CN104974547A - Method for extraction of cocoa bean pigment - Google Patents
Method for extraction of cocoa bean pigment Download PDFInfo
- Publication number
- CN104974547A CN104974547A CN201510325075.1A CN201510325075A CN104974547A CN 104974547 A CN104974547 A CN 104974547A CN 201510325075 A CN201510325075 A CN 201510325075A CN 104974547 A CN104974547 A CN 104974547A
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- CN
- China
- Prior art keywords
- cocoa beans
- pigment
- sodium carbonate
- extraction
- mentioned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 244000299461 Theobroma cacao Species 0.000 title claims abstract description 48
- 235000009470 Theobroma cacao Nutrition 0.000 title claims abstract description 37
- 244000046052 Phaseolus vulgaris Species 0.000 title claims abstract description 32
- 235000010627 Phaseolus vulgaris Nutrition 0.000 title claims abstract description 32
- 239000000049 pigment Substances 0.000 title claims abstract description 14
- 238000000605 extraction Methods 0.000 title claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 19
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 claims description 9
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 claims description 9
- 235000001046 cacaotero Nutrition 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 230000008595 infiltration Effects 0.000 claims description 4
- 238000001764 infiltration Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 235000013372 meat Nutrition 0.000 claims description 4
- 238000005554 pickling Methods 0.000 claims description 4
- 239000011833 salt mixture Substances 0.000 claims description 4
- 238000001694 spray drying Methods 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 235000016709 nutrition Nutrition 0.000 abstract description 2
- 230000035764 nutrition Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 230000036541 health Effects 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000002203 pretreatment Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000219161 Theobroma Species 0.000 description 2
- 235000019219 chocolate Nutrition 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- YAPQBXQYLJRXSA-UHFFFAOYSA-N theobromine Chemical compound CN1C(=O)NC(=O)C2=C1N=CN2C YAPQBXQYLJRXSA-UHFFFAOYSA-N 0.000 description 2
- 241000219071 Malvaceae Species 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical class CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002964 excitative effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000989 food dye Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229960004559 theobromine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Confectionery (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention discloses a method for extraction of cocoa bean pigment and relates to the technical field of pigment extraction. The method comprises raw material selection, pre-treatment, triturating and precooling, sodium carbonate extraction, and condensation and drying. The method has the advantages of simple processes, reasonable method, no pollution in the whole process, high efficiency and low extraction cost. The extracted cocoa pigment has high purity and no pollution, is suitable for industrial production, can be directly used as edible pigment, has a high nutrition value, has health functions, is safe and nontoxic and has good quality.
Description
Technical field
The present invention relates to technical field of pigment extraction, be specifically related to a kind of method extracting pigment in cocoa beans.
Background technology
Cocoa beans is the fruit of Sterculiaceae aiphyllium cocoa tree, the flat seed of long oval nut, oil-containing 53% ~ 58%, and the theobroma oil of squeezing out has unique perfume and melts performance, is the product of cocoa tree, and China started to introduce a fine variety this kind of trees in nineteen twenty-two.On the gentle slope that the atteration gratifyingly can being born in warm and moistening climate and be imbued with organic matter is formed, on impeded drainage and heavy clay or often, be then not suitable for growth by the place of typhoon.Cocoa beans moisture content 5.58%, fat 50.29%, nitrogenous substances 14.19%, Theobromine 1.55%, other non-nitrogen materials 13.91%, starch 8.77%, robust fibre 4.93%, containing phosphatase 24 0.4%, potassium 31.28% in its ash content, magnesium oxide 16.22%.Also containing nervous center excitatory substance and tannin such as caffeines in cocoa beans, tannin has much relations with chocolate color.The molten point of theobroma oil, close to the body temperature of people, has the characteristic of just melt in the mouth, at room temperature keeps certain hardness, and has unique cocoa aroma, has higher nutritive value, not oxidizable, is make chocolate main raw material.Cacao color is based on extracting a kind of pigment in cacao color, this pigment has the color of cocoa itself, one of indispensable pigment in some puffed foods of preparation simultaneously, because the resource of cocoa beans is relatively in short supply, therefore very large by cost cocoa beans extracting cacao color, a lot of enterprise all abandons using this type of mode,, a lot of safety problem can be there is in the mode of conversion chemical industry synthesis, but cacao color prepared by this mode, directly edible, likely can cause personal injury.
Summary of the invention:
It is simple that technical problem to be solved by this invention is to provide a kind of method, extracts the method extracting pigment in cocoa beans thoroughly.
