CN104836519A - Integrated intelligent glass window based on perovskite solar cell power supply and method for manufacturing same - Google Patents
Integrated intelligent glass window based on perovskite solar cell power supply and method for manufacturing same Download PDFInfo
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- CN104836519A CN104836519A CN201510127669.1A CN201510127669A CN104836519A CN 104836519 A CN104836519 A CN 104836519A CN 201510127669 A CN201510127669 A CN 201510127669A CN 104836519 A CN104836519 A CN 104836519A
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- 239000011521 glass Substances 0.000 title claims abstract description 64
- 238000000034 method Methods 0.000 title claims description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 238000004146 energy storage Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 238000004544 sputter deposition Methods 0.000 claims description 22
- 241001074085 Scophthalmus aquosus Species 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 16
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 12
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 11
- 235000012239 silicon dioxide Nutrition 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- JTCFNJXQEFODHE-UHFFFAOYSA-N [Ca].[Ti] Chemical compound [Ca].[Ti] JTCFNJXQEFODHE-UHFFFAOYSA-N 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims description 3
- 239000002086 nanomaterial Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000004528 spin coating Methods 0.000 claims description 3
- 239000013077 target material Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910001416 lithium ion Inorganic materials 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 11
- 238000000889 atomisation Methods 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 45
- 239000005341 toughened glass Substances 0.000 description 7
- 238000007733 ion plating Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S20/00—Supporting structures for PV modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The present invention discloses an integrated intelligent glass window based on perovskite solar cell power supply. The integrated intelligent glass window enables the light transmittance to be adjusted automatically or manually, can self heated in winter to achieve the purpose of preventing atomization, and comprises a window frame, a heating device, a glass part, an energy storage device and a control device, wherein the glass part comprises a perovskite solar cell layer, a transparent conductive film layer, an electrochromism layer and a glass substrate, and the control device comprises a manual control device and an automatic control device and is used to adjust the transmittance of the glass and heat automatically. When the integrated intelligent glass window is used, the original state of the integrated intelligent glass window is transparent, and the electrochromism layer is supplied with power under an automatic adjustment mode and after the light intensity reaches a certain intensity, so that the color of the integrated intelligent glass window changes, and the light transmittance of the glass is adjusted. When the light transmittance is adjusted manually, the gears can be selected manually to supply different currents to the electrochromism layer, so that the color of the glass changes, and the light transmittance is adjusted. Moreover, a heating switch can be turned on manually to heat the glass, thereby preventing the atomization.
Description
Technical field
The present invention relates to a kind of semiconductor device solar radiant energy being converted to electric energy, and be specially adapted for the method manufacturing or process these semiconductor device or its parts, be specifically related to a kind of integral intelligent windowpane based on perovskite solar cell for supplying power and manufacture method thereof.
Background technology
For a long time, researcher is from building safety always, outward appearance and heat insulation angle remove research and development building glass window, seldom natural resources is utilized to carry out produce power from by building glass, and be supplied to window, with the angle reducing building integral energy consumption, research carried out to glass for building purposes, the existing intelligent glass with electrochromic layer all needs external power source, cause installation loaded down with trivial details, window opening-closing easily causes wire access place to be leaked electricity frequently, fail safe is lower, and its variable color can not be made to reach the object of protection individual privacy at night, simultaneously in the winter time because the temperature difference cause of indoor and outdoor can make glass to occur fog affects daylighting and view, therefore be necessary to improve existing intelligent glass.
Through retrieval; Chinese patent literature CN102097507A discloses a kind of glass and preparation method thereof; the lead-in wire that this glass comprises toughened glass basic unit, the substrate coating that this toughened glass basic unit is formed successively, film photovoltaic cell layer and soiling protective layer and is arranged on described film photovoltaic cell layer, described substrate coating is for improving the tack of film photovoltaic cell layer in toughened glass basic unit and preventing the sodium ion in toughened glass basic unit from spreading in film photovoltaic cell layer.The present invention is by as in the toughened glass basic unit of substrate; form substrate coating, film photovoltaic cell layer and soiling protective layer successively; the glass obtained can be made to have good heat-insulation and heat-preservation, light transmittance, the performance such as antifouling; and effectively utilize solar power generation by film photovoltaic cell layer; for automobile etc. provides energy, reduce the oil consumption of automobile etc.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the invention provides a kind of integral intelligent windowpane based on perovskite solar cell for supplying power.
