CN105036209A - Clothing processing plant sewage treatment agent - Google Patents

Clothing processing plant sewage treatment agent Download PDF

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Publication number
CN105036209A
CN105036209A CN201510406576.2A CN201510406576A CN105036209A CN 105036209 A CN105036209 A CN 105036209A CN 201510406576 A CN201510406576 A CN 201510406576A CN 105036209 A CN105036209 A CN 105036209A
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parts
stirrer
sewage treatment
water
treatment agent
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CN201510406576.2A
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陈梦佳
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陈梦佳
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Priority to CN201510406576.2A priority Critical patent/CN105036209A/en
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Abstract

The invention relates to a clothing processing plant sewage treatment agent. The clothing processing plant sewage treatment agent consists of the following substances in parts by mass: 20-40 parts of benzotriazole, 20-40 parts of dendrobium leaf powder, 10-30 parts of ethylene bis stearamide, 15-30 parts of polyacrylamide, 40-60 parts of 5-tetrachlorosalicylanilide, 20-40 parts of ammonia percarbonate, 20-40 parts of diallyl dimethyl, 20-40 parts of polyaluminium sulfate, 20-40 parts of sulfonate, 20-40 parts of polyethylene glycol monostearate and 50-100 parts of deionized water. The sewage treatment agent disclosed by the invention is high in reaction speed, and does not generate poisonous and harmful gas in the process; a product obtained by reaction is stable, and is not decomposed into poisonous substances; the sewage treatment agent is efficient and non-poisonous, is safe for a human body before and after reaction, and is free of corrosion on an object; and the sewage treatment agent is high in sewage treatment efficiency and convenient to use.

Description

Clothes source mill sewage-treating agent
Technical field
The present invention relates to a kind of clothes source mill sewage-treating agent, belong to technical field of sewage.
Background technology
Current, environment protection has become the problem of World Focusing, and the emission request of municipal effluent is strict; country takes corresponding compulsory measure; seek a kind of effective sewage-treating agent, can reach sewage discharge requirement after can making sewage disposal, be numerous enterprises urgent need to solve the problem.Sewage disposal technology has a very important role to water saving, the problem such as energy-conservation, but also affects to environment in the use procedure of sewage treatment drug simultaneously.In cooling water system, water temperature is higher than under the various occasions of envrionment temperature, and the fouling of the inorganic salt such as calcium carbonate can bring serious consequence.In recent years, in making up plant's water treatment field, the water technology of using basic, non-adjust ph is growing.
Summary of the invention
The object of the present invention is to provide a kind of clothes source mill sewage-treating agent and preparation method thereof, this sewage-treating agent is efficient, nontoxic, corrosion-free to object, and the preparation method of this sewage-treating agent is simple.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of clothes source mill sewage-treating agent, is made up of the material of following mass fraction: this parallel triazole 20 ~ 40 parts, 20 ~ 40 parts, stem of noble dendrobium leaf powder, ethylene bis stearamide 10 ~ 30 parts, polyacrylamide 15 ~ 30 parts, 5-tetrachloro-salicylanilide 40 ~ 60 parts, percarbonic acid ammonia 20 ~ 40 parts, dimethyl diallyl 20 ~ 40 parts, polyaluminium sulfate 20 ~ 40 parts, 20 ~ 40 parts, sulfonic acid fat, polyethylene glycol stearate 20 ~ 40 parts, deionized water 50 ~ 100 parts.
The preparation method of clothes source mill of the present invention sewage-treating agent, adopts following steps:
(1) measure starting material according to above-mentioned mass fraction, clean mixing of materials prepares stirrer, adds secondary deionized water;
(2) stem of noble dendrobium leaf powder slowly being added material is mixed with in stirrer, record churning time, from unlatching mixing of materials prepare stirrer to stem of noble dendrobium leaf powder feed intake terminate required time be 5 ~ 10 minutes;
(3) this parallel triazole is slowly added material to be mixed with in stirrer and to stir;
(4) slowly drop into raw material ethylene bis stearamide under normal pressure, temperature is less than 60 DEG C, and terminate until reinforced, whole process completed in 40 minutes;
(5) slowly drop into polyacrylamide, 5-tetrachloro-salicylanilide and unclassified stores under normal pressure, temperature is less than 60 DEG C, terminates until reinforced, whole process completed in 40 minutes, pH controls between 8 ~ 9, and stop mixing of materials preparing stirrer, the examination and test of products is packed.
