CN104726225B - A kind of acidic cleaning of accompanied with sticky - Google Patents
A kind of acidic cleaning of accompanied with sticky Download PDFInfo
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- CN104726225B CN104726225B CN201310693414.2A CN201310693414A CN104726225B CN 104726225 B CN104726225 B CN 104726225B CN 201310693414 A CN201310693414 A CN 201310693414A CN 104726225 B CN104726225 B CN 104726225B
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- acidic cleaning
- accompanied
- surfactant
- sticky
- acid
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- 238000004140 cleaning Methods 0.000 title claims abstract description 35
- 230000002378 acidificating Effects 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 11
- 102000004190 Enzymes Human genes 0.000 claims abstract description 7
- 108090000790 Enzymes Proteins 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 229940051841 POLYOXYETHYLENE ETHER Drugs 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000005210 alkyl ammonium group Chemical group 0.000 claims abstract description 4
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 4
- -1 alkyl dimethyl Amine Chemical compound 0.000 claims description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 8
- 229940088598 Enzyme Drugs 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004382 Amylase Substances 0.000 claims description 4
- 102000013142 Amylases Human genes 0.000 claims description 4
- 108010065511 Amylases Proteins 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229940106157 CELLULASE Drugs 0.000 claims description 2
- 108010059892 Cellulase Proteins 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 240000000218 Cannabis sativa Species 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 230000003213 activating Effects 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 3
- 239000002280 amphoteric surfactant Substances 0.000 abstract description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 230000002195 synergetic Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003599 detergent Substances 0.000 description 4
- 235000011167 hydrochloric acid Nutrition 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N Nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- 235000015450 Tilia cordata Nutrition 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- KHSLHYAUZSPBIU-UHFFFAOYSA-M Benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229910052904 quartz Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 101700085747 sor Proteins 0.000 description 2
- 101710037885 sorF Proteins 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- KWXICGTUELOLSQ-UHFFFAOYSA-N 4-Dodecylbenzenesulfonic Acid Chemical compound CCCCCCCCCCCCC1=CC=C(S(O)(=O)=O)C=C1 KWXICGTUELOLSQ-UHFFFAOYSA-N 0.000 description 1
- 101700086558 CELA1 Proteins 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L Calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- CXRFDZFCGOPDTD-UHFFFAOYSA-M Cetrimide Chemical compound [Br-].CCCCCCCCCCCCCC[N+](C)(C)C CXRFDZFCGOPDTD-UHFFFAOYSA-M 0.000 description 1
- 102000033147 ERVK-25 Human genes 0.000 description 1
- 229940088597 Hormone Drugs 0.000 description 1
- 229940040461 Lipase Drugs 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241000498779 Myristica Species 0.000 description 1
- 235000009421 Myristica fragrans Nutrition 0.000 description 1
- 108091005771 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzyl-dodecyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 101710014338 eglS Proteins 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004676 glycans Polymers 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 102000004882 lipase Human genes 0.000 description 1
- 108090001060 lipase Proteins 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001702 nutmeg Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019833 protease Nutrition 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000001502 supplementation Effects 0.000 description 1
Abstract
A kind of acidic cleaning of accompanied with sticky, component and mass percent are：Amphoteric surfactant α carboxyls alkyl dimethyl amine oxides 1% 5%, cationic surfactant long chain alkyl ammonium salt 0.5% 3%, nonionic surfactant fatty alcohol polyoxyethylene ether 1% 3%, acid cleaner 10% 20%, enzyme preparation 1% 3%, essence 0.5% 1%, surplus is water, amounts to 100%.The synergistic effect that acidic cleaning provided by the invention is only relied between surfactant can play the effect of thickening, in addition not add thickener, and preparing process is simple, production cost is relatively low, and product viscosity is big, convenient for being attached to the surface of solids, cleaning efficiency is high, and speed is fast, safe and reliable.
Description
Technical field
The invention belongs to detergents and cosmetic technical fields, and in particular to a kind of acidic cleaning of accompanied with sticky.
