CN104961838A - Hydroxypropylated modified starch and preparation method thereof, and glass fiber wetting agent - Google Patents
Hydroxypropylated modified starch and preparation method thereof, and glass fiber wetting agent Download PDFInfo
- Publication number
- CN104961838A CN104961838A CN201510414989.5A CN201510414989A CN104961838A CN 104961838 A CN104961838 A CN 104961838A CN 201510414989 A CN201510414989 A CN 201510414989A CN 104961838 A CN104961838 A CN 104961838A
- Authority
- CN
- China
- Prior art keywords
- starch
- hydroxypropylation
- solution
- glass fiber
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003365 glass fiber Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229920000881 Modified starch Polymers 0.000 title abstract description 6
- 239000004368 Modified starch Substances 0.000 title abstract description 6
- 235000019426 modified starch Nutrition 0.000 title abstract description 6
- 239000000080 wetting agent Substances 0.000 title abstract 5
- 229920002472 Starch Polymers 0.000 claims abstract description 102
- 239000008107 starch Substances 0.000 claims abstract description 102
- 235000019698 starch Nutrition 0.000 claims abstract description 102
- 238000006243 chemical reaction Methods 0.000 claims abstract description 39
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 19
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 230000008961 swelling Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- 230000008595 infiltration Effects 0.000 claims description 30
- 238000001764 infiltration Methods 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 14
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical group [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000000967 suction filtration Methods 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 6
- 239000003002 pH adjusting agent Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- -1 hydroxypropyl Chemical group 0.000 abstract description 20
- 238000006266 etherification reaction Methods 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 5
- 238000004381 surface treatment Methods 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 238000009941 weaving Methods 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000002633 protecting effect Effects 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 239000011152 fibreglass Substances 0.000 description 9
- 229920002261 Corn starch Polymers 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 229920000856 Amylose Polymers 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- 235000019759 Maize starch Nutrition 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000013019 agitation Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920001685 Amylomaize Polymers 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 238000005491 wire drawing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/08—Ethers
- C08B31/12—Ethers having alkyl or cycloalkyl radicals substituted by heteroatoms, e.g. hydroxyalkyl or carboxyalkyl starch
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/321—Starch; Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B33/00—Preparation of derivatives of amylose
- C08B33/04—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Biochemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Description
Classification | Precursor convergency | Precursor stiffness | Disconnected hair flies silk | Ultimate strength/CN |
Comparative example 1 | Good | Better | Lousiness, disconnected hair are less | 2750 |
Comparative example 2 | Better | Better | Lousiness, disconnected hair are many | 2450 |
Embodiment 6 | Good | Good | Lousiness, disconnected hair are few | 3000 |
Claims (10)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510942752.4A CN105481989B (en) | 2015-07-15 | 2015-07-15 | Glass fiber impregnating compound added with modified starch |
CN201510414989.5A CN104961838B (en) | 2015-07-15 | 2015-07-15 | A kind of hydroxypropylation modified starch and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510414989.5A CN104961838B (en) | 2015-07-15 | 2015-07-15 | A kind of hydroxypropylation modified starch and preparation method thereof |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510942752.4A Division CN105481989B (en) | 2015-07-15 | 2015-07-15 | Glass fiber impregnating compound added with modified starch |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104961838A true CN104961838A (en) | 2015-10-07 |
CN104961838B CN104961838B (en) | 2017-03-01 |
Family
ID=54215945
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510942752.4A Active CN105481989B (en) | 2015-07-15 | 2015-07-15 | Glass fiber impregnating compound added with modified starch |
CN201510414989.5A Active CN104961838B (en) | 2015-07-15 | 2015-07-15 | A kind of hydroxypropylation modified starch and preparation method thereof |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510942752.4A Active CN105481989B (en) | 2015-07-15 | 2015-07-15 | Glass fiber impregnating compound added with modified starch |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN105481989B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105315379A (en) * | 2015-12-04 | 2016-02-10 | 东莞建泰生物科技有限公司 | Oil-proofing starch and production process and application thereof |
