6min at 100-120 DEG C of temperature, discharging;
(2) polydiallyl phthalate, polydicyclopentadiene, nano-sized molybdenum oxide, zirconium phosphate, ethylene bis stearamide are added in mixing roll, mixing 4-7min at 80-100 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, phenylbenzene tindichloride, tri-n-butylamine, Fischer-Tropsch wax, blue party stone flour, diisopropyl phthalate, be 240-260 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 60-80r/min, pelletizing after water cooling, dry, get product.
Beneficial effect of the present invention:
Outdoor provided by the invention is built on stilts to be laid supply lead jacket material and is made up of macromolecular material compounds such as ethylene-chlorotrifluoro-ethylene copolymer, polydiallyl phthalate, polydicyclopentadienes, and add the mineral fillers such as Nano titanium nitride, nano-sized molybdenum oxide, zirconium phosphate, blue party stone flour, make material when outdoor laid, by daylight, drench with rain and the impact of the condition such as freezing, there is excellent resistance to deterioration and erosion resistance.
Embodiment
A kind of outdoor making somebody a mere figurehead lays the anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material of supply lead oversheath, be made up of the raw material of following weight (kg): ethylene-chlorotrifluoro-ethylene copolymer 33, polydiallyl phthalate 24, polydicyclopentadiene 11, phenylbenzene tindichloride 3, tri-n-butylamine 4, two (4-carboxyl phenyl) phenyl phosphine oxide 12, iron carbonyl 6, ethylene bis stearamide 4, Nano titanium nitride 11, diisopropyl phthalate 14, nano-sized molybdenum oxide 8, zirconium phosphate 12, double stearic acid aluminium 5, Fischer-Tropsch wax 6, blue party stone flour 18, fire-retardant particle 19,
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight (kg): colemanite 25, brucite 18, boehmite 14, expanded graphite 12, Sodium Aluminium Carbonate Basic 8, basic magnesium chloride 7, brominated bisphenol-A epoxy resin 28, polyacrylic acid pentabromo-benzyl ester 27, hexaphenoxycyclotriphosphazene 11, dipentaerythritol diphosphites 8, chlorinatedpolyethylene 38; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 150 mesh sieves, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 80 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 95 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
Outdoor is maked somebody a mere figurehead and is laid the preparation method of supply lead oversheath with anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material, comprises the following steps:
(1) ethylene-chlorotrifluoro-ethylene copolymer, two (4-carboxyl phenyl) phenyl phosphine oxide, Nano titanium nitride, iron carbonyl, double stearic acid aluminium are added in mixing roll, mixing 3-6min at 100-120 DEG C of temperature, discharging;
(2) polydiallyl phthalate, polydicyclopentadiene, nano-sized molybdenum oxide, zirconium phosphate, ethylene bis stearamide are added in mixing roll, mixing 4-7min at 80-100 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, phenylbenzene tindichloride, tri-n-butylamine, Fischer-Tropsch wax, blue party stone flour, diisopropyl phthalate, be 240-260 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 60-80r/min, pelletizing after water cooling, dry, get product.
