CN105063670A - Electrolytic manganese solution supplementing system - Google Patents
Electrolytic manganese solution supplementing system Download PDFInfo
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- CN105063670A CN105063670A CN201510533331.6A CN201510533331A CN105063670A CN 105063670 A CN105063670 A CN 105063670A CN 201510533331 A CN201510533331 A CN 201510533331A CN 105063670 A CN105063670 A CN 105063670A
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- solution
- skimmer
- floating drum
- manganese
- manganese solution
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses an electrolytic manganese solution supplementing system. The bottom of a solution dispenser is connected with a dosing pool through a backflow electromagnetic valve, the dosing pool is provided with a stirring pump, and the dosing pool is connected with a solution inlet of the solution dispenser through a qualified manganese solution delivery pump; the dosing pool is connected with a high-concentration manganese solution higher-place pond through a high-concentration manganese solution electromagnetic valve. A floating barrel is arranged in the solution dispenser, symmetrical locating piles are arranged on the floating barrel, and upper locating blocks and lower locating blocks are arranged on the inner wall of the solution dispenser. Symmetrical sleeves are fixed to the upper portion of the solution dispenser, and sliding shafts penetrate through the interiors of the sleeves to be connected with the floating barrel. A plurality of measuring cups are arranged at the bottom of the solution dispenser side by side, and the lower portions of the measuring cups are connected with throttle pipes and electrolytic cells. Cleaning rods are connected to the lower portion of the floating barrel; cathode chambers and anode chambers of the electrolytic cells are all provided with overflow ports, and the cathode solution overflow ports are connected with the dosing pool through a cathode solution pump, a leaf filter and a cooling tower. The cathode solution overflow ports and the anode solution overflow ports are all provided with overflow control plates which can rotate by certain angles. According to the electrolytic manganese solution supplementing system, the technical problems that electrolytes are not uniform and efficiency is low in the electrolytic manganese solution supplementing process are solved, and application prospects are wide.
Description
Technical field
The present invention relates to a kind of electrolytic manganese fluid infusion system.
Background technology
Constantly supplement toward electrolyzer the necessary processing step that qualifying liquid to be electrolysed is electrolytic manganese production, the object of fluid infusion makes the processing parameter needed for electrolysis be stabilized in certain scope, as the concentration, temperature etc. of electrolytic solution, is conducive to the carrying out of electrolysis.Fluid infusion is completed by special fluid infusion system, and existing fluid infusion system is adopt feed flow supervisor to add the mode of branching valve toward electrolyzer fluid infusion mostly, and branching valve mainly adopts manually operated mode.
Generally there are up to a hundred electrolyzers in electrolytic manganese production workshop, thus need to complete fluid infusion manipulation to up to a hundred electrolyzers simultaneously, due to the defect of the difference of operating experience, the difference of electric tank working parameter and change, manual control valve, the electrolyzer of substantial amounts cannot keep more consistent efficient electrolysis state, makes electrolytic efficiency decline, power consumption improves, benefit reduces.
Summary of the invention
The technical problem to be solved in the present invention overcomes the deficiencies in the prior art exactly, provides a kind of defect that can make up the fluid infusion of manual control branching valve, and the electrolyzer of substantial amounts is consistent the fluid infusion system of efficient electrolysis state.
For overcoming the deficiencies in the prior art, the present invention takes following technical scheme:
A kind of electrolytic manganese fluid infusion system, comprises skimmer, it is characterized in that: connect dosing pond through return flow solenoid valve bottom skimmer, dosing pond is provided with mixing pump, and dosing pond connects skimmer fluid inlet through qualified manganese solution transferpump; Dosing pond connects high concentration manganese solution feed coefficient through high concentration manganese solution electromagnetic valve; Have floating drum in skimmer, floating drum has symmetrical spud, skimmer inwall is provided with upper and lower preset pieces, and floating drum floats and declines and limits by upper and lower preset pieces; Be fixed with symmetrical sleeve above skimmer, pass slide-bar in sleeve and connect floating drum; Be the side by side configuration of multiple Measuring glass bottom skimmer, connect a choker-line below each Measuring glass, below each choker-line, be provided with an electrolyzer; The multiple cleaning rods corresponding with Measuring glass are connected below floating drum; Electrolyzer is common the anode chamber and the cathode chamber diaphragm electrolytic cell, each electric tank cathode room is provided with an overflow port, overflow port connects catholyte collecting tray, and catholyte collecting tray connects dosing pond through negative electrode liquid pump, leaf filter, water cooling tower, and each electrolyzer anode chamber is also provided with an overflow port; Catholyte overflow port, anolyte overflow port are equipped with the overflow switchboard of angle rotatable.
