CN104662114B - 层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 - Google Patents
层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 Download PDFInfo
- Publication number
- CN104662114B CN104662114B CN201380049736.1A CN201380049736A CN104662114B CN 104662114 B CN104662114 B CN 104662114B CN 201380049736 A CN201380049736 A CN 201380049736A CN 104662114 B CN104662114 B CN 104662114B
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- acid
- adhesive composite
- duplexer
- lamination adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000003475 lamination Methods 0.000 title claims abstract description 27
- 239000007767 bonding agent Substances 0.000 title claims description 17
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 54
- 239000003822 epoxy resin Substances 0.000 claims abstract description 53
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 50
- 230000001070 adhesive effect Effects 0.000 claims abstract description 32
- 238000012986 modification Methods 0.000 claims abstract description 32
- 230000004048 modification Effects 0.000 claims abstract description 32
- 239000000853 adhesive Substances 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 25
- 239000002131 composite material Substances 0.000 claims abstract description 23
- 239000003792 electrolyte Substances 0.000 claims abstract description 21
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims 2
- 229920003023 plastic Polymers 0.000 abstract description 10
- 239000004033 plastic Substances 0.000 abstract description 10
- 239000005056 polyisocyanate Substances 0.000 abstract description 7
- 229920001228 polyisocyanate Polymers 0.000 abstract description 7
- -1 ethylene carbonate ester Chemical class 0.000 description 33
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 24
- 238000000034 method Methods 0.000 description 19
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000011255 nonaqueous electrolyte Substances 0.000 description 7
- 125000004437 phosphorous atom Chemical group 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000005030 aluminium foil Substances 0.000 description 6
- 229940106691 bisphenol a Drugs 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 150000002118 epoxides Chemical class 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 239000003495 polar organic solvent Substances 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 230000006978 adaptation Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000010030 laminating Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- NPAXBRSUVYCZGM-UHFFFAOYSA-N carbonic acid;propane-1,2-diol Chemical compound OC(O)=O.CC(O)CO NPAXBRSUVYCZGM-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000009740 moulding (composite fabrication) Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- PNWSHHILERSSLF-UHFFFAOYSA-N 4-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=CC=C(C(O)=O)C=C1C(O)=O PNWSHHILERSSLF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