Above-mentioned material has following characteristic:
(1) benzotriazole: in slushing oil (fat) series products, to copper and alloy thereof, the anticorrosion ability of silver and alloy thereof is obvious especially, be used for the vapour-phase inhibitor of Copper and its alloy, circulating water treatment agent, automobile antifreeze solution, photograph antifogging agent, macromolecule stabilizer, plant-growth regulator, lubricating oil additive etc.Also can control agent in chromium plating industry as chromium mist, prevent the producing and harm of chromium mist.Increase the luminance brightness of plating piece.This product also can with multiple Scale inhibitors, Biocidal algae-killing agent with the use of.Can be used for outdoor paint additive, obviously reduce face (painting) material cause because of ultraviolet damage fade.
(2) stem of noble dendrobium leaf powder: as health meals raw material, herbal pharmaceutical raw material, health Herb Tea raw material, health-preserving medicinal liquor raw material, facial mask external application raw material, other health raw materials.
(3) ethylene bis stearamide: hard and crisp white high melting-point wax, its industrial goods are the fine particle of yellowish, nontoxic, human body is had no side effect, be insoluble to most of solvent under normal temperature, soda acid and water medium are stablized, chlorinated hydrocarbons and the aromatic hydrocarbon solvent of heat can be dissolved in, its meal soapy feeling is comparatively strong, and more than 80 DEG C have wettable compound to glassware for drinking water.As the fusing point rising agent of petroleum products; Lubricant during metal wire-drawing and inhibitor; The Embedding Material of electrical element; The defoamer of paper industry and paper coating composition; In textile dyeing and finishing, can be used as dyeing engineering defoamer and permanently pull out aqua; In pitch, add this product, the viscosity of pitch can be reduced, improve the softening temperature of pitch, water resisting property and weathering resistance.
(4) polyacrylamide: high molecular weight water soluble polymer, be insoluble to most of organic solvent, there is good flocculence, the friction resistance between liquid can be reduced, divide by ion characteristic and can be divided into nonionic, negatively charged ion, positively charged ion and amphoteric Four types.In municipal sewage treatment, be mainly used in sludge dewatering, small part is used for waste water clarification.At several years of future, most of municipal sewage plant will adopt this product to make flocculation agent.The main flocculation agent being used as retention aid, dry reinforcer and wastewater treatment in paper industry.
(5) 5-tetrachloro-salicylanilide: canescence or beige crystalline powder, can reduce sludge yield effectively, can as uncoupling agents.
(6) percarbonic acid ammonia: colourless cubic crystal, normal containing 1 molecular crystal water; Soluble in water, the aqueous solution is in alkalescence.Be insoluble to ethanol, dithiocarbonic anhydride and strong aqua.Unstable in atmosphere, slightly water absorbability.As fertilizer, fire-fighting medium, washing composition for industry such as medicine, rubber, fermentations.As the raw material of saleratus, various ammonium salt, buffer reagent, dyeing and printing auxiliary, fertilizer and analytical reagent etc.For spot analysis lithium, radium and thorium and carbonate synthesis etc.
(7) dimethyl diallyl: colourless transparent liquid, soluble in water, ethanol, isopropylcarbinol, be insoluble to ester, ketone and other carbohydrate, forms polymer as cationic monomer by homopolymerization or copolymerization.Its homopolymer and the polymkeric substance with other monomers (diallyl amine), can be used as superior aldehyde-free colour stabilizer in dyeing and finishing auxiliaries for textile, film forming on fabric, improves dyefastness; In paper making additive, can be used as retention filtering agent, Paper Coating is antistatic; Decolouring, flocculation and purification is can be used in water treatment procedure, efficient and nontoxic; In household chemicals, can be used for the carding agent of shampoo, wetting agent and static inhibitor; In oil field chemical, can be used for flocculation agent, plugging agent etc.Dry Wet Strength Resin, retention filtration adjuvant can be done at paper industry and other monomer homopolymerizations.Its Main Function is charge neutrality, absorption, flocculation, purification, decolouring, especially as the properties-correcting agent of synthetic resins, gives electroconductibility, antistatic.