Described cleaning rod front end is provided with hairbrush.
Be provided with hose connection below described choker-line, supplement qualified manganese solution by connecting hose to corresponding electrolyzer.
Described anolyte overflow port jointed anode liquid collecting tray, anolyte collecting tray is through anode liquid pump jointed anode liquid pond for recovering.
The major parts of fluid infusion system is skimmer, skimmer is square container mostly, floating drum is had in skimmer, floating drum there is symmetrical spud, floating drum floats and declines owing to being subject to upper and lower preset pieces barrier effect, spud stroke is limited between preset pieces, thus controls floating and the descending stroke of floating drum; Symmetrical sleeve and slide-bar ensure that the accuracy that floating drum moves up and down.
Floating drum arranges corresponding cleaning rod with Measuring glass in addition, and form one-to-one relationship, there is hairbrush cleaning rod front end, and floating drum can be with electric brush repeatedly to scrub choker-line up and down, and make choker-line keep unimpeded, choker-line controls speed and the flow of fluid infusion.Be provided with hose connection below choker-line, supplement qualified manganese solution by connecting hose to corresponding electrolyzer.
Manganese solution qualified in dosing pond can be inputted skimmer by pipeline and fluid inlet by qualified manganese solution transferpump fast, floating drum floats to upper extreme position, qualifying liquid transferpump is closed by travel switch, open return flow solenoid valve simultaneously, liquid quick backflow in skimmer is allowed to enter dosing pond, now floating drum drops to lower limit position with liquid level, qualified manganese solution in Measuring glass is then transported to corresponding electrolyzer by choker-line and flexible pipe, realize electrolyzer quantitative, suitable speed supplements qualified manganese solution, liquid in Measuring glass can open qualifying liquid transferpump after exporting once again automatically, carry out going up liquid and supply once again, and realize floating drum band electric brush and move up and down, scrub choker-line, ensure unimpeded.
Electrolyzer is common diaphragm electrolytic cell, in the design, newly-increased catholyte overflow port is concentrated by catholyte collecting tray, by catholyte pump delivery, trace impurity is removed through leaf filter, dispelled the heat by water cooling tower again and complete circulation into dosing pond, water cooling tower can the catholyte of effective temperature-reducing backflow, and evaporates wherein water in a large number, effectively avoids the liquid expansion issues of electrolytic manganese production.
Dosing pond has mixing pump to keep the homogeneity of liquid in pond, simultaneously mn ion content in good time reasonable analysis liquid, then by high concentration manganese solution electromagnetic valve UNICOM high concentration manganese solution feed coefficient, keeps dosing pond mn ion content in moderate scope.
Though electrolyzer has barrier film to isolate, due to law of connected vessels, the liquid level of the anode chamber and the cathode chamber is consistent.Newly-increased anolyte overflow switchboard and catholyte overflow switchboard, the angle that can rotate and set overflow switchboard, to control the output flow of cathode and anode liquid, meets the demands.
Compared with prior art, beneficial effect of the present invention is also:
Measuring glass in skimmer can be arranged more, multiple row is arranged, reliable to multiple electrolyzer quantitative liquid feeding; Choker-line can keep unimpeded by repeatedly scrubbing up and down, thus obtains reliable flow velocity supply, and regulates to realize amount infused by controlling fluid infusion cup number per hour; Catholyte overflow allotment supply pump circulation, effectively can realize the liquid phase homogeneity of electrolyzer, and be convenient to effectively improve electrolysis electricity effect, less anolyte spillway discharge effectively can improve acidity, reduces later stage sulfuric acid input amount; Catholyte can temperature with high efficiency evaporate large quantity of moisture by water cooling tower, and greatly alleviate the liquid expansion ring packing pressure of electrolytic manganese production, direct radiating and cooling is also more efficient than the heat radiation of traditional calandria partition water cycle a lot; Valve plate type anode and cathode hydrorrhea flow modulation device is effectively simple especially, is convenient to manipulation.
In sum, the invention solves the many technical problems existed in electrolytic manganese fluid infusion process, have a extensive future.
Accompanying drawing explanation
Fig. 1 is the two dimensional structure schematic diagram of the present invention at floating drum upper limit.
Fig. 2 is the two dimensional structure schematic diagram of the present invention in floating drum lower limit.
Fig. 3 is overflow control principle drawing of the present invention.
In figure, each label represents:
1, floating drum; 2, skimmer; 3, sleeve; 4, slide-bar; 5, spud; 6, upper preset pieces; 7, lower preset pieces; 8, cleaning rod; 9, Measuring glass; 10, hairbrush; 11, choker-line; 12, hose connection; 13, electrolyzer; 14, anode liquid pump; 15, anolyte overflow port; 16 anolyte collecting traies; 17, catholyte collecting tray; 18, catholyte overflow port; 19, negative electrode liquid pump; 20, leaf filter; 21, skimmer fluid inlet; 22 return flow solenoid valves; 23, high concentration manganese solution feed coefficient; 24, water cooling tower; 25, mixing pump; 26, dosing pond; 27, qualified manganese solution transferpump; 28, high concentration manganese solution electromagnetic valve; 29, anolyte pond for recovering; 31, anolyte overflow switchboard; 32, catholyte overflow switchboard.
Embodiment
Now by reference to the accompanying drawings, the present invention is illustrated further.
Electrolytic manganese fluid infusion system, comprises skimmer as depicted in figs. 1 and 2, connects dosing pond 26 bottom skimmer 2 through return flow solenoid valve 22, and dosing pond 26 is provided with mixing pump 25, and dosing pond 26 connects skimmer fluid inlet 21 through qualified manganese solution transferpump 27; Dosing pond 26 connects high concentration manganese solution feed coefficient 23 through high concentration manganese solution electromagnetic valve 28; Have floating drum 1 in skimmer 2, floating drum 1 has symmetrical spud 5, skimmer 2 inwall is provided with upper and lower preset pieces 6,7, and floating drum floats and declines and limited by upper and lower preset pieces 6,7; Be fixed with symmetrical sleeve 3 above skimmer 2, pass slide-bar 4 in sleeve 3 and connect floating drum 1; Be the side by side configuration of multiple Measuring glass 9 bottom skimmer 2, connect a choker-line 11 below each Measuring glass 9, below each choker-line 11, be provided with an electrolyzer 13; The multiple cleaning rods 8 corresponding with Measuring glass are connected below floating drum 1; Electrolyzer 13 is common the anode chamber and the cathode chamber diaphragm electrolytic cell, each electric tank cathode room is provided with an overflow port 18, overflow port 18 connects catholyte collecting tray 17, catholyte collecting tray 17 connects dosing pond 26 through negative electrode liquid pump 19, leaf filter 20, water cooling tower 24, and each electrolyzer anode chamber is also provided with an overflow port 15; Catholyte overflow port 18, anolyte overflow port 15 are equipped with the overflow switchboard 32,31 of angle rotatable.
Described cleaning rod 8 front end is provided with hairbrush 10.
Be provided with hose connection 12 below described choker-line 11, supplement qualified manganese solution by connecting hose to corresponding electrolyzer.
