CN104814028B - Composition pesticide containing pyridine quinazoline and Moroxydine Hydrochloride - Google Patents
Composition pesticide containing pyridine quinazoline and Moroxydine Hydrochloride Download PDFInfo
- Publication number
- CN104814028B CN104814028B CN201510208188.3A CN201510208188A CN104814028B CN 104814028 B CN104814028 B CN 104814028B CN 201510208188 A CN201510208188 A CN 201510208188A CN 104814028 B CN104814028 B CN 104814028B
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- China
- Prior art keywords
- moroxydine hydrochloride
- pyridine quinazoline
- composition pesticide
- quinazoline
- disease
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229960002581 moroxydine hydrochloride Drugs 0.000 title claims abstract description 76
- BITDLWAQPKSXTF-UHFFFAOYSA-M 1-[(3-nitrophenyl)methoxymethyl]pyridin-1-ium;chloride Chemical compound [Cl-].[O-][N+](=O)C1=CC=CC(COC[N+]=2C=CC=CC=2)=C1 BITDLWAQPKSXTF-UHFFFAOYSA-M 0.000 title claims abstract description 74
- AMJZJYLMKHTSDG-UHFFFAOYSA-N pyridine;quinazoline Chemical compound C1=CC=NC=C1.N1=CN=CC2=CC=CC=C21 AMJZJYLMKHTSDG-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000000575 pesticide Substances 0.000 title claims abstract description 22
- 208000036142 Viral infection Diseases 0.000 claims abstract description 24
- 239000004480 active ingredient Substances 0.000 claims abstract description 12
- 230000002265 prevention Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000375 suspending agent Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 239000004563 wettable powder Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004530 micro-emulsion Substances 0.000 claims description 4
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002552 dosage form Substances 0.000 claims description 3
- UMHSKYSHOIGDPE-UHFFFAOYSA-N pyridine;quinoline Chemical group C1=CC=NC=C1.N1=CC=CC2=CC=CC=C21 UMHSKYSHOIGDPE-UHFFFAOYSA-N 0.000 claims description 3
- VWPYEPBQDNXCDS-UHFFFAOYSA-N guanidine;quinoline Chemical compound NC(N)=N.N1=CC=CC2=CC=CC=C21 VWPYEPBQDNXCDS-UHFFFAOYSA-N 0.000 claims description 2
- 238000009313 farming Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 9
- 241000238631 Hexapoda Species 0.000 abstract description 8
- 230000001225 therapeutic effect Effects 0.000 abstract description 5
- 239000013598 vector Substances 0.000 abstract description 4
- 201000010099 disease Diseases 0.000 description 48
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 48
- 241000700605 Viruses Species 0.000 description 18
- 241000196324 Embryophyta Species 0.000 description 16
- 239000003814 drug Substances 0.000 description 14
- 239000007921 spray Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 240000007594 Oryza sativa Species 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 238000013329 compounding Methods 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 235000002566 Capsicum Nutrition 0.000 description 7
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 7
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- 230000003449 preventive effect Effects 0.000 description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 6
- -1 synergist Substances 0.000 description 6
- 241000208125 Nicotiana Species 0.000 description 5
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 230000003612 virological effect Effects 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000006002 Pepper Substances 0.000 description 4
- 235000016761 Piper aduncum Nutrition 0.000 description 4
- 240000003889 Piper guineense Species 0.000 description 4
- 235000017804 Piper guineense Nutrition 0.000 description 4
- 235000008184 Piper nigrum Nutrition 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 235000017060 Arachis glabrata Nutrition 0.000 description 3
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- 240000008574 Capsicum frutescens Species 0.000 description 3
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- 240000009088 Fragaria x ananassa Species 0.000 description 3
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- 239000003381 stabilizer Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- 235000011171 Thladiantha grosvenorii Nutrition 0.000 description 2
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- 244000126002 Ziziphus vulgaris Species 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 235000021329 brown rice Nutrition 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
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- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000725138 Banana bunchy top virus Species 0.000 description 1
- 241001135993 Bean common mosaic virus strain peanut stripe Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- 241000931705 Cicada Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 240000001008 Dimocarpus longan Species 0.000 description 1
- 241000283073 Equus caballus Species 0.000 description 1
- 235000000235 Euphoria longan Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000578422 Graphosoma lineatum Species 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
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- 240000004658 Medicago sativa Species 0.000 description 1
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000724284 Peanut stunt virus Species 0.000 description 1
- 241000269799 Perca fluviatilis Species 0.000 description 1
- 241000702634 Rice black streaked dwarf virus Species 0.000 description 1