Technical scheme: for solving the problems of the technologies described above, integral intelligent windowpane based on perovskite solar cell for supplying power provided by the invention, comprise window frame and electro-heat equipment, glass part, energy storage device, control device, described glass part is transparent, comprise the perovskite solar cell layer, transparent conductive film layer, electrochromic layer and the glass substrate that stack successively, described control device comprises manual overvide and automatic control equipment, for regulating transmitance and the automatic heating of glass.
Particularly, the thickness of described perovskite solar cell layer is 200-500nm, comprises conductive layer, perovskite material, hole transmission layer, target material layer.
Particularly, described transparent conductive film layer is AZO transparent conductive film, and its thickness is 80 ~ 90nm.
Particularly, the thickness of described electrochromic layer is 110 ~ 115nm, comprises WO
3layer and ionic conduction regulating course.
Particularly, described energy storage device is plumbic acid, ni-mh or lithium ion battery.
The present invention proposes the manufacture method of the above-mentioned integral intelligent windowpane based on perovskite solar cell for supplying power simultaneously, comprises the following steps:
The first step, glass substrate preliminary treatment;
Second step, preparation substrate coating, adopts magnetron sputtering method to obtain the thick Al-Doped ZnO plated film of 85nm on the glass substrate;
3rd step, preparation tungsten oxide layer, uses tungsten particle as the tungsten oxide source of evaporating from shoe, with the underlayer temperature of 480-520 DEG C, substrate coating deposits the tungsten oxide layer that 110nm is thick;
4th step, preparation isolation coating, in tungsten oxide layer, magnetron sputtering obtains the thick silicon dioxide layer of 20nm;
5th step, obtains at the surface magnetic control sputtering of silicon dioxide layer the titanium dioxide layer that thickness is 100nm;
6th step, prepares perovskite solar cell layer, with the speed spin coating 500nm calcium titanium ore bed of 1000 revolutions per seconds on titanium dioxide layer, covers transparent carbon nano material film and draws wire.
Particularly, in second step and the 5th step, the process conditions of magnetron sputtering adopt two mass flow controllers control argon gas and oxygen flow to be respectively 55.0cm respectively
3/ min and 0.5cm
3/ min, sputtering pressure maintains 1.0Pa, and sputtering power is 80W, the temperature of glass is controlled to be 300 DEG C during sputtering by electric furnace and thermocouple.
Particularly, in the 4th step, the process conditions of magnetron sputtering are controlled by glass temperature at 260 ± 10 DEG C, and background vacuum is≤2.0 × 10
-3pa, working vacuum degree are 4.2 × 10
-1pa, working gas are flow is 300 standard milliliters/minute argon gas, and reacting gas is pure oxygen and oxygen component accounts for gas gross 15 volume %; Make glass carry out sputtering silicon dioxide with the speed of 16mm/s by target surface, target surface power setting is 2.2W/cm
2, target surface voltage is set as 370V.
Beneficial effect: the integral intelligent glazing system integrated level based on perovskite solar cell for supplying power of the present invention is high, installs simple, easy to maintenance, possesses electrochromism and heat-production functions, meet diversified user demand.Adopt the coating that manufacture method of the present invention obtains, its transparency and electricity conversion are in practicality and achieve good balance between cost and efficiency, possess good application prospect.
Except technical problem, the technical characteristic forming technical scheme and the advantage brought by the technical characteristic of these technical schemes that the present invention recited above solves, the advantage that the other technologies feature comprised in the other technologies problem that integral intelligent windowpane based on perovskite solar cell for supplying power of the present invention can solve, technical scheme and these technical characteristics bring, will be described in more detail by reference to the accompanying drawings.