Described anolyte overflow port 15 jointed anode liquid collecting tray 16, anolyte collecting tray 16 is through anode liquid pump 14 jointed anode liquid pond for recovering 29.
The major parts of fluid infusion system is skimmer 2, skimmer 2 is square container mostly, floating drum 1 is had in skimmer, floating drum 1 there is symmetrical spud 5, floating drum 1 floats and declines owing to being subject to upper and lower preset pieces 6,7 barrier effect, spud 5 stroke is limited between preset pieces, thus controls floating and the descending stroke of floating drum 1; Symmetrical sleeve 3 ensure that with slide-bar 4 accuracy that floating drum 1 moves up and down.
Floating drum arranges corresponding cleaning rod 8 with Measuring glass 9 in addition, form one-to-one relationship, there is hairbrush 10 cleaning rod 8 front end, and floating drum can be with electric brush 10 repeatedly to scrub choker-line 11 up and down, make choker-line 11 keep unimpeded, choker-line 11 controls speed and the flow of fluid infusion.Be provided with hose connection 12 below choker-line 11, supplement qualified manganese solution by connecting hose to corresponding electrolyzer 13.
Manganese solution qualified in dosing pond 26 can be inputted skimmer 2 by pipeline and fluid inlet 21 by qualified manganese solution transferpump 27 fast, floating drum 1 floats to upper extreme position (shown in Fig. 1), qualifying liquid transferpump 27 is closed by travel switch, open return flow solenoid valve 22 simultaneously, liquid quick backflow in skimmer 2 is allowed to enter dosing pond 26, now floating drum 1 drops to lower limit position (shown in Fig. 2) with liquid level, qualified manganese solution in Measuring glass 9 is then transported to corresponding electrolyzer 13 by choker-line 11 and flexible pipe, realize electrolyzer 13 quantitative, suitable speed supplements qualified manganese solution, liquid in Measuring glass 9 can open qualifying liquid transferpump 27 after exporting once again automatically, carry out going up liquid and supply once again, and realize floating drum 1 and be with electric brush 10 to move up and down, scrub choker-line 11, ensure unimpeded.
Electrolyzer 13 is common diaphragm electrolytic cell, in the design, newly-increased catholyte overflow port 18 is concentrated by catholyte collecting tray 17, carried by negative electrode liquid pump 19, trace impurity is removed through leaf filter 20, dispelled the heat by water cooling tower 24 again and complete circulation into dosing pond 26, water cooling tower 24 can the catholyte of effective temperature-reducing backflow, and evaporates wherein water in a large number, effectively avoids the liquid expansion issues of electrolytic manganese production.
Dosing pond 26 has mixing pump 25 to keep the homogeneity of liquid in pond, simultaneously mn ion content in good time reasonable analysis liquid, then by high concentration manganese solution electromagnetic valve 28 UNICOM high concentration manganese solution feed coefficient 23, keeps dosing pond mn ion content in moderate scope.
Though electrolyzer 13 has barrier film to isolate, due to law of connected vessels, the liquid level of the anode chamber and the cathode chamber is consistent.Newly-increased anolyte overflow switchboard 31 and catholyte overflow switchboard 32, the angle that can rotate and set overflow switchboard, to control the output flow of cathode and anode liquid, meets the demands.
Above-mentioned just preferred embodiment of the present invention, not does any pro forma restriction to the present invention.Any those of ordinary skill in the art, when not departing from technical solution of the present invention scope, can utilize the technology contents of above-mentioned announcement to make many possible variations and modification to technical solution of the present invention, or being revised as the Equivalent embodiments of equivalent variations.Therefore, every content not departing from technical solution of the present invention, according to the technology of the present invention essence to any simple modification made for any of the above embodiments, equivalent variations and modification, all should drop in the scope of technical solution of the present invention protection.
