CN104576628B - A kind of novel white-light LED structure and preparation method thereof - Google Patents

A kind of novel white-light LED structure and preparation method thereof Download PDF

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Publication number
CN104576628B
CN104576628B CN201310507360.6A CN201310507360A CN104576628B CN 104576628 B CN104576628 B CN 104576628B CN 201310507360 A CN201310507360 A CN 201310507360A CN 104576628 B CN104576628 B CN 104576628B
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China
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layer
chip
light led
blue
light
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CN201310507360.6A
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CN104576628A (en
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叶国光
郝锐
罗长得
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Guangdong De Li Photoelectric Co Ltd
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Guangdong De Li Photoelectric Co Ltd
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Abstract

The invention discloses a kind of novel white-light LED structure, including the blue-light LED chip and reddish yellow light LED chip for passing through glue bond, it is characterised in that:The blue chip includes substrate, the cushion grown successively on substrate, DBR layer, n-type semiconductor layer, luminescent layer, electronic barrier layer, p-type semiconductor material layer and transparent electrode layer;The reddish yellow optical chip includes substrate, the n-type semiconductor layer grown successively on substrate, luminescent layer, p-type semiconductor material layer and transparent electrode layer, and transparent electrode layer is provided with reflecting layer, while the preparation method for also describing the chip structure.The reddish yellow light that the present invention is sent by the blue light and reddish yellow optical chip that send blue chip carries out spectrum directly superposition to send white light, compared with existing White-light LED chip, without fluorescent material, illumination effect is good, improves LED energy conversion efficiencies and extends service life.

