CN104726024B - A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof - Google Patents
A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof Download PDFInfo
- Publication number
- CN104726024B CN104726024B CN201510108997.7A CN201510108997A CN104726024B CN 104726024 B CN104726024 B CN 104726024B CN 201510108997 A CN201510108997 A CN 201510108997A CN 104726024 B CN104726024 B CN 104726024B
- Authority
- CN
- China
- Prior art keywords
- component
- rubber
- butadiene
- rapid hardening
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of spraying rapid hardening modified waterproof asphalt materials, including component A and B component, component A to include：Rubber, pitch, softening agent, anion surfactant, stabilizer and water；B component includes inorganic salts, Complex aluminium-iron polymer and deionized water.Component A and B component are prepared respectively, are then applied again.The coating avoids pitch and mixes uneven situation with latex；It avoids simultaneously using anionic latex, larger reduces production cost, in actual industrial production and application, has important practical significance.
Description
Technical field
The present invention relates to a kind of coating in building field, and in particular to a kind of spraying rapid hardening modified waterproof asphalt material and
Preparation method.
Background technology
Spraying rapid hardening technology is one of the newest fruits of recent domestic building material industry, and cardinal principle is to pass through special process
Ultra-fine, suspension, the modified anion emulsified asphalt of micro-emulsion type and synthesising macromolecule copolymer are formulated, then cured with special type
Agent mixing, a kind of waterproof haveing excellent performance generated after reacting, antiseepage, anti-corrosion, protective coating.Due to its construction is simple, performance
It is excellent, it is increasingly improved in the status in buildings waterproof field.
It is adaptable to base to spray rapid hardening rubber asphalt, can be used for armored concrete, profiled sheet, plastics and each
On the base materials such as kind building material；Sprayed surface processing is easy, and no particular/special requirement can not do screed-coat, be less than in wetness
It can directly construct in the case of 80%；It in work progress, can work continuously, be free of volatile organic compounds, nontoxic nothing
Taste, non-exhaust emission is free from environmental pollution, can be adapted in closed space；Coating is weather-proof, resistance to acid and alkali, ageing-resistant performance
It is superior, without face layer protective layer, can effectively reduce engineering cost；Service life is up to 50 years or more, under not less than 5 DEG C environment
It can be used, the outstanding antistripping of comparative superiority, puncture resistant ability；It is i.e. plastic in 3-5 seconds after spraying, it can trample, and have
Surmount 15 times of ductility and 95% restoration and effective sound insulation value；A variety of forms of construction work (spraying, brushing etc.), flexibly letter
Just, the function demand superelevation elongation that can meet the various environment such as discharge outlet, parapet, negative and positive angle, cracking position, in this way may be used
To solve the leakage occurred because of stress deformation.Because it is spraying rapid hardening construction, it is possible to quickly form a tunic, lead
Cause its non-series-water.Patent CN 103627258A disclose a kind of spraying rapid hardening rubber asphalt preparation method, are mainly characterized by applying
Work is efficient, and adhesion strength is big, and high-low temperature resistant, while having higher elongation percentage.
Nevertheless, spraying rapid hardening rubber asphalt also has its shortcoming at present, for example asphalt emulsion and rubber latex are mixed
It closes uneven, leads to properties of product existing defects；The anionic emulsion cost of raw material is higher etc..
Invention content
The object of the present invention is to provide a kind of spraying rapid hardening modified waterproof asphalt materials and preparation method thereof.The mesh of the present invention
Be to be achieved through the following technical solutions：
A kind of spraying rapid hardening modified waterproof asphalt material, including component A and B component, the component A include：Rubber, drip
Blueness, softening agent, anion surfactant, stabilizer and water；The B component includes：Inorganic salts, Complex aluminium-iron polymer
And deionized water.
