CN104892034A - Ceramic possessing glaze stripping effect and preparation method thereof - Google Patents

Ceramic possessing glaze stripping effect and preparation method thereof Download PDF

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Publication number
CN104892034A
CN104892034A CN201510226093.4A CN201510226093A CN104892034A CN 104892034 A CN104892034 A CN 104892034A CN 201510226093 A CN201510226093 A CN 201510226093A CN 104892034 A CN104892034 A CN 104892034A
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Prior art keywords
ink
pottery
solvent
slurry
preparation
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CN104892034B (en
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汪庆刚
杨晓峰
杨元东
刘一军
潘利敏
谢志军
赵勇
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GUANGDONG MONALISA NEW MATERIAL GROUP CO Ltd
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GUANGDONG MONALISA NEW MATERIAL GROUP CO Ltd
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Abstract

The invention relates to a ceramic possessing glaze stripping effect and a preparation method thereof. The base substrate of the ceramic is sprayed with ink and a transparent glaze layer, the ink comprises a hydrophobicity compound, wherein, the hydrophobicity compound is a low molecular organic fluoride, and the hydrophobicity compound accounts for 0.05-5.0% of mass percentage of ink. The ink in the invention has hydrophobic effect, the ink is sprayed on the ceramic base substrate, a slurry by taking water as a solvent is sprayed on the ink, the slurry can be uniformly sprayed on the ink layer, due to hydrophobicity of the ink layer, and the slurry can be stripped to form recess. The ceramic base substrate is sintered and polished to obtain the ceramic product with recess on the surface, and the recess position is matte. The glaze stripping effect can be realized on the ceramic base substrate through the above mode.