Technical problem to be solved by this invention realizes by the following technical solutions:
Extract a method for pigment in cocoa beans, it is characterized in that, comprise following processing step:
A, choose ripe cocoa beans, cocoa beans is put into infiltrate and soak 5 hours, the solution that infiltrate is become with 2.5 parts of salt mixtures by 100 parts of pure water, pull out after infiltration, carry out airing, the cocoa beans after drying, remove inner meat, stay the seed coat of cocoa beans, for subsequent use;
B, by the seed coat of the cocoa beans after above-mentioned process dry, pulverize, then put into vessel;
C, vessel are directly placed on preset temp is in the ice chest of 0-1 DEG C, after precooling 25min, takes out nature and thaws, again dry;
D, step c is dried after material adopt after oxysuccinic acid carries out pickling, again use clean water;
E, by after above-mentioned washing material adopt sodium carbonate carry out lixiviate, extraction time controls at 5h, and during lixiviate, temperature controls at 75-85 DEG C, collect vat liquor, filter;
H, by above-mentioned filtrate flow through porousness polymeric adsorbent, then be 30% sodium carbonate solution drip washing resin by concentration, then collect this leacheate with 50% sodium carbonate solution drip washing resin, for subsequent use;
I, above-mentioned leacheate is filtered again after, throw in and concentrate to concentrating under reduced pressure tank, until after relative density 1 ± 0.01, the liquid after concentrated is carried out drying by spray drying technology, can cacao color be obtained.
The invention has the beneficial effects as follows: present invention process flow process is succinct, method is reasonable, omnidistance pollution-free, efficiency is high, and extraction cost is low, the cacao color of extraction, purity is high, pollution-free, the while of being applicable to industrial, also can directly eat as food dye, nutrition is high, have nourishing function, safety non-toxic, quality is better.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
Choose ripe cocoa beans, cocoa beans is put into infiltrate and soak 5 hours, the solution that infiltrate is become with 2.5 parts of salt mixtures by 100 parts of pure water, pulls out after infiltration, carry out airing, water content is advisable with 0.8, the cocoa beans after drying, remove inner meat, stay the seed coat of cocoa beans, for subsequent use; The seed coat of the cocoa beans after above-mentioned process is dried, pulverizes, then put into vessel; Vessel being directly placed on preset temp is in the ice chest of 0 DEG C, after precooling 25min, takes out nature and thaws, again dry; Material after oven dry uses clean water after adopting oxysuccinic acid to carry out pickling again; Adopt sodium carbonate to carry out lixiviate the material after above-mentioned washing, extraction time controls at 5h, and during lixiviate, temperature controls, at 75 DEG C, to collect vat liquor, filter; By above-mentioned filtrate flow through porousness polymeric adsorbent, then be 30% sodium carbonate solution drip washing resin by concentration, then collect this leacheate with 50% sodium carbonate solution drip washing resin, for subsequent use; After above-mentioned leacheate is filtered again, throw in and concentrate to concentrating under reduced pressure tank, until after relative density 1 ± 0.01, the liquid after concentrated is carried out drying by spray drying technology, can cacao color be obtained.
Embodiment 2
Choose ripe cocoa beans, cocoa beans is put into infiltrate and soak 5 hours, the solution that infiltrate is become with 2.5 parts of salt mixtures by 100 parts of pure water, pulls out after infiltration, carry out airing, water content is 1.0, the cocoa beans after drying, remove inner meat, stay the seed coat of cocoa beans, for subsequent use; The seed coat of the cocoa beans after above-mentioned process is dried, pulverizes, then put into vessel; Vessel being directly placed on preset temp is in the ice chest of 1 DEG C, after precooling 25min, takes out nature and thaws, again dry; Material after oven dry uses clean water after adopting oxysuccinic acid to carry out pickling again; Adopt sodium carbonate to carry out lixiviate the material after above-mentioned washing, extraction time controls at 5h, and during lixiviate, temperature controls, at 75 DEG C, to collect vat liquor, filter; By above-mentioned filtrate flow through porousness polymeric adsorbent, then be 30% sodium carbonate solution drip washing resin by concentration, then collect this leacheate with 50% sodium carbonate solution drip washing resin, for subsequent use; After above-mentioned leacheate is filtered again, throw in and concentrate to concentrating under reduced pressure tank, until after relative density 1 ± 0.01, the liquid after concentrated is carried out drying by spray drying technology, can cacao color be obtained.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (1)