Further, the component A includes by percentage to the quality：Rubber 10-20%, pitch 30-40%, softening agent
5-15%, anion surfactant 3-4%, stabilizer 0.05-0.1% and water 40-45%；The B component is with quality
Percentages include：Inorganic salts 8-18%, Complex aluminium-iron polymer 1-5% and deionized water 77-91%.
Further, the component A includes by percentage to the quality：Rubber 13-18%, pitch 32-37%, softening agent
8-12%, anion surfactant 3.3-3.6%, stabilizer 0.06-0.08% and water 40-45%；The B component with
Mass percent meter includes：Inorganic salts 11-15%, Complex aluminium-iron polymer 2-3.5% and deionized water 77-91%.
Further, the softening agent is aromatic hydrocarbons oleoresin (referring to aromatic naphtha), coumarone indene resin and C9 Petropols
At least one of.
Further, the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, chlorine
At least one of buna and butadiene-styrene block copolymer rubber.
Further, the anion surfactant is tall oil sulfonate, alkylsulfonate, alkyl benzene sulphonate
At least one of salt, alkyl sulfate and lignosulfonates.
Further, it is 8-18 in the alkyl institute carbon atom quantity of the anion surfactant.
Further, the alkyl institute carbon atom quantity in the anion surfactant is 11-15.
Further, the stabilizer is polyvinyl alcohol, polyurethane, polyacrylamide, hydroxyethyl cellulose, carboxymethyl
At least one of sodium cellulosate and bentonite.
Further, the inorganic salts are at least one of calcium chloride, sodium chloride and ammonium chloride.
A kind of preparation method of the spraying rapid hardening modified waterproof asphalt material, the preparation method includes component A
Preparation and B component preparation；
(1) preparation of component A：The pitch that parts by weight are 30-40 parts is added in reaction kettle and is warming up to 200 ± 10 by S1
DEG C, 5-15 parts of softening agent and 10-20 parts of rubber are added, 2h is stirred, colloid mill is opened, material is passed through by present retort
It squeezes into another empty retort, grinds one time after colloid mill；After the completion of grinding, stirs 1 hour, obtain modified pitch；S2 will be weighed
Amount number is the water of 40-45 parts that 3-4 parts of anion surfactant and 0.05-0.1 parts of stabilizer are dissolved in 40-80 DEG C
In, it is made into soap lye；Modified pitch in step S1 is added in colloid mill with the soap lye in step S2 through mechanism S3 simultaneously
Generate anion-modified asphalt emulsion, i.e. component A；
(2) preparation of B component：It is that 8-18 parts of inorganic salts and 1-5 parts of Complex aluminium-iron polymer are dissolved in by parts by weight
In 77-91 parts of deionized water, B component is obtained, it is spare；
(3) A, B component are sprayed with dedicated spraying equipment.
The present invention provides a kind of spraying rapid hardening modified waterproof asphalt materials and preparation method thereof, and what is mainly had is beneficial
Effect is：The coating not only has waterproof, antiseepage, anti-corrosion, high-low temperature resistant adaptable to base, sprayed surface processing letter
Just, long lifespan, molding be fast, form of construction work diversification, to be environmental-friendly without volatile organic compounds, non-toxic and tasteless
Type coating；And the more existing coating of properties of product of the coating have promoted by a relatively large margin, construction efficiency higher, adhesion strength
Bigger, and there is higher elongation percentage；Importantly, since the coating is using further modified method, pitch is avoided
Uneven situation is mixed with latex；It avoids simultaneously using anionic latex, larger reduces production cost, in practical work
During industry is produced and applied, there is important practical significance.
Specific implementation mode
A kind of spraying rapid hardening modified waterproof asphalt material described in the embodiment of the present invention and preparation method thereof, below with specific
Illustrate specific implementation mode for experiment case study, it should be understood that specific embodiment described herein is only used to explain this
Invention, is not intended to limit the present invention.
Embodiment 1
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber,
Pitch, softening agent, anion surfactant, stabilizer and water；The B component includes：Inorganic salts, Complex aluminium-iron polymerization
Object and deionized water.