(8) polyaluminium sulfate: composite polymer polymkeric substance, molecular structure is huge, high adsorption capacity, and purifying water effect is better than all traditional inorganic water purification agents.The flocs unit formed after dropping into former water is large, and sedimentation speed is fast, and active high, filterableness is good.And the strong adaptability to various former water, minimum on the pH value impact of water.No matter raw water turbidity height, Wastewater Pollutant concentration, its decontamination effect improving is remarkable.Consumption is few, little, easy to operate to equipment, corrosive pipeline, and purification cost is low.Can be widely used in process water and municipal effluent, after process, water-quality guideline can reach first discharge standard.Purification Drinking Water, the water quality after purification reaches the drinking water standard of national regulation.Waste water such as industry such as purification papermaking, printing and dyeing etc., consumption is few, and decolorizing effect is good, and processed water can reuse.
(9) sulfonic acid fat: be the compound that a class has general formula R 1SO2OR2.Normal is low melting point solid.The reaction that alcohol is obtained by reacting with it ester can be used for qualification.
(10) polyethylene glycol stearate: product is white waxy solid, in dispersion state in water.This product has good smoothness, flexibility, for the emulsifying agent of makeup, and has certain pearl effect and thickening power.
This beneficial effect of the invention is: the sewage-treating agent in this invention, and speed of response is fast, produces in process without toxic and harmful; Reacted resultant is stablized, and can not resolve into toxic substance again; Efficiently, nontoxic, reaction before and after to human-body safety, corrosion-free to object; High for sewage treating efficiency, easy to use.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
Embodiment 1
Clothes source mill sewage-treating agent in the present embodiment, is made up of the material of following mass fraction: this parallel triazole 20 parts, 20 parts, stem of noble dendrobium leaf powder, ethylene bis stearamide 10 parts, polyacrylamide 15 parts, 5-tetrachloro-salicylanilide 40 parts, percarbonic acid ammonia 20 parts, dimethyl diallyl 20 parts, polyaluminium sulfate 20 parts, 20 parts, sulfonic acid fat, polyethylene glycol stearate 20 parts, deionized water 50 parts.
The preparation method of a kind of clothes source mill of the present invention sewage-treating agent, described preparation method adopts following steps:
(1) measure starting material according to above-mentioned mass fraction, clean mixing of materials prepares stirrer, adds secondary deionized water;
(2) stem of noble dendrobium leaf powder slowly being added material is mixed with in stirrer, record churning time, from unlatching mixing of materials prepare stirrer to stem of noble dendrobium leaf powder feed intake terminate required time be 5 minutes;
(3) this parallel triazole is slowly added material to be mixed with in stirrer and to stir;
(4) slowly drop into raw material ethylene bis stearamide under normal pressure, temperature is less than 60 DEG C, and terminate until reinforced, whole process completed in 40 minutes;
(5) slowly drop into polyacrylamide, 5-tetrachloro-salicylanilide and unclassified stores under normal pressure, temperature is less than 60 DEG C, terminates until reinforced, whole process completed in 40 minutes, pH controls about 8, and stop mixing of materials preparing stirrer, the examination and test of products is packed.
Utilize the sewage-treating agent in the present embodiment, detect COD, BOD and SS (suspended substance in water quality) for waste water before treatment with the clear water of the rear solid-liquid separation of process respectively, and detect total nitrogen, total phosphorus and ammonia-nitrogen content, result is as follows:
COD and BOD drops to 1200mg/L and 380mg/L by initial 12500mg/L and 4890mg/L respectively; SS drops to 378mg/L by initial 3696mg/L; Total nitrogen content drops to 27mg/L by 77.6mg/L, and total phosphorous drops to 4.6mg/L by 13.6mg/L, and ammonia-nitrogen content drops to 6.6mg/L by 18.9mg/L.
Apparent effect measuring: before process, chroma in waste water is 2250 times, and the clear water colourity after process is less than 45 times; Compared to waste water before process, the foul odour of the clear water after process obviously alleviates; Before process, chroma in waste water is 110 times, and the clear water colourity after process drops to 26 times; Before process, turbidity of wastewater is 288NTU, and the clear water turbidity after process drops to 26NTU.