1. extract a method for pigment in cocoa beans, it is characterized in that, comprise following processing step:
A, choose ripe cocoa beans, cocoa beans is put into infiltrate and soak 5 hours, the solution that infiltrate is become with 2.5 parts of salt mixtures by 100 parts of pure water, pull out after infiltration, carry out airing, the cocoa beans after drying, remove inner meat, stay the seed coat of cocoa beans, for subsequent use;
B, by the seed coat of the cocoa beans after above-mentioned process dry, pulverize, then put into vessel;
C, vessel are directly placed on preset temp is in the ice chest of 0-1 DEG C, after precooling 25min, takes out nature and thaws, again dry;
D, step c is dried after material adopt after oxysuccinic acid carries out pickling, again use clean water;
E, by after above-mentioned washing material adopt sodium carbonate carry out lixiviate, extraction time controls at 5h, and during lixiviate, temperature controls at 75-85 DEG C, collect vat liquor, filter;
H, by above-mentioned filtrate flow through porousness polymeric adsorbent, then be 30% sodium carbonate solution drip washing resin by concentration, then collect this leacheate with 50% sodium carbonate solution drip washing resin, for subsequent use;
I, above-mentioned leacheate is filtered again after, throw in and concentrate to concentrating under reduced pressure tank, until after relative density 1 ± 0.01, the liquid after concentrated is carried out drying by spray drying technology, can cacao color be obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510325075.1A CN104974547A (en) | 2015-06-11 | 2015-06-11 | Method for extraction of cocoa bean pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510325075.1A CN104974547A (en) | 2015-06-11 | 2015-06-11 | Method for extraction of cocoa bean pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104974547A true CN104974547A (en) | 2015-10-14 |
Family
ID=54271529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510325075.1A Pending CN104974547A (en) | 2015-06-11 | 2015-06-11 | Method for extraction of cocoa bean pigment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104974547A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978758A (en) * | 2019-05-21 | 2020-11-24 | 江西丹霞生物科技股份有限公司 | Preparation method of high-purity cocoa shell color |
| CN111978759A (en) * | 2019-05-21 | 2020-11-24 | 江西丹霞生物科技股份有限公司 | Preparation method of cocoa shell pigment |
| CN116478556A (en) * | 2023-04-28 | 2023-07-25 | 青岛鹏远康华天然产物有限公司 | Method for extracting cocoa shell brown pigment from cocoa bean shells |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4940136B1 (en) * | 1970-01-08 | 1974-10-31 | ||
| JPS51115967A (en) * | 1975-04-01 | 1976-10-13 | Ezaki Glico Co | Production of polyphenolic color |
| CN87103294A (en) * | 1987-04-30 | 1988-11-09 | 江西省林业科学研究所 | Extraction Technology of Duosuike Food Pigment |
| CN1297469A (en) * | 1998-05-11 | 2001-05-30 | 西格弗里德·彼得 | Method for extracting carotene from raw materials containing carotene |
| CN1786081A (en) * | 2004-12-10 | 2006-06-14 | 西北工业大学 | Method of extracting natural yellow pigment from persimon leaf or persion bark |
-
2015
- 2015-06-11 CN CN201510325075.1A patent/CN104974547A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4940136B1 (en) * | 1970-01-08 | 1974-10-31 | ||
| JPS51115967A (en) * | 1975-04-01 | 1976-10-13 | Ezaki Glico Co | Production of polyphenolic color |
| CN87103294A (en) * | 1987-04-30 | 1988-11-09 | 江西省林业科学研究所 | Extraction Technology of Duosuike Food Pigment |
| CN1297469A (en) * | 1998-05-11 | 2001-05-30 | 西格弗里德·彼得 | Method for extracting carotene from raw materials containing carotene |
| CN1786081A (en) * | 2004-12-10 | 2006-06-14 | 西北工业大学 | Method of extracting natural yellow pigment from persimon leaf or persion bark |
Non-Patent Citations (1)
| Title |
|---|
| 华仲麟等: "可可豆壳提制食用色素初步试验", 《林产化学与工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978758A (en) * | 2019-05-21 | 2020-11-24 | 江西丹霞生物科技股份有限公司 | Preparation method of high-purity cocoa shell color |
| CN111978759A (en) * | 2019-05-21 | 2020-11-24 | 江西丹霞生物科技股份有限公司 | Preparation method of cocoa shell pigment |
| CN116478556A (en) * | 2023-04-28 | 2023-07-25 | 青岛鹏远康华天然产物有限公司 | Method for extracting cocoa shell brown pigment from cocoa bean shells |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151014 |