Background technology
Detergent can be divided into liquid form product, creamy product and powder product.Liquid cleaning agent is because its manufacturing process is simple, removes
Dirty efficiency is fast, easy to use, using more in life.At some Code in Hazardous Special Locations such as hard surfaces such as water closet pan, closestool, it is primarily present
The dirts such as calcium soap, organic matter and iron rust, these dirt strong adsorptions, ingredient is special, and therefore, such liquid cleaner should be acid
Product.At present, market liquid acidic cleaning product viscosity is very low, and cleaning agent and dirt are attached in vertical surface or inclined surface
That the time is short, and retention amount is lacked, and cleaning performance is poor, causes the wasting of resources.Since product viscosity is too low, also there are Product transport processes
In safety issue.
There are mainly three types of the methods reported in the literature at present that acidic cleaner can be used to thickening：Use dodecyl benzene sulfonic acid
Compatibility can effectively thicken acid solution sodium by a certain percentage with nonylphenol polyoxyethylene ether；With long-chain alkyl amine oxide or two
The mixture of methyl nutmeg amine oxide and chain alkyl trimethyl quaternary ammonium salt (the two ratio is respectively 1: 5 and 1: 1) can be effective
Thickening；Polysaccharide compound (xanthans), colloidal state SiO2Addition also can effectively increase the viscosity of acid solution.But these sides
Method there are it is apparent the defects of：It can be analyzed to Environmental Hormone Nonylphenol in nonylphenol polyoxyethylene ether natural environment, limited
It uses；And traditional alkyl amine oxide is expensive, formulation cost is excessively high；Xanthans, the easy Precipitations of colloidal state SiO2.
The content of the invention
It is an object of the invention to provide one kind can meet environmental requirement, while have the accompanied with sticky of preferable cost performance again
Acidic cleaning.α-carboxyl alkyl dimethyl amine oxides are added in formula, can be risen with other surfactant compounds
To good thickening effect.At low cost by α-carboxyl alkyl dimethyl amine oxides of natural fatty acids, easily biology drops
Solution, obtained detergent prepare simple and cost economy, possess moderately good viscosity, also have environmental protection, efficiently, cleaning performance
The characteristics of good.
The acidic cleaning of the present invention, component are with mass percent：Amphoteric surfactant α-carboxyl chain alkyl
Dimethyl amine 1%-5%, cationic surfactant long chain alkyl ammonium salt 0.5%-3%, nonionic surfactant
Fatty alcohol polyoxyethylene ether 1%-3%, acid cleaner 10%-20%, enzyme preparation 1%-3%, essence 0.5%-1%, surplus are
Water amounts to 100%.
The purpose of the present invention can reach by the following technical solutions：By proportioning by α-carboxyl long chain alkyl dimethyl oxygen
Change amine and long chain alkyl ammonium salt to be dissolved in the water, stir 15 minutes, add in fatty alcohol polyoxyethylene ether, it is to be mixed uniformly after,
Acid cleaner is added in, is stirred 30 minutes, then adds enzyme preparation and essence, the water for supplementing surplus stirs evenly.α-carboxyl is long
Alkyl group dimethyl amine, a length of C of carbochain12~C18；Cationic surfactant is chain alkyl trimethylammonium bromide, length
The one of which of alkyl group dimethyl benzyl ammonium chloride, long chain alkyl dimethyl Benzylphosphonium Bromide ammonium, a length of C of alkyl carbon chain12~
C16；Nonionic surfactant is one kind in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether；Acid cleaner
Select hydrochloric acid, oxalic acid, formic acid or phosphoric acid；Enzyme preparation selection lipase, amylase, protease or cellulase.
Beneficial effects of the present invention：
(1) α-carboxyl alkyl dimethyl amine oxides used in the present invention are a kind of new with amine oxide group
Surfactant, avoiding using traditional long-chain alkyl amine oxide, can obtain the sticky acid clean that cheap, performance is stablized
Agent.
(2) acidic cleaning preparing process of the invention is simple, and detergent can be attached to the surface of solids, and cleaning efficiency is high,
Speed is fast, safe and reliable.
