CN104529028B - Treatment process and device for polyculture fishpond waste water - Google Patents
Treatment process and device for polyculture fishpond waste water Download PDFInfo
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Abstract
一种混养鱼池废水的处理工艺及装置,属于废水处理技术领域。该处理工艺如下:废水放出先经过格栅,除去杂草等物质后,进入集水池收集,依次经第一加药桶、第二加药桶、曝气池、沉淀池、砂滤池过滤后进入回用水池,回用水池中的水经二次循环净化装置二次净化,得到净化后的能循环利用的水。本发明的处理工艺先经过第一加药桶里的藻类等使废达到自净,再经第二加药桶里的生物活化水处理剂,再依次经微波处理器、曝气池、沉淀池、砂滤池处理得到干净的水送至回用水池,回用水池内设置二次循环净化装置,经活性碳滤池内活性碳的吸附、精滤器及反渗透池的处理,其处理效果好,可保证水处理效果好,出水质量稳定,最终使水体达到水产养殖要求。
The invention discloses a process and device for treating waste water in polyculture fish ponds, belonging to the technical field of waste water treatment. The treatment process is as follows: the waste water is discharged through the grid first, and after removing weeds and other substances, it enters the collection tank for collection, and then passes through the first dosing tank, the second dosing tank, the aeration tank, the sedimentation tank, and the sand filter. Enter the reuse water pool, and the water in the reuse water pool is purified by the secondary circulation purification device to obtain purified water that can be recycled. The treatment process of the present invention first passes through the algae in the first dosing tank to make the waste self-cleaning, then passes through the biologically activated water treatment agent in the second dosing tank, and then passes through the microwave processor, aeration tank, sedimentation tank, The clean water obtained by the sand filter is sent to the reuse water pool, and a secondary circulation purification device is installed in the reuse water pool. After the adsorption of activated carbon in the activated carbon filter, the treatment of the fine filter and the reverse osmosis tank, the treatment effect is good and can be Ensure that the water treatment effect is good, the effluent quality is stable, and finally the water body meets the requirements of aquaculture.
Description
技术领域technical field
本发明属于废水处理技术领域,具体涉及一种环境污染少、处理方便、能回收循环利用的混养鱼池废水的处理工艺及装置。The invention belongs to the technical field of waste water treatment, and in particular relates to a treatment process and device for mixed fish pond waste water with less environmental pollution, convenient treatment and recyclable utilization.
背景技术Background technique
随着水产养殖业的迅速发展,由于养殖过程中投放的饲料所含的氮、磷等只有少部分被鱼同化,还有残剩饲料及鱼类排泄物形成的污染物对周围水体及沉积物等造成的污染正越来越受到政府和民众的关注;同时,养殖环境内的污染对水产养殖业进一步发展的制约作用也在逐渐显现。循环水(海水、淡水)同时还具有养殖周期短、产量及产品价格高等优点,在养殖业的应用被人们寄予厚望。但是水处理仍是制约水产养殖的主要因素,由于传统水处理技术是一个包括多种生物催化反应,水处理工艺流程复杂,水处理设备占地面积大,不利于管理,再加上海水盐度效应等制约,脱氮效率低,水处理完成效果差,出水质量不稳定,进而导致水产品质量差。With the rapid development of the aquaculture industry, only a small part of the nitrogen and phosphorus contained in the feed put in during the breeding process is assimilated by the fish, and the pollutants formed by the residual feed and fish excrement will affect the surrounding water body and sediments. Pollution caused by fish, etc. is getting more and more attention from the government and the public; at the same time, the restrictive effect of the pollution in the breeding environment on the further development of the aquaculture industry is also gradually emerging. Circulating water (sea water, fresh water) also has the advantages of short breeding cycle, high output and product price, and people have high hopes for its application in the breeding industry. However, water treatment is still the main factor restricting aquaculture. Because the traditional water treatment technology is a process involving a variety of biocatalytic reactions, the water treatment process is complicated, and the water treatment equipment occupies a large area, which is not conducive to management. In addition, the salinity of seawater Effects and other constraints, the denitrification efficiency is low, the water treatment effect is poor, and the quality of the effluent is unstable, which in turn leads to poor quality of aquatic products.
发明内容Contents of the invention
针对现有技术中存在的上述问题,本发明的目的在于提供一种环境污染少、处理方便、能回收循环利用的混养鱼池废水的处理工艺及装置。In view of the above-mentioned problems existing in the prior art, the object of the present invention is to provide a treatment process and device for polyculture fish pond wastewater that has less environmental pollution, is convenient to handle, and can be recycled and reused.