- 241000702632 Rice dwarf virus Species 0.000 description 1
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- 241000724205 Rice stripe tenuivirus Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241000191471 Strawberry crinkle cytorhabdovirus Species 0.000 description 1
- 241000413494 Strawberry mottle virus Species 0.000 description 1
- 241000724803 Sugarcane bacilliform virus Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 235000008529 Ziziphus vulgaris Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
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- 235000013527 bean curd Nutrition 0.000 description 1
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- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
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- 235000003642 hunger Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
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- MIOBBYRMXGNORL-UHFFFAOYSA-N pyrifluquinazon Chemical compound C1C2=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C2N(C(=O)C)C(=O)N1NCC1=CC=CN=C1 MIOBBYRMXGNORL-UHFFFAOYSA-N 0.000 description 1
- UBZJXAQDXUGXIZ-UHFFFAOYSA-N quinazoline;quinoline Chemical compound N1=CC=CC2=CC=CC=C21.N1=CN=CC2=CC=CC=C21 UBZJXAQDXUGXIZ-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
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- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical class [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
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- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The weight ratio of the invention discloses a kind of composition pesticide containing pyridine quinazoline and Moroxydine Hydrochloride, including the first active ingredient pyridine quinazoline and the second active ingredient Moroxydine Hydrochloride and common auxiliary element, pyridine quinazoline and Moroxydine Hydrochloride is 1:1~1:20.Experiments have shown that, composition pesticide of the present invention has significant synergistic function, propagates the insect vector of the viroses of plant by prevention and to the therapeutic effect of virosis itself, hence it is evident that improve the control effect to the viroses of plant through a large amount of.
Description
Technical field
The present invention relates to a kind of composition pesticides, and specifically one kind is effective with pyridine quinazoline and Moroxydine Hydrochloride
The composition pesticide of ingredient is suitable for prevention crop disease viral disease.
Background technology
The viroses of plant are often to cause heavy loss to agricultural production by the parasitogenic disease of plant virus, according to statistics,
The underproduction reaches 10-30%, about 20,000,000,000 dollars of economic loss caused by annual.China is a large agricultural country, every year because of virosis pair
The about tens billion of members of economic loss caused by grain-production, garden crop, industrial crops etc..Since the prevalence of virosis is led
If therefore, single by by taking viruliferous insect as caused by the malicious insect vector of the biography such as aphid, leafhopper, plant hopper, aleyrodid
Using the medicament of prevention virosis, control effect is not satisfactory, and the virosis that cannot fundamentally control on crops causes harm.
Pyridine quinazoline (Pyrifluquinazon), belongs to novel quinazoline quinoline insecticides, and the mechanism of action is to prevent pest
Feed is mainly used for preventing Phytophthira, aleyrodid class, scale insect on the crops such as vegetables, fruit tree and tealeaves until pest is slowly died of hunger
The suckings mouthpart insect such as class, leafhopper class, thrips class, can significantly reduce the propagation of viral vectors, which can be complete
Penetrate blade face, to below blade face the pest of predation and perch also can reach the purposes of effective prevention and control.
Moroxydine Hydrochloride (Moroxydine hydrochloride) is the agent for prevention and control of virus of a kind of wide spectrum, low toxicity, dilution
After liquid afterwards sprays application to plant leaf surface, medicament can be entered by aqueous vapor hole in plant, inhibit or destroy nucleic acid and lipoprotein
Formation, prevent virus reproduction process, play the role of controlling the virus.
The present inventor has made intensive studies the compounded formula screening of pyridine quinazoline and Moroxydine Hydrochloride, unexpected
Ground finds that pyridine quinazoline and Moroxydine Hydrochloride are compounded, and has within the scope of certain compound proportion significant synergistic
Effect, in actual use, pyridine quinazoline and Moroxydine Hydrochloride are used in compounding the biography that can either prevent the viroses of plant
Insect vector is broadcast, while can play therapeutic effect to virosis itself again, hence it is evident that improves the prevention effect to the viroses of plant
Fruit completes the present invention after further study.
Invention content
The purpose of the present invention is to provide a kind of prevention viroses of plant containing pyridine quinazoline and Moroxydine Hydrochloride
Composition pesticide, the composition have significant synergistic function, by prevent the viroses of plant biography poison insect vector with
And the therapeutic effect to virosis itself, hence it is evident that improve the control effect to the viroses of plant.
