CN104945781A - Waste glass powder sintered bricks and production method thereof - Google Patents
Waste glass powder sintered bricks and production method thereof Download PDFInfo
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- CN104945781A CN104945781A CN201510417747.1A CN201510417747A CN104945781A CN 104945781 A CN104945781 A CN 104945781A CN 201510417747 A CN201510417747 A CN 201510417747A CN 104945781 A CN104945781 A CN 104945781A
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- glass powder
- waste glass
- polyvinyl chloride
- pvc
- resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses waste glass powder sintered bricks and a production method thereof. The waste glass powder sintered bricks comprise, by weight, 20-25 parts of waste glass powder and other raw materials. According to the sintered bricks, by adopting the waste glass powder as the main raw material, clay resources are saved, the production cost is lowered, and the purpose of disposing the waste glass powder and preventing the waste glass powder from polluting the environment is achieved; under the synergistic effect of added antimonous oxide and chlorine in polyvinyl chloride resin, the flame retardancy of polyvinyl chloride is improved; through cooperation of a compound plasticizer composed of added dioctyl sebacate, dimethyl terephthalate, an antioxidant 616 and tetrabromophthalic anhydride and the polyvinyl chloride resin, the forward effect of the plasticizers is maximized, the usage quantity of the plasticizers is reduced while the low temperature resistance of the sintered bricks is improved, and flexibility is improved.
Description
Technical field
The present invention relates to building material technical field, is more particularly a kind of waste glass powder vitrified brick and production method thereof.
Background technology
At present, the mode of vitrified bond during most of brickmaking, is adopted to prepare, but along with the increase of clay produced quantity, clay resource is day by day deficient, not only increase cost of winning, also ecotope is caused to having a strong impact on simultaneously, therefore need badly and optimize and improve existing brick-making method to change the status quo.
Using sodium hydroxide decomposing zircon sand, is the main production that China produces basic zirconium chloride and zirconium dioxide now.China's basic zirconium chloride yearly capacity in 2007 has reached 150,000 t, occupies the first in the world.Demand as the zirconium dioxide of functional materials and structured material also constantly increases, and its production technique cost is lower, but shortcoming is to produce a large amount of wastes (often produce 1t zirconium dioxide product and about discharge sig water 5m3, acid white residue 1t).In recent years, along with production-scale expansion, the process problem of the waste produced in production process also becomes increasingly conspicuous.
Therefore, utilize waste glass powder vitrified brick make vitrified brick be turn waste into wealth, the effective measure of protection of the environment, farmland saving, there is good social and economic benefits.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, a kind of intensity is high, thermal conductivity is low, density is little waste glass powder vitrified brick and production method thereof are provided.
The object of the invention is to be achieved through the following technical solutions:
A kind of waste glass powder vitrified brick, is made up of following raw material: waste glass powder 66-75, antimonous oxide 5-10, polyvinyl chloride (PVC) RESINS 10-15, dioctyl sebacate 8-12, dimethyl terephthalate (DMT) 12-15, oxidation inhibitor 616 5-8, PHT4 10-15, polyvinyl chloride (PVC) RESINS 25-35, nano aluminium oxide 2-4, order tie native 10-15, ooze 8-12, polyvinyl acetate 5-10, tung oil 4-6, molasses 3-6, sodium lauroyl sareosine 1-2, leng sha balsam 3-5, asbestos wool 4-8, additive 6-8, water are appropriate;
Described additive is made up of the raw material of following weight part: garnet 8-12, Fluorite slag 5-10, Yellow river silt 10-16, Quilonum Retard 3-4, zirconium disilicide 4-6, cerium oxide nano hollow ball 2-3, turkey red oil 4-6, the withered powder 2-4 of tea; Preparation method is: at 800-1000 DEG C, process 2-3h after garnet, Fluorite slag, Yellow river silt being mixed, pulverize after cooling, cross 100-150 mesh sieve, add turkey red oil and the withered powder of tea again, grinding evenly, then adds remaining raw material, in 40-60 DEG C, stir 20-30min under 400-600r/min condition, filter, wash and dry, be ground to 150-200 order, obtain final product.
A production method for waste glass powder vitrified brick, is prepared from by following steps:
(1) pulverize after waste glass powder, antimonous oxide, polyvinyl chloride (PVC) RESINS, dioctyl sebacate, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4, polyvinyl chloride (PVC) RESINS, nano aluminium oxide, asbestos wool, order knot soil, ooze mixing and grind, then add molasses, sodium lauroyl sareosine, additive and appropriate water and stir, obtaining compound;
(2) compound is extruded into adobe by vacuum extruder by compound, the vacuum tightness of vacuum extruder is 0.5-0.8Mpa, and extrusion pressure is 6-10Mpa;
(3) by after the adobe of step (2) under field conditions (factors) airing 10-12 days at the temperature of 800-900 DEG C sinter molding;
(4) by after leng sha balsam, tung oil, polyvinyl acetate mixing 80-90 DEG C, 800-1000r/min stirs 5-10min, the fragment of brick surface that then even application is obtained in (3), 100-120 DEG C is incubated 2-4h, after cooling and get final product.