Description

A kind of have pottery dialling glaze effect and preparation method thereof
Technical field
The invention belongs to ceramic ink jet technical field, particularly relate to and a kind of there is the pottery and preparation method thereof dialling glaze effect, belong to building ceramic decoration field.
Background technology
Ceramic ink jet technology as a kind of new technique, to present ceramic tile personalized, art up, diversified, become more meticulous, the development of low-carbon environment-friendly has important effect; Since introducing First ceramic ink jet machine from China in 2009, through development in a few years, the share of market of ceramic ink jet product is more and more higher; The high speed development of ceramic ink jet technology result in the cut-throat competition of each large Ceramics Enterprises, only have and constantly technique, design are courageously combined with novel material, develop the ceramic ink of a series of specific function, and combine with traditional technology, develop the ceramic tile with special decorative effect, just can better based on market.
The ink that application number 201410163383.4 utilizes inorganic salt to prepare, forming Z-Correct bump mapping Z-correct by high temperature there is chemical reaction with cover-coat enamel, having certain requirement to glaze temperature, sagging place is not pure matte effect; And the inorganics used is containing toxic, is unfavorable for environmental protection.
There is the use of the ceramic ink dialling glaze effect, can make ceramic tile meticulousr embody concavo-convex texture, soft texture, the utilization particularly on imitative stone material, imitative wood grain tile, the use reducing concavo-convex grinding tool can be played, improve the decorative effect of ceramic tile simultaneously.Thus, there is the ink dialling glaze effect and become one of important directions of those skilled in the art's research.
Summary of the invention
The present invention is intended to overcome prior art and cannot realizes obtaining crack at ceramic surface simultaneously and sink and the technical problem of pure matt effect, the invention provides a kind ofly to have pottery dialling glaze effect and preparation method thereof.
The invention provides a kind of ink that can produce group glaze effect, described ink comprises hydrophobic compound, and wherein, hydrophobic compound is low molecule organic fluoride, the mass percent that hydrophobic compound accounts for ink is 0.05%-5.0%, preferred 0.1%-5.0%.
Preferably, low molecule organic fluoride comprises Freon 113, methyl chlorofluoride, perfluorotributylamine, ethyl difluoro and/or perfluor alkane etc.
Preferably, it is the solvent of 94%-99% that described ink also contains mass percent, and wherein, solvent comprises varsol and/or esters solvent.
Preferably, it is the organic toner of 0.1%-0.5% that described ink also contains mass percent, and organic toner preferable methyl is blue, methyl red.
Preferably, the contact angle of described ink and water is greater than 100 degree.
Preferably, described hydrophobic compound accounts for the mass percent of ink is 0.1%-2%.
Again, present invention also offers a kind of pottery adopting above-mentioned ink to prepare, on the base substrate of described pottery, spray printing has described ink, transparent layer successively.
Described in the present invention, ink has hydrophobic effect, thus in the ban on ceramic body after ink described in spray printing, the employing water that ink sprays etc. are as the slurry of solvent, although these slurries evenly spray in ink layer, but due to the hydrophobicity of ink layer, these slurries can be made to peel away, thus form depression.By such ceramic body through burning till, after the process such as polishing, surface can be obtained and there is depression and recess is the ceramic product of sub-light.Ink inside of the present invention can realize dialling glaze effect by such mode on ceramic body.
In addition, present invention also offers the preparation method of above-mentioned pottery, described preparation method comprises:
1) cover coat slurry, transparent layer slurry, the above-mentioned ink with group glaze effect is prepared;
2) spray printing cover coat slurry on ceramic body;
3) ink described in spray printing on the cover-coat enamel of ceramic body, and dry;
4) spray printing transparent layer slurry in the described ink layer of ceramic body;
5) prepared by above-mentioned steps base substrate through burning till, polishing obtains described pottery.
