CN104824862B - A kind of nice and cool socks worn applicable summer - Google Patents

A kind of nice and cool socks worn applicable summer Download PDF

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Publication number
CN104824862B
CN104824862B CN201510304843.5A CN201510304843A CN104824862B CN 104824862 B CN104824862 B CN 104824862B CN 201510304843 A CN201510304843 A CN 201510304843A CN 104824862 B CN104824862 B CN 104824862B
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China
Prior art keywords
fiber
polypropylene
nano
weight
socks
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CN201510304843.5A
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CN104824862A (en
Inventor
刘晋夫
李丽莎
熊国
林晓洁
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Shali Socks Corp Of Human Province
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SHALI SOCKS CORP OF HUMAN PROVINCE
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B11/00Hosiery; Panti-hose
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B17/00Selection of special materials for underwear

Abstract

The present invention discloses a kind of nice and cool socks worn applicable summer, it is made up of the blending according to a certain percentage of mint fibers, bamboo fibre, nano ceramic composite thin polypropylene multifunction fiber, mint fibers has salubrious effect, bamboo fibre can eliminate the unusual smell in deodorization, and nano ceramic composite thin polypropylene multifunction fiber has degerming effect, three kinds of fiber blends having been prepared at the most excellent health promoting socks of salubrious property and bacteria-eliminating efficacy of the invention.

