CN104767420B - A kind of transparent multicomputer nanometer hydroelectric generator and its manufacture method - Google Patents
A kind of transparent multicomputer nanometer hydroelectric generator and its manufacture method Download PDFInfo
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- CN104767420B CN104767420B CN201510164488.6A CN201510164488A CN104767420B CN 104767420 B CN104767420 B CN 104767420B CN 201510164488 A CN201510164488 A CN 201510164488A CN 104767420 B CN104767420 B CN 104767420B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/50—Hydropower in dwellings
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Abstract
The present invention relates to a kind of transparent multicomputer nanometer hydroelectric generator and its method processed, transparent multicomputer nanometer hydroelectric generator includes：Transparent functional film layer, transparent electrode layer, basalis, transparent electrode layer is arranged on basalis, transparent functional film layer is arranged on transparent electrode layer, transparent functional film layer is a kind of hydrophobic film, transparent electrode layer is made up of the arrangement of some transparent electrode arrays, the use for array and the transparent functional film layer that the present invention passes through transparency electrode realizes the preparation of transparent multicomputer nanometer hydroelectric generator, transparent functional film, transparent electrode layer, the refractive index of air causes function film to play the effect of anti-reflection film, add the transmitance of integral device, in addition, this generator it is simple in construction, it is with low cost, it can collect the current correlation energy in life, it can be widely applied to building glass, glass for vehicle window a series of needs the occasion of transparent material, it is expected to intelligent automobile, smart home is energized, there is very big application prospect.
Description
Technical field
The present invention relates to the micro-nano energy, hydroelectric field, and in particular to a kind of transparent multicomputer nanometer hydroelectric generator
And its manufacture method.
Background technology
The energy is most important for the development of civilization of the mankind.The energy is that all human civilizations are rely the basis of foundation, and is pushed away
Move prosperity and the development of human civilization.The traditional energy that oil and coal occupy leading position has greatly facilitated social hair
Exhibition, but also inevitably meet with two big safety problems.One is the supply security of traditional energy.Two be the use of traditional energy
Safety.It is exactly non-renewable and environmental pollution to summarize.For the dependence to fossil fuel that liberates mankind, obtained from environment
Energy is taken to attract increasing interest.Heat energy, wind energy, solar energy, water in environment can all be renewable resources.It is therein
Current correlation energy is inexhaustible green energy resource, and is not limited by daylight and weather.Traditional electromagnetic type hydroelectric generation
Machine has played huge effect collecting extensive flow energy field, but its bulky, complicated, cost are high etc.
Feature limits its application in daily life.
, Wang Zhonglin groups in 2013（Angew. Chem. Int. Ed.2013, 52(48), 12545.）Profit is reported
The friction generator for contacting powered composition with water and solid interface formation may have huge answer in terms of flow energy is collected
Use prospect.Transparent characteristic is one and played the part of in Novel Optoelectronic Device and the pith of field of electronic devices, and in real life
A very important role is drilled.On the other hand, constantly improving the efficiency of nanometer hydroelectric generator collection flow energy is
One very important research field.And single nanometer hydroelectric generator collects the limited efficacy of flow energy, and once meet
It will cause damage that is short-circuit and causing whole device to some damages.These all greatly limit nanometer hydroelectric generator in reality
Application in life.
The content of the invention
The present invention proposes a kind of can efficiently collect flow energy and simple in construction, cost is low, reliability is high transparent multimachine
Group nanometer hydroelectric generator and its manufacture method.
To achieve these goals, the present invention proposes following technical scheme：
A kind of transparent multicomputer nanometer hydroelectric generator, hydroelectric generation is realized using the current in daily life, described
Bright multicomputer nanometer hydroelectric generator is made of clear material.
Further, the transparent multicomputer nanometer hydroelectric generator includes：Transparent functional film layer, transparent electrode layer and
Basalis, the transparent electrode layer is arranged at basalis upper surface, and transparent functional film layer is arranged at transparent electrode layer upper surface,
Wherein transparent functional film layer is hydrophobic film, and transparent electrode layer is made up of the arrangement of some transparent electrode arrays.
Further, the transparent electrode arrays arrangement mode includes：Rectangular array arrangement, annular array, do not advise
Then array arrangement.
Further, the material of the transparent functional film layer includes：Polytetrafluoroethylene (PTFE)（PTFE）, polyvinyl chloride（PVC）、
Polypropylene is fine（PAN）, Kynoar（PVDF）And dimethyl silicone polymer（PDMS）.
Further, the material of the transparency electrode includes：Fluorine doped tin oxide（FTO）, tin indium oxide（ITO）, mix alumina
Change zinc（AZO）.