Preferably, the composition of cover coat comprises: be calculated in mass percent, SiO 259-62%, Al 2o 325-27%, Fe 2o 30.1-0.4%, TiO 20.1-0.3%, CaO0.2-0.4%, MgO0.1-0.3%, K 2o4.0-5.0%, Na 2o2.5-3.5%, P 2o 50.2-0.5%, ZrO 2: 5-7%;
The composition of transparent layer comprises: be calculated in mass percent, SiO 253-56%, Al 2o 313.5-15.5%, Fe 2o 3content < 0.3%, TiO 2content < 0.3%, CaO10-13%, MgO2.5-4%, K 2o1-2%, Na 2o3-6%, IL (represent loss on ignition, mainly refer to organism) 6-8%, ZnO2-4%.
Preferably, in cover coat slurry, solvent is water, and the proportioning of cover coat component and solvent is 1g:0.35 ~ 0.45ml;
In transparent layer slurry, solvent is water, and the proportioning of transparent layer component and solvent is 1g:0.35 ~ 0.45ml (water base is originally surface tension the most cheap maximum solvent);
Described used ink amount designs relevant with pattern effect, different pattern very different.
Preferably, firing temperature is 1180 ~ 1240 DEG C, and soaking time can be 15 ~ 30 minutes, and temperature rise rate is 10 ~ 50 DEG C/min.
Beneficial effect of the present invention:
1, creative: surface is formed more uniform little concavo-convex according to pattern lines, closer to lithotome, also has modelling effect;
2, good decorating effect: the imitative stone material porcelain brick relatively, present level is abundanter;
3, applied widely: the present invention by such environmental effects, can not be widely used in various inner-outer wall and ground decoration;
4, easy cleaning: this imitative stone material porcelain brick is fully sintered, and water-intake rate controls within 0.5%, and beats super clean bright after polishing, good antifouling effect, and glossiness is high; Easy cleaning;
5, durable: stable performance of the present invention, less by time, environmental impact factor, fastness to rubbing is high, can keep for a long time as new sensation, long service life, has wide market economy benefit.
Accompanying drawing explanation
Fig. 1 shows the contact angle (being greater than 100 degree) of ink and the water prepared in one embodiment of the present invention, wherein, and a-water surface layer, b-hydrophobicity ink, the angle of c-water surface layer and hydrophobicity ink;
Fig. 2 to show in one embodiment of the present invention hydrophobicity ink jet and transparent layer in conjunction with effect schematic diagram, wherein, and the pattern of 1-hydrophobicity ink printed, 2-transparent layer, 3-cover coat, 4-blank material layer;
Fig. 3 shows the photo in kind of pottery prepared by one embodiment of the present invention.
Embodiment
Further illustrate the present invention below in conjunction with accompanying drawing and following embodiment, should be understood that accompanying drawing and following embodiment are only for illustration of the present invention, and unrestricted the present invention.
Place of sinking, the similar stone material crack of being prepared by prior art cannot realize pure matt effect, the invention provides a kind ofly to have ceramic ink dialling glaze effect and preparation method thereof and using method, is intended to overcome this defect.
Object of the present invention can be realized by following technical elements:
By adding a certain proportion of low molecule hydrophobic compound in the ink, its pattern formed has strong hydrophobic performance, spray or drench superincumbent glaze at its superficial residence, special group glaze effect to be formed, form uniform Z-Correct bump mapping Z-correct according to change in pattern.Burn till through high temperature again, then polishing form strong light and dark contrast effect.
The hydrophobicity ink that ink for ink-jet print uses, mainly consist of solvent, hydrophobic compound, organic toner, ratio is solvent 94-99%, and hydrophobic compound is 0.1-5.0%, organic toner 0.1-0.5%.
Described solvent is varsol or esters solvent, as: vinylbenzene, ethylbenzene, ethyl acetate.
Hydrophobic compound is low molecule fluorochemical, as Freon 113, and methyl chlorofluoride etc.
Organic toner Methylene blue, methyl red etc.
Described hydrophobicity ink requires to be greater than 100 degree, as Fig. 1 with the contact angle of water.Demonstrate thus, ink inside of the present invention has good hydrophobicity.