Specific embodiment
Embodiment 1 is furnished with the acidic cleaning of 3.5% α-carboxyl Dimethylnonylamine oxide
| Material name | Mass percentage (%) in formula |
| α-carboxyl nonyl dimethyl amine | 3.5 |
| Cetyl trimethylammonium bromide | 1.5 |
| Aliphatic alcohol polyethenoxy (7) ether | 1 |
| Hydrochloric acid (36%) | 18 |
| Amylase | 1 |
| Essence | 0.5 |
| Water | It supplies to 100 |
Embodiment 2 is furnished with the acidic cleaning of 5% α-carboxyl undecyl dimethyl amine
| Material name | Mass percentage (%) in formula |
| α-carboxyl undecyl dimethyl amine | 5 |
| Cetyl trimethylammonium bromide | 3 |
| Aliphatic alcohol polyethenoxy (9) ether | 3 |
| Hydrochloric acid (36%) | 20 |
| Protease | 3 |
| Essence | 1 |
| Water | It supplies to 100 |
Embodiment 3 is furnished with the acidic cleaning of 4.8% α-carboxytridecyl dimethyl amine
Embodiment 4 is furnished with the acidic cleaning of 4.2% α-carboxypentadecyl dimethyl amine
| Material name | Mass percentage (%) in formula |
| α-carboxypentadecyl dimethyl amine | 4.2 |
| Dodecyl benzyl dimethyl ammonium chloride | 1 |
| Aliphatic alcohol polyethenoxy (9) ether | 2 |
| Oxalic acid | 15 |
| Protease | 3 |
| Essence | 0.5 |
| Water | It supplies to 100 |
Embodiment 5 is furnished with the acidic cleaning of 1% α-carboxypentadecyl dimethyl amine
| Material name | Mass percentage (%) in formula |
| α-carboxypentadecyl dimethyl amine | 1 |
| Dodecyl dimethyl benzyl ammonium bromide | 0.5 |
| Aliphatic alcohol polyethenoxy (9) ether | 2.5 |
| Hydrochloric acid (36%) | 15 |
| Cellulase | 2 |
| Essence | 1 |
| Water | It supplies to 100 |
Embodiment 6 is furnished with the acidic cleaning of 4% α-carboxyheptadecyl dimethyl amine
| Material name | Mass percentage (%) in formula |
| α-carboxyheptadecyl dimethyl amine | 4 |
| Dodecyl dimethyl benzyl ammonium bromide | 1.2 |
| Aliphatic alcohol polyethenoxy (7) ether | 1.5 |
| Phosphoric acid (85%) | 10 |
| Amylase | 1 |
| Essence | 0.5 |
| Water | It supplies to 100 |
Cleaning effect：
With reference to patent CN100487099C, by cleaning lime scale, the cleaning effect of acidic cleaning is evaluated.Tool
Body operating method is：When the Dali stone ceramic tile 1 that cleaning and dry size are 800mm × 800mm × 30mm at 80 DEG C is small.Then
It weighs to these bricks, is impregnated 10 seconds in 900mL test preparations, remove and stand 10 minutes.Then these are thoroughly cleaned
Brick, when with towel and re-dry 1 is small at 80 DEG C.Then thoroughly cool down and weigh again, pass through meter of poor quality twice
Calculate the loss proportion of lime scale.
The cleaning effect of embodiment such as following table：
| Example 1 | Example 2 | Example 3 | Example 4 | Embodiment 5 | It is commercially available | |
| Lime scale mass loss % | 0.0052 | 0.0055 | 0.0104 | 0.01032 | 0.0191 | 0.052 |
Acidic cleaner of the present invention is compared with the wall built-up performance of commercial product：
The wall brick of 25 × 33cm is selected, surface keeps smooth (make liquid can streamlined flow), when recording 25 DEG C with stopwatch
Sample flow time.Concrete operation method is as follows：Wall brick near vertical is put in desktop, draws 0.5 ± 0.01g sample drops in wall
Brick one end records the time, when the sample flow wall brick other end, stops timing.