- CEGRHPCDLKAHJD-UHFFFAOYSA-N 1,1,1-propanetricarboxylic acid Chemical compound CCC(C(O)=O)(C(O)=O)C(O)=O CEGRHPCDLKAHJD-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-ARJAWSKDSA-M 2-Methyl-2-butenoic acid Natural products C\C=C(\C)C([O-])=O UIERETOOQGIECD-ARJAWSKDSA-M 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- VUIWJRYTWUGOOF-UHFFFAOYSA-N 2-ethenoxyethanol Chemical compound OCCOC=C VUIWJRYTWUGOOF-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- GISWNRNUVGGVOS-UHFFFAOYSA-N 3,4-dihydroxybutan-2-yl prop-2-enoate Chemical compound OCC(O)C(C)OC(=O)C=C GISWNRNUVGGVOS-UHFFFAOYSA-N 0.000 description 1
- XYFRHHAYSXIKGH-UHFFFAOYSA-N 3-(5-methoxy-2-methoxycarbonyl-1h-indol-3-yl)prop-2-enoic acid Chemical compound C1=C(OC)C=C2C(C=CC(O)=O)=C(C(=O)OC)NC2=C1 XYFRHHAYSXIKGH-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- AOJJSUZBOXZQNB-TZSSRYMLSA-N Doxorubicin Chemical compound O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-TZSSRYMLSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- 229920003354 Modic® Polymers 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 229920003298 Nucrel® Polymers 0.000 description 1
- INHHFZUVCCBNTO-UHFFFAOYSA-N PAP Chemical compound OCC(O)CNC1=CC=CC=C1 INHHFZUVCCBNTO-UHFFFAOYSA-N 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IZJDCINIYIMFGX-UHFFFAOYSA-N benzo[f][2]benzofuran-1,3-dione Chemical compound C1=CC=C2C=C3C(=O)OC(=O)C3=CC2=C1 IZJDCINIYIMFGX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- CZORBZCFAPGTNL-UHFFFAOYSA-N butane-1,1,4,4-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)CCC(C(O)=O)C(O)=O CZORBZCFAPGTNL-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- AVKNGPAMCBSNSO-UHFFFAOYSA-N cyclohexylmethanamine Chemical compound NCC1CCCCC1 AVKNGPAMCBSNSO-UHFFFAOYSA-N 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- VUIFFVOKIWOJBA-UHFFFAOYSA-N dodeca-1,3-diene Chemical compound CCCCCCCCC=CC=C VUIFFVOKIWOJBA-UHFFFAOYSA-N 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- ALSOCDGAZNNNME-UHFFFAOYSA-N ethene;hex-1-ene Chemical compound C=C.CCCCC=C ALSOCDGAZNNNME-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FEPCMSPFPMPWJK-OLPJDRRASA-N maleopimaric acid Chemical compound C([C@]12C=C([C@H](C[C@@H]11)[C@H]3C(OC(=O)[C@@H]23)=O)C(C)C)C[C@@H]2[C@]1(C)CCC[C@@]2(C)C(O)=O FEPCMSPFPMPWJK-OLPJDRRASA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 229960003574 milrinone Drugs 0.000 description 1