Description

A kind of novel white-light LED structure and preparation method thereof
Technical field
The present invention relates to LED chip technical field, especially a kind of novel white-light LED structure and preparation method thereof.
Background technology
Light emitting diode(Light emitting diodle, abbreviation LED)According to the chemical constitution of different luminescent materials and Attribute, it is divided into inorganic LED(Commonly referred to as LED)And organic LED(Commonly referred to as OLEDs).In 1993, blue gallium nitride (GaN)LED technology is broken through, and realizes within 1996 inorganic LED white light emissions on this basis.Because white light LEDs have Low voltage drive, all solid state, low-power consumption, it is long-acting reliable the advantages that, white light LED part illumination association area application study all Receive academic and industrial circle great attention.Because white light LEDs are a kind of to meet the efficient of environmental protection and energy saving green illumination theory Light source, therefore, the semiconductor illumination technique based on white light LEDs at present(Forth generation lighting engineering)Obtained in worldwide Promotion and development energetically, is forming huge industry.White light LED part realizes that the mode of white light mainly has three kinds:1st, Blue-light LED chip excites yellow fluorescent powder, and white light is obtained by compound;2nd, ultraviolet LED excites red, green, blue three primary colors fluorescent powder, White light is obtained by compound;3rd, red, green, blue three-primary color LED multi-chip by integration packaging so as to obtaining white light.
Second of white light makes the red bluish-green three kinds of fluorescent material that need to select to match with ultraviolet wavelength, UV light sources, anti-UV Encapsulating material, and the making of these three materials and exploitation are all more difficult, therefore second of white light is also less on the market.The third is white Light preparation method is faced with mixed light difficulty, and user can observe a variety of different colors easily everywhere in front of this light source, together When three kinds of light driving it is more complicated, occur the change of color under different electric currents, the third is also less in market.At present most Commonly the first, i.e., in blue-light LED chip, just face coats one layer of yellow fluorescent powder and realizes the transmitting of white light, using the party The fluorescent material paint-on technique that method is realized, not only production efficiency is not high, and big with the product colour temperature difference of batch.It must be made follow-up Cheng Zhong, white light LEDs are fixed on cup centre and carry out die bond process, LED wafer die bond process due to equipment precision Problem, it is impossible to ensure that wafer is bonded at the middle of cup, for the mixed layer coated with fluorescent material, because chip is not in centre, Cause the optical path difference on both sides different so as to producing the inhomogeneities of color.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of novel white-light LED structure and preparation method thereof, can be without glimmering White light LEDs are realized in the case of light powder, to effectively improve chip light emitting efficiency and extend white light LEDs service life.
The technical scheme is that:A kind of novel white-light LED structure, including by the blue-light LED chip of glue bond and Reddish yellow light LED chip, the blue chip include substrate, the cushion grown successively on substrate, DBR layer, n-type semiconductor material The bed of material, luminescent layer, electronic barrier layer, p-type semiconductor material layer and transparent electrode layer;
In the blue chip, p-type semiconductor material layer is provided with anode, and n-type semiconductor layer is provided with negative electrode, Cathode and anode is equipped with bonding wire, and cathode and anode material is the one or more in Ti, Ni, Au, Ag, Pt, Cr and Wu, bonding wire material For the one or more in Cu, Al and Ag;
The DBR layer is made up of 2-15 cycle material layer, and each cycle material layer is by AlGaN, InGaN and GaN Two kinds of material layer compositions, the thickness of each material layer is the refractive index of 1/4,1/8 or 1/16 divided by material of blue light wavelength, blue DBR layer in optical chip has and prevents blue light from down launching and feux rouges can appear and from the effect of top-emission.
The reddish yellow optical chip includes substrate, the n-type semiconductor layer grown successively on substrate, luminescent layer, p-type half Conductor material layer and transparent electrode layer;Transparent electrode layer is provided with reflecting layer, and reflecting layer is metallic reflector and/or dbr structure, Dbr structure material is two kinds in AlGaN, InGaN and GaN, and the luminous energy of reddish yellow optical chip transmitting is by the reflection positioned at bottom Layer be emitted back towards and from top-emission;
In the reddish yellow optical chip, p-type semiconductor material layer is provided with anode, and n-type semiconductor layer is provided with negative electrode, Cathode and anode is equipped with bonding wire, and cathode and anode material is the one or more in Ti, Ni, Au, Ag, Pt, Cr and Wu, bonding wire material For the one or more in Cu, Al and Ag;
The size of the reddish yellow optical chip is more than or equal to the size of blue chip, is combined together by gluing, and realizes The transmitting of white light, the material of glue can be the one or more in organic silica gel, silver paste, heat-conducting glue, alloy weldering, and the thickness of glue is preferred For 100nm-100 um, to reduce the absorption of reddish yellow light.
Preferably, the substrate in blue chip and reddish yellow optical chip is initial substrates, organic semiconductor device or surface coarsening lining Bottom.
The cathode and anode of the reddish yellow optical chip and blue chip is located at the arranged on left and right sides of whole chip structure respectively, to subtract The absorption of electrode pair light is lacked.
Preferably, the blue chip include Sapphire Substrate, GaN cushions, DBR layer, n-type GaN layer, by InGaN With luminescent layer, AlGaN electronic barrier layers, p-type GaN layer and the ito transparent electrode layer of GaN material layer composition;The reddish yellow light core Piece includes GaP substrates, n-type AlInGaN layers, the Al that emission wavelength is 560-600nmxInyGazP luminescent layers, p-type AlInGaN Layer, ito transparent electrode layer and reflecting layer, wherein AlxInyGazIn P luminescent layers, preferably x and y molar fraction are 0.25- 0.5, x=y, z=1-x-y, luminescent layer can adjust the color of light by changing x, y and z size.