Technical solution：A kind of composition pesticide containing pyridine quinazoline and Moroxydine Hydrochloride, active ingredient are pyridine quinoline
The weight ratio of oxazoline and Moroxydine Hydrochloride, pyridine quinazoline and Moroxydine Hydrochloride is 1:1~1:20, pyridine quinazoline and hydrochloric acid
Weight percent of the quinoline guanidine weight summation in composition pesticide is 1~85%, remaining uses and can connect to allow in pesticide
The auxiliary element received.
The auxiliary element is solvent, emulsifier, wetting agent, dispersant, stabilizer, antifreezing agent, thickener, disintegration
One or more kinds of groups in agent, binder, antifoaming agent, bleeding agent, synergist, fire retardant, density adjuster and filler
It closing, the above substance is common known substance in pesticidal preparations, is varied from according to the different formulations of pesticide are prepared into, but
It is not particularly limited.
Composition pesticide of the present invention can be prepared into any one dosage form used in suitable agricultural production by known method,
Relatively good dosage form has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wettable powder and ultra low volume liquids.
The production technology of the various application forms of the composition pesticide belongs to existing known technology, no longer superfluous herein
It states.
The frequency of administration and amount of application of composition pesticide of the present invention change with crops, pest, weather condition and have a small amount of
Variation, can achieve the purpose that effectively to prevent by using dosage appropriate.
The target plant that the present invention is suitble to is rice, corn, sugarcane, rape, tobacco, peanut, soybean, tomato, capsicum, horse
Bell potato, melon, wild cabbage, strawberry, lichee, longan, jujube tree, cotton, banana, Siraitia grosvenorii and forest etc..
The present invention is suitble to prevent southern rice black-streaked dwarf disease, black streaked dwarf virus of rice, rice stunt, rice Huang
It is the short disease of short disease, rice gall dwarf virus disease, Rice Orange Leaf Disease, rice tooth, stripe disease, yellow stunt of wheat, wheat rosette stunt, small
Wheat soil-borne mosaic, wheat yellow mosaic, wheat shuttle streak mosaic disease, wheat red stunt, wheat streak mosaic, Corn Crude contracting
Disease, mosaic of sugarcane, sugarcane yellow leaf, sugarcane bacilliform virus disease, tobacco mosaic viruses disease, tobacco cucumber mosaic virus
Disease, tobacco potato Y virus disease, Strawberry mottle virus disease, strawberry light yellow edge virus disease, strawberry crinkle virus disease, strawberry edge
Arteries and veins virosis, peanut stripe viruses disease, peanut Cucumber Mosaic Virus, peanut stunt viral disease, peanut bud blight poison, big Tofu pudding
Leaf disease viral disease, soybean alfalfa mosaic viral disease, tomato virus disease, potato virus disease, pepper virus disease, banana bunchy top disease, dragon
The communication media of eye lichee witches' broom disease, Siraitia grosvenorii virosis, jujube tree jujube witches broom and virosis：Plant hopper, aphid, aleyrodid, leaf
Cicada, stinkbug silk worm, scale insect, wood louse and thrips etc..
Compared with the prior art, the advantages of the present invention are as follows：
1, two kinds of active ingredients of pyridine quinazoline and Moroxydine Hydrochloride compounding has significant synergistic function, both can be with
The communication media insect of the viroses of plant is prevented, while there is therapeutic effect again to virosis itself, hence it is evident that is improved to virus
The control effect of disease.
2, two kinds of active ingredients of pyridine quinazoline and Moroxydine Hydrochloride are used in compounding, and reduce Pesticide use number, are reduced
Use cost alleviates pollution to environment, has delayed the generation of viral resistance, increases the service life of pesticide.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of that invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
(1) Formulation Example
Each component percentage composition is weight percentage in following examples.
Embodiment 1：15% pyridine quinazoline Moroxydine Hydrochloride ultra low volume liquids
Pyridine quinazoline 5%, Moroxydine Hydrochloride 10%, durene 5%, N-Methyl pyrrolidone 10%, castor oil polyoxy
Vinethene 5%, oozes T 2% at lauryl sodium sulfate 5% soon, and methyl oleate complements to 100%.By above-mentioned active ingredient with molten
After agent stirring and dissolving, emulsifier, wetting agent and bleeding agent are added, is thoroughly mixed uniformly, you can 15% pyridine quinoline is made
Oxazoline Moroxydine Hydrochloride ultra low volume liquids.