Accompanying drawing explanation
Fig. 1 is the system architecture diagram of the windowpane of the embodiment of the present invention;
Fig. 2 is the sectional view of glass part in Fig. 1.
Embodiment
Embodiment:
As shown in Figure 1, the solar cell layer of the glass part of the present embodiment converts solar energy into electrical energy and is stored in energy storage device, current signal is sent to control device simultaneously, when electric current reaches certain numerical value, control device controls energy storage device electric discharge, to electrochromic layer and heater.As shown in Figure 2, glass is followed successively by solar cell layer 1, transparent conductive film layer 2, electrochromic layer 3, glass substrate 4 from top to bottom.
The initial condition of glass is transparent, powers, make it change color under automatic shaping modes after light intensity reaches some strength to electrochromic layer, thus regulates the light transmittance of glass; When manual adjustments, gear manually can be selected to provide different electric current to change glass colour to electrochromic layer, thus change light transmittance, and can manual unlocking heater switch be glass heats, prevent atomization.
Above-mentioned perovskite solar cell layer thickness is 200-500nm, comprises conductive layer, perovskite material, hole transmission layer, target material layer.
Wherein conductive film layer is AZO transparent conductive film, thickness 80 ~ 90nm.Electrochromic layer comprises WO
3layer and ionic conduction regulating course, thickness is 110 ~ 115nm.Glass substrate can adopt simple glass, carries out tempering process.
The preparation method of the integral intelligent windowpane of the present embodiment is as follows.
(1) reinforced glass substrate preliminary treatment
Glass (4mm) is cut into the glass plate of 20cm × 30cm × 4mm with automatic glass cutting machine, for subsequent use as glass substrate after the process such as tempering and cleaning.
(2) substrate coating is prepared
Use magnetic controlled sputtering ion plating equipment (multi sphere-magnetron sputtering ion plating machine, Beijing Beiyi Innovation Vacuum Technology Co., Ltd., JP-700) on glass substrate for subsequent use, sputtering forms Al-Doped ZnO plated film, and adopts two mass flow controllers to control argon gas respectively and oxygen flow is respectively 55.0cm
3/ min and 0.5cm
3/ min, sputtering pressure maintains 1.0Pa, and sputtering power is 80W.By electric furnace and thermocouple, the temperature of base material is controlled to be 300 DEG C during sputtering.The thickness of the AZO obtained on toughened glass surface after having sputtered is 85nm.
(3) tungsten oxide layer is prepared
Use tungsten particle as the tungsten oxide source of evaporating from shoe, with the underlayer temperature of 480-520 DEG C, by close-spaced sublimation, in the tungsten oxide layer that the substrate coating surface deposition 110nm obtained is thick.
(4) system isolation silicon dioxide coating
Use magnetic controlled sputtering ion plating equipment (multi sphere-magnetron sputtering ion plating machine, Beijing Beiyi Innovation Vacuum Technology Co., Ltd., JP-700) to sputter in tungsten oxide layer for subsequent use and form silicon dioxide plated film.Being controlled by glass temperature for subsequent use at 260 ± 10 DEG C, is≤2.0 × 10 at background vacuum
-3pa, working vacuum degree are 4.2 × 10
-1the high-purity argon gas of Pa, working gas to be flow be 99.999% of 300 standard milliliters/minute (sccm), reacting gas be 99.995% high purity oxygen and under oxygen component accounts for the condition of gas gross 15 volume about %, glass for subsequent use is made to carry out sputtering silicon dioxide with the speed of 16mm/s by target surface, target surface power setting is 2.2W/cm2, target surface voltage is set as 370V, and the thickness of the silicon dioxide layer obtained on toughened glass surface after having sputtered is 20nm.