A kind of preparation method of novel white-light LED structure, blue chip use MOCVD (Metal- with reddish yellow optical chip
Organic Chemical Vapor Deposition) fabrication techniques, including following two steps:
1st, blue chip and reddish yellow optical chip are pasted by the glue that thickness is 100nm-100 um, the negative electrode of blue chip It is located at homonymy or heteropleural with the negative electrode of reddish yellow optical chip;
2nd, directly it is packaged lead on the basis of above-mentioned bonding chip.
The lead of blue chip and the reddish yellow optical chip is in series or in parallel.
Beneficial effects of the present invention are:The substrate of blue chip is linked together by the substrate of glue and reddish yellow optical chip, DBR layer is set in blue chip, DBR layer is located between active region and the buffering area of blue chip, and the blue light for being sent to bottom is whole Reflect back and reddish yellow light can appear, reddish yellow optical chip bottom sets reflecting layer, will be sent to the reddish yellow light of bottom all reflection and Projected from top, while the direct superposition of two kinds of spectrum is with regard to that can send white light.It is of the invention compared with existing White-light LED chip, Without fluorescent material, illumination effect is good, improves LED energy conversion efficiencies and extends service life.
Brief description of the drawings
Fig. 1 is the diagrammatic cross-section of the embodiment of the present invention 1;
Fig. 2 is the front schematic view of the embodiment of the present invention 1;
Fig. 3 is the schematic bottom view of the embodiment of the present invention 1;
Fig. 4 is the diagrammatic cross-section of the embodiment of the present invention 2;
Fig. 5 is the front schematic view of the embodiment of the present invention 2;
Fig. 6 is the schematic bottom view of the embodiment of the present invention 2.
In figure, 1- glue, 2- Sapphire Substrates, 3- cushions, 4- DBR layers, 5-n type GaN layers, 6- luminescent layers(Blue light), 7- Electronic barrier layer, 8-p type GaN layers, 9- transparent electrode layers, 10- anodes(Blue light), 11-GaP substrates, 12-n type AlInGaN layers, 13- luminescent layers(Reddish yellow light), 14- p-type AlInGaN layers, 15- transparent electrode layers, 16- anodes(Reddish yellow light), 17- negative electrodes(It is blue Light), 18- negative electrodes(Reddish yellow light), 19- reflecting layer.
Embodiment
The embodiment of the present invention is described further below in conjunction with the accompanying drawings:
Embodiment 1:As Figure 1-3, a kind of novel white-light LED structure, including with heat-conducting glue(1)The blue-ray LED of bonding Chip and reddish yellow light LED chip, wherein, blue chip includes Sapphire Substrate(2), in Sapphire Substrate(2)On set successively The GaN cushions put(3), the DBR layer that is made up of AlGaN and GaN material layer(4), n-type GaN layer(5), by 2 cycle material layer groups Into luminescent layer(6), AlGaN electronic barrier layers(7), p-type GaN layer(8)With ito transparent electrode layer(9), wherein p-type GaN layer (8)It is provided with anode(10), n-type GaN layer(5)It is provided with negative electrode(17), cathode and anode is equipped with bonding wire, and cathode and anode material is Ag, bonding wire material are Cu;
Reddish yellow optical chip includes GaP substrates(11), in GaP substrates(11)On the n-type AlInGaN layers that set gradually (12)、Al0.3In0.3Ga0.4P luminescent layers(13), p-type AlInGaN layers(14), ito transparent electrode layer(15)And metallic reflector (19), wherein p-type AlInGaN layers(14)It is provided with anode(16), n-type AlInGaN layers(12)It is provided with negative electrode(18), yin, yang Pole is equipped with bonding wire, and cathode and anode material is Ag, and bonding wire material is Cu;
In the present embodiment, the size of reddish yellow optical chip is equal to the size of blue chip, reddish yellow optical chip negative electrode(18)With indigo plant Optical chip negative electrode(17)Positioned at homonymy.
The preparation method of embodiment 1 is corresponding blue chip and reddish yellow optical chip to be made using MOCVD technologies, then use Thickness is 200 nm heat-conducting glue(1)Blue chip and reddish yellow optical chip are pasted, different stickup directions can make blue chip Negative electrode(17)With the negative electrode of reddish yellow optical chip(18)Then it is homonymy, then above-mentioned in homonymy or heteropleural, the embodiment Lead is directly packaged on the basis of bonding chip, the chip structure being formed in embodiment 1.
Embodiment 2:As Figure 4-Figure 6, a kind of novel white-light LED structure, including with organic silica gel(1)The blue light of bonding LED chip and reddish yellow light LED chip, wherein, blue chip includes Sapphire Substrate(2), in Sapphire Substrate(2)On successively The GaN cushions of setting(3), the DBR layer that is made up of AlGaN and GaN material layer(4), n-type GaN layer(5), by 12 cycle materials The luminescent layer of layer composition(6), AlGaN electronic barrier layers(7), p-type GaN layer(8)With ito transparent electrode layer(9), wherein p-type GaN Layer(8)It is provided with anode(10), n-type GaN layer(5)It is provided with negative electrode(17), cathode and anode is equipped with bonding wire, and cathode and anode material is equal For Ag, bonding wire material is Cu;
Reddish yellow optical chip includes GaP substrates(11), in GaP substrates(11)On the n-type AlInGaN layers that set gradually (12)、Al0.4In0.4Ga0.2P luminescent layers(13), p-type AlInGaN layers(14), ito transparent electrode layer(15)And metallic reflector (19), wherein p-type AlInGaN layers(14)It is provided with anode(16), n-type AlInGaN layers(12)It is provided with negative electrode(18), yin, yang Pole is equipped with bonding wire, and cathode and anode material is Ag, and bonding wire material is Cu, in the present embodiment, GaP substrates(11)Right side is by part Peel off so that the negative electrode of reddish yellow optical chip(18)Set upward, the convenient negative electrode with blue chip(17)Enter line lead;
In the present embodiment, the size of reddish yellow optical chip is more than the size of blue chip, and reddish yellow optical chip has more part and sent out The luminous energy penetrated without directly launching inside blue chip, improves light extraction efficiency, reddish yellow optical chip negative electrode(18)With blue light Chip negative electrode(17)Positioned at homonymy.
The preparation method of embodiment 2 is:Corresponding blue chip and reddish yellow optical chip is made using MOCVD technologies, then used Thickness is 2000nm organic silica gel(1)Blue chip and reddish yellow optical chip are pasted, make blue light core by adjusting stickup direction Piece negative electrode(17)With reddish yellow optical chip negative electrode(18)Positioned at homonymy, lead is directly packaged on this basis, is formed reality Apply the chip structure in example 2.