- VWUPWEAFIOQCGF-UHFFFAOYSA-N milrinone lactate Chemical compound [H+].CC(O)C([O-])=O.N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C VWUPWEAFIOQCGF-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 125000005473 octanoic acid group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001627 poly(4-methyl styrene) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- KVWOTUDBCFBGFJ-UHFFFAOYSA-N tert-butyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC(C)(C)C KVWOTUDBCFBGFJ-UHFFFAOYSA-N 0.000 description 1
- QROFQHQXTMKORN-UHFFFAOYSA-N tert-butyl 2-phenylacetate Chemical compound CC(C)(C)OC(=O)CC1=CC=CC=C1 QROFQHQXTMKORN-UHFFFAOYSA-N 0.000 description 1
- WMOVHXAZOJBABW-UHFFFAOYSA-N tert-butyl acetate Chemical compound CC(=O)OC(C)(C)C WMOVHXAZOJBABW-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002769 thiazolinyl group Chemical group 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
本发明可得到一种层压用粘接剂组合物、使用了该层压用粘接剂组合物的层叠体以及二次电池,所述层压用粘接剂组合物使金属层与塑料层的粘接性优异,满足防湿性、耐热性、绝缘性、耐久性等,并且兼具耐电解质性,经过长时间后不发生层间剥离。本发明提供一种层压用粘接剂组合物、使用了该层压用粘接剂组合物的层叠体、以及二次电池。所述层压用粘接剂组合物的特征在于,含有改性聚烯烃树脂(A)、磷酸改性化合物(B),优选还含有环氧树脂、多异氰酸酯化合物。
Description
技术领域
本发明涉及层压用粘接剂、使用了该粘接剂的层叠体以及二次电池。
背景技术
锂离子电池所代表的二次电池的构成在于,在正极与负极之间将电解液密封等。另外,作为用于密封将正极和负极的电荷向外部取出用的引线的密封袋,可使用将铝箔等金属箔、金属蒸镀层与塑料贴合而得的层叠体。
对于该层叠体,需要作为二次电池所需的物性、防湿性、密封性、耐扎入性、绝缘性、耐热性、耐寒性、耐腐蚀性,特别是需要不溶于电解质的耐电解质性。
因此,现有技术中提出了如下的密封袋,即,层叠体的最内层使用马来酸改性聚烯烃树脂,且由同样的马来酸改性聚烯烃树脂构成热密封部,由此来提高密封可靠性(例如,参照专利文献1~4)。一般地说,马来酸改性聚烯烃树脂与金属的粘接性和热密封性优异,因此经常被用作粘接性树脂。但是,在作为上述的电池用密封膜来使用的情况下,虽然在刚层叠后显示出优异的粘接力,但耐电解质性低,经过长时间后会发生层间剥离,因而无法用作密封膜。
现有技术文献
专利文献
专利文献1:日本特开平9-283101号公报
专利文献2:国际公开WO01/017043
专利文献3:日本特开平8-193148号公报
专利文献4:日本特开2010-277959
发明内容
发明要解决的课题
因此,为了解决上述问题,本发明的目的在于得到一种层压用粘接剂组合物、使用了该层压用粘接剂组合物的层叠体和二次电池。所述层压用粘接剂组合物使金属层与塑料层的粘接性优异,满足防湿性、耐热性、绝缘性、耐久性等,并且兼具耐电解质性,经过长时间后不发生层间剥离。
解决课题的方法
为了解决上述问题,本发明人进行了深入研究,结果发现,通过将烯烃树脂与后述的磷酸改性化合物组合,从而能够大幅提高粘接性和耐电解质性,至此完成了本发明。即,本发明提供一种层压用粘接剂组合物,其特征在于,含有聚烯烃树脂(A)、磷酸改性化合物(B)。
发明效果
本发明的粘接剂组合物通过用于铝箔等金属层与塑料层之间,从而表现出优异的粘接性。结果,使用了本粘接剂的层叠体能够发挥出良好的耐湿性、耐热性、耐溶剂性、耐久性等。另外,在使用该层叠体作为二次电池用层叠体的情况下,对碳酸丙二醇酯、碳酸乙二醇酯等电解质具有优异的耐性,因此不会发生经过长时间后的层间剥离。
具体实施方式
本发明的层压用粘接剂组合物含有聚烯烃树脂(A)、磷酸改性化合物(B)。
作为本发明中使用的聚烯烃树脂(A),可举出例如碳原子数2~8的烯烃的均聚物、共聚物,碳原子数2~8的烯烃与其他单体的共聚物。具体地,可举出例如高密度聚乙烯(HDPE)、低密度聚乙烯(LDPE)、线状低密度聚乙烯树脂等聚乙烯,聚丙烯、聚异丁烯、聚(1-丁烯)、聚4-甲基戊烯、聚乙烯基环己烷、聚苯乙烯、聚(对甲基苯乙烯)、聚(α-甲基苯乙烯)、乙烯·丙烯嵌段共聚物、乙烯·丙烯无规共聚物、乙烯·1-丁烯共聚物、乙烯·4-甲基-1-戊烯共聚物、乙烯·己烯共聚物等α-烯烃共聚物,乙烯·乙酸乙烯酯共聚物、乙烯·丙烯酸共聚物、乙烯·甲基丙烯酸甲酯共聚物、乙烯·乙酸乙烯酯·甲基丙烯酸甲酯共聚物、离聚物树脂等。另外,也可以使用将这些聚烯烃氯化后的氯代聚烯烃。
如上所述,本发明中使用的聚烯烃树脂(A)能够使用各种类型,特别地,更优选在聚烯烃树脂中引入了各种官能团(例如羧基、羟基等)的改性聚烯烃树脂。另外,这些改性聚烯烃树脂中,从使金属层的密合性进一步提高,且耐电解质性优异的方面出发,更优选为具有1~200mg KOH/g的酸值的改性聚烯烃树脂(以下记作酸改性聚烯烃树脂)和/或具有1~200mg KOH/g的羟值的改性聚烯烃树脂(以下记作羟基改性聚烯烃树脂)。
酸改性聚烯烃树脂是指在分子中具有羧基或羧酸酐基的聚烯烃树脂,其通过利用不饱和羧酸或其衍生物将聚烯烃改性而合成。作为其改性方法,可以使用接枝改性、共聚化。