The invention has the advantages that:
Vitrified brick of the present invention adopts waste glass powder to be that clay resource not only saved by main raw material(s), reduces production cost, also solves the process problem of zirconium white residue, avoids its pollution to environment; In addition, it is high that vitrified brick of the present invention has intensity, and bearing capacity is strong, and density is little, and thermal conductivity is low, and meet the requirement of people, applied range, market outlook are large.The antimonous oxide that the present invention adds is by the synergy with the chlorine element in polyvinyl chloride (PVC) RESINS, enhance the flame retardant resistance of polyvinyl chloride, plasticizer and the polyvinyl chloride (PVC) RESINS of the dioctyl sebacate added, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4 composition are arranged in pairs or groups, the positive acting of this several softening agent is maximized, decrease the consumption of softening agent while improve the resistance to low temperature of product, increase snappiness.
Embodiment
Embodiment 1
A kind of waste glass powder vitrified brick, is made up of following weight raw material: waste glass powder 66 kg, antimonous oxide 5 kg, polyvinyl chloride (PVC) RESINS 10 kg, dioctyl sebacate 8 kg, dimethyl terephthalate (DMT) 12 kg, oxidation inhibitor 616 5 kg, PHT4 10 kg, polyvinyl chloride (PVC) RESINS 25 kg, nano aluminium oxide 2 kg, order tie native 10kg, ooze 8kg, polyvinyl acetate 5kg, tung oil 4kg, molasses 3kg, sodium lauroyl sareosine 1kg, leng sha balsam 3kg, asbestos wool 4kg, additive 6kg, water are appropriate;
Described additive is made up of the raw material of following weight: garnet 8kg, Fluorite slag 5kg, Yellow river silt 10kg, Quilonum Retard 3kg, zirconium disilicide 4kg, cerium oxide nano hollow ball 2kg, turkey red oil 4kg, the withered powder 2kg of tea; Preparation method is: at 800 DEG C, process 3h after garnet, Fluorite slag, Yellow river silt being mixed, pulverize after cooling, cross 100 mesh sieves, add turkey red oil and the withered powder of tea again, grinding evenly, then adds remaining raw material, in 40 DEG C, stir 30min under 400r/min condition, filter, wash and dry, be ground to 150 orders, obtain final product.
A production method for waste glass powder vitrified brick, is prepared from by following steps:
(1) pulverize after waste glass powder, antimonous oxide, polyvinyl chloride (PVC) RESINS, dioctyl sebacate, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4, polyvinyl chloride (PVC) RESINS, nano aluminium oxide, asbestos wool, order knot soil, ooze mixing and grind, then add molasses, sodium lauroyl sareosine, additive and appropriate water and stir, obtaining compound;
(2) compound is extruded into adobe by vacuum extruder by compound, the vacuum tightness of vacuum extruder is 0.5-0.8Mpa, and extrusion pressure is 6-10Mpa;
(3) by after the adobe of step (2) under field conditions (factors) airing 10-12 days at the temperature of 800-900 DEG C sinter molding;
(4) by after leng sha balsam, tung oil, polyvinyl acetate mixing 80-90 DEG C, 800-1000r/min stirs 5-10min, the fragment of brick surface that then even application is obtained in (3), 100-120 DEG C is incubated 2-4h, after cooling and get final product.
Embodiment 2
Waste glass powder 75 kg, antimonous oxide 10 kg, polyvinyl chloride (PVC) RESINS 15 kg, dioctyl sebacate 12 kg, dimethyl terephthalate (DMT) 15 kg, oxidation inhibitor 616 8 kg, PHT4 15 kg, polyvinyl chloride (PVC) RESINS 35 kg, nano aluminium oxide 4 kg, order tie native 12kg, ooze 810kg, polyvinyl acetate 8kg, tung oil 5kg, molasses 4.5kg, sodium lauroyl sareosine 1.5kg, leng sha balsam 4kg, asbestos wool 6kg, additive 7kg, water are appropriate;
Described additive is made up of the raw material of following weight: garnet 10kg, Fluorite slag 8kg, Yellow river silt 12kg, Quilonum Retard 3.5kg, zirconium disilicide 5kg, cerium oxide nano hollow ball 2.5kg, turkey red oil 5kg, the withered powder 3kg of tea; Preparation method is: at 900 DEG C, process 2.5h after garnet, Fluorite slag, Yellow river silt being mixed, pulverize after cooling, cross 100 mesh sieves, add turkey red oil and the withered powder of tea again, grinding evenly, then adds remaining raw material, in 50 DEG C, stir 25min under 500r/min condition, filter, wash and dry, be ground to 150 orders, obtain final product.
The preparation method of waste glass powder vitrified brick is with embodiment 1.
The antimonous oxide that the present invention adds is by the synergy with the chlorine element in polyvinyl chloride (PVC) RESINS, enhance the flame retardant resistance of polyvinyl chloride, plasticizer and the polyvinyl chloride (PVC) RESINS of the dioctyl sebacate added, dimethyl terephthalate (DMT), oxidation inhibitor 616, PHT4 composition are arranged in pairs or groups, the positive acting of this several softening agent is maximized, decrease the consumption of softening agent while improve the resistance to low temperature of product, increase snappiness.