Embodiment 2
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber
10kg, pitch 40kg, softening agent 5kg, anion surfactant 4kg, stabilizer 0.05kg and water 45kg；The B groups
Divide and includes：Inorganic salts 8kg, Complex aluminium-iron polymer 5kg and deionized water 77kg.
The composition of the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene rubber
At least one of glue and butadiene-styrene block copolymer rubber, such as the rubber can be specially：1. butadiene-styrene rubber；
2. neoprene；3. butadiene-styrene block copolymer rubber；4. EP rubbers and butadiene-styrene block copolymer
Rubber；5., isoprene rubber and neoprene；6. butadiene-styrene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；7. nitrile rubber, EP rubbers and neoprene；8. butadiene rubber, EP rubbers, isoprene rubber and butadiene-benzene second
Alkene block copolymer rubber；9. EP rubbers, isoprene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；10. butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene are embedding
Section copolymer rubber.
The softening agent is aromatic naphtha.
The anion surfactant is tall oil sulfonate, alkylsulfonate, alkylbenzene sulfonate, alkylsurfuric acid
Salt and lignosulfonates.Wherein, the carbon contained by the alkyl in alkylsulfonate, alkylbenzene sulfonate and alkyl sulfate is former
Subnumber amount be 8-18, preferably 11~15.
The stabilizer is polyvinyl alcohol.
The inorganic salts are calcium chloride.
Embodiment 3
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber
20kg, pitch 30kg, softening agent 15kg, anion surfactant 3kg, stabilizer 0.1kg and water 40kg；The B groups
Divide and includes：Inorganic salts 18kg, Complex aluminium-iron polymer 1kg and deionized water 91kg.
The composition of the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene rubber
At least one of glue and butadiene-styrene block copolymer rubber, such as the rubber can be specially：1. butadiene-styrene rubber；
2. neoprene；3. butadiene-styrene block copolymer rubber；4. EP rubbers and butadiene-styrene block copolymer
Rubber；5., isoprene rubber and neoprene；6. butadiene-styrene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；7. nitrile rubber, EP rubbers and neoprene；8. butadiene rubber, EP rubbers, isoprene rubber and butadiene-benzene second
Alkene block copolymer rubber；9. EP rubbers, isoprene rubber, neoprene and butadiene-styrene block copolymer rubber；
10. butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene block
Copolymer rubber.
The softening agent is coumarone indene resin and C9 Petropols.
The anion surfactant is alkylsulfonate, alkylbenzene sulfonate, alkyl sulfate and lignin
Sulfonate.Wherein, the amount of carbon atom contained by the alkyl in alkylsulfonate is 11, contained by the alkyl in alkylbenzene sulfonate
Amount of carbon atom is 13, and the amount of carbon atom contained by alkyl in alkyl sulfate is 14.
The stabilizer is hydroxyethyl cellulose.
The inorganic salts are sodium chloride.
Embodiment 4
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber
13kg, pitch 37kg, softening agent 8kg, anion surfactant 3.6kg, stabilizer 0.06kg and water 45kg；The B
Component includes：Inorganic salts 15kg, Complex aluminium-iron polymer 2kg and deionized water 91kg.
The composition of the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene rubber
At least one of glue and butadiene-styrene block copolymer rubber, such as the rubber can be specially：1. butadiene-styrene rubber；
2. neoprene；3. butadiene-styrene block copolymer rubber；4. EP rubbers and butadiene-styrene block copolymer
Rubber；5., isoprene rubber and neoprene；6. butadiene-styrene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；7. nitrile rubber, EP rubbers and neoprene；8. butadiene rubber, EP rubbers, isoprene rubber and butadiene-benzene second
Alkene block copolymer rubber；9. EP rubbers, isoprene rubber, neoprene and butadiene-styrene block copolymer rubber；
10. butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene block
Copolymer rubber.