酸改性聚烯烃树脂为使至少1种能够聚合的烯属不饱和羧酸或其衍生物与改性前的聚烯烃树脂进行接枝改性或共聚化而得的接枝改性聚烯烃。作为改性前的聚烯烃树脂,可举出上述的聚烯烃树脂,其中,优选丙烯的均聚物、丙烯与α-烯烃的共聚物、乙烯的均聚物、以及乙烯与α-烯烃的共聚物等。它们可以单独使用1种,也可以组合使用2种以上。
作为用于与改性前的聚烯烃树脂进行接枝改性或者共聚化的烯属不饱和羧酸或其衍生物,可举出例如丙烯酸、甲基丙烯酸、马来酸、衣康酸、柠康酸、中康酸、马来酸酐、4-甲基环己-4-烯-1,2-二甲酸酐、双环[2.2.2]辛-5-烯-2,3-二甲酸酐、1,2,3,4,5,8,9,10-八氢萘-2,3-二甲酸酐、2-辛-1,3-螺[4.4]二酮-7-烯、双环[2.2.1]庚-5-烯-2,3-二甲酸酐、马来海松酸、四氢邻苯二甲酸酐、甲基-双环[2.2.1]庚-5-烯-2,3-二甲酸酐、甲基-降冰片-5-烯-2,3-二甲酸酐、降冰片-5-烯-2,3-二甲酸酐等。优选使用马来酸酐。它们可以单独使用或组合使用2种以上。
为了使选自烯属不饱和羧酸或其衍生物中的接枝单体与改性前的聚烯烃树脂进行接枝,可以采用各种方法。可举出例如,将聚烯烃树脂熔融,在其中添加接枝单体而进行接枝反应的方法;将聚烯烃树脂溶解于溶剂而制得溶液,并在其中添加接枝单体而进行接枝反应的方法;将溶解于有机溶剂的聚烯烃树脂与上述不饱和羧酸等混合,以上述聚烯烃树脂的软化温度或熔点以上的温度进行加热,在熔融状态下同时进行自由基聚合和脱氢反应的方法等。为了在任一情况下均使上述接枝单体高效地进行接枝共聚,优选在自由基引发剂的存在下实施接枝反应。接枝反应通常在60~350℃的条件下进行。相对于改性前的聚烯烃树脂100重量份,自由基引发剂的使用比例为通常0.001~1重量份的范围。
作为自由基引发剂,优选有机过氧化物,可举出例如过氧化苯甲酰、过氧化二氯苯甲酰、二枯基过氧化物、二叔丁基过氧化物、2,5-二甲基-2,5-二(过氧化苯甲酸酯)己炔-3、1,4-双(过氧化叔丁基异丙基)苯、过氧化月桂酰、过氧乙酸叔丁酯、2,5-二甲基-2,5-二(过氧化叔丁基)己炔-3、2,5-二甲基-2.5-二(过氧化叔丁基)己烷、过氧化苯甲酸叔丁酯、过氧化苯基乙酸叔丁酯、过氧化异丁酸叔丁酯、过氧化仲辛酸叔丁酯、过氧化新戊酸叔丁酯、过氧化新戊酸枯基酯和过氧化二乙基乙酸叔丁酯等。另外,也可以使用偶氮化合物,例如偶氮二异丁腈、二甲基偶氮异丁酸酯等。
这些自由基引发剂可以根据接枝反应的工艺来选择最适的物质,但通常优选使用二枯基过氧化物、二叔丁基过氧化物、2,5-二甲基-2,5-二(过氧化叔丁基)己炔-3、2,5-二甲基-2.5-二(过氧化叔丁基)己烷、1,4-双(过氧化叔丁基异丙基)苯等二烷基过氧化物。
作为这些酸改性聚烯烃树脂,可举出例如马来酸酐改性聚丙烯、乙烯-(甲基)丙烯酸共聚物、乙烯-丙烯酸酯-马来酸酐三元共聚物、或乙烯-甲基丙烯酸酯-马来酸酐三元共聚物。具体地市售有三菱化学(株)制“MODIC”、三井化学(株)制“ADMER”、“UNISTOLE”、东洋化成(株)制“ト一ヨ一タツク”、三洋化成(株)制“Youmex”、JapanPolyethylene Corporation制“レクスパ一ルEAA”“レクスパ一ルET”、陶氏化学(株)制“PRIMACOR”、三井杜邦聚合化学制“NUCREL”、ARKEMA制“BONDINE”。
羟基改性聚烯烃树脂是在分子中具有羟基的聚烯烃树脂,其通过利用后述的含有羟基的(甲基)丙烯酸酯、或者含有羟基的乙烯基醚,将聚烯烃进行接枝改性或者共聚化而合成。改性前的聚烯烃树脂、改性方法与酸改性聚烯烃树脂的情况相同。
作为上述含有羟基的(甲基)丙烯酸酯,可举出(甲基)丙烯酸羟基乙酯;(甲基)丙烯酸羟基丙酯、(甲基)丙烯酸甘油酯;内酯改性(甲基)丙烯酸羟基乙酯、(甲基)丙烯酸聚乙二醇酯、(甲基)丙烯酸聚丙二醇酯等。作为上述含有羟基的乙烯基醚,可举出2-羟基乙基乙烯基醚、二乙二醇单乙烯基醚、4-羟基丁基乙烯基醚等。
作为本发明中使用的磷酸改性化合物(B),可举出选自下述通式(1)、(2)、(3)、(4)和(5)中的1种以上的化合物。
(式中的R1、R2、R3、R4、R5、R6分别独立地为数均分子量350~3000的环氧树脂的残基和/或改性环氧树脂的残基,R7、R10和R11分别独立地表示碳原子数为8以下的亚烷基,R8、R9和R12分别独立地表示环氧基、异丙烯基或乙烯基。)
上述通式(1)、(2)和(3)所示的化合物为利用环氧树脂将具有与磷原子键合的羟基的化合物进行改性后的磷酸改性环氧树脂(B-Ep)。
上述磷酸改性环氧树脂(B-Ep)通过使环氧树脂(B1)、具有与磷原子键合的羟基的化合物(B2)、和根据需要的碳原子数为3~5的一元羧酸(B3)反应而得到。
作为环氧树脂(B1),可举出例如乙二醇、丙二醇、己二醇、新戊二醇、三羟甲基乙烷、三羟甲基丙烷、季戊四醇、甘油、二甘油、山梨糖醇、螺二醇或者氢化双酚A等脂肪族多元醇二缩水甘油醚型环氧树脂。
另外,可举出双酚A、双酚F、双酚S、双酚AD等的二缩水甘油醚型环氧树脂、苯酚酚醛清漆树脂、甲酚酚醛清漆树脂的缩水甘油醚即酚醛清漆型环氧树脂等芳香族环氧树脂;芳香族系多羟基化合物的环氧乙烷或环氧丙烷加成物等多元醇类的二缩水甘油醚型环氧树脂。
另外,可举出聚乙二醇、聚丙二醇或聚四亚甲基二醇等聚醚多元醇的聚缩水甘油醚型环氧树脂;双(3,4-环氧环己基甲基)己二酸酯、3,4-环氧环己基甲基-3’,4’-环氧环己基甲酸酯等环状脂肪族型聚环氧树脂。
另外,可举出丙烷三甲酸、丁烷四甲酸、己二酸、邻苯二甲酸、对苯二甲酸或偏苯三酸等多元羧酸的聚缩水甘油酯型环氧树脂;丁二烯、己二烯、辛二烯、十二烷二烯、环辛二烯、α-蒎烯或乙烯基环己烯等烃系二烯的双环氧树脂。
另外,可举出聚丁二烯或聚异戊二烯等二烯聚合物的环氧树脂;或者四缩水甘油基二氨基二苯基甲烷、四缩水甘油基双氨基甲基环己烷、二缩水甘油基苯胺或四缩水甘油基间苯二亚甲基二胺等缩水甘油基胺型环氧树脂;或者含有如三嗪或乙内酰脲这样的各种杂环的环氧树脂等。
其中,若使用双酚A型环氧树脂等芳香族环氧树脂,则密合性和耐腐蚀性良好,因此优选。
关于具体例,作为双酚A型环氧树脂,可举出DIC(株)制“EPICLON850、860、1050、1055、2055”,三菱化学(株)制“jER 828、834、1001、1002、1004、1007”等。
作为具有与磷原子键合的羟基的化合物(B2),没有特别限制,只要在磷原子上具有至少1个羟基即可,可举出例如下述通式(5)所示的化合物。
(通式(5)中,R13、R14分别相同或各自表示碳原子数1~12的烷基、烯基、苄基或羟基)
