CN105084840A - Grade-A fireproof efficient homogeneous thermal self-insulation block - Google Patents

Grade-A fireproof efficient homogeneous thermal self-insulation block Download PDF

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Publication number
CN105084840A
CN105084840A CN201510582803.7A CN201510582803A CN105084840A CN 105084840 A CN105084840 A CN 105084840A CN 201510582803 A CN201510582803 A CN 201510582803A CN 105084840 A CN105084840 A CN 105084840A
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China
Prior art keywords
perlite
water
building block
haydite
heat insulation
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CN201510582803.7A
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CN105084840B (en
Inventor
华雷广
韩金涛
么传杰
常秀丽
张云强
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SHANDONG LIAOJIAN GROUP Co.,Ltd.
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Liaocheng Jinxin Building Energy Saving Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a grade-A fireproof efficient homogeneous thermal self-insulation block belonging to the technical field of building materials. The thermal self-insulation block with relatively high strength, relatively low heat conductivity coefficient as well as relatively strong water resistance and weather resistance is formed through reasonably designing the ratio of materials such as ceramsite, fragmented ceramsite particles, a perlite modifier, perlite, perlite powder, cement, coal ash, silica fume, a water reducing agent, a waterproof agent, a power shrinkage reducing agent and water, so that the national requirement for saving energy of a civil building by 75% at present and in future can be met; in addition, all the materials are inorganic materials, and the fireproof performance is up to the grade A, so that fire hazards of a thermal insulation filler wall of an exterior wall are thoroughly eliminated, meanwhile, the aim of saving energy by 75% is achieved, and the national requirements for the fireproof grade of an external thermal insulation product of the exterior wall and a higher energy-saving standard are met; and the production process is simple, and the grade-A fireproof efficient homogeneous thermal self-insulation block has a relatively high popularization value and a very wide market prospect.