CN109652981A (en) * | 2018-11-22 | 2019-04-19 | 安徽华明太合生物工程有限公司 | A kind of starch base glass fibre infiltration film forming agent and preparation method thereof |
CN111072790A (en) * | 2019-12-27 | 2020-04-28 | 河南新孚望新材料科技有限公司 | Preparation method of modified starch for glass fiber cloth |
CN111072791A (en) * | 2019-12-27 | 2020-04-28 | 河南新孚望新材料科技有限公司 | Preparation method of high amylose starch for coating agent |
CN111100215A (en) * | 2019-12-30 | 2020-05-05 | 河南新孚望新材料科技有限公司 | Preparation method of hydroxypropyl high amylose starch for water-based paint |
CN111535029A (en) * | 2020-04-17 | 2020-08-14 | 安徽工程大学 | Sizing glass filament yarn and sizing method thereof |
CN112813561A (en) * | 2020-12-31 | 2021-05-18 | 南京玻璃纤维研究设计院有限公司 | Flat glass fiber fabric and preparation method thereof |
CN116099030A (en) * | 2022-11-15 | 2023-05-12 | 青岛海诺生物工程有限公司 | Chitosan breathable adhesive bandage and preparation method thereof |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106316158A (en) * | 2016-08-31 | 2017-01-11 | 郭舒洋 | Method for preparing impregnating compound from compound modified tapioca starch |
CN107759110A (en) * | 2017-10-31 | 2018-03-06 | 常州菲胜图自动化仪器有限公司 | A kind of preparation method of good beaming type glass fiber infiltration agent |
CN108585547A (en) * | 2018-07-19 | 2018-09-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of glass fibre high efficiency infiltration agent composition |
CN111977990B (en) * | 2020-09-08 | 2021-02-09 | 清远忠信电子材料有限公司 | High-performance impregnating compound for superfine electronic yarn and preparation method thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4281111A (en) * | 1978-06-28 | 1981-07-28 | Anheuser-Busch, Incorporated | Cold water hydrating starch |
CN101831262A (en) * | 2010-05-21 | 2010-09-15 | 吉林省轻工业设计研究院 | Special corn biomass-based adhesive and method for preparing same |
CN102030832A (en) * | 2010-12-10 | 2011-04-27 | 浙江大学 | Method for preparing compound modified starch for replacing gelatin |
CN102304188A (en) * | 2011-07-18 | 2012-01-04 | 西南科技大学 | Preparation method of starch type film-forming agent for glass fiber wetting agent |
CN103232548A (en) * | 2013-04-12 | 2013-08-07 | 西南科技大学 | A method for preparing an esterified starch film former for glass fiber wetting |
CN103669034A (en) * | 2013-11-22 | 2014-03-26 | 北京中纺化工股份有限公司 | Reactive printing gum and preparation method thereof |
CN103936873A (en) * | 2014-05-07 | 2014-07-23 | 重庆市化工研究院 | Preparation method of modified high amylose starch for glass fiber wetting agent |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE631196A (en) * | 1962-04-18 | |||
DE3765418D1 (en) * | 1987-03-11 | 1990-11-08 | Nat Starch Chem Invest | HETEROPOLYSACCHARIDES CONTAINING ALDEHYDE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE. |
JP2003212604A (en) * | 2002-01-25 | 2003-07-30 | Nippon Starch Chemical Co Ltd | Modified starch, glass fiber sizing agent and glass fiber stuck therewith |
CN103708741B (en) * | 2013-12-19 | 2017-02-01 | 清远忠信世纪玻纤有限公司 | Starch-type textile impregnating compound and preparation method thereof |
-
2015
- 2015-07-15 CN CN201510942752.4A patent/CN105481989B/en active Active
- 2015-07-15 CN CN201510414989.5A patent/CN104961838B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4281111A (en) * | 1978-06-28 | 1981-07-28 | Anheuser-Busch, Incorporated | Cold water hydrating starch |
CN101831262A (en) * | 2010-05-21 | 2010-09-15 | 吉林省轻工业设计研究院 | Special corn biomass-based adhesive and method for preparing same |
CN102030832A (en) * | 2010-12-10 | 2011-04-27 | 浙江大学 | Method for preparing compound modified starch for replacing gelatin |
CN102304188A (en) * | 2011-07-18 | 2012-01-04 | 西南科技大学 | Preparation method of starch type film-forming agent for glass fiber wetting agent |
CN103232548A (en) * | 2013-04-12 | 2013-08-07 | 西南科技大学 | A method for preparing an esterified starch film former for glass fiber wetting |
CN103669034A (en) * | 2013-11-22 | 2014-03-26 | 北京中纺化工股份有限公司 | Reactive printing gum and preparation method thereof |
CN103936873A (en) * | 2014-05-07 | 2014-07-23 | 重庆市化工研究院 | Preparation method of modified high amylose starch for glass fiber wetting agent |
Non-Patent Citations (5)
Title |
---|
张燕萍: "《变性淀粉制造与应用 第二版》", 31 July 2007, 化学工业出版社 * |
徐忠 等: "羟丙基淀粉制备的影响因素及性能研究", 《农产品加工 学刊》 * |
武宗文 等: "氧化羟丙基淀粉浆料性能研究", 《棉纺织技术》 * |
程建军: "《淀粉工艺学》", 31 December 2011, 科学出版社 * |
郑学晶 等: "《天然高分子材料》", 31 December 2010, 化学工业出版社 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105315379A (en) * | 2015-12-04 | 2016-02-10 | 东莞建泰生物科技有限公司 | Oil-proofing starch and production process and application thereof |
CN109652981A (en) * | 2018-11-22 | 2019-04-19 | 安徽华明太合生物工程有限公司 | A kind of starch base glass fibre infiltration film forming agent and preparation method thereof |
CN111072790A (en) * | 2019-12-27 | 2020-04-28 | 河南新孚望新材料科技有限公司 | Preparation method of modified starch for glass fiber cloth |