具有通式(6)所示的结构的化合物中,从密合性和作业性优异的方面出发,特别优选磷酸。
作为碳原子数为3~5的一元羧酸(B3),可举出例如丙酸、乳酸、丁酸、戊酸等饱和羧酸类,丙烯酸、甲基丙烯酸、乙烯基乙酸、巴豆酸、惕各酸、3,3-二甲基丙烯酸或戊烯酸等烯属不饱和一元羧酸类。
其中,从所得到的磷酸改性环氧树脂的稳定性的观点出发,优选烯属不饱和一元羧酸,特别优选丙烯酸和/或甲基丙烯酸。
对于环氧树脂(B1)与具有与磷原子键合的羟基的化合物(B2)的反应而言,其条件没有特别限制,可以在无催化剂化的条件下在常温下缓慢地使两者进行反应来得到目标产物。但是,特别地,更优选在存在或不存在溶剂和催化剂的条件下在50~200℃、优选在80~140℃下进行反应来得到磷酸改性环氧树脂(B-Ep)。
此时,优选相对于环氧树脂(B1)中存在的环氧基1.0摩尔,具有与磷原子键合的羟基的化合物(B2)中的羟基的总摩尔数达到0.9~1.0摩尔的比率,这从所得到的磷酸改性环氧树脂(B-Ep)的稳定性变得良好的方面出发优选。
另外,在并用一元羧酸的情况下,优选以相对于上述环氧树脂(B1)中存在的环氧基1.0摩尔,羧酸中的羧基的摩尔数与具有与磷原子键合的羟基的化合物中与磷原子键合的羟基的摩尔数的总量达到0.9~1.0摩尔的方式进行调整。
在并用一元羧酸的情况下,作为制造磷酸改性环氧树脂(B-Ep)的方法,可举出例如下述的(1)~(3)的方法。
下述的方法中,可根据需要使用有机溶剂、催化剂等。
(1)一次性加入环氧树脂(B1)、碳原子数为3~5的一元羧酸(B3)和具有与磷原子键合的羟基的化合物(B2),并使它们进行反应的方法。
(2)使上述环氧树脂和上述羧酸进行反应,接着使上述磷化合物进行反应的方法。
(3)使上述环氧树脂与上述磷化合物进行反应,接着使上述羧酸进行反应的方法。
其中,从反应效率的观点出发,优选上述(2)的方法。另外,作为上述催化剂,优选使用三苯基膦、胺化合物等在环氧基与酸的反应中使用的物质。
上述通式(4)、(5)所示的化合物为利用2价的含羟基化合物将具有与磷原子键合的羟基的化合物改性后的磷酸改性酯化合物(B-Es)。
对于本发明的层压用粘接剂组合物而言,由于可兼具与金属层和塑料层的密合性,因此粘接性更为优异,另外,从粘接剂的贮藏稳定性和作业性的观点出发,优选相对于聚烯烃树脂(A)100重量份,以0.1~30重量份的比例配合磷酸改性化合物(B)。
作为本发明中使用的环氧树脂(C),可以使用制造上述的磷酸改性环氧树脂(B-Ep)时使用的环氧树脂(B1)。
特别地,从可提高粘接性和耐电解质性的方面出发,更优选环氧树脂(C)与酸改性聚烯烃树脂组合使用。可认为这是由于交联密度增高而可抑制电解质的浸透的缘故。
从兼顾粘接性和耐电解质性与抗粘连性(耐ブロツキング性)的观点出发,本发明的层压用粘接剂组合物中,更优选相对于聚烯烃树脂(A)100重量份,以0.1~30重量份的比例配合环氧树脂(C)。
作为本发明中使用的多异氰酸酯化合物(D),可举出在分子内具有至少2个异氰酸酯基的化合物。作为多异氰酸酯化合物,可举出例如甲苯二异氰酸酯、苯二亚甲基二异氰酸酯、二苯基甲烷二异氰酸酯、1,6-六亚甲基二异氰酸酯、异佛尔酮二异氰酸酯、4,4’-亚甲基双(环己基异氰酸酯)、赖氨酸二异氰酸酯、三甲基六亚甲基二异氰酸酯、1,3-(异氰酸根合甲基)环己烷、1,5-萘二异氰酸酯、三苯基甲烷三异氰酸酯等多异氰酸酯;这些多异氰酸酯的加合物、缩二脲体、异氰脲酸酯体等多异氰酸酯的衍生物等。
特别地,从粘接性和耐电解质性优异的方面出发,多异氰酸酯化合物(D)更优选与羟基改性聚烯烃树脂组合使用。
作为本发明的层压用粘接剂组合物中使用的有机溶剂,只要能够使上述的聚烯烃树脂(A)、磷酸改性化合物(B)溶解或者分散,就没有特别限定,可举出例如乙酸甲酯、乙酸丁酯、乙酸丁酯等酯系溶剂;丙酮、甲基乙基酮、甲基异丁基酮、二异丁基酮、环己酮等酮系溶剂;甲苯、二甲苯等芳香族烃类等。其中,从干燥性、作业性优异的方面出发,优选酯系溶剂。
本发明的层压用粘接剂组合物也可以根据需要而含有其他添加剂等。作为添加剂,可举出用于形成膜、涂布膜等的树脂组合物中一般使用的添加剂等。作为添加剂,可举出例如流平剂;胶态二氧化硅、氧化铝溶胶等无机微粒;聚甲基丙烯酸甲酯系的有机微粒;消泡剂;防粘剂;硅烷偶联剂;粘性调节剂;紫外线吸收剂;金属惰性化剂;过氧化物分解剂;阻燃剂;增强剂;增塑剂;润滑剂;防锈剂;荧光性增白剂;无机系热线吸收剂;防火剂;防静电剂;脱水剂等。
通过将本发明的层压用粘接剂组合物与铝箔等金属层、以及聚乙烯、聚丙烯等聚烯烃片、聚对苯二甲酸乙二醇酯等聚酯等中的1种或多种塑料层贴合,可得到本发明的层叠体。
而且,通过使本发明的层压用粘接剂组合物以任意比例溶解/分散于例如酯系溶剂、酮系溶剂、芳香族系烃、脂肪族烃、脂环族烃等适当的溶剂或分散剂,使用辊涂法、凹版涂布法、棒涂法等周知的涂布方法将其涂布于金属箔,并进行干燥,由此能够形成粘接层。
本发明的层压用粘接剂组合物的干燥涂布重量优选在0.5~20.0g/m2的范围内。若低于0.5g/m2,则难以连续均匀地涂布,另一方面,若超过20.0g/m2,则涂布后的溶剂脱离性降低,作业性显著下降,并且产生溶剂残留的问题。
在上述金属箔的一面涂敷本发明的层压用粘接剂组合物后,重叠塑料层,利用干式层压(干式层叠法)进行贴合,由此可得到本发明的层叠体。层压辊的温度优选室温~60℃左右,压力优选10~300kg/cm2左右。
另外,本发明的层叠体优选在制成后进行熟化。熟化条件为在室温~100℃下、12~240小时之间,在该过程中产生粘接强度。
本发明的层叠体能够作为一次电池或二次电池的电解液密封膜或电极部保护膜使用,此时,在塑料层侧与极性有机溶剂和/或盐类等接触地进行使用。特别是通过在与包含极性有机溶剂和盐的非水电解质接触的状态下进行使用,从而能够特别优选作为非水电解质电池、固体电池等的二次电池电解液密封膜或二次电池电极部保护膜使用。此时,通过按照使塑料层相对的方式进行折叠并进行热密封,从而能够作为电池用密封袋来使用。本发明中使用的粘接剂的热密封性优异,因此可防止非水电解质的泄漏,电池可长期使用。
作为上述极性有机溶剂,可举出非质子性的极性溶剂,例如碳酸烷基酯、酯、酮等。具体地,可举出碳酸乙二醇酯、碳酸丙二醇酯、碳酸丁二醇酯、碳酸二甲酯、碳酸乙基甲酯、碳酸二乙酯,γ-丁内酯、1,2-二甲氧基乙烷、四氢呋喃、2-甲基四氢呋喃、1,3-二氧戊环、4-甲基-1,3-二氧戊环、甲酸甲酯、4-甲基-1,3-二氧代甲基甲酸酯(4-メチル-1,3-ジオキソメチルフォ一メ一ト)、乙酸甲酯、丙酸甲酯等。