Claims (7)

1. a kind of novel white-light LED structure, including existed by the blue-light LED chip and reddish yellow light LED chip, its feature of glue bond In:The blue chip includes Sapphire Substrate, grows successively on a sapphire substrate GaN cushions, DBR layer, n-type GaN layer, the luminescent layer being made up of InGaN and GaN material layer, AlGaN electronic barrier layers, p-type GaN layer and ito transparent electrode layer; N-type AlInGaN layers, the emission wavelength 560- that the reddish yellow optical chip includes GaP substrates, grown successively on a gap substrate 600nm AlxInyGazP luminescent layers, p-type AlInGaN layers, ito transparent electrode layer and reflecting layer, wherein AlxInyGazP light In layer, x and y molar fraction are 0.25-0.5, x=y, z=1-x-y.
2. novel white-light LED structure according to claim 1, it is characterised in that:The size of the reddish yellow optical chip is more than Or the size equal to blue chip.
3. novel white-light LED structure according to claim 1, it is characterised in that:The DBR layer is by 2-15 cycle material Layer composition, each cycle material layer are made up of two kinds of material layers in AlGaN, InGaN and GaN, the thickness of each material layer For the 1/4 of blue light wavelength, 1/8 or 1/16 divided by the refractive index of material.
4. novel white-light LED structure according to claim 1, it is characterised in that:The reflecting layer be metallic reflector and/ Or dbr structure, dbr structure material are two kinds in AlGaN, InGaN and GaN.
5. novel white-light LED structure according to claim 1, it is characterised in that:The material of the glue is organic silica gel, silver One or more in slurry, heat-conducting glue, alloy weldering, the thickness of glue is 100nm-100um.
6. novel white-light LED structure according to claim 1, it is characterised in that:In the blue chip, p-type semiconductor Material layer is provided with anode, and n-type semiconductor layer is provided with negative electrode, and cathode and anode is equipped with bonding wire cathode and anode material and is One or more in Ti, Ni, Au, Ag, Pt, Cr and Wu, bonding wire material are the one or more in Cu, Al and Ag.
7. novel white-light LED structure according to claim 1, it is characterised in that:In the reddish yellow optical chip, p-type is partly led Body material layer is provided with anode, and n-type semiconductor layer is provided with negative electrode, and cathode and anode is equipped with bonding wire, and cathode and anode material is equal For the one or more in Ti, Ni, Au, Ag, Pt, Cr and Wu, bonding wire material is the one or more in Cu, Al and Ag.
CN201310507360.6A 2013-10-25 2013-10-25 A kind of novel white-light LED structure and preparation method thereof Expired - Fee Related CN104576628B (en)

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CN109950792A (en) * 2019-03-29 2019-06-28 钟祥博谦信息科技有限公司 The distributed bragg reflector mirror of gallium nitride and the preparation method of resonant cavity
GB2592017B (en) * 2020-02-11 2022-08-03 Plessey Semiconductors Ltd Multicolour light emitting structure
CN111834505B (en) * 2020-06-12 2022-04-08 福州大学 Three-pole luminous tube based on wavelength down-conversion and manufacturing method thereof
CN113690268A (en) * 2021-07-01 2021-11-23 河源市众拓光电科技有限公司 Visible light communication cascade type array LED chip

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CN102201507A (en) * 2010-03-25 2011-09-28 Lg伊诺特有限公司 Light-emitting device

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CN102171847A (en) * 2008-10-03 2011-08-31 港大科桥有限公司 Semiconductor color-tunable broadband light sources and full-color microdisplays
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