所述的一种混养鱼池废水的处理工艺,其特征在于包括如下步骤:Described a kind of treatment process of polyculture fish pond wastewater is characterized in that comprising the steps:
1)将混养鱼池废水放出,先经过格栅,除去杂草等物质后,进入集水池收集;1) Release the wastewater from the polyculture fish pond, first pass through the grille, remove weeds and other substances, and then enter the collection tank for collection;
2)当集水池内的水集至集水池体积一半时,放入第一加药桶中进行第一次净化;2) When the water in the sump is collected to half the volume of the sump, put it into the first dosing barrel for the first purification;
3)净化后再由第一水泵将水泵入第二加药桶内,进行二次净化,再经过微波处理器处理;3) After purification, the first water pump pumps the water into the second dosing barrel for secondary purification, and then it is processed by a microwave processor;
4)将微波处理器处理后的废水放入曝气池、沉淀池、砂滤池过滤后进入回用水池;4) Put the wastewater treated by the microwave processor into the aeration tank, sedimentation tank, sand filter tank and filter it into the reuse pool;
5)通过第二水泵将回用水池中的水泵入活性碳滤池吸附后,再经精滤器过滤,最后经过反渗透池作用后再回到回用水池,得到净化后的能循环利用的水。5) The water in the reuse pool is pumped into the activated carbon filter for adsorption through the second water pump, then filtered through the fine filter, and finally returned to the reuse pool after being processed by the reverse osmosis tank to obtain purified water that can be recycled .
所述的一种混养鱼池废水的处理工艺,其特征在于步骤2)所述的第一加药桶培养有藻类和细菌,去废水中的厌氧废液。The process for treating wastewater from a polyculture fish pond is characterized in that algae and bacteria are cultivated in the first dosing tank described in step 2), and the anaerobic waste liquid in the wastewater is removed.
所述的一种混养鱼池废水的处理工艺,其特征在于步骤3)中所述的第二加药桶内加入生物活化水处理剂,所述的生物活化水处理剂由以下重量份数的组分组成:氧化镁6-8份、氧化硅25-45份、氧化铝1-3份、甲基蓝0.5-1份、次氯酸钠2-6份、石灰10-16份。The process for treating wastewater from polyculture fish ponds is characterized in that a biologically activated water treatment agent is added to the second dosing tank described in step 3), and the biologically activated water treatment agent consists of the following parts by weight Component composition: 6-8 parts of magnesium oxide, 25-45 parts of silicon oxide, 1-3 parts of aluminum oxide, 0.5-1 part of methylene blue, 2-6 parts of sodium hypochlorite, 10-16 parts of lime.
所述的一种混养鱼池废水的处理工艺,其特征在于步骤3)中所述的第二加药桶内加入生物活化水处理剂,所述的生物活化水处理剂由以下重量份数的组分组成:氧化镁7份、氧化硅30份、氧化铝2份、甲基蓝0.8份、次氯酸钠4份、石灰15份。The process for treating wastewater from polyculture fish ponds is characterized in that a biologically activated water treatment agent is added to the second dosing tank described in step 3), and the biologically activated water treatment agent consists of the following parts by weight Component composition: 7 parts of magnesium oxide, 30 parts of silicon oxide, 2 parts of aluminum oxide, 0.8 parts of methylene blue, 4 parts of sodium hypochlorite, 15 parts of lime.
所述的一种混养鱼池废水的处理工艺,其特征在于步骤5)中所述的精滤器内设置至少一层微孔过滤膜,所述的微孔过滤膜的孔径大小为0.2-0.4 微米。The process for treating wastewater from polyculture fish ponds is characterized in that at least one layer of microporous filtration membrane is arranged in the fine filter described in step 5), and the pore size of the microporous filtration membrane is 0.2-0.4 Microns.
所述的混养鱼池废水的处理装置,其特征在于包括依次通过管道连接的格栅、集水池、第一加药桶、第一水泵、第二加药桶、微波处理器、曝气池、沉淀池、砂滤池及回用水池,水经栅格除去粗杂质后,经集水池进水口进入集水池,再经集水池出水口从第一加药桶的进水口进入第一加药桶,从第一加药桶的出水口经第一水泵进入第二加药桶,再经第二加药桶的出水口依次进入微波处理器、曝气池、沉淀池、砂滤池,经处理后水进入回用水池收集,所述的回用水池上还设置二次循环净化装置。The treatment device for mixed fish pond wastewater is characterized in that it includes a grille, a sump, a first dosing tank, a first water pump, a second dosing tank, a microwave processor, and an aeration tank connected sequentially through pipelines. , sedimentation tank, sand filter tank and reuse water tank. After removing coarse impurities through the grid, the water enters the sump through the water inlet of the sump, and then enters the first dosing tank from the water inlet of the first dosing barrel through the water outlet of the sump. barrel, from the outlet of the first dosing barrel to the second dosing barrel through the first water pump, and then through the outlet of the second dosing barrel to enter the microwave processor, aeration tank, sedimentation tank, and sand filter in turn, and then The treated water enters the reuse water pool for collection, and a secondary circulation purification device is also installed on the reuse water pool.
所述的混养鱼池废水的处理装置,其特征在于所述的二次循环净化装置包括依次通过管道连接的第二水泵、活性碳滤池、精滤器及反渗透池,所述的第二水泵的进水口与回用水池连接,反渗透池的出水口与回用水池连接,将二次净化后的水送回至回用水池。The treatment device for the mixed fish pond wastewater is characterized in that the secondary circulation purification device includes a second water pump, an activated carbon filter, a fine filter and a reverse osmosis tank connected by pipelines in sequence, and the second The water inlet of the water pump is connected to the reuse water pool, and the water outlet of the reverse osmosis tank is connected to the reuse water pool, so that the secondary purified water is sent back to the reuse water pool.