CN111072791A (en) * | 2019-12-27 | 2020-04-28 | 河南新孚望新材料科技有限公司 | Preparation method of high amylose starch for coating agent |
CN111100215A (en) * | 2019-12-30 | 2020-05-05 | 河南新孚望新材料科技有限公司 | Preparation method of hydroxypropyl high amylose starch for water-based paint |
CN111535029A (en) * | 2020-04-17 | 2020-08-14 | 安徽工程大学 | Sizing glass filament yarn and sizing method thereof |
CN111535029B (en) * | 2020-04-17 | 2022-10-11 | 安徽工程大学 | Sizing glass filament yarn and sizing method thereof |
CN112813561A (en) * | 2020-12-31 | 2021-05-18 | 南京玻璃纤维研究设计院有限公司 | Flat glass fiber fabric and preparation method thereof |
CN116099030A (en) * | 2022-11-15 | 2023-05-12 | 青岛海诺生物工程有限公司 | Chitosan breathable adhesive bandage and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN105481989A (en) | 2016-04-13 |
CN105481989B (en) | 2020-07-03 |
CN104961838B (en) | 2017-03-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104961838A (en) | Hydroxypropylated modified starch and preparation method thereof, and glass fiber wetting agent | |
CN104164199A (en) | Starch based biomass functional adhesive and preparation method thereof | |
CN101831262B (en) | Special corn biomass-based adhesive and method for preparing same | |
CN104448010B (en) | A kind of instant polyanion cellulose and preparation method thereof | |
CN105367673A (en) | Oxidation crosslinking modified starch and preparation method thereof | |
CN111533840B (en) | Environment-friendly water-resistant reinforced latex for paper and preparation method and application thereof | |
CN115125760A (en) | Surface sizing agent for white cardboard and preparation method thereof | |
EP3444310A1 (en) | Microfibrillated cellulose as rheology modifier in adhesives | |
CN112239960B (en) | Production method of fulvic acid straw plant fiber degradable mulching film | |
CN111269670B (en) | Preparation method of modified starch adhesive | |
CN101357994B (en) | Carboxymethyl wood flour with high degree of substitution and preparation method thereof | |
CN108485299A (en) | A kind of preparation method of plant fiber tableware | |
CN111364284B (en) | Modified sizing starch, surface sizing liquid and preparation method and application thereof | |
CN105481987A (en) | Method for preparing pregelatinized starch from wheat B starch | |
CN105646723B (en) | A kind of dialdehyde starch and preparation method thereof | |
CN104860551A (en) | Preparation method of chitosan modified starch impregnating compound | |
CN104164800A (en) | Preparation method for producing degradable materials by using banana stalks | |
CN107587388A (en) | A kind of resistant to elevated temperatures extrusion coating paper and preparation method thereof | |
CN105239387B (en) | A kind of method that full biological enzyme prepares high-performance environment-friendly spinning sizing agent | |
CN111286286B (en) | Preparation method of water-resistant starch adhesive | |
CN100402556C (en) | Sodium carboxymethyl hemicellulose with paper-making black liquor as raw material and producing method thereof | |
CN102532328A (en) | Starch pigment and preparation method thereof as well as coating and coated paper using the starch pigment | |
CN104222738A (en) | Preparation method of high-activity soluble glucomannan fibers | |
CN109929260A (en) | A method of environment-friendly degradable polymerization sheet is manufactured using agriculture and forestry organic waste material | |
CN105442370B (en) | A kind of method that bleached bamboo pulp plate prepares dissolving pulp |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information |
Address after: 462300 Henan Luohe economic and Technological Development Zone, Luo Road and Hengshan Road intersection Applicant after: HENAN HENGRUI STARCH TECHNOLOGY CO., LTD. Address before: Zhaoling people of East Luohe 462300 Henan province No. 73 Applicant before: Luohe Hengrui Chemical Co., Ltd. |
|
COR | Change of bibliographic data | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Hydroxypropylated modified starch and preparation method thereof, and glass fiber wetting agent Effective date of registration: 20190307 Granted publication date: 20170301 Pledgee: Bank of China Limited by Share Ltd Luohe branch Pledgor: HENAN HENGRUI STARCH TECHNOLOGY CO., LTD. Registration number: 2019990000186 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200409 Granted publication date: 20170301 Pledgee: Bank of China Limited by Share Ltd Luohe branch Pledgor: HENAN HENGRUI STARCH TECHNOLOGY Co.,Ltd. Registration number: 2019990000186 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Hydroxypropylated modified starch and preparation method thereof, and glass fiber wetting agent Effective date of registration: 20200413 Granted publication date: 20170301 Pledgee: Bank of China Limited by Share Ltd Luohe branch Pledgor: HENAN HENGRUI STARCH TECHNOLOGY Co.,Ltd. Registration number: Y2020980001452 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210120 Granted publication date: 20170301 Pledgee: Bank of China Limited by Share Ltd. Luohe branch Pledgor: HENAN HENGRUI STARCH TECHNOLOGY Co.,Ltd. Registration number: Y2020980001452 |