Example 1 and 1,2,3 result of the test of commercial product are as follows：
| Sample | Example 5 | Embodiment 6 | Commercially available 1 | Commercially available 2 | Commercially available 3 |
| Residence time/s | 465 | 505 | 30 | 80 | 65 |
Using the acidic cleaning cleaning closestool of the present invention, accomodation ground when hard surfaces, infiltration in 5-8 minute is only needed,
It is rinsed again with clear water, you can reach preferable cleannes.
Claims (6)
1. a kind of acidic cleaning of accompanied with sticky, component presses following mass percentage composition：α-carboxyl long chain alkyl dimethyl
Amine oxide surfactant 1%-5%, cationic surfactant long chain alkyl ammonium salt 0.5%-3%, non-ionic surface are lived
Property agent fatty alcohol polyoxyethylene ether 1%-3%, acid cleaner 10%-20%, enzyme preparation 1%-3%, essence 0.5%-1% are remaining
It measures as water, amounts to 100%.
2. the acidic cleaning of a kind of accompanied with sticky according to claim 1, which is characterized in that contain α-carboxylic in the component
Base long linear alkyl dimethyl amine oxide surfactant, carbon chain length C12~C18, content is not less than 1%.
A kind of 3. acidic cleaning of accompanied with sticky according to claim 1, which is characterized in that the cation surface activating
Agent is quaternary surfactant, i.e. chain alkyl trimethyl quaternary ammonium salt or long chain alkyl dimethyl benzyl quaternary ammonium salt, carbon chain length
For C12~C16。
4. a kind of acidic cleaning of accompanied with sticky according to claim 1, it is characterized in that, nonionic surfactant is fat
One kind in fat alcohol polyoxyethylene (7) ether, aliphatic alcohol polyethenoxy (9) ether.
5. a kind of acidic cleaning of accompanied with sticky according to claim 1, it is characterized in that, acid cleaner selection hydrochloric acid, grass
Acid, formic acid or phosphoric acid.
6. a kind of acidic cleaning of accompanied with sticky according to claim 1, it is characterized in that, enzyme preparation selection amylase, egg
White enzyme or cellulase.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310693414.2A CN104726225B (en) | 2013-12-18 | 2013-12-18 | A kind of acidic cleaning of accompanied with sticky |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310693414.2A CN104726225B (en) | 2013-12-18 | 2013-12-18 | A kind of acidic cleaning of accompanied with sticky |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104726225A CN104726225A (en) | 2015-06-24 |
| CN104726225B true CN104726225B (en) | 2018-05-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310693414.2A Expired - Fee Related CN104726225B (en) | 2013-12-18 | 2013-12-18 | A kind of acidic cleaning of accompanied with sticky |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104726225B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107034475B (en) * | 2017-05-05 | 2019-06-18 | 奎克化学（中国）有限公司 | A kind of super-pressure spray cleaning agent and its preparation method and application |
| CN107929168A (en) * | 2017-12-28 | 2018-04-20 | 江南大学 | A kind of moisturizing betaplex gentle cleansing milk |
| CN108948896A (en) * | 2018-08-01 | 2018-12-07 | 张顺林 | A kind of metope interfacial agents and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0060710A1 (en) * | 1981-03-17 | 1982-09-22 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions containing alpha-amine oxide surfactants |
| US4359413A (en) * | 1981-03-17 | 1982-11-16 | The Procter & Gamble Company | Solid detergent compositions containing alpha-amine oxide surfactants |
| CN1354243A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Preparation method of liquid toilet pan cleaning agent |
-
2013
- 2013-12-18 CN CN201310693414.2A patent/CN104726225B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0060710A1 (en) * | 1981-03-17 | 1982-09-22 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions containing alpha-amine oxide surfactants |
| US4359413A (en) * | 1981-03-17 | 1982-11-16 | The Procter & Gamble Company | Solid detergent compositions containing alpha-amine oxide surfactants |
| CN1354243A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Preparation method of liquid toilet pan cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 天然脂肪酸衍生的α-羧基长链烷基氧化胺的性能研究;胡瑜、齐丽云等;《新技术新产品》;20120615(第6期);第43-45页 * |
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