Description

The efficient homogeneous heat insulation building block of a kind of A level fp
Technical field
The present invention relates to the efficient homogeneous heat insulation building block of a kind of A level fp, belong to the technical field of material of construction.
Background technology
Along with country is to the progressively raising of energy conservation standard, the requirement of External Wall energy-saving heat preserving is more and more higher, and the provinces and cities such as the cities such as present Beijing have performed the standard of energy-conservation 75%, Shandong also perform successively, and this is trend of the times.At present, the insulating brick on market is mainly earth and fires and form hollow and fire the burn-free cement brick that adobe or formula material are mainly cement, sand, limestone particle are made.The wall brick of this kind of hollow is empty due to middle portion, hammers into wall nail suspension extension weight and there will be situation about easily loosening.For homogeneous building block, because current techniques limit, the used for filler wall heat insulation building block that can reach energy-conservation 75% mostly is compound heat insulation building block, and namely concrete segment and organic insulation material such as the Material claddings such as styrofoam, extruded sheet, urethane use, to reach energy-saving index.But the organic materials inside composite block still serious fire can occur under certain condition, bring serious threat to the lives and properties of resident, so fire safety problem does not still solve.
Summary of the invention
The object of the present invention is to provide the efficient homogeneous heat insulation building block of A level fp, adopt the materials such as haydite, haydite fragment particle, slag, perlite properties-correcting agent, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent, water, through appropriate design proportioning, through extrusion molding, the present invention thoroughly solves the A level fire safety problem of self-heat preserving building block of exterior wall, and realizes the indices of energy-conservation 75% and architectural exterior-protecting construction.
The technical scheme that technical solution problem of the present invention is taked is:
The efficient homogeneous heat insulation building block of a kind of A level fp, is characterized in that, be made up of following raw material through mechanical presses:
Haydite and haydite fragment particle, slag, perlite properties-correcting agent, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent, water.
Further, be made up through mechanical presses of the raw material of following weight percent:
Haydite and haydite fragment particle 20-30%, slag 3-9%, perlite 30-40%, perlite powder 5-10%, cement 20-30%, flyash 5-10%, silicon ash 1-3%, water reducer 0.2-0.7%, water-resisting agent 0.2-0.6%, powder economization agent 0.1-0.4%, the summation of above material is 100%;
The addition of described water is 50% of above material gross weight;
The addition of described perlite properties-correcting agent is 5% of water addition.
Further, described perlite properties-correcting agent is weak yellow liquid, is the mixture of silane hydrophober and methyl silicate hydrophober.The two combined action, realizes excellent hydrophobicity performance.
Further, in perlite properties-correcting agent, the weight ratio of silane hydrophober, methyl silicate hydrophober is 1:10.
Further, described cement is the one in ordinary Portland cement or complex cement;
Described perlite meets the requirement of JC/T209-2012 " pearlstone ";
Described flyash is second class powered coal ash, and the dioxide-containing silica of described silicon ash is greater than 90%.
Further, described haydite be leca, lytag, coal gangue haydite one or more, tap density is not more than 200kg/m 3;
Described haydite fragment particle is formed by haydite fragmentation, and the particle diameter after fragmentation is between 1-10mm;
The weight ratio of described haydite and haydite fragment particle is 1:1;
Described perlite density is not more than 200kg/m 3;
Described perlite powder density is not more than 100kg/m 3.
Further, described powder economization agent is METOLATP871 powder economization agent, white powder, and activeconstituents can be completely soluble in water, and its effective constituent is the diatomic alcohol compounds on carrier, and aerated density is 400g/L.
Further, described water-resisting agent is ferric chloride waterproofing agent;
Described water reducer is methyne sodium naphthalene sulfonate (MF) water reducer.
Further, the physical dimension of the efficient homogeneous heat insulation building block of described A level fp can be come to determine voluntarily as required, and can cut.
Present invention also offers the preparation method of the efficient homogeneous heat insulation building block of a kind of A level fp, it is characterized in that, comprise the following steps:
(1) take raw material according to above-mentioned proportioning, then the haydite taken and haydite fragment particle, slag, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent are mixed, stir with stirrer;
(2) water taken and perlite properties-correcting agent are mixed, add in the material stirred in step (1), continue to stir, until hand is grabbed and agglomeratingly not scattered;
(3) building block extrusion equipment molding device sent into by the material that will process through step (2), with the compression factor extrusion molding of about 2:1;
(4) the material web mould of extrusion molding in step (3) is sent into curing room maintenance, obtain the efficient homogeneous heat insulation building block of A level fp of the present invention.
Mechanism of the present invention is: with cement as gelling material, haydite and fragment thereof and perlite is adopted to hold concurrently lagging material as aggregate, and carry out rational gradation composition, using flyash, slag etc. as filler, suitable interpolation respective additive improves every physical characteristics of the present invention, makes it to reach the technical requirements of this type of building material product and the index of energy-conservation 75%.Due to use is all inorganic materials, all belong to non-fire material, therefore fire resistance rating of the present invention can reach A1 level.
Gordian technique uses light ceramic and fragment thereof and perlite not only to carry out grating as aggregate but also as lagging material, adopt haydite and haydite fragment particle, the two uses simultaneously, optimize lagging material to hold concurrently the anti-compression property of aggregate, by haydite fragment particle, make grating more reasonable, solve the problem that the excessive ultimate compression strength caused of haydite particle diameter is inadequate.Employ the perlite properties-correcting agent developed voluntarily, this properties-correcting agent is mixed by methyl silicate hydrophober and silane hydrophober simultaneously, the two synergy.Methyl silicate hydrophober is under the effect of water and carbonic acid gas, generate methyl siliconic acid alcohol, methyl siliconic acid alcohol generates the thick insoluble waterproof macromolecular compound of several molecule on structured material surface and inside, and netted silicone resin, has good waterproof action.Meanwhile, silane hydrophober discharges ethanol and is combined with base material and is converted into silicone resin polymkeric substance, finally forms the silicone resin film of one deck hydrophobic on the pore surface of base material, further enhances hydrophobic effect.Both solved the contradiction of thermal conductivity and ultimate compression strength, and inhibit again the high characteristic of perlite water-intake rate to solve hydrophobic problem of the present invention, water-intake rate, frost resistance and weathering resistance are protected.