Embodiment 2：16% pyridine quinazoline Moroxydine Hydrochloride suspending agent
Pyridine quinazoline 1%, Moroxydine Hydrochloride 15%, aerosol-OT salt 10%, acrylate homopolymer sodium
Salt 5%, glycerine 3%, methylcellulose 1%, silicone oil 0.1%, deionized water supplies 100%.By above-mentioned active ingredient, moistening
Agent, dispersant, antifreezing agent, thickener and antifoaming agent disperse through high speed shear, are sanded in sand mill, are formed in water-medium
High dispersive, the suspension system of stabilization, you can 16% pyridine quinazoline Moroxydine Hydrochloride suspending agent is made.
Embodiment 3：32% pyridine quinazoline Moroxydine Hydrochloride aqueous emulsion
Pyridine quinazoline 2%, Moroxydine Hydrochloride 30%, methyl naphthalene 10%, cyclohexanone 5%, terminal hydroxy group polyoxyethylene polyoxy
Propylene ether 10%, polycarboxylate 5%, sodium citrate 1%, glycerine 1%, deionized water supplies 100%.By it is above-mentioned effectively at
Point, solvent, emulsifier, dispersant and stabilizer be mixed to form oil phase, antifreezing agent dissolve in water forms water phase, in cutter work
Slowly oil phase is added in water phase under, and continues shearing about 30 minutes, 32% pyridine quinazoline Moroxydine Hydrochloride is made
Aqueous emulsion.
Embodiment 4：40% pyridine quinazoline Moroxydine Hydrochloride microemulsion
Pyridine quinazoline 5%, Moroxydine Hydrochloride 35%, trimethylbenzene 10%, cyclohexanone 5%, terminal hydroxy group polyoxyethylene polyoxy
Propylene ether 10%, sodium citrate 2%, organosilicon 1%, azone 2%, deionized water supplies 100%.Active ingredient solvent is complete
Then fully dissolved adds emulsifier, stabilizer, bleeding agent, synergist and is uniformly mixed, is eventually adding deionized water, fully stirs
After mixing, you can 40% pyridine quinazoline Moroxydine Hydrochloride microemulsion is made.
Embodiment 5：80% pyridine quinazoline Moroxydine Hydrochloride water dispersible granules
Pyridine quinazoline 5%, Moroxydine Hydrochloride 75%, Nekal BX 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, six
Sodium hexametaphosphate 2%, kaolin supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, disintegrant and filler are mixed equal
It is even, it is crushed with micro jet, through mediating, is then added in fluidized-bed granulation dryer and is granulated, dries, sieve,
It can be prepared by 80% pyridine quinazoline Moroxydine Hydrochloride water dispersible granules.
Embodiment 6：70% pyridine quinazoline Moroxydine Hydrochloride wettable powder
Pyridine quinazoline 10%, Moroxydine Hydrochloride 60%, neopelex 10%, rosin segmented polyoxyethylene ether
Polyoxypropylene ether sulfonate 5%, attapulgite supplies 100%.Active ingredient, wetting agent, dispersant and filler are mixed by above-mentioned
It closes, is uniformly mixed again through air-flow crushing after mechanical crushing, you can 70% pyridine quinazoline Moroxydine Hydrochloride wettable powder is made
Agent.
(2) the indoor biological determination of activity of the present composition and field efficacy verification
Embodiment 7：The indoor joint toxicity measuring test of pyridine quinazoline and Moroxydine Hydrochloride to stripe disease
The susceptible rice varieties of potting are cultivated indoors, when rice shoot is grown to 1 leaf, 1 heart~2 1 heart of leaf, carry out inoculated identification.Often
Basin cover is sealed with translucent cover, top with gauze, and the worm amount that needs, 2~3 age small brown rice planthoppers of access (the malicious rate of band are calculated by 5 small brown rice planthoppers of every seedling
About 40%).Daily expelling parasite 2 times makes tested rice seedling uniformly be infected by poison.The medicament for preparing various concentration is uniformly sprayed on confession
It tries on seedling, often 50 plants of processing, 4 repetitions, 14 days classification investigation state of an illness, calculate preventive effect, measure EC after medicine50Value.