A kind of manufacture method of transparent multicomputer nanometer hydroelectric generator, methods described comprises the following steps：
A. there will be fluorine doped tin oxide（FTO）The glass of transparent electrode arrays is positioned in supersonic cleaning machine, is used successively
Clean ten minutes, dry stand-by in acetone, isopropanol and ethanol cleaning, each solution；
B. by polytetrafluoroethylene (PTFE)（PTFE）Emulsion（60%）Dilute, be well mixed stand-by in proportion；
C. covered, then will be diluted the part that transparency electrode is connected with wire is given on glass with Kapton Tape
Polytetrafluoroethylene (PTFE)（PTFE）Emulsion is spin-coated on fluorine doped tin oxide using sol evenning machine（FTO）The glass of transparent electrode arrays
On, 1500 turns of rotating speed, 10 seconds time；
D. the Kapton Tape on the sheet glass after step c processing is removed, sheet glass is placed in 60 degree of bakings in baking oven
It is dry 10 minutes；
E. the sheet glass after step d processing is placed in high temperature furnace into 380 degree to be heated at high temperature two minutes, taking-up is stand-by；
F. each transparency electrode difference connecting wire, and giving over to the part use that transparency electrode is connected with wire in step c
Glue is encapsulated, to prevent water directly contacts transparency electrode from causing short circuit, obtains transparent multicomputer nanometer hydroelectric generator.
Further, the polytetrafluoroethylene (PTFE)（PTFE）The polytetrafluoroethylene (PTFE)（PTFE）The extension rate of emulsion is 4-
100 times.
Further, the polytetrafluoroethylene (PTFE)（PTFE）It can be replaced：Polyvinyl chloride（PVC）, polypropylene it is fine（PAN）, it is poly-
Vinylidene（PVDF）Or dimethyl silicone polymer（PDMS）.
Further, the fluorine doped tin oxide（FTO）It can be replaced：Tin indium oxide（ITO）Or Al-Doped ZnO（AZO）.
Further, the transparency electrode quantity is 2 ~ 1000.
The beneficial effects of the present invention are realized by the use of array and the transparent functional film layer of transparency electrode
The array of the preparation of transparent multicomputer nanometer hydroelectric generator, transparent functional film layer and transparency electrode can effectively improve generating
The output of machine, may be such that transparent functional film plays anti-reflection film by matching transparent thin film layer, transparency electrode, the refractive index of air
Effect, add the transmitance of whole device, make whole device more penetrating in addition, this generator it is simple in construction, into
This is cheap, has very high efficiency of energy collection compared to single generator, and independent mutually wherein between each transparency electrode,
The failure of indivedual transparency electrodes does not interfere with the operation of whole generating set, and it can collect the current correlation energy in life,
And can further use in the fields such as building, vehicles collection rainwater energy, it is expected to intelligent automobile, smart home realization
Energy supply, has great application prospect.
Brief description of the drawings
The transparent multicomputer nanometer hydroelectric generator structural representations of Fig. 1；
Fig. 2 is transparent electrode layer transparent electrode arrays arrangement schematic diagram.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples
The present invention is explained in further detail.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, and
It is not used in the restriction present invention.
On the contrary, the present invention covers any replacement done in the spirit and scope of the present invention being defined by the claims, repaiied
Change, equivalent method and scheme.Further, in order that the public has a better understanding to the present invention, below to the thin of the present invention
It is detailed to describe some specific detail sections in section description.Part without these details for a person skilled in the art
Description can also understand the present invention completely.
As shown in Figure 1 and Figure 2, a kind of transparent multicomputer nanometer hydroelectric generator, is realized using the current in daily life
Hydroelectric generation, for realizing that the transparent multicomputer nanometer hydroelectric generator is made of clear material, is widely used in building glass
Glass, glass for vehicle window or it is a series of need the occasion of transparent material, the transparent multicomputer nanometer hydroelectric generator includes：Transparent work(
Energy film layer 1, transparent electrode layer 2 and transparent base layer 3, the transparent electrode layer 2 are arranged at the upper surface of transparent base layer 3, institute
State transparent functional film layer 1 and be arranged at the upper surface of transparent electrode layer 2, the transparent functional film layer 1 is hydrophobic film, institute
Stating transparent functional film 1 material of layer includes：Polytetrafluoroethylene (PTFE)（PTFE）, polyvinyl chloride（PVC）, polypropylene it is fine（PAN）, gather inclined fluorine
Ethene（PVDF）And dimethyl silicone polymer（PDMS）, the transparent electrode layer 2 is made up of some array arrangements of transparency electrode 4,
The array arrangement mode of transparency electrode 4 includes：Annular array, rectangular array arrangement, irregular array arrangement, Mei Gesuo
State separate between transparency electrode 4, so a small number of failures of transparency electrodes 4 will not bring damage or the non-work of whole device
Make, improve the job stability of generator, the material of the transparency electrode 4 includes：Fluorine doped tin oxide（FTO）, tin indium oxide
（ITO）And Al-Doped ZnO（AZO）, any transparent material can be used in the material of transparent base layer 3, such as：Glass, crystal, thoroughly
Bright plastics etc., when water flow through it is out-of-date, can powered when current pass through isolated pipe or air, and powered current from contact thoroughly
Bright function film layer 1 can produce electrical potential difference, circuit to transparent functional film layer 1 is left between transparent electrode layer 2 and ground electrode
The flowing of electronics will be produced between middle ground electrode and transparent electrode layer 2, this creates the terminal electric energy, the transparent functional is thin
The refractive index of the material of film layer 1 is between air refraction and the Refractive Index of Material of transparent electrode layer 2, and transparent functional film layer 1
Thickness is less than 1 micron, and transparent functional film layer 1 serves the effect of anti-reflection film, and which adds transparent multicomputer nanometer water
The transmitance of power generator, because layer 1 and transparent functional film layer 1 are to sky from transparent electrode layer 2 to transparent functional film
The reflected light of vapor interface generates interference, reduces the reflected light of optics, adds transmitance, whole device is more led to
Thoroughly.