The softening agent is C9 Petropols.
The anion surfactant is tall oil sulfonate, alkylbenzene sulfonate and lignosulfonates.Its
In, the amount of carbon atom contained by alkyl in alkylbenzene sulfonate is 15.
The stabilizer is polyurethane and sodium carboxymethylcellulose.
The inorganic salts are ammonium chloride.
Embodiment 5
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber
18kg, pitch 32kg, softening agent 12kg, anion surfactant 3.3kg, stabilizer 0.08kg and water 40kg；The B
Component includes：Inorganic salts 11kg, Complex aluminium-iron polymer 3.5kg and deionized water 77kg.
The composition of the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene rubber
At least one of glue and butadiene-styrene block copolymer rubber, such as the rubber can be specially：1. butadiene-styrene rubber；
2. neoprene；3. butadiene-styrene block copolymer rubber；4. EP rubbers and butadiene-styrene block copolymer
Rubber；5., isoprene rubber and neoprene；6. butadiene-styrene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；7. nitrile rubber, EP rubbers and neoprene；8. butadiene rubber, EP rubbers, isoprene rubber and butadiene-benzene second
Alkene block copolymer rubber；9. EP rubbers, isoprene rubber, neoprene and butadiene-styrene block copolymer rubber；
10. butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene block
Copolymer rubber.
The softening agent is aromatic naphtha and coumarone indene resin.
The anion surfactant is alkyl sulfate.Wherein, the carbon contained by the alkyl in alkyl sulfate is former
Subnumber amount is 12.
The stabilizer is polyacrylamide, hydroxyethyl cellulose and bentonite.
The inorganic salts are calcium chloride and ammonium chloride.
Embodiment 6
Novel spraying rapid hardening modified waterproof asphalt material：Including component A and B component, the component A includes：Rubber
15kg, pitch 34kg, softening agent 10kg, anion surfactant 3.5kg, stabilizer 0.07kg and water 43kg；The B
Component includes：Inorganic salts 13kg, Complex aluminium-iron polymer 3kg and deionized water 85kg.
The composition of the rubber is butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene rubber
At least one of glue and butadiene-styrene block copolymer rubber, such as the rubber can be specially：1. butadiene-styrene rubber；
2. neoprene；3. butadiene-styrene block copolymer rubber；4. EP rubbers and butadiene-styrene block copolymer
Rubber；5., isoprene rubber and neoprene；6. butadiene-styrene rubber, neoprene and butadiene-styrene block copolymer rubber
Glue；7. nitrile rubber, EP rubbers and neoprene；8. butadiene rubber, EP rubbers, isoprene rubber and butadiene-benzene second
Alkene block copolymer rubber；9. EP rubbers, isoprene rubber, neoprene and butadiene-styrene block copolymer rubber；
10. butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene block
Copolymer rubber.
The softening agent is aromatic naphtha, coumarone indene resin and C9 Petropols.
The anion surfactant is tall oil sulfonate.
The stabilizer is polyvinyl alcohol, polyurethane, polyacrylamide, hydroxyethyl cellulose, sodium carboxymethylcellulose
And bentonite.
The inorganic salts are calcium chloride, sodium chloride and ammonium chloride.
Embodiment 7
The preparation method of novel spraying rapid hardening modified waterproof asphalt material, including the preparation of component A and the preparation of B component；
(1) preparation of component A：S1：Quantitative pitch is added in reaction kettle and is warming up to 190 DEG C, adds quantitative softening agent and rubber
Glue stirs 2h, opens colloid mill, and material is squeezed into another empty retort by present retort after colloid mill, is ground one time；
After the completion of grinding, stirs 1 hour, obtain modified pitch；S2：Quantitative anion surfactant and stabilizer are dissolved in 40 DEG C
Water in, be made into soap lye；S3：Modified pitch in step S1 is added in colloid mill with the soap lye in step S2 through machine simultaneously
Tool effect generates anion-modified asphalt emulsion, i.e. component A；
(2) preparation of B component：Quantitative inorganic salts and Complex aluminium-iron polymer are dissolved in deionized water, B groups are obtained
Point, it is spare；
(3) component A and B component are sprayed with dedicated spraying equipment, component A and B component special are set relevant
The standby automatic novel mixing of middle meeting.