As shown in Table 1, EC of the Moroxydine Hydrochloride to stripe disease50Value is 49.21ppm, and pyridine quinazoline is to water
Rice stripe is without activity, however, pyridine quinazoline and Moroxydine Hydrochloride are 1:1~1:It is multiple in the range of 20 (by weight)
To the EC of stripe disease after matching50Value is compared with Moroxydine Hydrochloride exclusive use and be decreased significantly, respectively less than
49.21ppm shows synergistic function after illustrating pyridine quinazoline and Moroxydine Hydrochloride compounding to stripe disease；
Especially with 1:15 (by weight) compoundings, synergistic function are the most notable.It can be seen that pyridine quinazoline is compounded with Moroxydine Hydrochloride
With reasonability and feasibility.
The indoor joint toxicity measuring result of table 1, pyridine quinazoline and Moroxydine Hydrochloride to stripe disease
| Medicament title and proportioning (weight ratio) | EC50(ppm) |
| Pyridine quinazoline | ---- |
| Moroxydine Hydrochloride | 49.21 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:1) | 40.58 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:5) | 39.61 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:10) | 38.76 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:15) | 37.12 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:20) | 37.94 |
Embodiment 8：The indoor joint toxicity measuring test of pyridine quinazoline and Moroxydine Hydrochloride to tobacco mosaic virus disease
The tobacco disease leaf for infecting TMV is shredded to the 4-5 leaf phases and is put into mortar by Potted tobacco susceptible variety plant indoors,
0.02M (PH7.0) phosphate buffer of 8 times of sick leaf weight is added, grinds pulp, a little diatomite is then added, grinds cigarette receiving
Leaf is rinsed with water the blade of inoculation after inoculation.The 2-3hr after blade dries uniformly sprays the medicament for preparing various concentration
On for examination plant, 3 plants are often handled, every plant of 3 leaves are repeated 4 times, and withered spot number is investigated after 4 days, and it is (anti-to calculate scab inhibiting rate
Effect), measure EC50Value.
The indoor joint toxicity measuring result of table 2, pyridine quinazoline and Moroxydine Hydrochloride to tobacco mosaic virus disease
| Medicament title and proportioning (weight ratio) | EC50(ppm) |
| Pyridine quinazoline | ---- |
| Moroxydine Hydrochloride | 47.96 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:1) | 38.93 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:5) | 38.18 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:10) | 37.43 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:15) | 36.46 |
| Pyridine quinazoline:Moroxydine Hydrochloride (1:20) | 37.59 |
As shown in Table 2, EC of the Moroxydine Hydrochloride to tobacco mosaic virus disease50Value is 47.96ppm, and pyridine quinazoline is to cigarette
Careless mosaic virus is without activity, however, pyridine quinazoline and Moroxydine Hydrochloride are 1:1~1:It is multiple in the range of 20 (by weight)
To the EC of tobacco mosaic virus disease after matching50Value is compared with Moroxydine Hydrochloride exclusive use and be decreased significantly, respectively less than
47.96ppm shows synergistic function after illustrating pyridine quinazoline and Moroxydine Hydrochloride compounding to tobacco mosaic virus disease；
Especially with 1:15 (by weight) compoundings, synergistic function are the most notable.It can be seen that pyridine quinazoline is compounded with Moroxydine Hydrochloride
With reasonability and feasibility.
Embodiment 9：Prevent the field control effectiveness test of corn rough dwarf
Start to spray the 1st time medicine when 1 leaf has just been unfolded in emergence of corn, sprayed every 1 week 1 time, spray 5 times altogether later, the 5th spray
20d experimental investigations result after medicine.According to data correlation study standard grading, disease index is counted, calculates preventive effect.
Table 3, each field control effectiveness test result handled to corn rough dwarf
As shown in Table 3,20d after the 5th spray, 16% Moroxydine Hydrochloride pyridine quinazoline suspending agent, 80% hydrochloric acid
Quinoline guanidine pyridine quinazoline water dispersible granules and 32% Moroxydine Hydrochloride pyridine quinazoline aqueous emulsion prevent corn rough dwarf
20% Moroxydine Hydrochloride wettable powder and the exclusive use of 20% pyridine quinazoline suspending agent will be significantly better than by controlling effect, and preventive effect is equal
Up to 85% or more, while not finding that compound drug generates poisoning to corn during pilot survey.
Embodiment 10：Prevent the field control effectiveness test of pepper virus disease
It is colonized in capsicum and starts within 1 week to spray the 1st time medicine after slow seedling, sprayed every 1 week 1 time, spray 5 times altogether later, after the 5th spray
10d experimental investigation results.According to data correlation study standard grading, disease index is counted, calculates preventive effect.