作为盐,可举出锂盐、钠盐、钾盐等碱金属盐。电池用中,一般使用LiPF6、LiBF4、Li-酰亚胺等锂盐。
非水电解质为在环状碳酸酯、链状碳酸酯、它们的混合物等非质子性极性有机溶剂中溶解0.5~3mmol上述碱金属盐而得的物质。
本发明的层叠体即使在与上述极性溶剂和/或盐类、特别是它们的混合物即非水电解质接触的状态下使用,也不会发生金属层、粘接层、塑料层的层间剥离,能够长期使用。
本发明的电池为具有由上述层叠体形成的电池电解液密封膜或电池电极部保护膜的电池。本发明的电池中,上述膜不发生层间剥离,而且能够防止非水电解质的泄漏,因此电池能够长期稳定地使用。
如上所述,本发明的层叠体与金属层和塑料层的粘接力优异,并且对极性有机溶剂或盐的耐久力优异,即使与非水电解质等接触,也不发生层间剥离。因此,使用这样的层叠体作为电池电解液密封膜或电池电极部保护膜的电池、以及使用这样的层叠体作为二次电池电解液密封膜或二次电池电极部保护膜的二次电池能够长期稳定地使用。
实施例
以下,举出实施例和比较例详细地说明本发明。
合成例1(磷酸改性环氧树脂(B)的合成例)
使用氢氧化钠作为催化剂,通过常规方法,利用由表氯醇和双酚A所制造的“EPICLON 850”(DIC(株)制,环氧当量185)600份、双酚A 250份而得到环氧当量900的环氧树脂。将所得环氧树脂溶解于分别为400/200/200份的二甲苯/乙二醇单丁醚/1-丁基醇后,在80℃下少量多次地滴加89%磷酸24份,进行10小时反应,在确认不发生粘度变化后,用乙二醇单丁醚进行调整直到不挥发成分达到50%,然后得到粘度(25℃)为W的磷酸改性环氧树脂(b-1)。
合成例2(磷酸改性环氧树脂(B)的合成例)
在具备搅拌器、温度计、回流冷凝器和氮气导入管的反应容器中加入“jER 1001”(三菱化学(株)制BPA型环氧树脂、环氧当量475)545.5份、和二乙二醇二甲基醚259.0份,边加热进行溶解,边升温至80℃。溶解后,在80℃下加入丙烯酸59.7份,接着加入二丁基羟基甲苯0.6份、三苯基膦2.4份,边用1小时升温至110℃边进行搅拌。在110℃下保持3小时继续进行反应,在酸值达到1.0mg KOH/g以下时,降温至80℃,用1小时连续滴加由85%磷酸12.1份和二乙二醇二甲醚70.2份构成的混合物。滴加结束后继续在80℃下反应4小时,接着加入二乙二醇二甲醚50.5份,由此得到不挥发成分为64.0%、并且酸值为9.0的磷酸改性环氧树脂(b-2)的溶液。
(实施例1)
相对于酸改性聚烯烃树脂“UNISTOLE P-401”(固体成分酸值55mgKOH/g,加热残留成分8%,三井化学(株)制)100重量份,将磷酸改性环氧树脂(b-1)以2.0重量份、环氧树脂“DENACOL EX-321”(环氧当量140,不挥发成分100%,Nagase Chemtex(株)制)以1.0重量份的比例进行混合分散,制成粘接剂。
使用棒涂布机将上述粘接剂以涂布量达到5.0g/m2(固体成分)的方式涂布于厚度50μm的铝箔,然后使稀释溶剂挥发,进行干燥。在层压辊温度为室温、压力30kg/cm2、速度20m/分钟的条件下将涂布有粘接剂的铝箔的粘接剂面与厚度70μm的CPP(未拉伸聚丙烯)膜(东丽(株)制“ZK93KM”)层压,制作具有铝箔/粘接层/CPP膜(未拉伸聚丙烯膜)的层构成的层叠体。接着,将该复合膜进行60℃/3天的熟化,进行粘接剂的固化,得到本发明的层叠体1。
按照表1配合其他粘接剂,与实施例1同样地制作粘接剂。然后利用与层叠体1同样的制作方法制作各层叠体。
对于各例中得到的层叠体,评价了粘接性能以及耐电解质性,表1示出其结果。此外,各性能试验的条件如下所述。
粘接强度:在(株)A&D制万能拉力试验机中,将试样切割为15mm宽,测定180°剥离强度。
耐电解质性A:在碳酸乙二醇酯中在40℃下将层叠体浸渍30天,由浸渍前后的粘接强度的保持率,如下所述地实施评价。
○:90%以上,
△:90~70%,
×:70%以下
耐电解质性B:在碳酸丙二醇酯中在40℃下将层叠体浸渍30天,由浸渍前后的粘接强度的保持率,如下所述地实施评价。
○:90%以上,
△:90~70%,
×:70%以下
作为比较例,如表2所述地进行配合,与实施例同样地制作层叠体。然后,使用该层叠体来评价粘接强度、耐电解质性。
[表1]
[表2]
UNISTOLE P-401(三井化学(株)制)酸改性聚烯烃树脂
固体成分酸值55mg KOH/g,加热残留成分8%
UNISTOLE P-902(三井化学(株)制)酸改性聚烯烃树脂
固体成分酸值55mg KOH/g,加热残留成分22%
UNISTOLE P-901(三井化学(株)制)羟基改性聚烯烃树脂
固体成分羟值50mg KOH/g,加热残留成分22%
DENACOL EX-321(Nagase Chemtex(株)制)环氧树脂
环氧当量140,不挥发成分100%
EPICLON 860(DIC(株)制)双酚A型环氧树脂
环氧当量240,不挥发成分100%
TAKENATE D-101(三井武田化学(株)制)HDI加合物
NCO%13,不挥发成分75%
Claims (5)
1.一种用于一次电池或二次电池的电解液密封膜的层压用粘接剂组合物,其特征在于,
仅包含具有酸基的聚烯烃树脂(A)、磷酸改性环氧树脂(B)、以及环氧树脂(C)作为树脂成分,
各成分的配合比例为:相对于所述聚烯烃树脂(A)100重量份,以0.1~30重量份的比例配合磷酸改性环氧树脂(B),以0.1~30重量份的比例配合环氧树脂(C)。
2.如权利要求1所述的层压用粘接剂组合物,其中,
所述具有酸基的聚烯烃树脂(A)具有1~200mg KOH/g的酸值。
3.如权利要求1所述的层压用粘接剂组合物,其中,
所述磷酸改性环氧树脂(B)为选自下述通式(1)、(2)和(3)中的1种以上的化合物,
式中的R1、R2、R3、R4、R5、R6分别独立地为数均分子量350~3000的环氧树脂的残基和/或改性环氧树脂的残基,
4.一种层叠体,其在金属层与聚烯烃树脂层之间使用了权利要求1~3中任一项所述的层压用粘接剂组合物。
5.一种二次电池,其包含权利要求4所述的层叠体。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012-210867 | 2012-09-25 | ||