Description

A kind of nice and cool socks worn applicable summer
Technical field
The present invention relates to a kind of socks, the nice and cool socks that specific design is worn a kind of applicable summer.
Background technology
During the broiling summer, foot is easy to perspire, particularly sole.If wearing the socks that permeability is bad, foot can feel sultry, moist, feel bad very much, is also easy to induce the foot such as tinea pedis, tinea pedis disease.Although can wear sandals by light in summer, but in formal occasion, this is clumsy thing after all.Particularly male, still likes wearing leather shoes, be necessary for wearing socks simultaneously summer.Accordingly it is desirable to there is one the most ventilative but also attractive in appearance, it is particularly suitable for the socks of dress in summer.
Summary of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of socks being particularly suitable for wearing, feel nice and cool and keep some strength summer.
In order to solve above-mentioned technical problem, the present invention provides a kind of nice and cool socks worn applicable summer, is made up according to the ratio blending that weight ratio is 20~30:30~50:50~70 of the first fiber, the second fiber, the 3rd fiber;
Described first fiber is mint fibers;
Described second fiber is bamboo fibre;
Described 3rd fiber is nano ceramic composite thin polypropylene multifunction fiber.
Preferably, described 3rd fiber is made up of following raw materials according component: nano-ceramic powder: 12~45 weight portions;Polypropylene: 100~180 weight portions: Tissuemat E: 30~40 weight portions.
Preferably, described nano ceramics meal component is ZrO2, or ZrC, TiO2, and Ag+ antibacterial in one or more mixing, wherein ZrO2Not less than 10 weight portions.
Preferably, the preparation technology of described 3rd fiber is: by described nano-ceramic powder through Aqueous dispersions, make nano-dispersed water-soluble colloidal state ceramic size, mix with Tissuemat E, polypropylene and solvent naphtha the most again, formed water, oil two-phase mixtures system, after chemical reaction, product is dried becomes the dry pre-dispersed presoma of nano ceramics;Prepared through composite master batch by pre-dispersed for nano ceramics presoma, compound slice is prepared and after spinning, forms nano ceramic composite thin polypropylene multifunction fiber.
Preferably, the filament number 0.5~1.5D of described nano ceramic composite thin polypropylene multifunction fiber, fibrous fracture intensity is more than 2.5cN/dtex;The particle diameter of the nano-ceramic powder used and the dispersion in composite master batch and composite thin polypropylene multifunction fiber thereof are less than 100nm.
Preferably, described first fiber: the second fiber, the weight ratio of the 3rd fiber are 20~30:35~50:55~65.
Preferably, described first fiber: the second fiber, the weight ratio of the 3rd fiber are 20~30:35~45:55~65.
Preferably, described first fiber: the second fiber, the weight ratio of the 3rd fiber are 25~28:35~45:55~65.
According to the present invention, socks have the first fiber, the second fiber, the 3rd fiber blend to make, wherein the first fiber is mint fibers, second fiber is bamboo fibre, 3rd fiber is nano ceramic composite thin polypropylene multifunction fiber, mint fibers can keep salubrious, bamboo fibre can perspire, nano ceramic composite thin polypropylene multifunction fiber can play the effect keeping some strength, and can be degerming, by selecting suitable ratio, it is possible to prepare and can either keep some strength, the socks of cooling effect and bacteria-eliminating efficacy can be played again.
Detailed description of the invention
First fiber, mint fibers: under the temperature conditions of 10~40 DEG C, beta-schardinger dextrin-and Oleum menthae are mixed, Oleum menthae is embedded into beta-schardinger dextrin-inner chamber with the state of molecule, form beta-schardinger dextrin-Oleum menthae clathrate, adhesion is the strongest, thus cause the volatility reduction of Oleum menthae, and the outside of beta-schardinger dextrin-molecule has stronger polarity, causing beta-schardinger dextrin-Oleum menthae micropowder also to have certain dissolubility and dispersibility, Oleum menthae mass percent shared by beta-schardinger dextrin-micropowder is 5%~25%;Add water in beta-schardinger dextrin-Oleum menthae micropowder, emulsifying dispersant, carry out mechanically actuated by special emulsifying device, it is thus achieved that uniform aqueous solution.Make fiber pulp, add Caustic soda wherein and make alkali cellulose, sodium cellulose xanghate is formed after being then passed through experienced, Carbon bisulfide yellow, the beta-schardinger dextrin-Oleum menthae micropowder that directly interpolation has been made wherein, control its additional proportion accounting for the mass percent of fiber by dosing pump is 0.2%, finally by Caustic soda dissolving, mixing, deaeration, filtration, maturation, wet spinning, post processing, obtains mint fibers finished product after drying.
Second fiber, bamboo fibre: prepare bamboo fibre according to the second embodiment disclosed in Chinese patent ZL200710148370.
3rd fiber, nano ceramic composite thin polypropylene multifunction fiber: weigh 30 parts of ZrO2Nano-ceramic powder, the ethyl oleate potassium sulfonate adding the 2wt% of ceramics weight and water, ball milling 30hr obtains the nano ceramics moisture pulp that concentration is 30wt%;Water adds 35 parts of Tissuemat Es, 25 parts of powdered polypropylenes and No. 120 solvent naphthas, the consumption of solvent naphtha and water is respectively the 35wt% of ceramics weight and 15 times, ceramic size stirring is added at 60~95 DEG C, form water, oil two-phase mixtures system, then the rosin amine of ceramics weight 2wt% is added, pass through chemical reaction, Nano Ceramic Particles is from aqueous phase separation and is coated with by Tissuemat E and enters oil phase, be combined formation bulky grain with polypropylene powder simultaneously, at 95 DEG C, constant temperature 2hr volatilizes solvent naphtha, it is cooled to less than 60 DEG C taking-ups, at 85 DEG C, dry 48hr obtain dry granular nanometer ZrO2The pre-dispersed presoma of composition polymer;This pre-dispersed presoma melts through screw extruder at 200 DEG C, mediate, extrude and the operation such as pelletizing, makes nano ceramics composite polypropylene master batch;By this master batch and remaining 130 parts of polypropylene chips through screw extruder second melting, it is blended and composite polypropylene fibre section is made in pelletizing;290 DEG C, high speed spinning under the conditions of 2800m/s, it is thus achieved that the ZrO of component requirements2Nano ceramic composite thin polypropylene multifunction fiber, fiber dimensious 75D/72f (filament number 1.0D), intensity is more than 3.0cN/dtex.
Embodiment 1:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 25:35:55 according to weight ratio, and make socks according to method blending disclosed in Chinese patent ZL200810000496.7.
Embodiment 2:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 30:35:70 according to weight ratio, and make socks according to method similarly to Example 1.
Embodiment 3:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 35:35:65 according to weight ratio, and make socks according to method similarly to Example 1.
Embodiment 4:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 28:45:68 according to weight ratio, and make socks according to method similarly to Example 1.
Embodiment 5:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 22:48:68 according to weight ratio, and make socks according to method similarly to Example 1.
Embodiment 6:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 26:34:65 according to weight ratio, and make socks according to method similarly to Example 1.
Comparative example 1:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 5:48:68 according to weight ratio, and make socks according to method similarly to Example 1.
Comparative example 2:
By the first fiber: the second fiber: the 3rd fiber is the ratio of 26:34:30 according to weight ratio, and make socks according to method similarly to Example 1.
Above-described embodiment and comparative example are tested respectively the bio wave photon energy launching 2~25 μm under at normal temperature, to staphylococcus aureus and escherichia coli bacteriostasis rate, ultraviolet ray transmissivity.
Test properties is as follows:
And accurate according to following (a) 5 grades of evaluation forms, 10 expert groups form evaluation group and the socks of six embodiments are evaluated salubrious sense.According to following (b) 4 grades of criterions, judge with the average mark of the sample obtained by 5 grades of evaluation criterions.
Finding according to (a) 5 grades of evaluation criterion tests, result is as follows:
Find according to the test of (b) 4 rank criterion,
The salubrious sense result of embodiment 1-comparative example 2 is as follows:
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative example 1 Comparative example 2
Clearly feel effect Excellent Excellent Excellent Excellent Excellent Excellent Very poor Excellent
Clearly feel mark 3.7 3.8 3.7 3.9 3.8 3.7 1.1 3.7
Bamboo fibre, mint fibers being combined blending with nano ceramic composite thin polypropylene multifunction fiber and be used for manufacturing socks of the invention, has prepared and has i.e. had salubrious property, can reach again the health promoting socks of good bacteria-eliminating efficacy.
The above is only the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (2)