Claims (2)
1. a waste glass powder vitrified brick, is characterized in that: be made up of following raw material: waste glass powder 66-75, antimonous oxide 5-10, polyvinyl chloride (PVC) RESINS 10-15, dioctyl sebacate 8-12, dimethyl terephthalate (DMT) 12-15, oxidation inhibitor 616 5-8, PHT4 10-15, polyvinyl chloride (PVC) RESINS 25-35, nano aluminium oxide 2-4, order tie native 10-15, ooze 8-12, polyvinyl acetate 5-10, tung oil 4-6, molasses 3-6, sodium lauroyl sareosine 1-2, leng sha balsam 3-5, asbestos wool 4-8, additive 6-8, water are appropriate;
Described additive is made up of the raw material of following weight part: garnet 8-12, Fluorite slag 5-10, Yellow river silt 10-16, Quilonum Retard 3-4, zirconium disilicide 4-6, cerium oxide nano hollow ball 2-3, turkey red oil 4-6, the withered powder 2-4 of tea; Preparation method is: at 800-1000 DEG C, process 2-3h after garnet, Fluorite slag, Yellow river silt being mixed, pulverize after cooling, cross 100-150 mesh sieve, add turkey red oil and the withered powder of tea again, grinding evenly, then adds remaining raw material, in 40-60 DEG C, stir 20-30min under 400-600r/min condition, filter, wash and dry, be ground to 150-200 order, obtain final product.
2. the production method of a kind of waste glass powder vitrified brick according to claim 1, is characterized in that being prepared from by following steps:
(1) pulverize after waste glass powder 66-75, antimonous oxide 5-10, polyvinyl chloride (PVC) RESINS 10-15, dioctyl sebacate 8-12, dimethyl terephthalate (DMT) 12-15, oxidation inhibitor 616 5-8, PHT4 10-15, polyvinyl chloride (PVC) RESINS 25-35, nano aluminium oxide, asbestos wool, order knot soil, ooze mixing and grind, then add molasses, sodium lauroyl sareosine, additive and appropriate water and stir, obtaining compound;
(2) compound is extruded into adobe by vacuum extruder by compound, the vacuum tightness of vacuum extruder is 0.5-0.8Mpa, and extrusion pressure is 6-10Mpa;
(3) by after the adobe of step (2) under field conditions (factors) airing 10-12 days at the temperature of 800-900 DEG C sinter molding;
(4) by after leng sha balsam, tung oil, polyvinyl acetate mixing 80-90 DEG C, 800-1000r/min stirs 5-10min, the fragment of brick surface that then even application is obtained in (3), 100-120 DEG C is incubated 2-4h, after cooling and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510417747.1A CN104945781A (en) | 2015-07-16 | 2015-07-16 | Waste glass powder sintered bricks and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510417747.1A CN104945781A (en) | 2015-07-16 | 2015-07-16 | Waste glass powder sintered bricks and production method thereof |
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| CN104945781A true CN104945781A (en) | 2015-09-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510417747.1A Pending CN104945781A (en) | 2015-07-16 | 2015-07-16 | Waste glass powder sintered bricks and production method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189214A (en) * | 2016-08-02 | 2016-12-07 | 苏州锐特捷化工制品有限公司 | A kind of preparation method of high intensity MC nylon modified fibre composite base material |
| CN106221199A (en) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | A kind of high strength graphite alkene nylon composite junction brick preparation method |
| CN106243701A (en) * | 2016-08-01 | 2016-12-21 | 苏州锐特捷化工制品有限公司 | A kind of preparation method of high temperature resistant expansion composite environmental-friendly construction substrate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN104628255A (en) * | 2013-11-06 | 2015-05-20 | 杜栋 | New technology of waste glass reuse |
| CN104672696A (en) * | 2014-12-31 | 2015-06-03 | 宣城福美达新材料有限公司 | Glass fiber reinforced PVC (polyvinyl chloride) plastic supporting plate and preparation method thereof |
-
2015
- 2015-07-16 CN CN201510417747.1A patent/CN104945781A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN104628255A (en) * | 2013-11-06 | 2015-05-20 | 杜栋 | New technology of waste glass reuse |
| CN104672696A (en) * | 2014-12-31 | 2015-06-03 | 宣城福美达新材料有限公司 | Glass fiber reinforced PVC (polyvinyl chloride) plastic supporting plate and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243701A (en) * | 2016-08-01 | 2016-12-21 | 苏州锐特捷化工制品有限公司 | A kind of preparation method of high temperature resistant expansion composite environmental-friendly construction substrate |
| CN106189214A (en) * | 2016-08-02 | 2016-12-07 | 苏州锐特捷化工制品有限公司 | A kind of preparation method of high intensity MC nylon modified fibre composite base material |
| CN106221199A (en) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | A kind of high strength graphite alkene nylon composite junction brick preparation method |
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Application publication date: 20150930 |
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