CN105062246A - PVC foaming coating, PVC foaming wallpaper and preparation method thereof - Google Patents
PVC foaming coating, PVC foaming wallpaper and preparation method thereof Download PDFInfo
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- CN105062246A CN105062246A CN201510518158.2A CN201510518158A CN105062246A CN 105062246 A CN105062246 A CN 105062246A CN 201510518158 A CN201510518158 A CN 201510518158A CN 105062246 A CN105062246 A CN 105062246A
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- pvc foam
- whipping agent
- pvc
- wallpaper
- parts
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- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- 238000000576 coating method Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 8
- 238000005187 foaming Methods 0.000 title abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011591 potassium Substances 0.000 claims abstract description 8
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 8
- 239000011701 zinc Substances 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 41
- 239000006260 foam Substances 0.000 claims description 39
- 238000003756 stirring Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 239000012760 heat stabilizer Substances 0.000 claims description 6
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical group O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 claims description 5
- 241000276489 Merlangius merlangus Species 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 238000004049 embossing Methods 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 abstract 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 239000004005 microsphere Substances 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000006224 matting agent Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 241001417490 Sillaginidae Species 0.000 description 2
- 238000005703 Whiting synthesis reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a PVC foaming coating. The PVC foaming coating comprises, by weight, 330-350 parts of environmentally-friendly plasticizer, 360-390 parts of PVC paste resin, 15-18 parts of liquid stabilizer, 20-22 parts of AC foaming agent, 20-22 parts of microsphere foaming agent, 75-80 parts of titanium dioxide, 250-275 parts of ground calcium carbonate and 30-33 parts of matting agent. By means of the potassium/zinc liquid stabilizer, the AC foaming agent and the microsphere foaming agent, the foaming function of the PVC foaming coating can be effectively improved, the foaming ratio of PVC foaming wallpaper can be improved, and satisfactory foaming quality can be obtained.
Description
Technical field
The present invention relates to a kind of PVC foam coating, PVC foam wallpaper and preparation method thereof.
Background technology
PVC foam wallpaper is a kind of novel indoor wall finishing material, the whippy asperities of this wallpaper surface, and can be printed on floral designs in foaming plane, shape is as effects such as embossment, wood grain, ceramic tiles, have pattern true to nature, stereoscopic sensation is strong, the advantage such as good decorating effect, acoustical absorption heat preserving.
At present at the PVC foam wallpaper used mainly with PVC paste resin for main raw material, the performance of PVC paste resin produces material impact to foaming wall paper products quality.Therefore, in the process of preparation PVC foam coating, usually the various auxiliary agents such as stablizer, whipping agent, softening agent can be added, with the PVC coating of processability excellence.But undesirable at the frothing function of the PVC foam coating used at present, well cannot accomplish uniform in foaming, have a strong impact on the quality of PVC foam goods.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art, first object of the present invention is to provide the desirable PVC foam coating of a kind of frothing function.
To achieve these goals, a kind of PVC foam coating designed by the present invention, by weight, comprises following component:
Environment-friendlyplasticizer plasticizer: 330-350 part;
PVC paste resin: 360-390 part;
Liquid stabilisers: 15-18 part;
AC whipping agent: 20-22 part;
Microballoon whipping agent: 20-22 part;
Titanium dioxide: 75-80 part;
Coarse whiting: 250-275 part;
Flatting silica: 30-33 part.
Preferably, described environment-friendlyplasticizer plasticizer is DOTP.
Preferably, described liquid stabilisers is potassium/zinc liquid heat stabilizer.
Preferably, the weight ratio of described AC whipping agent and microballoon whipping agent is 1: 1.
DOTP: dioctyl terephthalate is a kind of environment-friendly type low-viscosity (mobile) liquid of near colorless.Compared with dioctyl phthalate (DOP) (DOP) conventional at present, there is the advantages such as heat-resisting, cold-resistant, difficult volatilization, anti-extraction, flexibility and electrical insulation capability are good, in goods, demonstrate excellent persistence, resistance to soap water-based and low-temperature pliability.