1. the nice and cool socks worn applicable summer, it is characterised in that by the first fiber, the second fiber, 3rd fiber is made according to the ratio blending that weight ratio is 25:35:55;
Described first fiber is mint fibers;
Described second fiber is bamboo fibre;
Described 3rd fiber is nano ceramic composite thin polypropylene multifunction fiber;Described 3rd fiber by under Row raw material components is made: the ZrO of 30 weight portions2Nano-ceramic powder;Polypropylene: 155 weight portions;Poly-second Alkene wax: 35 weight portions;
The preparation technology of described 3rd fiber is: weigh 30 parts of ZrO2Nano-ceramic powder, interpolation ceramics The ethyl oleate potassium sulfonate of the 2wt% of weight and water, ball milling 30hr obtains the nanometer pottery that concentration is 30wt% Porcelain moisture pulp;Water adds 35 parts of Tissuemat Es, 25 parts of powdered polypropylenes and No. 120 solvent naphthas, molten Agent oil and the consumption of water are respectively the 35wt% of ceramics weight and 15 times, add pottery at 60~95 DEG C Porcelain slurry agitation, forms water, oil two-phase mixtures system, then adds the rosin amine of ceramics weight 2wt%, By chemical reaction, Nano Ceramic Particles is from aqueous phase separation and is coated with by Tissuemat E and enters oil phase, with Time be combined formation bulky grain with polypropylene powder, at 95 DEG C, constant temperature 2hr volatilizes solvent naphtha, is cooled to Less than 60 DEG C taking-ups, dry 48hr at 85 DEG C and obtain dry granular nanometer ZrO2Composite polymeric The pre-dispersed presoma of thing;This pre-dispersed presoma melts through screw extruder at 200 DEG C, mediates, squeezes Go out and pelletizing operation, make nano ceramics composite polypropylene master batch;This master batch is gathered with remaining 130 parts Propylene section through screw extruder second melting, be blended and pelletizing make composite polypropylene fibre section; 290 DEG C, high speed spinning under the conditions of 2800m/s, it is thus achieved that the ZrO of component requirements2Nano ceramic composite thin denier Polypropylene multifunctional fibre.
Socks the most according to claim 1, it is characterised in that described 3rd fiber dimensious 75D/72f, Wherein filament number 1.0D.
CN201510304843.5A 2015-06-04 2015-06-04 A kind of nice and cool socks worn applicable summer Active CN104824862B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105019035A (en) * 2015-07-29 2015-11-04 湖南莎丽袜业股份有限公司 Preparation method of all bamboo fibers and sock
CN105088389A (en) * 2015-08-17 2015-11-25 俞尧芳 Anti-ultraviolet polyester fibers and preparation method thereof
CN106637488A (en) * 2016-12-06 2017-05-10 钦州市高新技术产业服务中心 Antibacterial and deodorization polypropylene fiber and preparation method thereof

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* Cited by examiner, † Cited by third party
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AU2003234975A1 (en) * 2002-05-31 2003-12-19 Ganggang Yu Natural anti-bacterial material and its use, anti-bacterial production
JP2008303475A (en) * 2007-06-05 2008-12-18 Horihokku:Kk Sock
JP4859762B2 (en) * 2007-06-15 2012-01-25 義臣 吉田 Bamboo fiber manufacturing method and manufacturing apparatus
CN100497771C (en) * 2007-06-15 2009-06-10 吴进前 Nano ceramic composite thin polypropylene multifunctional fiber and preparing method
CN101613886B (en) * 2009-07-30 2011-06-15 江苏微纺纺织服装有限公司 Production process of mint fibers
CN201595183U (en) * 2009-12-13 2010-10-06 杭州个个爽竹纤维开发有限公司 Bamboo fiber infrared-ray antibacterial socks
CN202206884U (en) * 2011-09-08 2012-05-02 湖南莎丽袜业股份有限公司 Silk stocking
CN104328651A (en) * 2014-11-06 2015-02-04 李志坚 Preparation method of odor-resisting and sterilizing health functional fabric

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Application publication date: 20150812

Assignee: Hunan Jing Zhuxin Materials Development Co. Ltd.

Assignor: Shali Socks Corp Of Human Province

Contract record no.: 2016430000019

Denomination of invention: Cool sock suitable for being worn in summer

Granted publication date: 20160831

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Record date: 20160907

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Patentee before: Shali Socks Corp Of Human Province

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Pledgor: HUNAN SHALI SOCKS Co.,Ltd.

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