Perlite, both perlite powders use simultaneously, the space that perlite powder exists after effectively filling above material mixing, both ensure that the due heat insulation effect of perlite, and have served again the problem that product surface is smooth, attractive in appearance.
The invention has the beneficial effects as follows:
(1) the efficient homogeneous heat insulation building block of A level fp of the present invention solves the fire safety problem of current heat insulation building block, completely eliminate the disaster hidden-trouble of exterior-wall heat insulation infilled wall, solve the problem of energy-conservation 75% simultaneously, meet the national fire resistance rating about external wall thermal insulation product to require and higher energy conservation standard requirement, and production process is simple, has higher promotional value and boundless market outlook.
(2) the key technical indexes of the efficient homogeneous heat insulation building block of a kind of A of the present invention level fp is: ultimate compression strength >=2.5Mpa, thermal conductivity≤0.11w/m.k, water-intake rate≤15%, air shrinkage value≤0.6mm/m, coefficient of softening >=0.85, frost resistance and weathering resistance meet the requirements.
(3) the efficient homogeneous heat insulation building block of a kind of A level fp of the present invention has higher-strength, comparatively low thermal conductivity, the heat insulation building block of stronger water resistance and weather resistance, can realize current and from now on country to covil construction propose energy-conservation 75% requirement, and all material adopts inorganic materials, fire resistance reaches A level, completely eliminate the disaster hidden-trouble of exterior-wall heat insulation infilled wall, solve the problem of energy-conservation 75% simultaneously, meet the national fire resistance rating about external wall thermal insulation product to require and higher energy conservation standard requirement, and production process is simple, there are higher promotional value and boundless market outlook.
Embodiment
Embodiment 1:
Raw material ratio (weight percent): haydite and haydite fragment particle 26%, slag 3.4%, perlite 34%, perlite powder 9%, cement 20%, flyash 5%, silicon ash 1.7%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.4%, ferric chloride waterproofing agent 0.3%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.2%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method:
(1) take raw material according to above-mentioned proportioning, then the haydite taken and haydite fragment particle, slag, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent are mixed, stir with stirrer;
(2) water taken and perlite properties-correcting agent are mixed, add in the material stirred in step (1), continue to stir, until hand is grabbed and agglomeratingly not scattered;
(3) building block extrusion equipment molding device sent into by the material that will process through step (2), with the compression factor extrusion molding of about 2:1;
(4) the material web mould of extrusion molding in step (3) is sent into curing room maintenance, obtain the efficient homogeneous heat insulation building block of A level fp of the present invention.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
Embodiment 2:
Raw material ratio (weight percent): haydite and haydite fragment particle 22%, slag 6%, perlite 30%, perlite powder 10%, cement 22%, flyash 7%, silicon ash 1.9%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.3%, ferric chloride waterproofing agent 0.4%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.4%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method is with embodiment 1.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
Embodiment 3:
Raw material ratio (weight percent): haydite and haydite fragment particle 30%, slag 3%, perlite 32%, perlite powder 5%, cement 20%, flyash 8.2%, silicon ash 1.1%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.3%, ferric chloride waterproofing agent 0.3%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.3%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method is with embodiment 1.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
Embodiment 4:
Raw material ratio (weight percent): haydite and haydite fragment particle 20%, slag 9%, perlite 33%, perlite powder 6%, cement 25%, flyash 5%, silicon ash 1%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.4%, ferric chloride waterproofing agent 0.3%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.3%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method is with embodiment 1.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
Embodiment 5:
Raw material ratio (weight percent): haydite and haydite fragment particle 20%, slag 4%, perlite 40%, perlite powder 6%, cement 20%, flyash 8%, silicon ash 1%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.4%, ferric chloride waterproofing agent 0.4%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.2%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method is with embodiment 1.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
Embodiment 6:
Raw material ratio (weight percent): haydite and haydite fragment particle 20.7%, slag 4%, perlite 30%, perlite powder 5%, cement 30%, flyash 6%, silicon ash 3%, water reducer (methyne sodium naphthalene sulfonate (MF) water reducer) 0.6%, ferric chloride waterproofing agent 0.4%, powder economization agent (the METOLATP871 powder economization agent that German MUNZING chemical company produces) 0.3%.
The addition of water is 50% of above starting material gross weight;
The addition of perlite properties-correcting agent (mixture of silane hydrophober, methyl silicate hydrophober weight ratio 1:10) is 5% of above-mentioned water addition.
Preparation method is with embodiment 1.
The efficient homogeneous heat insulation building block of A level fp of the present embodiment is of a size of 390mm × 270mm × 190mm (long × wide × high).
The technique effect data of the insulation blocks of above embodiment 1-6 are as shown in table 1 below:
The key technical indexes of the heat insulation building block of the above embodiment 1-6 of table 1
Above-described embodiment; the just one of the present invention more preferably in embodiment; the usual change that those skilled in the art carries out in the scope of the present invention program and replacement, and the change of physical dimension of the present invention, all should be included in protection scope of the present invention.