A kind of manufacture method of transparent multicomputer nanometer hydroelectric generator, its step is as follows：
A. there will be fluorine doped tin oxide（FTO）The glass of transparent electrode arrays is positioned in supersonic cleaning machine, is used successively
Clean ten minutes, dry stand-by in acetone, isopropanol and ethanol cleaning, each solution；
B. by polytetrafluoroethylene (PTFE)（PTFE）Emulsion（60%）Dilute, be well mixed stand-by in proportion；
C. covered, then will be diluted the part that transparency electrode is connected with wire is given on glass with Kapton Tape
Polytetrafluoroethylene (PTFE)（PTFE）Emulsion is spin-coated on fluorine doped tin oxide using sol evenning machine（FTO）The glass of transparent electrode arrays
On, 1500 turns of rotating speed, 10 seconds time；
D. the Kapton Tape on the sheet glass after step c processing is removed, sheet glass is placed in 60 degree of bakings in baking oven
It is dry 10 minutes；
E. the sheet glass after step d processing is placed in high temperature furnace into 380 degree to be heated at high temperature two minutes, taking-up is stand-by；
F. each transparency electrode difference connecting wire, and giving over to the part use that transparency electrode is connected with wire in step c
Glue is encapsulated, to prevent water directly contacts transparency electrode from causing short circuit, obtains transparent multicomputer nanometer hydroelectric generator.
Above-mentioned steps are performed in order.
The quantity of transparency electrode 4 of the transparent multicomputer nanometer hydroelectric generator is 2-1000.
The polytetrafluoroethylene (PTFE)（PTFE）The extension rate of emulsion is 4-100 times.
The material for making transparent functional film layer 1 is not limited to above-mentioned polytetrafluoroethylene (PTFE)（PTFE）, it can also be used
He includes material：Polyvinyl chloride（PVC）, polypropylene it is fine（PAN）, Kynoar（PVDF）And dimethyl silicone polymer
（PDMS）.
The material for making transparency electrode 4 is not limited to above-mentioned fluorine doped tin oxide（FTO）, other materials can also be used,
Including：Tin indium oxide（ITO）, Al-Doped ZnO（AZO）.
Emulsion is made in the material for preparing transparent functional film layer 1 by the above method, by controlling its multiple diluted can spirit
The thickness of regulation transparent functional film layer 1 living, emulsion extension rate is bigger, is finally prepared in the case where other conditions are constant
Film thickness it is smaller, it is adaptable to different application occasion, emulsion is uniform and be close to using film made from sol evenning machine spin coating in addition
In transparent electrode layer 2, directly covered compared to using transparent functional film layer, its contact is good, gap influence generating will not be produced
Efficiency.
The beneficial effects of the present invention are realized by the use of array and the transparent functional film layer of transparency electrode
The array of the preparation of transparent multicomputer nanometer hydroelectric generator, transparent functional film layer and transparency electrode can effectively improve generating
The output of machine, may be such that transparent functional film plays anti-reflection film by matching transparent thin film layer, transparency electrode, the refractive index of air
Effect, add the transmitance of whole device, make whole device more penetrating in addition, this generator it is simple in construction, into
This is cheap, has very high efficiency of energy collection compared to single generator, and independent mutually wherein between each transparency electrode,
The failure of indivedual transparency electrodes does not interfere with the operation of whole generating set, and it can collect the current correlation energy in life,
And can further use in the fields such as building, vehicles collection rainwater energy, it is expected to intelligent automobile, smart home realization
Energy supply, has great application prospect.
