CN104830396A - Preparation method of sludge clean fuel - Google Patents

Preparation method of sludge clean fuel Download PDF

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Publication number
CN104830396A
CN104830396A CN201510239203.0A CN201510239203A CN104830396A CN 104830396 A CN104830396 A CN 104830396A CN 201510239203 A CN201510239203 A CN 201510239203A CN 104830396 A CN104830396 A CN 104830396A
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CN
China
Prior art keywords
clean fuel
sludge
parts
mud
slag
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510239203.0A
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Chinese (zh)
Inventor
王震宇
于佳
司甲岭
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Tianjin Your Environmental Protection Technology Co Ltd Of God
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Tianjin Your Environmental Protection Technology Co Ltd Of God
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Application filed by Tianjin Your Environmental Protection Technology Co Ltd Of God filed Critical Tianjin Your Environmental Protection Technology Co Ltd Of God
Priority to CN201510239203.0A priority Critical patent/CN104830396A/en
Publication of CN104830396A publication Critical patent/CN104830396A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Treatment Of Sludge (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a preparation method of a sludge clean fuel. The preparation method disclosed by the invention is characterized by comprising the following steps: roasting sludge at high temperature at first, so that the moisture content is decreased to 5% and below, then, mixing the sludge with acetylene sludge, manganese and iron slag, sphalerite, blast furnace slag, an oxidizing agent and a synergist material, crushing initially, and then, secondarily crushing till the particle size is 100-200 meshes. The sludge clean fuel prepared by adopting the technical scheme can be directly doped with coal to burn; negative effects to a coal-fired furnace can be avoided; the sludge clean fuel can be directly applied to daily industrials and civil direct combustion boilers; practical detection proves that the heat value of the sludge clean fuel is 3500-5000 Kcal/Kg and achieves the medium heat value fuel grade; and, due to the sludge clean fuel, accumulation of sludge and industrial wastes and pollution to the environment are greatly reduced.