Potassium/zinc liquid heat stabilizer: have good thermostability and inspire bubble dual-use function, while the thermostability improving PVC foam wallpaper, can also improve the expansion ratio of PVC foam wallpaper.
AC whipping agent: Cellmic C 121, AC whipping agent is orange crystals powder, and decomposition temperature is 190 ~ 205 DEG C, and gas forming amount is 200 1 300ml/g.The performance of AC whipping agent and the particle diameter of powder particle have comparatively Important Relations.The AC whipping agent that the less and size distribution of median size is comparatively concentrated, specific surface area is comparatively large, can decompose, complete foaming process when being heated in comparatively short duration.The comparatively large and AC whipping agent of wider distribution of particle diameter, when being heated, small-particle first decomposes, and it is slow that macroparticle then decomposes, and not only makes foamed time extend, and is unfavorable for obtaining uniform foam structure.AC whipping agent is through special modification, and decomposition temperature can reduce, thus is suitable for the needs of variant production.Have stable performance, nonflammable, do not pollute, nonpoisonous and tasteless, mould do not corroded goods do not dyeed, decomposition temperature is adjustable, does not affect the features such as solidification and shaping speed.
Microballoon whipping agent: the gas providing foaming, plays nucleator effect simultaneously in Bubble Formation Process.AC whipping agent macrobead in reaction process diminishes gradually, and lattice is destroyed gradually, final dispersion, dissolves, and is wrapped by microballoon, and that can avoid in AC whipping agent decomposition course is sudden, decomposes comparatively mild, is conducive to the homogeneity foamed.
The second object of the present invention is that providing a kind of adopts above-mentioned PVC foam coating to prepare the method for PVC foam wallpaper, comprises the following steps:
Step one, environment-friendlyplasticizer plasticizer and liquid stabilisers are put in mixing kettle, turn on agitator stirs with 1000 revs/min of rotating speeds, be heated to 40 degrees Celsius simultaneously, agitator continues to stir with 1000 revs/min of rotating speeds, and drop into PVC paste resin, AC whipping agent, microballoon whipping agent, titanium dioxide, coarse whiting, flatting silica successively while stirring, after feeding intake, agitator is again with the rotating speed Keep agitation of 1200 revs/min, stir 30 minutes, obtain raw product;
Step 2, above-mentioned raw product is obtained slurry by 80 object metre filter;
Step 3, on base fabric the above-mentioned slurry of uniform coating 1 millimeter of-2 mm of thickness, then toast 0.5 minute in the baking oven of 200 degrees Celsius-220 degrees Celsius, heating plasticizing forms wallpaper work in-process;
Step 4: carried out printing and embossing by above-mentioned wallpaper work in-process, forms PVC foam wallpaper.
The third object of the present invention is the PVC foam wallpaper providing a kind of above-mentioned preparation method to obtain, the uniform in foaming of this PVC foam wallpaper, and pore structure is desirable.
The invention has the beneficial effects as follows: by AC whipping agent and microballoon whipping agent, effectively can promote the frothing function of PVC foam coating, through the experiment that contriver is a large amount of, especially in the weight ratio of AC whipping agent and microballoon whipping agent 1: 1 time, the frothing function of obtained PVC foam coating is best, by the uniform in foaming of PVC foam wallpaper obtained by this PVC foam coating, pore structure is desirable; Adopt potassium/zinc liquid stabilizer simultaneously, can produce with AC whipping agent and act synergistically, guarantee the decomposition completely of AC whipping agent, improve the expansion ratio of PVC foam wallpaper further, obtain satisfied foaming quality.
Embodiment
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
The preparation method of PVC foam wallpaper: comprise the following steps:
Step one, 330 parts of environment-friendlyplasticizer plasticizer and 15 parts of liquid stabilisers are put in mixing kettle, turn on agitator stirs with 1000 revs/min of rotating speeds, be heated to 40 degrees Celsius simultaneously, agitator continues to stir with 1000 revs/min of rotating speeds, and drop into 360 parts of PVC paste resins, 20 parts of AC whipping agents, 20 parts of microballoon whipping agents, 75 parts of titanium dioxides, 250 parts of coarse whitings, 30 parts of flatting silicas successively while stirring, after feeding intake, agitator is again with the rotating speed Keep agitation of 1200 revs/min, stir 30 minutes, obtain raw product;
Step 2, above-mentioned raw product is obtained slurry by 80 object metre filter;
Step 3, on base fabric the above-mentioned slurry of uniform coating 1 mm of thickness, then toast 0.5 minute in the baking oven of 200 degrees Celsius, heating plasticizing forms wallpaper work in-process;
Step 4: carried out printing and embossing by above-mentioned wallpaper work in-process, forms PVC foam wallpaper.
In the present embodiment, environment-friendlyplasticizer plasticizer is DOTP, and liquid stabilisers is potassium/zinc liquid heat stabilizer, and the weight ratio of AC whipping agent and microballoon whipping agent is 1: 1.
Embodiment 2:
The preparation method of PVC foam wallpaper: comprise the following steps:
Step one, 350 parts of environment-friendlyplasticizer plasticizer and 18 parts of liquid stabilisers are put in mixing kettle, turn on agitator stirs with 1000 revs/min of rotating speeds, be heated to 40 degrees Celsius simultaneously, agitator continues to stir with 1000 revs/min of rotating speeds, and drop into 390 parts of PVC paste resins, 22 parts of AC whipping agents, 22 parts of microballoon whipping agents, 80 parts of titanium dioxides, 275 parts of coarse whitings, 33 parts of flatting silicas successively while stirring, after feeding intake, agitator is again with the rotating speed Keep agitation of 1200 revs/min, stir 30 minutes, obtain raw product;
Step 2, above-mentioned raw product is obtained slurry by 80 object metre filter;
Step 3, on base fabric the above-mentioned slurry of uniform coating 1.5 mm of thickness, then toast 0.5 minute in the baking oven of 220 degrees Celsius, heating plasticizing forms wallpaper work in-process;
Step 4: carried out printing and embossing by above-mentioned wallpaper work in-process, forms PVC foam wallpaper.
In the present embodiment, environment-friendlyplasticizer plasticizer is DOTP, and liquid stabilisers is potassium/zinc liquid heat stabilizer, and the weight ratio of AC whipping agent and microballoon whipping agent is 1: 1.
Integrated embodiment 1 and embodiment 2, and draw through the experimental summary that contriver is a large amount of, AC whipping agent, microballoon whipping agent and potassium/zinc liquid heat stabilizer is added in PVC foam coating, especially in the weight ratio of AC whipping agent and microballoon whipping agent 1: 1, and AC whipping agent with the weight ratio of PVC paste resin when 5%-6%, the foaming obtaining PVC foam goods with PVC foam coating is the most even, and pore structure is the most desirable.
Claims (6)
1. a PVC foam coating, is characterized in that: by weight, comprises following component:
Environment-friendlyplasticizer plasticizer: 330-350 part;
PVC paste resin: 360-390 part;
Liquid stabilisers: 15-18 part;
AC whipping agent: 20-22 part;
Microballoon whipping agent: 20-22 part;
Titanium dioxide: 75-80 part;
Coarse whiting: 250-275 part;
Flatting silica: 30-33 part.
2. PVC foam coating according to claim 1, is characterized in that: described environment-friendlyplasticizer plasticizer is DOTP.
3. PVC foam coating according to claim 1, is characterized in that: described liquid stabilisers is potassium/zinc liquid heat stabilizer.
4. PVC foam coating according to claim 1, is characterized in that: the weight ratio of described AC whipping agent and microballoon whipping agent is 1: 1.
5. adopt the arbitrary described PVC foam coating of claim 1-4 to prepare a method for PVC foam wallpaper, it is characterized in that: comprise the following steps:
Step one, environment-friendlyplasticizer plasticizer and liquid stabilisers are put in mixing kettle, turn on agitator stirs with 1000 revs/min of rotating speeds, be heated to 40 degrees Celsius simultaneously, agitator continues to stir with 1000 revs/min of rotating speeds, and drop into PVC paste resin, AC whipping agent, microballoon whipping agent, titanium dioxide, coarse whiting, flatting silica successively while stirring, after feeding intake, agitator is again with the rotating speed Keep agitation of 1200 revs/min, stir 30 minutes, obtain raw product;
Step 2, above-mentioned raw product is obtained slurry by 80 object metre filter;
Step 3, on base fabric the above-mentioned slurry of uniform coating 1 millimeter of-2 mm of thickness, then toast 0.5 minute in the baking oven of 200 degrees Celsius-220 degrees Celsius, heating plasticizing forms wallpaper work in-process;
Step 4: carried out printing and embossing by above-mentioned wallpaper work in-process, forms PVC foam wallpaper.
6. the PVC foam wallpaper that obtains of preparation method according to claim 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510518158.2A CN105062246A (en) | 2015-08-12 | 2015-08-12 | PVC foaming coating, PVC foaming wallpaper and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510518158.2A CN105062246A (en) | 2015-08-12 | 2015-08-12 | PVC foaming coating, PVC foaming wallpaper and preparation method thereof |
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| CN105062246A true CN105062246A (en) | 2015-11-18 |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105648836A (en) * | 2016-01-04 | 2016-06-08 | 金戈炜业（江苏）壁纸有限公司 | Wallpaper PVC layer |
| CN105860368A (en) * | 2016-06-22 | 2016-08-17 | 苏州同花盛鞋业有限公司 | PVC material as well as preparation method and application thereof |
| CN107217543A (en) * | 2017-07-17 | 2017-09-29 | 河南顺美国际家居股份有限公司 | A kind of intaglio plate of matte wallpaper imitates cylinder production technology |
| CN107298811A (en) * | 2017-05-25 | 2017-10-27 | 江苏郁金香装饰材料有限公司 | A kind of flame wallpaper slurry and its preparation method |
| CN107326725A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of cylinder foaming wallpaper slurry and its preparation method |
| CN107326726A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of cylinder matte foaming wallpaper slurry and its preparation method |
| CN107326727A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of smart casing pressure wallpaper slurry of intaglio plate and its preparation method |
| CN107739559A (en) * | 2017-10-13 | 2018-02-27 | 广西大自然壁高高新装饰材料有限公司 | A kind of coating sizing-agent of high whiteness and preparation method thereof |
| CN107905039A (en) * | 2017-11-07 | 2018-04-13 | 龙冉装饰材料有限公司 | A kind of preparation method of polyurethane embossing wallpaper |
| CN108129973A (en) * | 2018-01-18 | 2018-06-08 | 东莞市阿克尔纳米水性涂料有限公司 | A kind of hard foamed material surface coatings of PU and preparation method thereof |
| CN108189491A (en) * | 2016-10-20 | 2018-06-22 | 邹玉华 | The noctilucence silk ornament materials of the higher ranked building interior trim of antibacterial and mouldproof |
| CN108867172A (en) * | 2018-07-26 | 2018-11-23 | 武汉菡美洛建筑材料有限公司 | A kind of sound insulation Environment-friendlywallpaper wallpaper |
| CN110387752A (en) * | 2019-07-09 | 2019-10-29 | 思嘉环保材料科技（上海）有限公司 | A kind of preparation method of high magnification PVC coating foamed material slurry |
| CN119859362A (en) * | 2025-03-25 | 2025-04-22 | 天津嘉泰伟业化工有限公司 | Styrene-methyl methacrylate copolymer foaming material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102218877A (en) * | 2011-03-28 | 2011-10-19 | 无锡市瑞莺合成革有限公司 | Processing method of multifunctional environment-friendly polyvinyl chloride composite decorative material |