Claims (10)
1. a kind of manufacture method of transparent multicomputer nanometer hydroelectric generator, it is characterised in that methods described comprises the following steps：
A. the glass with fluorine doped tin oxide FTO transparent electrode arrays is positioned in supersonic cleaning machine, acetone, different is used successively
Clean ten minutes, dry stand-by in propyl alcohol and ethanol cleaning, each solution；
B. concentration is diluted in proportion for 60% polytetrafluoroethylene PTFE emulsion, be well mixed stand-by；
C. covered with Kapton Tape the part that transparency electrode is connected with wire is given on glass, it is then poly- by what is diluted
Tetrafluoroethene PTFE emulsion is spin-coated on the glass with fluorine doped tin oxide FTO transparent electrode arrays using sol evenning machine, rotating speed
1500 turns, 10 seconds time；
D. the Kapton Tape on the sheet glass after step c processing is removed, sheet glass is placed in 60 degree of drying 10 in baking oven
Minute；
E. the sheet glass after step d processing is placed in high temperature furnace into 380 degree to be heated at high temperature two minutes, taking-up is stand-by；
F. each transparency electrode difference connecting wire, and sealed the part that transparency electrode is connected with wire is given in step c with glue
Dress, to prevent water directly contacts transparency electrode from causing short circuit, obtains transparent multicomputer nanometer hydroelectric generator.
2. transparent multicomputer nanometer hydroelectric generator manufacture method according to claim 1, it is characterised in that described poly- four
The extension rate of PVF PTFE emulsion is 4-100 times.
3. transparent multicomputer nanometer hydroelectric generator manufacture method according to claim 2, it is characterised in that described poly- four
PVF PTFE can be replaced：The fine PAN of polyvinylchloride, polypropylene, Kynoar PVDF or dimethyl silicone polymer
PDMS。
4. transparent multicomputer nanometer hydroelectric generator manufacture method according to claim 1, it is characterised in that the fluorine doped
Tin oxide FTO can be replaced：Tin indium oxide ITO or Al-Doped ZnO AZO.
5. transparent multicomputer nanometer hydroelectric generator manufacture method according to claim 1, it is characterised in that described transparent
Number of electrodes is 2~1000.
6. a kind of transparent multicomputer nanometer hydroelectric generator, based on the method described in one of the claims 1-5, using daily
Current in life realize hydroelectric generation, it is characterised in that the transparent multicomputer nanometer hydroelectric generator is by transparent material system
Into.
7. transparent multicomputer nanometer hydroelectric generator according to claim 6, it is characterised in that the transparent multicomputer is received
Rice hydroelectric generator includes：Transparent functional film layer, transparent electrode layer and basalis, the transparent electrode layer are arranged at basalis
Upper surface, transparent functional film layer is arranged at transparent electrode layer upper surface, and wherein transparent functional film layer is hydrophobic film, transparent
Electrode layer is made up of the arrangement of some transparent electrode arrays.
8. transparent multicomputer nanometer hydroelectric generator according to claim 7, it is characterised in that the transparent electrode arrays
Arrangement mode includes：Rectangular array arrangement, annular array, irregular array arrangement.
9. transparent multicomputer nanometer hydroelectric generator according to claim 7, it is characterised in that the transparent functional film
The material of layer includes：The fine PAN of polytetrafluoroethylene PTFE, polyvinylchloride, polypropylene, Kynoar PVDF and poly dimethyl
Siloxanes PDMS.
10. transparent multicomputer nanometer hydroelectric generator according to claim 7, it is characterised in that the transparency electrode
Material includes：Fluorine doped tin oxide FTO or tin indium oxide ITO or Al-Doped ZnO AZO.
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| CN103811663A (en) * | 2014-02-27 | 2014-05-21 | 西南大学 | Annealed free organic solar cell and production method thereof |
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| CN201375515Y (en) * | 2009-04-03 | 2010-01-06 | 复旦大学 | Electric potential mapping electrode of |
| SG178580A1 (en) * | 2009-09-03 | 2012-03-29 | Molecular Nanosystems Inc | Methods and systems for making electrodes having at least one functional gradient therein and devices resulting therefrom |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103137337A (en) * | 2011-11-30 | 2013-06-05 | 现代自动车株式会社 | Dye-sensitized solar cell module using thin glass substrate and method of manufacturing the same |
| CN103811663A (en) * | 2014-02-27 | 2014-05-21 | 西南大学 | Annealed free organic solar cell and production method thereof |
Non-Patent Citations (2)
| Title |
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| Harvesting Water Drop Energy by a Sequential Contact-Electrification and Electrostatic-Induction Process;Zong-Hong Lin等;《ADVANCED MATERIALS》;20140515;第26卷(第27期);第4690-4696页，图1-2 * |
| Linear-Grating Triboelectric Generator Based on Sliding Electrification;Guang Zhu等;《NANO LETTERS》;20130411;第13卷(第5期);第2288页及图6 * |
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