Wherein, above-mentioned rubber, pitch, softening agent, anion surfactant, stabilizer, water, inorganic salts, clad aluminum
The content and composition of iron polymer and deionized water do not do repetition restriction herein with shown in Examples 1 to 6.
Embodiment 8
The preparation method of novel spraying rapid hardening modified waterproof asphalt material, including the preparation of component A and the preparation of B component；
(1) preparation of component A：S1：Quantitative pitch is added in reaction kettle and is warming up to 200 DEG C, then is proportionally added into softening agent and rubber
Glue stirs 2h, opens colloid mill, and material is squeezed into another empty retort by present retort after colloid mill, is ground one time；
After the completion of grinding, stirs 1 hour, obtain modified pitch；S2：Anion surfactant and stabilizer are dissolved in 80 DEG C in proportion
Water in, be made into soap lye；S3：Modified pitch in step S1 is added in colloid mill with the soap lye in step S2 through machinery simultaneously
Effect generates anion-modified asphalt emulsion, i.e. component A；
(2) preparation of B component：Inorganic salts and Complex aluminium-iron polymer are dissolved in deionized water in proportion, obtain B groups
Point, it is spare；
(3) component A and B component are sprayed with dedicated spraying equipment.
Wherein, above-mentioned rubber, pitch, softening agent, anion surfactant, stabilizer, water, inorganic salts, clad aluminum
The content and composition of iron polymer and deionized water do not do repetition restriction herein with shown in Examples 1 to 6.
Embodiment 9
The preparation method of novel spraying rapid hardening modified waterproof asphalt material, including the preparation of component A and the preparation of B component；
(1) preparation of component A：S1：Quantitative pitch is added in reaction kettle and is warming up to 210 DEG C, then is proportionally added into softening agent and rubber
Glue stirs 2h, opens colloid mill, and material is squeezed into another empty retort by present retort after colloid mill, is ground one time；
After the completion of grinding, stirs 1 hour, obtain modified pitch；S2：Anion surfactant and stabilizer are dissolved in 60 DEG C in proportion
Water in, be made into soap lye；S3：Modified pitch in step S1 is added in colloid mill with the soap lye in step S2 through machinery simultaneously
Effect generates anion-modified asphalt emulsion, i.e. component A；
(2) preparation of B component：Inorganic salts and Complex aluminium-iron polymer are dissolved in deionized water in proportion, obtain B groups
Point, it is spare；
(3) component A and B component are sprayed with dedicated spraying equipment.
Wherein, above-mentioned rubber, pitch, softening agent, anion surfactant, stabilizer, water, inorganic salts, clad aluminum
The content and composition of iron polymer and deionized water do not do repetition restriction herein with shown in Examples 1 to 6.
The present invention is not limited to above-mentioned preferred forms, anyone under the inspiration of the present invention made by the related present invention
Any modification or change, it is every have technical solution identical or similar to the present application, all fall within the present invention protection model
Within enclosing.
Claims (7)
1. a kind of spraying rapid hardening modified waterproof asphalt material, including component A and B component, it is characterised in that：The component A with
Mass percent meter includes：Rubber 10-20%, pitch 30-40%, softening agent 5-15%, anion surfactant 3-4%,
Stabilizer 0.05-0.1% and water 40-45%；
The B component includes by percentage to the quality：Inorganic salts 8-18%, Complex aluminium-iron polymer 1-5% and deionization
Water 77-91%；
The softening agent is at least one of aromatic naphtha, coumarone indene resin and C9 Petropols, the anionic surface
Activating agent be tall oil sulfonate, alkylsulfonate, alkylbenzene sulfonate, alkyl sulfate and lignosulfonates in extremely
Few one kind；
The preparation method of the spraying rapid hardening modified waterproof asphalt material includes the preparation of component A and the preparation of B component；
(1) preparation of component A：
The pitch that mass percent is 30-40% is added in reaction kettle and is warming up to 190~210 DEG C by S1, adds 5-15%'s
The rubber of softening agent and 10-20% stirs 2h, opens colloid mill, material is squeezed into after colloid mill by present retort another
In empty retort, grind one time；After the completion of grinding, stirs 1 hour, obtain modified pitch；
The stabilizer of anion surfactant and 0.05-0.1% that mass percent is 3-4% is dissolved in 40-80 DEG C by S2
In the water of 40-45%, it is made into soap lye；
S3 by the soap lye in modified pitch and the step S2 in step S1 be added simultaneously in colloid mill through mechanism generate it is cloudy from
Sub- modified pitch emulsion, i.e. component A；
(2) preparation of B component：
The Complex aluminium-iron polymer of inorganic salts and 1-5% that mass percent is 8-18% is dissolved in the deionized water of 77-91%
In, B component is obtained, it is spare；
(3) it is sprayed in use, spraying equipment is added in component A and B component.
2. spraying rapid hardening modified waterproof asphalt material according to claim 1, it is characterised in that：The component A is with matter
Measuring percentages includes：Rubber 13-14.2%, pitch 32-37%, softening agent 8-12%, anion surfactant 3.3-
3.6%, stabilizer 0.06-0.08% and water 40-45%；The B component includes by percentage to the quality：Inorganic salts 11-
15%, Complex aluminium-iron polymer 2-3.5% and deionized water 77-84.2%.
3. spraying rapid hardening modified waterproof asphalt material according to claim 1 or 2, it is characterised in that：The rubber is
Butadiene-styrene rubber, butadiene rubber, nitrile rubber, EP rubbers, isoprene rubber, neoprene and butadiene-styrene block are total
At least one of copolymer rubber.
4. spraying rapid hardening modified waterproof asphalt material according to claim 1, it is characterised in that：In the anion table
Alkyl institute carbon atom quantity in the activating agent of face is 8-18.
5. spraying rapid hardening modified waterproof asphalt material according to claim 4, it is characterised in that：In the anion table
Alkyl institute carbon atom quantity in the activating agent of face is 11-15.
6. spraying rapid hardening modified waterproof asphalt material according to claim 1 or 2, it is characterised in that：The stabilizer
For at least one in polyvinyl alcohol, polyurethane, polyacrylamide, hydroxyethyl cellulose, sodium carboxymethylcellulose and bentonite
Kind.
7. spraying rapid hardening modified waterproof asphalt material according to claim 1 or 2, it is characterised in that：The inorganic salts
For at least one of calcium chloride, sodium chloride and ammonium chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510108997.7A CN104726024B (en) | 2015-03-12 | 2015-03-12 | A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510108997.7A CN104726024B (en) | 2015-03-12 | 2015-03-12 | A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104726024A CN104726024A (en) | 2015-06-24 |
| CN104726024B true CN104726024B (en) | 2018-08-17 |
Family
ID=53450466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510108997.7A Active CN104726024B (en) | 2015-03-12 | 2015-03-12 | A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104726024B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118695B (en) * | 2017-04-10 | 2019-12-10 | 中国铁道科学研究院金属及化学研究所 | Rubber modified asphalt waterproof coating and preparation method and use method thereof |