(5) perovskite solar cell layer is prepared
Adopt on the surface of silicon dioxide and use magnetic controlled sputtering ion plating equipment (multi sphere-magnetron sputtering ion plating machine, Beijing Beiyi Innovation Vacuum Technology Co., Ltd., JP-700) sputtering forms titanium oxide filming, and adopts two mass flow controllers to control argon gas respectively and oxygen flow is respectively 55.0cm
3/ min and 0.5cm
3/ min, sputtering pressure maintains 1.0Pa, and sputtering power is 80W.By electric furnace and thermocouple, the temperature of base material is controlled to be 300 DEG C during sputtering.The thickness of the titanium dioxide layer obtained on surface after having sputtered is 100nm; Again above with the speed spin coating 500nm calcium titanium ore bed of 1000 revolutions per seconds, cover transparent carbon nano material film, draw wire.Obtain transparency 29%, electricity conversion 8.2%.
Comparative example 1
Prepare glass D1 according to the method for embodiment 1, difference is, perovskite solar cell thickness is 200nm.
Comparative example 2
Prepare glass D2 according to the method for embodiment 1, difference is, perovskite solar cell thickness is 300nm.
Comparative example 3
Prepare glass D3 according to the method for embodiment 1, difference is, perovskite solar cell thickness is 400nm.
Performance test
(1) light transmittance
According to GB/T 2680-94 standard, glass D1-D3 prepared by the glass A1-A6 prepared by embodiment 1-6 and comparative example 1-3 measures respective light transmittance by light transmittance mist degree analyzer (Shanghai Precision Scientific Apparatus Co., Ltd), and its result represents in Table 1.
(2) electricity conversion
Adopt the electricity conversion of open solar module tester (newport) tested glass A1-A6 and D1-D3 respectively, its result is as shown in table 1.
Table 1: comparative example performance test data
Below by reference to the accompanying drawings embodiments of the present invention are described in detail, but the present invention is not limited to described execution mode.For those of ordinary skill in the art, in the scope of principle of the present invention and technological thought, multiple change, amendment, replacement and distortion are carried out to these execution modes and still falls within the scope of protection of the present invention.
Claims (8)
1. the integral intelligent windowpane based on perovskite solar cell for supplying power, it is characterized in that: comprise window frame and electro-heat equipment, glass part, energy storage device, control device, described glass part is transparent, comprise the perovskite solar cell layer, transparent conductive film layer, electrochromic layer and the glass substrate that stack successively, described control device comprises manual overvide and automatic control equipment, for regulating transmitance and the automatic heating of glass.
2. the integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 1, it is characterized in that: the thickness of described perovskite solar cell layer is 200-500nm, comprise conductive layer, perovskite material, hole transmission layer, target material layer.
3. the integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 1, it is characterized in that: described transparent conductive film layer is AZO transparent conductive film, its thickness is 80 ~ 90nm.
4. the integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 1, is characterized in that: the thickness of described electrochromic layer is 110 ~ 115nm, comprises WO
3layer and ionic conduction regulating course.
5. the integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 1, is characterized in that: described energy storage device is plumbic acid, ni-mh or lithium ion battery.
6., based on a manufacture method for the integral intelligent windowpane of perovskite solar cell for supplying power, it is characterized in that comprising the following steps:
The first step, glass substrate preliminary treatment;
Second step, preparation substrate coating, adopts magnetron sputtering method to obtain the thick Al-Doped ZnO plated film of 85nm on the glass substrate;
3rd step, preparation tungsten oxide layer, uses tungsten particle as the tungsten oxide source of evaporating from shoe, with the underlayer temperature of 480-520 DEG C, substrate coating deposits the tungsten oxide layer that 110nm is thick;
4th step, preparation isolation coating, in tungsten oxide layer, magnetron sputtering obtains the thick silicon dioxide layer of 20nm;
5th step, obtains at the surface magnetic control sputtering of silicon dioxide layer the titanium dioxide layer that thickness is 100nm;
6th step, prepares perovskite solar cell layer, with the speed spin coating 500nm calcium titanium ore bed of 1000 revolutions per seconds on titanium dioxide layer, covers transparent carbon nano material film and draws wire.
7. the manufacture method of a kind of integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 6, it is characterized in that: in second step and the 5th step, the process conditions of magnetron sputtering adopt two mass flow controllers control argon gas and oxygen flow to be respectively 55.0cm respectively
3/ min and 0.5cm
3/ min, sputtering pressure maintains 1.0Pa, and sputtering power is 80W, the temperature of glass is controlled to be 300 DEG C during sputtering by electric furnace and thermocouple.