More specifically, Fig. 2 show hydrophobicity ink and transparent layer in one embodiment of the present of invention in conjunction with design sketch: on blank material layer, spray printing has cover coat, the pattern adopting hydrophobicity ink printed and transparent layer successively.Ink inside of the present invention can, by means of lyophobic dust wherein, make ink present hydrophobicity.And then, due to the hydrophobicity of ink, make the ceramic body printing this ink, when continuing spray transparent, even if be equally distributed during spray, but the existence of hydrophobic pattern formed due to ink, these slurries are peeled away, such ceramic body passes through techniques such as burning till, can obtain having the pottery dialling glaze effect.
The composition of described cover coat can be:
By percentage to the quality, SiO 2: 59-62%; Al 2o 3: 25-27%; Fe 2o 3: 0.1-0.4%; TiO 2: 0.1-0.3%; CaO:0.2-0.4%; MgO:0.1-0.3%; K 2o:4.0-5.0%; Na 2o:2.5-3.5%; P 2o 5: 0.2-0.5%; ZrO 2: 5-7%.
On the pattern of described hydrophobicity ink printed, can spray printing transparent layer.
The composition of described transparent can be:
By percentage to the quality, SiO 2: 53-56%; Al 2o 3: 13.5-15.5%; Fe 2o 3: < 0.3%; TiO 2: < 0.3%; CaO:10-13%; MgO:2.5-4%; K 2o:1-2%; Na 2o:3-6%; IL:6-8%; ZnO:2-4%.
Following beneficial effect can be reached after the present invention adopts technique scheme:
1, creative: surface is formed more uniform little concavo-convex according to pattern lines, closer to lithotome, also has modelling effect;
2, good decorating effect: the imitative stone material porcelain brick relatively, present level is abundanter;
3, applied widely: the present invention by such environmental effects, can not be widely used in various inner-outer wall and ground decoration;
4, easy cleaning: this imitative stone material porcelain brick is fully sintered, and water-intake rate controls within 0.5%, and beats super clean bright after polishing, good antifouling effect, and glossiness is high; Easy cleaning;
5, durable: stable performance of the present invention, less by time, environmental impact factor, fastness to rubbing is high, can keep for a long time as new sensation, long service life, has wide market economy benefit.
Exemplify embodiment below further to describe the present invention in detail.Should understand equally; following examples are only used to further illustrate the present invention; can not be interpreted as limiting the scope of the invention, some nonessential improvement that those skilled in the art's foregoing according to the present invention is made and adjustment all belong to protection scope of the present invention.The processing parameter etc. that following example is concrete is also only an example in OK range, and namely those skilled in the art can be done in suitable scope by explanation herein and select, and do not really want the concrete numerical value being defined in Examples below.
Embodiment 1
Preparation method of the present invention can comprise the following steps:
1, prepare cover coat slurry, transparent slurry by required proportioning, wherein, the amount ratio of cover coat component and solvent is 1g:0.4mL, and in cover coat slurry, solvent is water, consisting of of cover coat: by percentage to the quality, SiO 2: 59.57%; Al 2o 3: 25.55%; Fe 2o 3: 0.29%; TiO 2: 0.12%; CaO:0.28%; MgO:0.11%; K 2o:4.47%, Na 2o:2.80%, P 2o 5: 0.30%, ZrO 26.21%;
The amount ratio of transparent layer component and solvent is 1g:0.35 ~ 0.45mL, and in transparent slurry, solvent is water, and transparent consists of: by percentage to the quality, SiO 2: 53.87%; Al 2o 3: 14.38%; Fe 2o 3: 0.17%; TiO 2: 0.16%; CaO:11.29%; MgO:3.21%; K 2o:1.05%; Na 2o:5.27%; IL:7.14%; ZnO:2.58%;
2, ink for ink-jet print is made by oneself: solvent is 98.5%, defoamer 0.3%; Hydrophobic organic compound 1.2%; Methyl red 0.2%; After stirring, be used in inside special passage;
3, by spray or the adobe spray step 2 of having drenched cover-coat enamel) ink prepared, used ink amount designs relevant with pattern effect, different pattern very different;
4, dry through little dry kiln after having sprayed ink, guarantee that ink is killed completely;
5, adobe after drying, spray or drench the transparent slurry configured on request;
(firing temperature is 1200 DEG C, and soaking time is 20 minutes, and temperature rise rate is 30 DEG C/min) polishing is afterwards burnt till through kiln, with 1 group, 800 order, 1,000 2 groups, orders, 1,500 4 groups, orders; 1800 3 groups, orders; Polishing; Require after polishing that glossiness can reach 35-40 degree; Beat super clean bright again.
As can be seen from Figure 3, the ceramic surface prepared in the present invention has depression, and presents matt effect.