JP2012210867 | 2012-09-25 | ||
PCT/JP2013/075263 WO2014050686A1 (ja) | 2012-09-25 | 2013-09-19 | ラミネート用接着剤、これを用いた積層体及び二次電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104662114A CN104662114A (zh) | 2015-05-27 |
CN104662114B true CN104662114B (zh) | 2016-08-10 |
Family
ID=50388091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380049736.1A Active CN104662114B (zh) | 2012-09-25 | 2013-09-19 | 层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP5664836B2 (zh) |
KR (1) | KR101603933B1 (zh) |
CN (1) | CN104662114B (zh) |
TW (1) | TWI579358B (zh) |
WO (1) | WO2014050686A1 (zh) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5700166B1 (ja) * | 2014-08-01 | 2015-04-15 | 東洋インキScホールディングス株式会社 | 接着剤組成物、積層体、蓄電デバイス用包装材、蓄電デバイス用容器および蓄電デバイス |
CN105658753B (zh) * | 2014-09-17 | 2017-06-13 | Dic株式会社 | 层压用胶粘剂、使用了该胶粘剂的层叠体、以及二次电池 |
WO2016142974A1 (ja) | 2015-03-06 | 2016-09-15 | 日本電気株式会社 | 近接サービス通信のための装置及び方法 |
JP5900680B1 (ja) * | 2015-03-25 | 2016-04-06 | 東洋インキScホールディングス株式会社 | 接着剤組成物、積層体、蓄電デバイス用包装材、蓄電デバイス用容器および蓄電デバイス |
WO2016199754A1 (ja) * | 2015-06-10 | 2016-12-15 | 凸版印刷株式会社 | 蓄電装置用外装材 |
JP6660688B2 (ja) * | 2015-08-06 | 2020-03-11 | 藤森工業株式会社 | 接着性積層体、接着性積層体の製造方法、及び積層体 |
CN107922806B (zh) * | 2015-08-28 | 2020-06-26 | Dic株式会社 | 层压用粘接剂、多层膜和使用了其的二次电池 |
JP6768362B2 (ja) * | 2015-09-17 | 2020-10-14 | 藤森工業株式会社 | 電池外装用積層体、電池外装用積層体の製造方法、電池外装体及び電池 |
CN106549118B (zh) * | 2015-09-17 | 2020-04-28 | 藤森工业株式会社 | 电池外装用层叠体、电池外装用层叠体的制造方法、电池外装体以及电池 |
CN113263812B (zh) * | 2015-09-17 | 2022-11-29 | 藤森工业株式会社 | 电池外装用层叠体、电池外装体以及电池 |
CN108140837A (zh) * | 2015-10-16 | 2018-06-08 | 三菱化学株式会社 | 二次电池电极用粘合剂树脂、使用其的二次电池电极用粘合剂树脂组合物、二次电池电极用浆料、二次电池用电极以及二次电池 |
CN108368316B (zh) | 2016-01-21 | 2024-07-16 | 三井化学株式会社 | 组合物、层叠体、包装材料、电池壳体用包装材料及电池 |
JP6902827B2 (ja) * | 2016-02-08 | 2021-07-14 | 藤森工業株式会社 | 接着性樹脂組成物、被着体接着方法、及び接着性樹脂フィルム |
JP6850539B2 (ja) * | 2016-02-25 | 2021-03-31 | 藤森工業株式会社 | 電池外装用積層体、電池外装体及び電池 |
JP6826370B2 (ja) * | 2016-03-18 | 2021-02-03 | 藤森工業株式会社 | 樹脂被覆金属積層体の製造方法及び電池外装体の製造方法 |
CN109563385B (zh) * | 2016-08-10 | 2021-06-11 | 东洋纺株式会社 | 聚烯烃系粘合剂组合物 |
KR102340015B1 (ko) * | 2016-08-10 | 2021-12-16 | 도요보 가부시키가이샤 | 폴리올레핀계 접착제 조성물 |
CN109642134B (zh) * | 2016-09-07 | 2021-07-06 | 琳得科株式会社 | 粘结剂组合物、密封片和密封体 |
JP6911635B2 (ja) * | 2017-08-24 | 2021-07-28 | 東洋インキScホールディングス株式会社 | 接着剤組成物および積層体 |
JP6642778B2 (ja) * | 2017-10-04 | 2020-02-12 | Dic株式会社 | 接着剤、積層体、電池用部材及び電池 |
TWI785173B (zh) * | 2017-12-26 | 2022-12-01 | 日商迪愛生股份有限公司 | 接著劑、積層體、電池用包裝材料及電池 |
KR101996883B1 (ko) * | 2018-03-14 | 2019-07-08 | (주)이지켐 | 무봉제형 보호복 및 이의 제조방법 |
WO2021060000A1 (ja) * | 2019-09-26 | 2021-04-01 | 東洋紡フイルムソリューション株式会社 | 燃料電池用接合体、及び積層体 |
JP7488715B2 (ja) | 2020-08-04 | 2024-05-22 | マクセル株式会社 | 金属-ゴム複合部材及びその製造方法 |