Claims (10)

1. the efficient homogeneous heat insulation building block of A level fp, is characterized in that, be made up of following raw material through mechanical presses:
Haydite and haydite fragment particle, slag, perlite properties-correcting agent, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent, water.
2. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, is characterized in that, be made up of the raw material of following weight percent through mechanical presses:
Haydite and haydite fragment particle 20-30%, slag 3-9%, perlite 30-40%, perlite powder 5-10%, cement 20-30%, flyash 5-10%, silicon ash 1-3%, water reducer 0.2-0.7%, water-resisting agent 0.2-0.6%, powder economization agent 0.1-0.4%, the summation of above material is 100%;
The addition of described water is 50% of above material gross weight;
The addition of described perlite properties-correcting agent is 5% of water addition.
3. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, it is characterized in that, described perlite properties-correcting agent is weak yellow liquid, is the mixture of silane hydrophober and methyl silicate hydrophober.
4. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 3, is characterized in that,
In perlite properties-correcting agent, the weight ratio of silane hydrophober, methyl silicate hydrophober is 1:10.
5. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, is characterized in that,
Described cement is the one in ordinary Portland cement or complex cement;
Described perlite meets the requirement of JC/T209-2012 " pearlstone ";
Described flyash is second class powered coal ash, and the dioxide-containing silica of described silicon ash is greater than 90%.
6. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, is characterized in that,
Described haydite be leca, lytag, coal gangue haydite one or more, tap density is not more than 200kg/m 3;
Described haydite fragment particle is formed by haydite fragmentation, and the particle diameter after fragmentation is between 1-10mm;
The weight ratio of described haydite and haydite fragment particle is 1:1;
Described perlite density is not more than 200kg/m 3;
Described perlite powder density is not more than 100kg/m 3.
7. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, it is characterized in that, described powder economization agent is METOLATP871 powder economization agent, white powder, activeconstituents can be completely soluble in water, its effective constituent is the diatomic alcohol compounds on carrier, and aerated density is 400g/L.
8. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, is characterized in that,
Described water-resisting agent is ferric chloride waterproofing agent;
Described water reducer is methyne sodium naphthalene sulfonate (MF) water reducer.
9. the efficient homogeneous heat insulation building block of a kind of A level fp according to claim 1, is characterized in that, the physical dimension of the efficient homogeneous heat insulation building block of described A level fp can be come to determine voluntarily as required, and can cut.
10. a preparation method for the arbitrary described efficient homogeneous heat insulation building block of A level fp of claim 1-9, is characterized in that, comprise the following steps:
(1) raw material is taken according to the arbitrary described proportioning of claim 1-9, then the haydite taken and haydite fragment particle, slag, perlite, perlite powder, cement, flyash, silicon ash, water reducer, water-resisting agent, powder economization agent are mixed, stir with stirrer;
(2) water taken and perlite properties-correcting agent are mixed, add in the material stirred in step (1), continue to stir, until hand is grabbed and agglomeratingly not scattered;
(3) building block extrusion equipment molding device sent into by the material that will process through step (2), with the compression factor extrusion molding of about 2:1;
(4) the material web mould of extrusion molding in step (3) is sent into curing room maintenance, obtain the efficient homogeneous heat insulation building block of A level fp of the present invention.
CN201510582803.7A 2015-09-15 2015-09-15 A kind of efficient homogeneous heat insulation building block of A levels fireproof Active CN105084840B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106146030A (en) * 2016-07-12 2016-11-23 广西南宁桂尔创环保科技有限公司 A kind of Novel environment-friendlymaterial material for making building block
CN110436854A (en) * 2019-08-23 2019-11-12 同济大学 A kind of waterproof fireproofing light heat insulation material and preparation method thereof
WO2021134236A1 (en) * 2019-12-30 2021-07-08 青岛理工大学 Lightweight aggregate ultra-high performance concrete and preparation method therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1439614A (en) * 2002-02-22 2003-09-03 胡永生 Light filling materials for wall body
CN102515686A (en) * 2011-11-29 2012-06-27 李子现 Light wall body material
CN102863190A (en) * 2011-07-07 2013-01-09 刘学厚 Inorganic composite waterproof, fireproof and heat preservation material for buildings

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1439614A (en) * 2002-02-22 2003-09-03 胡永生 Light filling materials for wall body
CN102863190A (en) * 2011-07-07 2013-01-09 刘学厚 Inorganic composite waterproof, fireproof and heat preservation material for buildings
CN102515686A (en) * 2011-11-29 2012-06-27 李子现 Light wall body material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106146030A (en) * 2016-07-12 2016-11-23 广西南宁桂尔创环保科技有限公司 A kind of Novel environment-friendlymaterial material for making building block
CN110436854A (en) * 2019-08-23 2019-11-12 同济大学 A kind of waterproof fireproofing light heat insulation material and preparation method thereof
WO2021134236A1 (en) * 2019-12-30 2021-07-08 青岛理工大学 Lightweight aggregate ultra-high performance concrete and preparation method therefor
JP2022518306A (en) * 2019-12-30 2022-03-15 青▲島▼理工大学 Lightweight aggregate Ultra-high performance concrete and its preparation method

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Inventor after: Hua Leiguang

Inventor after: Chang Xiuli

Inventor after: Han Jintao

Inventor after: Yun Jie Jie

Inventor after: Zhang Yunqiang

Inventor before: Hua Leiguang

Inventor before: Han Jintao

Inventor before: Yun Jie Jie

Inventor before: Chang Xiuli

Inventor before: Zhang Yunqiang

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Effective date of registration: 20200605

Address after: Dongchang Road 252000 in Shandong province Liaocheng city Dongchangfu District No. 139

Patentee after: SHANDONG LIAOJIAN GROUP Co.,Ltd.

Address before: 252000, Shandong, Liaocheng Province, south of Tong Road, Ji Tan Expressway East (crossing shop office, Industrial Park)

Patentee before: LIAOCHENG JINXIN BUILDING ENERGY SAVING Co.,Ltd.

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