8. the manufacture method of a kind of integral intelligent windowpane based on perovskite solar cell for supplying power according to claim 6, it is characterized in that: in the 4th step, the process conditions of magnetron sputtering are controlled by glass temperature at 260 ± 10 DEG C, and background vacuum is≤2.0 × 10
-3pa, working vacuum degree are 4.2 × 10
-1pa, working gas are flow is 300 standard milliliters/minute argon gas, and reacting gas is pure oxygen and oxygen component accounts for gas gross 15 volume %; Make glass carry out sputtering silicon dioxide with the speed of 16mm/s by target surface, target surface power setting is 2.2W/cm
2, target surface voltage is set as 370V.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510127669.1A CN104836519A (en) | 2015-03-24 | 2015-03-24 | Integrated intelligent glass window based on perovskite solar cell power supply and method for manufacturing same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510127669.1A CN104836519A (en) | 2015-03-24 | 2015-03-24 | Integrated intelligent glass window based on perovskite solar cell power supply and method for manufacturing same |
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| CN104836519A true CN104836519A (en) | 2015-08-12 |
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ID=53814197
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|---|---|---|---|
| CN201510127669.1A Pending CN104836519A (en) | 2015-03-24 | 2015-03-24 | Integrated intelligent glass window based on perovskite solar cell power supply and method for manufacturing same |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106410034A (en) * | 2016-09-30 | 2017-02-15 | 中国科学院上海硅酸盐研究所 | Perovskite solar cell with thermochromism performance and preparation method thereof |
| CN109285904A (en) * | 2018-09-21 | 2019-01-29 | 苏州腾晖光伏技术有限公司 | A kind of adjustable two-sided photovoltaic module of light transmittance |
| CN109962163A (en) * | 2019-01-28 | 2019-07-02 | 江汉大学 | Photovoltaic film and preparation method thereof, window |
| CN110161768A (en) * | 2019-05-31 | 2019-08-23 | Oppo广东移动通信有限公司 | Electrochromic device and electronic equipment |
| US10457204B2 (en) | 2018-02-22 | 2019-10-29 | Ford Global Technologies, Llc | Vehicle illuminated display |
| CN112260617A (en) * | 2020-10-20 | 2021-01-22 | 厦门大学 | Energy-conserving glass of self-driven integrated type photoelectricity discoloration assembly |
| CN113668996A (en) * | 2021-08-05 | 2021-11-19 | 西北工业大学深圳研究院 | Self-powered intelligent color-changing glass based on transparent photovoltaic cell and preparation method thereof |
| CN114185218A (en) * | 2020-09-15 | 2022-03-15 | 海安南京大学高新技术研究院 | Electrochromic power generation hollow glass |
| CN115268160A (en) * | 2022-08-08 | 2022-11-01 | 安徽华菱汽车有限公司 | Automobile and color-changing glass |
| CN114185218B (en) * | 2020-09-15 | 2024-04-05 | 海安南京大学高新技术研究院 | Electrochromic power generation hollow glass |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2020056983A1 (en) * | 2018-09-21 | 2020-03-26 | 苏州腾晖光伏技术有限公司 | Double-sided photovoltaic assembly with adjustable light transmittance, and bipv assembly |
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| CN109962163B (en) * | 2019-01-28 | 2023-06-27 | 江汉大学 | Photovoltaic film, preparation method thereof and window |
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| CN114185218A (en) * | 2020-09-15 | 2022-03-15 | 海安南京大学高新技术研究院 | Electrochromic power generation hollow glass |
| CN114185218B (en) * | 2020-09-15 | 2024-04-05 | 海安南京大学高新技术研究院 | Electrochromic power generation hollow glass |
| CN112260617A (en) * | 2020-10-20 | 2021-01-22 | 厦门大学 | Energy-conserving glass of self-driven integrated type photoelectricity discoloration assembly |
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