Embodiment 2
Clothes source mill sewage-treating agent in the present embodiment, is made up of the material of following mass fraction: this parallel triazole 30 parts, 30 parts, stem of noble dendrobium leaf powder, ethylene bis stearamide 20 parts, polyacrylamide 18 parts, 5-tetrachloro-salicylanilide 50 parts, percarbonic acid ammonia 30 parts, dimethyl diallyl 30 parts, polyaluminium sulfate 30 parts, 30 parts, sulfonic acid fat, polyethylene glycol stearate 30 parts, deionized water 80 parts.
The preparation method of clothes source mill of the present invention sewage-treating agent, described preparation method adopts following steps:
(1) measure starting material according to above-mentioned mass fraction, clean mixing of materials prepares stirrer, adds secondary deionized water;
(2) stem of noble dendrobium leaf powder slowly being added material is mixed with in stirrer, record churning time, from unlatching mixing of materials prepare stirrer to stem of noble dendrobium leaf powder feed intake terminate required time be 8 minutes;
(3) this parallel triazole is slowly added material to be mixed with in stirrer and to stir;
(4) slowly drop into raw material ethylene bis stearamide under normal pressure, temperature is less than 60 DEG C, and terminate until reinforced, whole process completed in 40 minutes;
(5) slowly drop into polyacrylamide, 5-tetrachloro-salicylanilide and unclassified stores under normal pressure, temperature is less than 60 DEG C, terminates until reinforced, whole process completed in 40 minutes, pH controls about 9, and stop mixing of materials preparing stirrer, the examination and test of products is packed.
Clear water respectively for waste water before treatment and solid-liquid separation detects COD, BOD and SS (suspended substance in water quality), and detects total nitrogen, total phosphorus and ammonia-nitrogen content, and result is as follows:
COD and BOD drops to 1400mg/L and 290mg/L by initial 11000mg/L and 3590mg/L respectively; SS drops to 350mg/L by initial 3626mg/L; Total nitrogen content 88.8mg/L drops to 24mg/L, and total phosphorous drops to 1.6mg/L by 11.9mg/L, and ammonia-nitrogen content drops to 8.5mg/L by 17.6mg/L.
Apparent effect measuring: before process, chroma in waste water is 2100 times, and the clear water colourity after process is less than 45 times; Compared to waste water before process, the foul odour of the clear water after process obviously alleviates; Before process, chroma in waste water is 115 times, and the clear water colourity after process drops to 28 times; Before process, turbidity of wastewater is 268NTU, and the clear water turbidity after process drops to 48NTU.
Embodiment 3
Clothes source mill sewage-treating agent in the present embodiment, is made up of the material of following mass fraction: this parallel triazole 40 parts, 40 parts, stem of noble dendrobium leaf powder, ethylene bis stearamide 30 parts, polyacrylamide 30 parts, 5-tetrachloro-salicylanilide 60 parts, percarbonic acid ammonia 40 parts, dimethyl diallyl 40 parts, polyaluminium sulfate 40 parts, 40 parts, sulfonic acid fat, polyethylene glycol stearate 40 parts, deionized water 100 parts.
The preparation method of a kind of clothes source mill of the present invention sewage-treating agent, described preparation method adopts following steps:
(1) measure starting material according to above-mentioned mass fraction, clean mixing of materials prepares stirrer, adds secondary deionized water;
(2) stem of noble dendrobium leaf powder slowly being added material is mixed with in stirrer, record churning time, from unlatching mixing of materials prepare stirrer to stem of noble dendrobium leaf powder feed intake terminate required time be 10 minutes;
(3) this parallel triazole is slowly added material to be mixed with in stirrer and to stir;
(4) slowly drop into raw material ethylene bis stearamide under normal pressure, temperature is less than 60 DEG C, and terminate until reinforced, whole process completed in 40 minutes;
(5) slowly drop into polyacrylamide, 5-tetrachloro-salicylanilide and unclassified stores under normal pressure, temperature is less than 60 DEG C, terminates until reinforced, whole process completed in 40 minutes, pH controls about 8.5, and stop mixing of materials preparing stirrer, the examination and test of products is packed.