Claims (4)
1. an electrolytic manganese fluid infusion system, comprises skimmer, it is characterized in that: connect dosing pond through return flow solenoid valve bottom skimmer, dosing pond is provided with mixing pump, and dosing pond connects skimmer fluid inlet through qualified manganese solution transferpump; Dosing pond connects high concentration manganese solution feed coefficient through high concentration manganese solution electromagnetic valve; Have floating drum in skimmer, floating drum has symmetrical spud, skimmer inwall is provided with upper and lower preset pieces, and floating drum floats and declines and limits by upper and lower preset pieces; Be fixed with symmetrical sleeve above skimmer, pass slide-bar in sleeve and connect floating drum; Be the side by side configuration of multiple Measuring glass bottom skimmer, connect a choker-line below each Measuring glass, below each choker-line, be provided with an electrolyzer; The multiple cleaning rods corresponding with Measuring glass are connected below floating drum; Electrolyzer is common the anode chamber and the cathode chamber diaphragm electrolytic cell, each electric tank cathode room is provided with an overflow port, overflow port connects catholyte collecting tray, and catholyte collecting tray connects dosing pond through negative electrode liquid pump, leaf filter, water cooling tower, and each electrolyzer anode chamber is also provided with an overflow port; Catholyte overflow port, anolyte overflow port are equipped with the overflow switchboard of angle rotatable.
2. electrolytic manganese fluid infusion system according to claim 1, is characterized in that: described cleaning rod front end is provided with hairbrush.
3. electrolytic manganese fluid infusion system according to claim 1, is characterized in that: be provided with hose connection below described choker-line, supplements qualified manganese solution by connecting hose to corresponding electrolyzer.
4. electrolytic manganese fluid infusion system according to claim 1, is characterized in that: described anolyte overflow port jointed anode liquid collecting tray, anolyte collecting tray is through anode liquid pump jointed anode liquid pond for recovering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510533331.6A CN105063670B (en) | 2015-08-27 | 2015-08-27 | Electrolytic manganese fluid infusion system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510533331.6A CN105063670B (en) | 2015-08-27 | 2015-08-27 | Electrolytic manganese fluid infusion system |
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| Publication Number | Publication Date |
|---|---|
| CN105063670A true CN105063670A (en) | 2015-11-18 |
| CN105063670B CN105063670B (en) | 2017-10-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510533331.6A Expired - Fee Related CN105063670B (en) | 2015-08-27 | 2015-08-27 | Electrolytic manganese fluid infusion system |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201284503Y (en) * | 2008-09-22 | 2009-08-05 | 谭江涛 | Reclaimed water reclamation plant |
| CN103334150A (en) * | 2013-07-10 | 2013-10-02 | 皆利士多层线路版(中山)有限公司 | Automatic quantitative adding system |
| CN104032328A (en) * | 2014-06-04 | 2014-09-10 | 杭州三耐环保科技有限公司 | Environmental-protection and energy-conversion type diaphragm electrolysis device |
-
2015
- 2015-08-27 CN CN201510533331.6A patent/CN105063670B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201284503Y (en) * | 2008-09-22 | 2009-08-05 | 谭江涛 | Reclaimed water reclamation plant |
| CN103334150A (en) * | 2013-07-10 | 2013-10-02 | 皆利士多层线路版(中山)有限公司 | Automatic quantitative adding system |
| CN104032328A (en) * | 2014-06-04 | 2014-09-10 | 杭州三耐环保科技有限公司 | Environmental-protection and energy-conversion type diaphragm electrolysis device |
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| CN105063670B (en) | 2017-10-13 |
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| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Guo Hongbing Inventor after: Zhu Yuqin Inventor after: Guo Shu Inventor before: Yin Yongzhong Inventor before: Yao Maojun Inventor before: Xiang Yuxin |
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| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170912 Address after: 224043 Yancheng City province Jiangsu Dagang Town Park Road No. 1, machine equipment Applicant after: Jiangsu Yuanhua Lightweight Equipment Co., Ltd. Address before: 416000 Hunan, Xiangxi Tujia and Miao Autonomous Prefecture, Jishou City People's road, No. 120 Applicant before: Jishou University |
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| GR01 | Patent grant | ||
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171013 Termination date: 20180827 |