CN104529108B - 一种厌氧消化-Fenton反应耦合去除污泥中持久性有机污染物的方法 - Google Patents
一种厌氧消化-Fenton反应耦合去除污泥中持久性有机污染物的方法 Download PDFInfo
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- CN104529108B CN104529108B CN201510014229.5A CN201510014229A CN104529108B CN 104529108 B CN104529108 B CN 104529108B CN 201510014229 A CN201510014229 A CN 201510014229A CN 104529108 B CN104529108 B CN 104529108B
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- Prior art keywords
- mud
- anaerobic
- digestion
- sludge
- fenton
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- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 27
- 239000002957 persistent organic pollutant Substances 0.000 title claims abstract description 19
- 230000002688 persistence Effects 0.000 title claims abstract description 18
- 230000008878 coupling Effects 0.000 title claims abstract description 15
- 238000010168 coupling process Methods 0.000 title claims abstract description 15
- 238000005859 coupling reaction Methods 0.000 title claims abstract description 15
- 239000010802 sludge Substances 0.000 claims abstract description 46
- 230000029087 digestion Effects 0.000 claims abstract description 34
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000003071 polychlorinated biphenyls Chemical class 0.000 claims abstract description 10
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 claims abstract description 10
- 239000012028 Fenton's reagent Substances 0.000 claims description 13
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 239000000356 contaminant Substances 0.000 claims description 4
- 239000010865 sewage Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 2
- 238000004108 freeze drying Methods 0.000 claims description 2
- 238000012544 monitoring process Methods 0.000 claims description 2
- 230000002572 peristaltic effect Effects 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 7
- 230000008859 change Effects 0.000 abstract description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 239000003546 flue gas Substances 0.000 abstract description 2
- 239000010801 sewage sludge Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 17
- 230000018044 dehydration Effects 0.000 description 9
- 238000006297 dehydration reaction Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 238000004065 wastewater treatment Methods 0.000 description 5
- 238000000855 fermentation Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 2
- 230000036983 biotransformation Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
- C02F11/04—Anaerobic treatment; Production of methane by such processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/06—Treatment of sludge; Devices therefor by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
- C02F2101/327—Polyaromatic Hydrocarbons [PAH's]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510014229.5A CN104529108B (zh) | 2015-01-07 | 2015-01-07 | 一种厌氧消化-Fenton反应耦合去除污泥中持久性有机污染物的方法 |
Applications Claiming Priority (1)
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CN201510014229.5A CN104529108B (zh) | 2015-01-07 | 2015-01-07 | 一种厌氧消化-Fenton反应耦合去除污泥中持久性有机污染物的方法 |
Publications (2)
Publication Number | Publication Date |
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CN104529108A CN104529108A (zh) | 2015-04-22 |
CN104529108B true CN104529108B (zh) | 2016-09-14 |
Family
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CN201510014229.5A Expired - Fee Related CN104529108B (zh) | 2015-01-07 | 2015-01-07 | 一种厌氧消化-Fenton反应耦合去除污泥中持久性有机污染物的方法 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105174676B (zh) * | 2015-09-30 | 2017-09-22 | 沈阳建筑大学 | 基于电化学污泥预处理的电芬顿源头污泥减量化方法及系统 |
CN105366899B (zh) * | 2015-12-10 | 2018-01-02 | 东华大学 | 一种臭氧‑厌氧铁还原联用污泥减量的芬顿氧化工艺 |
CN105800897B (zh) * | 2016-05-11 | 2018-10-02 | 合肥工业大学 | 一种利用零价铁强化剩余污泥和秸秆快速固态厌氧消化的方法 |
CN106587560B (zh) * | 2017-01-10 | 2020-04-28 | 广东工业大学 | 短期厌氧消化在污泥脱水中的新应用 |
CN108793591A (zh) * | 2018-06-06 | 2018-11-13 | 广西师范大学 | 一种基于厌氧-多相类芬顿耦合和土地渗滤技术的处理含抗生素畜禽养殖废水的装置 |
CN109912156A (zh) * | 2019-03-26 | 2019-06-21 | 华中科技大学 | 一种叶绿素铁钠盐调理促进剩余污泥产甲烷的方法 |
CN115043480A (zh) * | 2022-06-10 | 2022-09-13 | 天俱时工程科技集团有限公司 | 一种制药废水的处理方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5719100A (en) * | 1980-07-09 | 1982-02-01 | Ebara Infilco Co Ltd | Disposal of sludge from night soil digester |
KR101044989B1 (ko) * | 2010-12-01 | 2011-06-29 | 지에스건설 주식회사 | 유기성 슬러지의 생물학적 처리 방법 및 이에 사용되는 장치 |
CN103613262A (zh) * | 2013-12-13 | 2014-03-05 | 广西大学 | 超声波联合芬顿反应和厌氧消化处理工业污泥的方法及设备 |
CN103755096B (zh) * | 2014-01-17 | 2015-03-04 | 上海交通大学 | 用于剩余污泥处理的耦合Fenton氧化和厌氧消化的反应装置 |
-
2015
- 2015-01-07 CN CN201510014229.5A patent/CN104529108B/zh not_active Expired - Fee Related
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CN104529108A (zh) | 2015-04-22 |
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Effective date of registration: 20180427 Address after: 313100 No. 158-1 Bai Xi Road, Changxing County Taihu street, Huzhou, Zhejiang. Patentee after: ZHEJIANG HEZE ENVIRONMENTAL TECH SHARES CO.,LTD. Address before: 211816 Puzhu South Road, Pukou District, Nanjing, Jiangsu Province, No. 30 Patentee before: Nanjing University of Technology |
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Address after: 313100 No. 158-1 Bai Xi Road, Changxing County Taihu street, Huzhou, Zhejiang. Patentee after: Zhejiang Heze Environmental Technology Co.,Ltd. Address before: 313100 No. 158-1 Bai Xi Road, Changxing County Taihu street, Huzhou, Zhejiang. Patentee before: ZHEJIANG HEZE ENVIRONMENTAL TECH SHARES CO.,LTD. |
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