Description

A kind of preparation method of mud clean fuel
Technical field
The present invention relates to clean energy technology field, be specifically related to a kind of preparation method of mud clean fuel.
Background technology
Along with national economy and social development, daily life intensive degree is more and more higher, and the organic waste of generation gets more and more, and causes great impact to the living environment of the mankind.Municipal sludge is as the byproduct of sewerage system, it is the sedimentable matter that sewage work produces in water treatment procedure, both containing a large amount of microorganism, organic matter and nutritive substance, it has large, unstable, easily corruption, high stench the feature of capacity, also contain the heavy metal, pathogenic agent microorganism etc. that exceed standard in a large number in mud simultaneously, if do not dealt carefully with, the hazardous and noxious substances such as wherein comprised heavy metal, pathogenic agent microorganism, once penetrate into soil, can cause the irreversible poisoning of crop pollution soil; Once go deep into underground water, valuable water resources will be polluted, potential safety hazard is caused to the safe drinking water of resident.In the treating processes of municipal sludge, it is high that current Problems existing concentrates on dehydration cost, and refuse landfill is unwilling to process.Be rich in organic mud in a large number to expose in atmosphere, be very easy to smelly, and then can cause mosquito fly, agricultural chemicals deinsectization is adding two degree of possibilities polluted again virtually.And getting more and more along with sewage work's foundation, the output of mud, also in increase, allows municipal sludge process be absorbed in a kind of dilemma.
In addition on the one hand, along with the fast development of China's industry, various industrial waste radix increases severely day by day.Especially the industrial discharge amount such as metallurgy, large-scale mining is huge.The industrial waste substantial amounts of China, of a great variety, complicated component, process is difficulty quite.At present in China, a few industrial waste is only had to be utilized, such as: part flyash is for the production of cement, production building brick.Major part industrial waste still saves as master, such as blast furnace slag, ferromanganese ore slag etc. with passiveness heap.A large amount of passivenesses of industrial waste are stored up and are not only taken a large amount of soil, cause the waste of manpower and materials, and many industrial residues contain material soluble in water, by leaching contaminated soil and water body.The industrial waste of powdery, flies upward with the wind, atmosphere pollution, and what have goes back emitting offensive odor and poison gas.Some refuses even silt river course up, pollute water system, affect biological growth, and harm resident is healthy.
For current this situation, need to develop a kind of sewage sludge harmlessness, energy, mass-producing method of comprehensive utilization, not only can solve serious pollution problem, the clean fuel that directly can utilize, meet combustion row standard can also be obtained simultaneously.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of mud clean fuel, not only can solve serious pollution problem, can also obtain the clean fuel that directly can utilize, meet combustion row standard simultaneously.
In order to solve the problem, the present invention is by the following technical solutions:
A kind of mud clean fuel, is characterized in that: each constituent mass number of described mud clean fuel is:
Carbide slag 10 ~ 15 parts;
Ferromanganese ore slag 5 ~ 15 parts;
25 ~ 30 parts, zink sulphide stone;
Blast furnace slag 1 ~ 5 part;
30 ~ 40 parts, mud;
1 ~ 5 part, oxygenant;
Synergistic agent 0.5 ~ 3 part.
Described oxygenant is one or more the mixture in calcium peroxide, Potcrate, sodium chlorate, potassium permanganate.
Described synergistic agent is one or more the mixture in ferrocene, metallic aluminium powder, metal iron powder, metal magnesium powder.
A kind of preparation method of mud clean fuel, it is characterized in that: preparation process is, first high bake is carried out to mud, make it moisture and be reduced to less than 5%, then carry out mixing pulverizing for the first time with carbide slag, ferromanganese ore slag, zink sulphide stone, blast furnace slag, oxygenant, synergistic agent material, then carry out separating twice to grain diameter and be of a size of 100 ~ 200 orders.
Implement technical scheme of the present invention, there is following beneficial effect: adopt the mud clean fuel prepared by this technical scheme can directly and coal adulterate and burn, can not cause negative impact to coal-fired furnace kiln, this mud clean fuel can directly apply to daily industry, civilian direct-combustion boiler.Detect through reality and prove, the calorific value of described mud clean fuel is 3500 ~ 5000Kcal/Kg, reaches medium Btu fuel rank.The pollution that the heap sum that this mud clean fuel greatly reduces municipal sludge and trade waste causes environment.
Embodiment
Below in conjunction with specific embodiment, the present invention is further elaborated.
Embodiment 1
First to municipal sludge high bake, make it water content and be reduced to 4%, then carbide slag 14.5 parts, ferromanganese ore slag 13 parts, 30 parts, zink sulphide stone, blast furnace slag 1 part, 40 parts, mud, calcium peroxide 1 part is added successively, aluminium powder 0.5 part, pulverize for the first time, then carry out separating twice, grinding is 100 ~ 200 orders to the particle diameter of particle, is finished product.
Embodiment 2
First to municipal sludge high bake, make it water content and be reduced to 1%, then carbide slag 10 parts, ferromanganese ore slag 7 parts, 30 parts, zink sulphide stone, blast furnace slag 5 parts, 40 parts, mud, sodium chlorate 5 parts is added successively, ferrocene 3 parts, pulverize for the first time, then carry out separating twice, grinding is 100 ~ 200 orders to the particle diameter of particle, is finished product.
Embodiment 3
First to municipal sludge high bake, make it water content and be reduced to 3%, then carbide slag 15 parts, ferromanganese ore slag 15 parts, 27 parts, zink sulphide stone, blast furnace slag 5 parts, 30 parts, mud, 5 parts, Potcrate is added successively, iron powder 3 parts, pulverize for the first time, then carry out separating twice, grinding is 100 ~ 200 orders to the particle diameter of particle, is finished product.
Embodiment 4
First to municipal sludge high bake, make it water content and be reduced to 3%, then carbide slag 15 parts, ferromanganese ore slag 15 parts, 25 parts, zink sulphide stone, blast furnace slag 4 parts, 35 parts, mud, 4 parts, potassium permanganate is added successively, 2 parts, magnesium powder, pulverize for the first time, then carry out separating twice, grinding is 100 ~ 200 orders to the particle diameter of particle, is finished product.
Embodiment 5
First to municipal sludge high bake, make it water content and be reduced to 3%, then carbide slag 15 parts, ferromanganese ore slag 5 parts, 29 parts, zink sulphide stone, blast furnace slag 5 parts, 40 parts, mud, calcium peroxide 4 parts is added successively, 2 parts, magnesium powder, pulverize for the first time, then carry out separating twice, grinding is 100 ~ 200 orders to the particle diameter of particle, is finished product.
The above; be only the present invention's preferably embodiment, but protection scope of the present invention is not limited thereto, any people being familiar with this technology is in the technical scope disclosed by the present invention; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.