The outdoor that above-described embodiment obtains makes somebody a mere figurehead that to lay supply lead oversheath as shown in the table by the performance test results of anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material:
Table 1 outdoor is built on stilts lays the performance test results of supply lead oversheath with anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material
Claims (2)
1. an outdoor is maked somebody a mere figurehead and is laid the anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material of supply lead oversheath, it is characterized in that, be made up of the raw material of following weight part: ethylene-chlorotrifluoro-ethylene copolymer 27-39, polydiallyl phthalate 16-28, polydicyclopentadiene 10-15, phenylbenzene tindichloride 2-4, tri-n-butylamine 3-5, two (4-carboxyl phenyl) phenyl phosphine oxide 10-15, iron carbonyl 4-8, ethylene bis stearamide 3-6, Nano titanium nitride 8-13, diisopropyl phthalate 12-17, nano-sized molybdenum oxide 5-10, zirconium phosphate 10-15, double stearic acid aluminium 4-6, Fischer-Tropsch wax 5-7, blue party stone flour 15-20, fire-retardant particle 17-22,
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight part: colemanite 24-36, brucite 16-28, boehmite 12-24, expanded graphite 10-15, Sodium Aluminium Carbonate Basic 6-12, basic magnesium chloride 5-10, brominated bisphenol-A epoxy resin 24-32, polyacrylic acid pentabromo-benzyl ester 25-35, hexaphenoxycyclotriphosphazene 10-15, dipentaerythritol diphosphites 5-10, chlorinatedpolyethylene 35-45; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 100-150 mesh sieve, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 70-80 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 90-100 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
2. a kind of outdoor according to claim 1 is maked somebody a mere figurehead and is laid the preparation method of supply lead oversheath with anti-aging corrosion-resistant ethylene-chlorotrifluoro-ethylene copolymer material, it is characterized in that, comprises the following steps:
(1) ethylene-chlorotrifluoro-ethylene copolymer, two (4-carboxyl phenyl) phenyl phosphine oxide, Nano titanium nitride, iron carbonyl, double stearic acid aluminium are added in mixing roll, mixing 3-6min at 100-120 DEG C of temperature, discharging;
(2) polydiallyl phthalate, polydicyclopentadiene, nano-sized molybdenum oxide, zirconium phosphate, ethylene bis stearamide are added in mixing roll, mixing 4-7min at 80-100 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, phenylbenzene tindichloride, tri-n-butylamine, Fischer-Tropsch wax, blue party stone flour, diisopropyl phthalate, be 240-260 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 60-80r/min, pelletizing after water cooling, dry, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534744.6A CN105086125A (en) | 2015-08-25 | 2015-08-25 | Anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material for outer sheaths of outdoor overhead laid power lines and method for manufacturing anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510534744.6A CN105086125A (en) | 2015-08-25 | 2015-08-25 | Anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material for outer sheaths of outdoor overhead laid power lines and method for manufacturing anti-aging and anticorrosion ethylene-chlorotrifluoroethylene copolymer material |
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| Publication Number | Publication Date |
|---|---|
| CN105086125A true CN105086125A (en) | 2015-11-25 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1180363A (en) * | 1995-02-13 | 1998-04-29 | 雷伊化学公司 | Fluoropolymer compositions |
| CN101939796A (en) * | 2007-12-28 | 2011-01-05 | 钟渊得克萨斯公司 | Polyimide and fluoropolymer bonding layers with improved bond strength |
| CN103779008A (en) * | 2014-01-13 | 2014-05-07 | 袁志敏 | Macromolecule composite-fiber logging cable and preparation method thereof |
| CN103992629A (en) * | 2014-04-22 | 2014-08-20 | 天长市富信电子有限公司 | Sheath material for automobile power line and preparation method thereof |
| CN104371191A (en) * | 2014-10-30 | 2015-02-25 | 安徽电信器材贸易工业有限责任公司 | Special material for protective casing for preventing pests and rats from biting communication cable and preparation method of special material |
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2015
- 2015-08-25 CN CN201510534744.6A patent/CN105086125A/en active Pending
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| CN1180363A (en) * | 1995-02-13 | 1998-04-29 | 雷伊化学公司 | Fluoropolymer compositions |
| CN101939796A (en) * | 2007-12-28 | 2011-01-05 | 钟渊得克萨斯公司 | Polyimide and fluoropolymer bonding layers with improved bond strength |
| CN103779008A (en) * | 2014-01-13 | 2014-05-07 | 袁志敏 | Macromolecule composite-fiber logging cable and preparation method thereof |
| CN103992629A (en) * | 2014-04-22 | 2014-08-20 | 天长市富信电子有限公司 | Sheath material for automobile power line and preparation method thereof |
| CN104371191A (en) * | 2014-10-30 | 2015-02-25 | 安徽电信器材贸易工业有限责任公司 | Special material for protective casing for preventing pests and rats from biting communication cable and preparation method of special material |
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