Clear water respectively for waste water before treatment and solid-liquid separation detects COD, BOD and SS (suspended substance in water quality), and detects total nitrogen, total phosphorus and ammonia-nitrogen content, and result is as follows:
COD and BOD drops to 1220mg/L and 280mg/L by initial 14500mg/L and 4890mg/L respectively; SS drops to 340mg/L by initial 3986mg/L; Total nitrogen content drops to 28mg/L by 78.6mg/L, and total phosphorous drops to 4.8mg/L by 18.6mg/L, and ammonia-nitrogen content drops to 8.5mg/L by 20.9mg/L.
Apparent effect measuring: before process, chroma in waste water is 2400 times, and the clear water colourity after process is less than 38 times; Compared to waste water before process, the foul odour of the clear water after process obviously alleviates; Before process, chroma in waste water is 150 times, and the clear water colourity after process drops to 29 times; Before process, turbidity of wastewater is 459NTU, and the clear water turbidity after process drops to 52NTU.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (2)

1. a clothes source mill sewage-treating agent, is characterized in that: be made up of the material of following mass fraction: this parallel triazole 20 ~ 40 parts, 20 ~ 40 parts, stem of noble dendrobium leaf powder, ethylene bis stearamide 10 ~ 30 parts, polyacrylamide 15 ~ 30 parts, 5-tetrachloro-salicylanilide 40 ~ 60 parts, percarbonic acid ammonia 20 ~ 40 parts, dimethyl diallyl 20 ~ 40 parts, polyaluminium sulfate 20 ~ 40 parts, 20 ~ 40 parts, sulfonic acid fat, polyethylene glycol stearate 20 ~ 40 parts, deionized water 50 ~ 100 parts.
2. clothes source mill according to claim 1 sewage-treating agent, is characterized in that: its preparation method adopts following steps:
(1) measure starting material according to above-mentioned mass fraction, clean mixing of materials prepares stirrer, adds secondary deionized water;
(2) stem of noble dendrobium leaf powder slowly being added material is mixed with in stirrer, record churning time, from unlatching mixing of materials prepare stirrer to stem of noble dendrobium leaf powder feed intake terminate required time be 5 ~ 10 minutes;
(3) this parallel triazole is slowly added material to be mixed with in stirrer and to stir;
(4) slowly drop into raw material ethylene bis stearamide under normal pressure, temperature is less than 60 DEG C, and terminate until reinforced, whole process completed in 40 minutes;
(5) slowly drop into polyacrylamide, 5-tetrachloro-salicylanilide and unclassified stores under normal pressure, temperature is less than 60 DEG C, terminates until reinforced, whole process completed in 40 minutes, pH controls between 8 ~ 9, and stop mixing of materials preparing stirrer, the examination and test of products is packed.
CN201510406576.2A 2015-07-12 2015-07-12 Clothing processing plant sewage treatment agent Pending CN105036209A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105540703A (en) * 2016-02-26 2016-05-04 山东五洲检测有限公司 Composite efficient sewage treatment agent based on natural ore and preparing method thereof
CN108617708A (en) * 2018-06-29 2018-10-09 四川建源节能科技有限公司 Water body detergent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000246013A (en) * 1999-02-26 2000-09-12 Jien Ri Flocculating sedimentation agent and flocculation treatment method
CN101381170A (en) * 2007-09-07 2009-03-11 袁晓东 Corrosion inhibitor of internal combustion engine cooling liquid and production process
CN103641245A (en) * 2013-12-27 2014-03-19 姚为 Papermaking wastewater treating agent and preparation method thereof
CN104163509A (en) * 2014-07-31 2014-11-26 青岛华承天机械制造有限公司 Highly efficient penetrating scale inhibitor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000246013A (en) * 1999-02-26 2000-09-12 Jien Ri Flocculating sedimentation agent and flocculation treatment method
CN101381170A (en) * 2007-09-07 2009-03-11 袁晓东 Corrosion inhibitor of internal combustion engine cooling liquid and production process
CN103641245A (en) * 2013-12-27 2014-03-19 姚为 Papermaking wastewater treating agent and preparation method thereof
CN104163509A (en) * 2014-07-31 2014-11-26 青岛华承天机械制造有限公司 Highly efficient penetrating scale inhibitor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105540703A (en) * 2016-02-26 2016-05-04 山东五洲检测有限公司 Composite efficient sewage treatment agent based on natural ore and preparing method thereof
CN108617708A (en) * 2018-06-29 2018-10-09 四川建源节能科技有限公司 Water body detergent

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