Claims (10)

1. one kind has the pottery dialling glaze effect, it is characterized in that, on the base substrate of described pottery, spray printing has ink, transparent layer successively, described ink comprises hydrophobic compound, wherein, hydrophobic compound is low molecule organic fluoride, and the mass percent that hydrophobic compound accounts for ink is 0.05%-5.0%, preferred 0.1%-5.0%.
2. pottery according to claim 1, is characterized in that, low molecule organic fluoride comprises Freon 113, methyl chlorofluoride, perfluorotributylamine, ethyl difluoro and/or perfluor alkane.
3. pottery according to claim 1 and 2, is characterized in that, it is the solvent of 94%-99% that described ink also contains mass percent, and wherein, described solvent comprises varsol and/or esters solvent.
4. according to the pottery in claim 1-3 described in any one, it is characterized in that, it is the organic toner of 0.1%-0.5% that described ink also contains mass percent, and organic toner comprises Methylene blue, methyl red.
5., according to described pottery arbitrary in claim 1-4, it is characterized in that, the contact angle of described ink and water is greater than 100 degree.
6., according to described pottery arbitrary in claim 1-5, it is characterized in that, the mass percent that described hydrophobic compound accounts for ink is 0.1%-2%.
7. the preparation method of arbitrary described pottery in claim 1-6, it is characterized in that, described preparation method comprises:
1) cover coat slurry, transparent layer slurry, described ink is prepared;
2) spray printing cover coat slurry on ceramic body;
3) ink described in spray printing on the cover-coat enamel of ceramic body, and dry;
4) spray printing transparent layer slurry in the described ink layer of ceramic body;
5) prepared by above-mentioned steps base substrate through burning till, polishing obtains described pottery.
8. preparation method according to claim 7, is characterized in that, the composition of cover coat comprises: be calculated in mass percent, SiO 259-62%, Al 2o 325-27%, Fe 2o 30.1-0.4%, TiO 20.1-0.3%, CaO0.2-0.4%, MgO0.1-0.3%, K 2o4.0-5.0%, Na 2o2.5-3.5%, P 2o 50.2-0.5%, ZrO 2: 5-7%;
The composition of transparent layer comprises: be calculated in mass percent, SiO 253-56%, Al 2o 313.5-15.5%, Fe 2o 3content < 0.3%, TiO 2content < 0.3%, CaO10-13%, MgO2.5-4%, K 2o1-2%, Na 2o3-6%, IL6-8%, ZnO2-4%.
9. the preparation method according to claim 7 or 8, is characterized in that, in cover coat slurry, solvent is water, and cover coat composition is 1g:0.35-0.45ml with the proportioning of solvent;
In transparent layer slurry, solvent is water, and transparent layer composition is 1g:0.35-0.45ml with the proportioning of solvent.
10., according to described preparation method arbitrary in claim 7-9, it is characterized in that, firing temperature is 1180-1240 DEG C, and soaking time is 15-30 minute, and temperature rise rate is 10-50 DEG C/min.
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CN105647287A (en) * 2016-03-15 2016-06-08 佛山市迈瑞思科技有限公司 Ceramic ink with glaze separating function, and preparation method and production method thereof
CN105924233A (en) * 2016-04-29 2016-09-07 山东狮子王陶瓷科技有限公司 Peeling-glaze marble tile and preparation method thereof
CN106187212A (en) * 2016-07-11 2016-12-07 山东狮子王陶瓷科技有限公司 The preparation method of entire body marble ceramic tile
CN107217808A (en) * 2017-05-04 2017-09-29 万利(中国)有限公司 A kind of structure and preparation technology for pushing glaze decorative brick aside
CN110483103A (en) * 2019-08-26 2019-11-22 广东萨米特陶瓷有限公司 A kind of ceramic board and preparation method thereof of three-dimensional fine braiding grain effect
CN110627531A (en) * 2019-10-30 2019-12-31 广东强辉陶瓷有限公司 Plain light micro-etched wood grain ceramic tile and production process thereof
CN113321537A (en) * 2021-08-04 2021-08-31 佛山市三水新明珠建陶工业有限公司 Metal glazed tile and preparation method thereof
CN114227880A (en) * 2021-12-31 2022-03-25 广东萨米特陶瓷有限公司 Color ceramic rock plate with texture modeling and preparation method thereof

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CN105647287A (en) * 2016-03-15 2016-06-08 佛山市迈瑞思科技有限公司 Ceramic ink with glaze separating function, and preparation method and production method thereof
CN105924233A (en) * 2016-04-29 2016-09-07 山东狮子王陶瓷科技有限公司 Peeling-glaze marble tile and preparation method thereof
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CN110627531A (en) * 2019-10-30 2019-12-31 广东强辉陶瓷有限公司 Plain light micro-etched wood grain ceramic tile and production process thereof
CN110627531B (en) * 2019-10-30 2022-08-19 广东强辉陶瓷有限公司 Plain light micro-etching wood grain ceramic tile and production process thereof
CN113321537A (en) * 2021-08-04 2021-08-31 佛山市三水新明珠建陶工业有限公司 Metal glazed tile and preparation method thereof
CN113321537B (en) * 2021-08-04 2021-12-31 新明珠集团股份有限公司 Metal glazed tile and preparation method thereof
CN114227880A (en) * 2021-12-31 2022-03-25 广东萨米特陶瓷有限公司 Color ceramic rock plate with texture modeling and preparation method thereof
CN114227880B (en) * 2021-12-31 2023-09-19 广东萨米特陶瓷有限公司 Color ceramic rock plate with texture and shape and preparation method thereof

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