KR102522216B1 (ko) * | 2020-09-04 | 2023-04-18 | 율촌화학 주식회사 | 프라이머층 조성물, 이를 이용한 이차전지 파우치 필름 및 그 제조 방법 |
CN113583596B (zh) * | 2021-07-29 | 2022-03-25 | 四川大学 | 一种阻燃型聚烯烃系粘合剂组合物及其制备方法 |
CN114262579B (zh) * | 2021-12-30 | 2023-11-24 | 江苏睿捷新材料科技有限公司 | 金属复合膜及其应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1526784A (zh) * | 2003-03-07 | 2004-09-08 | 东洋油墨制造株式会社 | 粘结剂和上述粘结剂的制造方法以及塑料薄膜层压钢板 |
JP2004339384A (ja) * | 2003-05-16 | 2004-12-02 | Toyo Ink Mfg Co Ltd | 接着剤及び該接着剤を用いてなるプラスチックフィルムラミネート鋼板 |
CN101241976A (zh) * | 2007-02-05 | 2008-08-13 | 索尼株式会社 | 引线密封膜和非水电解质电池 |
JP2011256339A (ja) * | 2010-06-11 | 2011-12-22 | Sanyo Chem Ind Ltd | 金属ラミネート用接着剤 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4006609B2 (ja) * | 1997-12-03 | 2007-11-14 | 大日本インキ化学工業株式会社 | プラスチックフィルムラミネート鋼板用接着剤組成物 |
JP4652534B2 (ja) * | 2000-07-24 | 2011-03-16 | 日鉄住金鋼板株式会社 | ポリオレフィン樹脂シートラミネート金属板 |
-
2013
- 2013-09-19 KR KR1020157007254A patent/KR101603933B1/ko active IP Right Grant
- 2013-09-19 JP JP2014538434A patent/JP5664836B2/ja active Active
- 2013-09-19 CN CN201380049736.1A patent/CN104662114B/zh active Active
- 2013-09-19 WO PCT/JP2013/075263 patent/WO2014050686A1/ja active Application Filing
- 2013-09-24 TW TW102134269A patent/TWI579358B/zh active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1526784A (zh) * | 2003-03-07 | 2004-09-08 | 东洋油墨制造株式会社 | 粘结剂和上述粘结剂的制造方法以及塑料薄膜层压钢板 |
JP2004339384A (ja) * | 2003-05-16 | 2004-12-02 | Toyo Ink Mfg Co Ltd | 接着剤及び該接着剤を用いてなるプラスチックフィルムラミネート鋼板 |
CN101241976A (zh) * | 2007-02-05 | 2008-08-13 | 索尼株式会社 | 引线密封膜和非水电解质电池 |
JP2011256339A (ja) * | 2010-06-11 | 2011-12-22 | Sanyo Chem Ind Ltd | 金属ラミネート用接着剤 |
Also Published As
Publication number | Publication date |
---|---|
TWI579358B (zh) | 2017-04-21 |
KR20150042290A (ko) | 2015-04-20 |
JP5664836B2 (ja) | 2015-02-04 |
KR101603933B1 (ko) | 2016-03-16 |
CN104662114A (zh) | 2015-05-27 |
TW201425512A (zh) | 2014-07-01 |
JPWO2014050686A1 (ja) | 2016-08-22 |
WO2014050686A1 (ja) | 2014-04-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104662114B (zh) | 层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 | |
CN105658753B (zh) | 层压用胶粘剂、使用了该胶粘剂的层叠体、以及二次电池 | |
KR101899265B1 (ko) | 폴리올레핀계 접착제 조성물 | |
TWI711676B (zh) | 積層用接著劑、多層薄膜、及使用其之二次電池 | |
WO2019188284A1 (ja) | ポリオレフィン系接着剤組成物 | |
CN108368402A (zh) | 层压用粘接剂组合物、层叠体和二次电池 | |
CN108473836A (zh) | 层压用粘接剂组合物、层叠体和二次电池 | |
KR102518707B1 (ko) | 폴리올레핀계 접착제 조성물 | |
JP6733674B2 (ja) | リチウムイオン電池用包装材料 | |
CN106876614A (zh) | 电池包装用层叠体、电池包装体以及电池 | |
CN111971360B (zh) | 聚烯烃系粘接剂组合物 | |
TW201823407A (zh) | 聚烯烴系黏著劑組成物 | |
CN108884367A (zh) | 层压用粘接剂、使用该粘接剂的层叠体以及二次电池 | |
TW201740601A (zh) | 積層用接著劑、使用其之積層體、及二次電池 | |
KR20190035748A (ko) | 폴리올레핀계 접착제 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |