CN104857823B - A kind of gas cleaning pressure solution device and method thereof - Google Patents
A kind of gas cleaning pressure solution device and method thereof Download PDFInfo
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- CN104857823B CN104857823B CN201510257795.9A CN201510257795A CN104857823B CN 104857823 B CN104857823 B CN 104857823B CN 201510257795 A CN201510257795 A CN 201510257795A CN 104857823 B CN104857823 B CN 104857823B
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- flue gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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Abstract
The invention discloses a kind of gas cleaning pressure solution device and method thereof, the equipment includes becoming pipe suction inlet, smoke-intake pipe road, fixed lifting rope, fixing pipe steel tower, fixed station, enters cigarette short tube, smoke extractor, cigarette water return pipe, first reactor, the second reaction tube, the 3rd reactor, circulatory pool and honeycomb shower nozzle.The gas cleaning pressure of the present invention, which solves the step of equipment handles flue gas, is, multiple times of filtration eliminates thick, the particle dust in flue gas first by way of physical filtering, again by removing carbon monoxide, denitration and desulfurized step, the deep clean of flue gas is realized, the present situation of air pollution weight is effectively improved.
Description
Technical field
The invention belongs to field of fume treatment equipment, more particularly, to a kind of gas cleaning pressure solution device and method thereof.
Background technology
Power plant, chemical plant, cement plant, the industrial gas emission of Industrial Stoves, fuel combustion etc. generate a large amount of flue gases, cigarette
Gas is the mixture of gas and flue dust, is the main cause for polluting air.The composition of flue gas is very complicated, and gas includes：Water steams
Vapour, SO2、N2、O2、CO、CO2, hydrocarbon and oxynitrides etc., flue dust include the ash content of fuel, coal grain, oil droplet with
And high-temperature split product etc., therefore pollution of the flue gas to environment is the combined pollution of a variety of poisonous substances.Harmfulness of the flue dust to human body
Relevant with the size of particle, it is that diameter is less than 10 microns of floating dust that the mostly of harm are produced to human body, is especially floatd with 1-2.5 microns
Dirt is that PM2.5 harmfulness is maximum.PM2.5 is compared with the bulky grain thing such as PM10, and fine particle particle diameter is small, rich in it is substantial amounts of it is poisonous,
Harmful substance and residence time length, fed distance in an atmosphere is remote.Breathing problem can be triggered；Carried bacteria, virus cause
Cancer；Trigger cardiovascular and cerebrovascular disease；Influence thus to health and atmosphere quality is bigger.
SO2, CO, the pollution such as nitrogen oxides be the main cause for causing atmosphere pollution, the SO largely discharged during burning2, cause
There is the acid rain of large area in China, and continues to develop.The acid rain of China is mainly sulfuric acid type, is made by anthropogenic discharge's sulfur dioxide
Into, and nitrogen oxides is combined with the water in air and eventually changes into nitric acid and nitrate, nitric acid is also one of origin cause of formation of acid rain,
Present China is very big to the economic loss caused in terms of crops, forest and health due to the pollution of acid rain, and this is
Key factor as restriction China's economy and social development.Nitrogen oxides can be produced with other pollutant reactions under certain condition
Raw photochemical pollution, endangers the health of human body.CO be it is a kind of to blood and nervous system toxicity very strong pollutant, it is empty
Carbon monoxide in gas, by respiratory system, into blood of human body, with the hemoglobin in blood, the flesh red eggs in muscle
In vain, combined containing ferrous respiratory enzyme, form reversible conjugate, significant threat is caused to health.
If fume emission directly will be caused larger air pollution into air, therefore, SO will contained2, CO, nitrogen
The fume emission of oxide and fine particle needs to carry out purified treatment before into air, can so reduce air dirty
Dye, is conducive to the health of human body.So, some gas cleaning cleaners arise at the historic moment；In the past quite a while,
Electric cleaner plays critically important role wherein；The continuous improvement required however as people living environment, both at home and abroad
Environmental protection organization has also accordingly put into effect new discharge standard, has higher requirement to the control of pollution sources.
But, current flue-gas purification treatment device obtains not thorough to the pollutant process in flue gas, and the effect of processing is equal
It is not ideal, also remain harmful gas.Patent document CN201310631871.9 discloses a kind of " flue gas ash removal
Desulphurization system ", the system considers also to remain carbon monoxide and nitrogen oxides in the flue gas after processing that these have
Evil gas, causes the flue gas after processing still harmful.
The content of the invention
The present invention in order to overcome the deficiencies in the prior art there is provided a kind for the treatment of effect thoroughly gas cleaning pressure solution equipment and
Its method.
To achieve these goals, the present invention uses following technical scheme：A kind of gas cleaning pressure solution equipment, including：Become
Pipe suction inlet, smoke-intake pipe road, fixing pipe steel tower, fixed station enters cigarette short tube, smoke extractor, cigarette water return pipe, the first reaction of arranged in series
Device, second reactor, the 3rd reactor and circulatory pool, the honeycomb for being placed in each reactor upper end being connected by pipeline with compression pump
Shower nozzle；The first reactor is the longitudinally mounted filter being made up of by-pass filtration net and secondary filtration net, and second is anti-
It is the device that removes carbon monoxide provided with heater and cupric oxide to answer device, and the 3rd reactor is nitrogen oxide absorbent device, is
The molecular sieve being made up of h-mordenite or Hydrogen soap zeolite, circulatory pool be by reaction solution, steam supply valve, positive displacement pump, sedimentation basin,
The desulfurizer that compression pump, demister, heat exchanger and exhaust outlet are constituted.
The air intake in smoke-intake pipe road of the present invention becomes pipe suction inlet into the trapezoid of upper open-ended, smoke-intake pipe provided with pipe suction inlet is become
Road is connected by becoming pipe suction inlet with pollution sources, is become pipe suction inlet and is closely connected with throat, prevents smoke spillage；Fixing pipe steel tower
It is connected by fixed lifting rope with smoke-intake pipe road；Fixed station upper end secures smoke-intake pipe road and fixing pipe steel tower；Enter cigarette short tube left
Side is connected with smoke-intake pipe road, and right side is connected with first reactor；Smoke extractor is centrally positioned in on cigarette short tube.Honeycomb shower nozzle
The liquid reacted with flue gas can be sprayed.
Present invention also offers the method for processing flue gas, it is characterised in that the described method comprises the following steps：
Step one：Start gas cleaning pressure solution equipment, in the presence of smoke extractor, flue gas is fixed on by the suction of change pipe suction inlet
In smoke-intake pipe road on fixing pipe steel tower, flue gas enters first reactor further through cigarette short tube is entered afterwards；
Step 2：By-pass filtration net, which is first passed through, into the flue gas in first reactor filters off coarse sand, bulky grain, then by two
Level screen pack filters off the particle that diameter is less than 10 microns, and the liquid that honeycomb shower nozzle sprays further cleans flue gas ash removal；
Step 3：Reacted flue gas is entered in second reactor by cigarette water return pipe, and heater is passed through in reactor
Reaction of carbon monoxide generation carbon dioxide in scorching hot cupric oxide and flue gas, the liquid that honeycomb shower nozzle sprays further cleans cigarette
Gas dedusting；
Step 3：Flue gas is entered in the 3rd reactor by cigarette water return pipe after reaction, and molecular sieve in reactor is by flue gas
In nitrogen oxide absorbent, honeycomb shower nozzle spray liquid further clean flue gas ash removal；
Step 4：Reacted flue gas is entered in circulatory pool by cigarette water return pipe, and the reaction solution in circulatory pool is by lime
Stone flour, which adds water, is made slurries as absorbent, calcium carbonate in sulfur dioxide and slurries in flue gas and is blasted by steam supply valve
Air oxidation reaction generation calcium sulfate is carried out in the presence of compression pump, calcium sulfate reached after certain saturation degree, and crystallization is formed
Dihydrate gypsum；The calcium plaster discharged through circulatory pool positive displacement pump is precipitated into sedimentation basin, and the flue gas after desulfurization is removed by demister
Droplet, then after heat exchanger heat temperature raising, air is discharged into by exhaust outlet.
Beneficial effect：
1st, the invention provides a kind of gas cleaning pressure solution equipment, the mode multiple times of filtration for first passing through physical filtering is eliminated
Thick, particle dust in flue gas, make flue gas obtain preferable purification.
2nd, the present invention by flue gas sequentially pass through filtering dust, remove carbon monoxide, denitration and desulfurized step, realize flue gas
Deep clean, effectively improve air pollution weight present situation.
3rd, when the gas cleaning pressure solution device structure in the present invention is simple, easy to maintenance and significantly reduces processing flue gas
Operating cost.And desulfurized effect is good, desulfuration byproduct can be made.
Brief description of the drawings
Fig. 1 is the structural representation that flue gas of the present invention presses solution equipment.
In figure, 1, become pipe suction inlet；2nd, smoke-intake pipe road；3rd, fixed lifting rope；4th, fixing pipe steel tower；5th, fixed station；6th, cigarette is entered short
Pipe；7th, smoke extractor；8th, first reactor；8-1, by-pass filtration net；8-2, secondary filtration net；9th, cigarette water return pipe；10th, the second reaction
Pipe；10-1, heater；10-2, the container equipped with cupric oxide；11st, the 3rd reactor；11-1, molecular sieve；12nd, circulatory pool；
12-1, reaction solution；12-2, steam supply valve；12-3, positive displacement pump；12-4, sedimentation basin；12-5, compression pump；12-6, demister；12-7、
Heat exchanger；12-8, exhaust outlet；13rd, honeycomb shower nozzle.
Embodiment
For the present invention is better described, technical scheme is readily appreciated, of the invention is typical but non-limiting
Embodiment is as follows：
Embodiment 1
Gas cleaning pressure solution equipment by change pipe suction inlet 1, smoke-intake pipe road 2, fixed lifting rope 3, fixing pipe steel tower 4, fixed station 5,
Enter cigarette short tube 6, smoke extractor 7, first reactor 8, by-pass filtration net 8-1, secondary filtration net 8-2, cigarette water return pipe 9, second to react
Pipe 10, heater 10-1, the container 10-2 equipped with cupric oxide, the 3rd reactor 11, molecular sieve 11-1, circulatory pool 12, reaction
Liquid 12-1, steam supply valve 12-2, positive displacement pump 12-3, sedimentation basin 12-4, compression pump 12-5, demister 12-6, heat exchanger 12-7, exhaust
Mouth 12-8, honeycomb shower nozzle 13 are constituted.
Exemplified by the pollution flue gas for taking heavy metal pollution enterprise of Jiangsu Province, major pollutants are dust, two in sample flue gas
Sulfur oxide, carbon monoxide and nitrogen oxides, experiment probe into gas cleaning pressure solution equipment of the present invention and polluter in flue gas are gone
Except effect.
Start gas cleaning pressure solution equipment, in the presence of smoke extractor 7, flue gas is fixed on fixation by the suction of change pipe suction inlet 1
On pipe steel tower in 4 smoke-intake pipe road 2, flue gas enters first reactor 8 further through cigarette short tube 6 is entered afterwards, first passes through by-pass filtration
Net 8-1 and filter off coarse sand, bulky grain, then the particle that diameter is less than 10 microns is filtered off by secondary filtration net 8-2, honeycomb shower nozzle 13 sprays
The liquid gone out further cleans flue gas ash removal；Reacted flue gas is entered in second reactor 10 by cigarette water return pipe, reactor
In reaction of carbon monoxide generation carbon dioxide in scorching hot cupric oxide 10-2 and flue gas, the liquid that honeycomb shower nozzle 13 sprays enters one
Step cleaning flue gas ash removal；Reacted flue gas is entered in the 3rd reactor 11 by cigarette water return pipe, the molecular sieve 11- in reactor
1 by the nitrogen oxide absorbent in flue gas, and the liquid that honeycomb shower nozzle 13 sprays further cleans flue gas ash removal；Reacted flue gas leads to
Cross cigarette water return pipe to enter in circulatory pool 12, the reaction solution 12-1 in circulatory pool is agstone to add water slurries are made as absorption
Calcium carbonate in sulfur dioxide and slurries in agent, flue gas and air is blasted by steam supply valve 12-2 carry out oxidation reaction generation
Calcium sulfate, calcium sulfate reaches after certain saturation degree that crystallization forms dihydrate gypsum；The calcium plaster discharged through circulatory pool positive displacement pump 12-3
Into sedimentation basin 12-4 precipitations, the flue gas after desulfurization removes droplet by demister 12-6, then is risen by heat exchanger 12-7 heating
Wen Hou, air is discharged into by exhaust outlet 12-8.The smoke pollution after gas cleaning pressure solution equipment processing by the present invention is greatly
Reduce.Granular material discharged concentration is controlled in 0.01mg/ in the flue gas after gas cleaning pressure solution equipment processing by the present invention
m3Within, the concentration of emission of sulfur dioxide is controlled in 6-7mg/m3, the concentration of emission control of nitrogen oxides is in 5-7mg/m3, an oxygen
The concentration of emission for changing nitrogen is controlled in 6-10mg/m3, reached GB18484-2001 standards and consumer waste incineration contamination control
Standard.
Some embodiments of the present invention are the foregoing is only, the present invention, all use equivalent substitutions or equivalent change is not intended to limit
The technical scheme that the mode changed is obtained, all falls within protection scope of the present invention.
Claims (6)
1. a kind of gas cleaning pressure solution equipment, it is characterised in that the equipment includes：Change pipe suction inlet (1), smoke-intake pipe road (2), Gu
Determine lifting rope (3), fixing pipe steel tower (4), fixed station (5) enters cigarette short tube (6), and smoke extractor (7) passes through cigarette water return pipe (9) successively phase
First reactor (8) even, second reactor (10), the 3rd reactor (11) and circulatory pool (12), pass through pipeline and compression pump
The connected honeycomb shower nozzle (13) for being placed in each reactor upper end；The air intake of the smoke-intake pipe road (2), which is provided with, becomes pipe suction inlet (1),
Smoke-intake pipe road (2) is connected by becoming pipe suction inlet (1) with pollution sources, and is connected by fixed lifting rope (3) with fixing pipe steel tower (4)
Connect；Fixed station (5) upper end secures smoke-intake pipe road (2) and fixing pipe steel tower (4)；Enter on the left of cigarette short tube (6) and smoke-intake pipe road (2)
It is connected, right side is connected with first reactor (8)；Smoke extractor (7) is centrally positioned in on cigarette short tube (6)；Described first is anti-
It is the longitudinally mounted filter being made up of by-pass filtration net (8-1) and secondary filtration net (8-2), the second reaction to answer device (8)
Device (10) is the device that removes carbon monoxide provided with heater (10-1) and cupric oxide (10-2), and the 3rd reactor (11) is nitrogen
Oxide adsorbent device, circulatory pool be by reaction solution (12-1), steam supply valve (12-2), positive displacement pump (12-3), sedimentation basin (12-4),
The desulfurizer that compression pump (12-5), demister (12-6), heat exchanger (12-7) and exhaust outlet (12-8) are constituted.
2. a kind of gas cleaning pressure solution equipment according to claim 1, it is characterised in that the change pipe suction inlet (1) is upper
The trapezoid of open-ended.
3. a kind of gas cleaning pressure solution equipment according to claim 1, it is characterised in that the change pipe suction inlet (1) and cigarette
The tight-lipped close connection of chimney.
4. a kind of gas cleaning pressure solution equipment according to claim 1, it is characterised in that the honeycomb shower nozzle (13) can
Spray the liquid reacted with flue gas.
5. a kind of gas cleaning pressure solution equipment according to claim 1, it is characterised in that the 3rd reactor (11) nitrogen
Oxide adsorbent device is the molecular sieve (11-1) being made up of h-mordenite or Hydrogen soap zeolite.
6. the method that gas cleaning pressure solution equipment described in a kind of claim 1 handles flue gas, it is characterised in that methods described includes
Following steps：
Step one：Start gas cleaning pressure solution equipment, in the presence of smoke extractor (7), flue gas is sucked by change pipe suction inlet (1) and fixed
In smoke-intake pipe road (2) on fixing pipe steel tower (4), flue gas enters first reactor (8) further through cigarette short tube (6) is entered afterwards；
Step 2：By-pass filtration net (8-1) is first passed through into the flue gas in first reactor (8) and filters off coarse sand, bulky grain, then is passed through
Cross secondary filtration net (8-2) and filter off the particle that diameter is less than 10 microns, the liquid that honeycomb shower nozzle (13) sprays further cleans cigarette
Gas dedusting；
Step 3：Reacted flue gas is entered in second reactor (10) by cigarette water return pipe (9), by heating dress in reactor
The reaction of carbon monoxide generation carbon dioxide in (10-1) scorching hot cupric oxide (10-2) and flue gas is put, honeycomb shower nozzle (13) sprays
Liquid further clean flue gas ash removal；
Step 3：Flue gas is entered in the 3rd reactor (11) by cigarette water return pipe (9) after reaction, the molecular sieve (11- in reactor
1) by the nitrogen oxide absorbent in flue gas, the liquid that honeycomb shower nozzle (13) sprays further cleans flue gas ash removal；
Step 4：Reacted flue gas is entered in circulatory pool (12) by cigarette water return pipe (9), the reaction solution (12-1) in circulatory pool
It is agstone to add water slurries are made as absorbent, calcium carbonate in sulfur dioxide and slurries in flue gas and passing through is supplied
The air that air valve (12-2) is blasted carries out oxidation reaction generation calcium sulfate in the presence of compression pump (12-5), and calcium sulfate reaches one
Determine after saturation degree, crystallization forms dihydrate gypsum；The calcium plaster discharged through circulatory pool positive displacement pump (12-3) enters sedimentation basin (12-4)
Precipitation, the flue gas after desulfurization removes droplet by demister (12-6), then after heat exchanger (12-7) heat temperature raising, by being vented
Mouth (12-8) is discharged into air.
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| CN201510257795.9A CN104857823B (en) | 2015-05-19 | 2015-05-19 | A kind of gas cleaning pressure solution device and method thereof |
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| CN104857823B true CN104857823B (en) | 2017-11-07 |
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| CN106237854B (en) * | 2016-08-31 | 2019-03-08 | 许昌森 | A kind of gas cleaning pressure solution equipment and application method |
| CN107115782A (en) * | 2017-06-27 | 2017-09-01 | 洛阳龙门药业有限公司 | A kind of pharmaceutical factory fume treatment auxiliary |
| CN108795448B (en) * | 2018-06-12 | 2020-10-27 | 浙江鑫旭塑业有限公司 | Plasma coking device |
| CN108854505A (en) * | 2018-06-17 | 2018-11-23 | 曾文飞 | A kind of electrolytic aluminium waste Flash Gas Compression Skid System and processing method |
| CN108954816A (en) * | 2018-07-20 | 2018-12-07 | 芜湖新农夫机械有限公司 | A kind of hot-blast stove |
| CN111192332B (en) * | 2018-11-14 | 2023-04-07 | 九阳股份有限公司 | Smoke detection-based smoke machine control method and smoke machine |
| CN114356002B (en) * | 2021-12-03 | 2023-08-25 | 河南省第五建设集团有限公司 | Intelligent building environment-friendly control system |
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| JPH06262038A (en) * | 1993-03-12 | 1994-09-20 | Sumitomo Heavy Ind Ltd | Method for treatment of exhaust gas |
| CN101700463A (en) * | 2008-02-19 | 2010-05-05 | 孙伟杰 | Method for desulfurating and denitrating and recovering sulfur resource in closed cycle way |
| CN103406122B (en) * | 2013-08-06 | 2015-05-13 | 湖南师范大学 | Catalyst for desorbing nitrogen oxides and carbon monoxide at low temperature and preparation method thereof |
| CN103657319A (en) * | 2013-11-26 | 2014-03-26 | 江苏海宏机械制造有限公司 | Flue gas dust-removing and sulfur-removing system |
| CN204699578U (en) * | 2015-05-19 | 2015-10-14 | 许昌森 | A kind of gas cleaning pressure solution equipment |
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