As shown in Table 4,10d after the 5th spray, 16% Moroxydine Hydrochloride pyridine quinazoline suspending agent, 80% hydrochloric acid
Quinoline guanidine pyridine quinazoline water dispersible granules and 32% Moroxydine Hydrochloride pyridine quinazoline aqueous emulsion prevent pepper virus disease
20% Moroxydine Hydrochloride wettable powder and the exclusive use of 20% pyridine quinazoline suspending agent will be significantly better than by controlling effect, and preventive effect is equal
Up to 85% or more, while not finding that compound drug generates poisoning to capsicum during pilot survey.
Table 4, each field control effectiveness test result handled to pepper virus disease
Embodiment 11：Prevent the field control effectiveness test of tomato virus disease
Start to spray the 1st time medicine in tomato early stage, be sprayed later every 1 week 1 time, is sprayed altogether 3 times, 14d tune after the 3rd spray
Look into test result.According to data correlation study standard grading, disease index is counted, calculates preventive effect.
Table 5, each field control effectiveness test result handled to tomato virus disease
As shown in Table 5,14d after the 3rd spray, 16% Moroxydine Hydrochloride pyridine quinazoline suspending agent, 80% hydrochloric acid
Quinoline guanidine pyridine quinazoline water dispersible granules and 32% Moroxydine Hydrochloride pyridine quinazoline aqueous emulsion prevent tomato virus disease
20% Moroxydine Hydrochloride wettable powder and the exclusive use of 20% pyridine quinazoline suspending agent will be significantly better than by controlling effect, and preventive effect is equal
Up to 85% or more, while not finding that compound drug generates poisoning to tomato during pilot survey.
In conclusion the present invention uses the prevention phytopathy of two kinds of active ingredient of pyridine quinazoline and Moroxydine Hydrochloride compounding
The composition pesticide of viral disease has significant synergistic function, can both prevent the communication media insect of virosis, while right
Virosis itself has therapeutic effect again, hence it is evident that the control effect to virosis is improved, and the lasting period is long, to crop safety,
It is worth promoting and applying in agricultural production.
Claims (3)
1. a kind of composition pesticide containing pyridine quinazoline and Moroxydine Hydrochloride, it is characterised in that：Active ingredient is pyridine quinoline
The weight ratio of oxazoline and Moroxydine Hydrochloride, pyridine quinazoline and Moroxydine Hydrochloride is 1:1~1:20, pyridine quinazoline and hydrochloric acid
Weight percent of the quinoline guanidine weight summation in composition pesticide is 1~85%.
2. the composition pesticide according to claim 1 containing pyridine quinazoline and Moroxydine Hydrochloride, it is characterised in that：Institute
It can be suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wettable powder to state dosage form of the composition pesticide in practical application
One kind in agent, ultra low volume liquids.
3. a kind of composition pesticide according to claim 1 containing pyridine quinazoline and Moroxydine Hydrochloride is in prevention farming
Application in object virosis.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1823055A (en) * | 2003-05-12 | 2006-08-23 | 日本农药株式会社 | Process for producing substituted aminoquinazolinone derivative, intermediate therefor, and pest control agent |
| CN101730471A (en) * | 2007-06-28 | 2010-06-09 | 先正达参股股份有限公司 | methods of controlling insects |
| CN102742590A (en) * | 2012-06-18 | 2012-10-24 | 江西众和化工有限公司 | Insecticidal and bactericidal composition containing imidacloprid and moroxydine hydrochloride |
| CN102858161A (en) * | 2010-04-27 | 2013-01-02 | 先正达参股股份有限公司 | Methods of controlling neonicotinoid resistant aphids |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1823055A (en) * | 2003-05-12 | 2006-08-23 | 日本农药株式会社 | Process for producing substituted aminoquinazolinone derivative, intermediate therefor, and pest control agent |
| CN101730471A (en) * | 2007-06-28 | 2010-06-09 | 先正达参股股份有限公司 | methods of controlling insects |
| CN102858161A (en) * | 2010-04-27 | 2013-01-02 | 先正达参股股份有限公司 | Methods of controlling neonicotinoid resistant aphids |
| CN102742590A (en) * | 2012-06-18 | 2012-10-24 | 江西众和化工有限公司 | Insecticidal and bactericidal composition containing imidacloprid and moroxydine hydrochloride |
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