Claims (4)

1. a mud clean fuel, is characterized in that: each constituent mass number of described mud clean fuel is:
Carbide slag 10 ~ 15 parts;
Ferromanganese ore slag 5 ~ 15 parts;
25 ~ 30 parts, zink sulphide stone;
Blast furnace slag 1 ~ 5 part;
30 ~ 40 parts, mud;
1 ~ 5 part, oxygenant;
Synergistic agent 0.5 ~ 3 part.
2. mud clean fuel according to claim 1, is characterized in that: described oxygenant is one or more the mixture in calcium peroxide, Potcrate, sodium chlorate, potassium permanganate.
3. mud clean fuel according to claim 1, is characterized in that: described synergistic agent is one or more the mixture in ferrocene, metallic aluminium powder, metal iron powder, metal magnesium powder.
4. according to the preparation method of the mud clean fuel described in any one in claims 1 to 3, it is characterized in that, preparation process is: first carry out high bake to mud, make it moisture and be reduced to less than 5%, then carry out mixing pulverizing for the first time with carbide slag, ferromanganese ore slag, zink sulphide stone, blast furnace slag, oxygenant, synergistic agent material, then carry out separating twice to grain diameter and be of a size of 100 ~ 200 orders.
CN201510239203.0A 2015-05-12 2015-05-12 Preparation method of sludge clean fuel Pending CN104830396A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510239203.0A CN104830396A (en) 2015-05-12 2015-05-12 Preparation method of sludge clean fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510239203.0A CN104830396A (en) 2015-05-12 2015-05-12 Preparation method of sludge clean fuel

Publications (1)

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CN104830396A true CN104830396A (en) 2015-08-12

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753667A (en) * 2016-12-02 2017-05-31 天津丰茂科技有限公司 A kind of biomass fuel of energy-conserving and environment-protective and preparation method thereof
CN108034469A (en) * 2017-12-13 2018-05-15 柳州市金升汽车配件有限公司 A kind of Environment-friendlyfuel fuel and preparation method thereof
CN111205901A (en) * 2020-03-23 2020-05-29 重庆霏洋环保科技股份有限公司 Method for preparing quick-burning charcoal material by using pepper branches

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217625A (en) * 1992-10-02 1993-06-08 Texaco Inc. Process for disposing of sewage sludge
CN1351133A (en) * 2000-10-30 2002-05-29 徐彬 Briquette additive for preparing active slag
CN1377943A (en) * 2001-04-02 2002-11-06 张伟艳 High temperature coal combustion supporting and sulphur fixing agent
CN1810940A (en) * 2006-03-03 2006-08-02 清华大学 Sludge fuel stick and its prepn
CN104164269A (en) * 2014-08-26 2014-11-26 山东大学 Biomass solid formation fuel additive and doping method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217625A (en) * 1992-10-02 1993-06-08 Texaco Inc. Process for disposing of sewage sludge
CN1351133A (en) * 2000-10-30 2002-05-29 徐彬 Briquette additive for preparing active slag
CN1377943A (en) * 2001-04-02 2002-11-06 张伟艳 High temperature coal combustion supporting and sulphur fixing agent
CN1810940A (en) * 2006-03-03 2006-08-02 清华大学 Sludge fuel stick and its prepn
CN104164269A (en) * 2014-08-26 2014-11-26 山东大学 Biomass solid formation fuel additive and doping method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753667A (en) * 2016-12-02 2017-05-31 天津丰茂科技有限公司 A kind of biomass fuel of energy-conserving and environment-protective and preparation method thereof
CN108034469A (en) * 2017-12-13 2018-05-15 柳州市金升汽车配件有限公司 A kind of Environment-friendlyfuel fuel and preparation method thereof
CN111205901A (en) * 2020-03-23 2020-05-29 重庆霏洋环保科技股份有限公司 Method for preparing quick-burning charcoal material by using pepper branches

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Application publication date: 20150812

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