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN103436086A (en) * | 2013-08-07 | 2013-12-11 | 苏州凹凸彩印厂 | Foaming printing ink |
| CN104494257A (en) * | 2014-12-31 | 2015-04-08 | 思嘉环保材料科技（上海）有限公司 | Heat-preservation foaming material for tent and preparation method of heat-preservation foaming material for tent |
-
2015
- 2015-08-12 CN CN201510518158.2A patent/CN105062246A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102218877A (en) * | 2011-03-28 | 2011-10-19 | 无锡市瑞莺合成革有限公司 | Processing method of multifunctional environment-friendly polyvinyl chloride composite decorative material |
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN103436086A (en) * | 2013-08-07 | 2013-12-11 | 苏州凹凸彩印厂 | Foaming printing ink |
| CN104494257A (en) * | 2014-12-31 | 2015-04-08 | 思嘉环保材料科技（上海）有限公司 | Heat-preservation foaming material for tent and preparation method of heat-preservation foaming material for tent |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105648836B (en) * | 2016-01-04 | 2018-06-19 | 江苏金戈炜业环保科技股份有限公司 | A kind of wallpaper layer of PVC |
| CN105648836A (en) * | 2016-01-04 | 2016-06-08 | 金戈炜业（江苏）壁纸有限公司 | Wallpaper PVC layer |
| CN105860368A (en) * | 2016-06-22 | 2016-08-17 | 苏州同花盛鞋业有限公司 | PVC material as well as preparation method and application thereof |
| CN108357185A (en) * | 2016-10-20 | 2018-08-03 | 吴彬 | The manufacture craft of noctilucence silk ornament materials |
| CN108221399A (en) * | 2016-10-20 | 2018-06-29 | 吴彬 | The manufacture craft of the noctilucence silk ornament materials of building interior trim |
| CN108189491A (en) * | 2016-10-20 | 2018-06-22 | 邹玉华 | The noctilucence silk ornament materials of the higher ranked building interior trim of antibacterial and mouldproof |
| CN107326725A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of cylinder foaming wallpaper slurry and its preparation method |
| CN107326727A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of smart casing pressure wallpaper slurry of intaglio plate and its preparation method |
| CN107326726A (en) * | 2017-05-25 | 2017-11-07 | 江苏郁金香装饰材料有限公司 | A kind of cylinder matte foaming wallpaper slurry and its preparation method |
| CN107298811A (en) * | 2017-05-25 | 2017-10-27 | 江苏郁金香装饰材料有限公司 | A kind of flame wallpaper slurry and its preparation method |
| CN107217543A (en) * | 2017-07-17 | 2017-09-29 | 河南顺美国际家居股份有限公司 | A kind of intaglio plate of matte wallpaper imitates cylinder production technology |
| CN107739559A (en) * | 2017-10-13 | 2018-02-27 | 广西大自然壁高高新装饰材料有限公司 | A kind of coating sizing-agent of high whiteness and preparation method thereof |
| CN107905039A (en) * | 2017-11-07 | 2018-04-13 | 龙冉装饰材料有限公司 | A kind of preparation method of polyurethane embossing wallpaper |
| CN108129973A (en) * | 2018-01-18 | 2018-06-08 | 东莞市阿克尔纳米水性涂料有限公司 | A kind of hard foamed material surface coatings of PU and preparation method thereof |
| CN108867172A (en) * | 2018-07-26 | 2018-11-23 | 武汉菡美洛建筑材料有限公司 | A kind of sound insulation Environment-friendlywallpaper wallpaper |
| CN110387752A (en) * | 2019-07-09 | 2019-10-29 | 思嘉环保材料科技（上海）有限公司 | A kind of preparation method of high magnification PVC coating foamed material slurry |
| CN119859362A (en) * | 2025-03-25 | 2025-04-22 | 天津嘉泰伟业化工有限公司 | Styrene-methyl methacrylate copolymer foaming material and preparation method thereof |
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Address after: 315600, Zhejiang, Ningbo, Taoyuan province Ninghai Street Jinshan five road 9, Ningbo superior environmental protection coating Co., Ltd. Applicant after: Ningbo superior environmental protection material Co., Ltd. Address before: 315600, Zhejiang, Ningbo, Taoyuan province Ninghai Street Jinshan five road 9, Ningbo superior environmental protection coating Co., Ltd. Applicant before: Ningbo Gaojia Environmental Protection Paint Co.,Ltd. |
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Application publication date: 20151118 |
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