| CN108727984A (en) * | 2018-06-15 | 2018-11-02 | 安徽艾米伦特建材科技有限公司 | Chloroprene rubber waterproof coating and preparation method thereof |
| CN110760265A (en) * | 2019-10-29 | 2020-02-07 | 山东北方创信防水科技股份有限公司 | Preparation method of secondary alkyl sodium sulfonate emulsified asphalt waterproof coating |
| CN111690152B (en) * | 2020-07-08 | 2023-03-24 | 中铁四局集团有限公司 | Rubber modified asphalt latex and preparation method and application thereof |
| CN113402984A (en) * | 2021-07-08 | 2021-09-17 | 克拉玛依友联工程建设有限公司 | Spraying quick-setting rubber asphalt waterproof coating and preparation method thereof |
| CN114716834B (en) * | 2022-04-11 | 2023-04-25 | 山东京博石油化工有限公司 | Modified emulsified asphalt, preparation method and application thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5936015A (en) * | 1998-10-16 | 1999-08-10 | Creanova Inc. | Rubber-modified asphalt paving binder |
| CN102329568A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing triaryl phosphate |
| CN102965014A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water-proofing material for pitched roof |
| CN104140761A (en) * | 2014-08-06 | 2014-11-12 | 苏州卓越工程塑料有限公司 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
| CN104194629B (en) * | 2014-09-11 | 2017-02-15 | 北京东方雨虹防水技术股份有限公司 | Non-cured rubber asphalt waterproofing coating with flame retardance property and preparation method thereof |
-
2015
- 2015-03-12 CN CN201510108997.7A patent/CN104726024B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104726024A (en) | 2015-06-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104726024B (en) | A kind of spraying rapid hardening modified waterproof asphalt material and preparation method thereof | |
| CN103360933B (en) | Non-bituminous water-based spraying rapid hardening rubber water-proof paint and preparation method thereof | |
| CN107118695A (en) | A kind of Rubber Modified Asphalt Waterproof Coating and preparation method thereof and application method | |
| CN102965016B (en) | High temperature resistant type spraying rapid hardening rubber asphalt waterproof coating | |
| CN106398536A (en) | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof | |
| CN107868616A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN110016289B (en) | High-performance polymer modified asphalt waterproof coating and preparation method thereof | |
| CN107043598A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN104140575A (en) | Wear-resistant shock-absorbing foaming rubber material | |
| CN104529300A (en) | Geopolymer-base sea-base concrete protective coating | |
| CN105419508B (en) | A kind of corrosion-resistant, the not stratified water-proof acrylic acid paint of one-component | |
| CN104370489B (en) | A kind of alkali-free liquid accelerator and preparation method thereof | |
| CN105925091A (en) | Water-borne corrosion-resistant and waterproof coating for concrete structure | |
| CN102659364A (en) | Spraying mortar and manufacture method thereof | |
| CN111040633B (en) | Spraying quick-setting waterproof coating for marine corrosion prevention and preparation and construction method thereof | |
| CN102604503A (en) | Coating for offshore steel structure buildings and preparation method thereof | |
| CN105417986A (en) | Early-strength waterproof agent for ordinary Portland cement | |
| CN104231864B (en) | A kind of water-based epoxy micaceous sheet iron strip rust anti-corrosive primer | |
| CN108690979A (en) | A kind of hot-dip galvanizing sheet steel passivator and preparation method | |
| CN101735550A (en) | Low-smell furan resin | |
| CN110229545A (en) | A kind of aqueous inorganic zinc silicate coating and its production technology | |
| CN101767883A (en) | Method for synthesizing barium strontium scale inhibitor | |
| CN111609223B (en) | PE high-pressure water supply pipe and preparation method thereof | |
| CN104673094A (en) | Quick-setting waterproof paint | |
| CN110746167B (en) | Antirust environment-friendly cement-based material and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200610 Address after: 064100 south side of Huxing Road, Yutian Economic Development Zone, Yutian County, Tangshan City, Hebei Province Patentee after: Jindun building materials (Tangshan) Co., Ltd Address before: 101313 Beijing city east of Shunyi District Li Sui Zhen Xin Zhuang Yan Road, Taiping wood Patentee before: BEIJING JINDUN BUILDING MATERIAL Co.,Ltd. |