所述的混养鱼池废水的处理装置,其特征在于所述的格栅包括粗格栅和细格栅。The treatment device for mixed fish pond wastewater is characterized in that the grid includes a coarse grid and a fine grid.
所述的一种混养鱼池废水的处理工艺,其特征在于微波处理器内加有敏化剂及无机絮剂剂,敏化剂及无机絮剂剂均选用市售的常规敏化剂及无机絮剂剂试剂即可。The process for treating waste water from a mixed fish pond is characterized in that a sensitizer and an inorganic flocculant are added in the microwave processor, and the sensitizer and the inorganic flocculant are all selected from commercially available conventional sensitizers and Inorganic flocculant reagent can be used.
本发明通过采用上述技术,与现有技术相比,具有如下有益效果:Compared with the prior art, the present invention has the following beneficial effects by adopting the above-mentioned technology:
1)本发明的处理工艺简单、操作方便,先经过第一加药桶里的藻类等使废达到自净,再经第二加药桶里的生物活化水处理剂,有效除去水中的氮、磷等杂质,再依次经微波处理器、曝气池、沉淀池、砂滤池处理得到干净的水送至回用水池,回用水池内设置二次循环净化装置,经栅格除去粗杂质后,经活性碳滤池内活性碳的吸附、精滤器及反渗透池的处理,得到进一步的净化,得到纯净的水,可以回收利用;1) The treatment process of the present invention is simple and easy to operate. First, the waste is self-purified through the algae in the first dosing tank, and then the biologically activated water treatment agent in the second dosing tank effectively removes nitrogen and phosphorus in the water and other impurities, and then the clean water obtained by microwave processor, aeration tank, sedimentation tank, and sand filter is sent to the reuse water pool. A secondary cycle purification device is installed in the reuse water pool. After the coarse impurities are removed by the grid, the The adsorption of activated carbon in the activated carbon filter, the treatment of the fine filter and the reverse osmosis tank can be further purified, and pure water can be obtained, which can be recycled;
2)本发明的处理装置结构简单、连接方便,结构简单,整体占地面积小,投资成本低,设计合理,而且使用的基本都是常用的设备,操作简单快捷,处理效果好,可保证水处理效果好,出水质量稳定,最终使水体达到水产养殖要求。2) The treatment device of the present invention is simple in structure, convenient in connection, simple in structure, small in overall floor area, low in investment cost, reasonable in design, and basically uses commonly used equipment, simple and fast in operation, good in treatment effect, and can ensure water The treatment effect is good, the effluent quality is stable, and finally the water body meets the requirements of aquaculture.
附图说明Description of drawings
图1 为本发明的处理装置结构示意图。Fig. 1 is a schematic structural diagram of the processing device of the present invention.
图中:1-格栅,2-集水池,3-第一加药桶,4-第一水泵,5-第二加药桶,6-微波处理器,7-曝气池,8-沉淀池,9-砂滤池,10-回用水池,11-第二水泵,12-活性碳滤池,13-精滤器,14-反渗透池。In the figure: 1-grid, 2-collection tank, 3-first dosing tank, 4-first water pump, 5-second dosing tank, 6-microwave processor, 7-aeration tank, 8-sedimentation Pool, 9-sand filter, 10-reuse water pool, 11-second water pump, 12-activated carbon filter, 13-fine filter, 14-reverse osmosis pool.
具体实施方式detailed description
以下结合说明书附图对本发明作进一步的描述,但本发明的保护范围并不仅限于此:The present invention will be further described below in conjunction with accompanying drawing of description, but protection scope of the present invention is not limited thereto:
如图1所示,本发明的混养鱼池废水的处理装置,包括依次通过管道连接的格栅1、集水池2、第一加药桶3、第一水泵4、第二加药桶5、微波处理器6、曝气池7、沉淀池8、砂滤池9及回用水池10,格栅1包括粗格栅(直径为0.5-1cm)和细格栅(直径为0.05-0.15cm),水经栅格1除去粗杂质后,经集水池2进水口进入集水池2,将水从集水池2出水口从第一加药桶3的进水口进入第一加药桶3,从第一加药桶3的出水口经第一水泵4进入第二加药桶5,再经第二加药桶5的出水口依次进入微波处理器6、曝气池7、沉淀池8、砂滤池9,经处理后水进入回用水池10收集,所述的回用水池10上还设置二次循环净化装置,二次循环净化装置包括依次通过管道连接的第二水泵11、活性碳滤池12、精滤器13及反渗透池14,所述的第二水泵11的进水口与回用水池10连接,反渗透池14的出水口与回用水池10连接,将二次净化后的水送回至回用水池10。As shown in Fig. 1, the treatment device of mixed fish pond wastewater of the present invention comprises grid 1, sump 2, the first dosing bucket 3, the first water pump 4, the second dosing bucket 5 connected by pipelines successively , microwave processor 6, aeration tank 7, sedimentation tank 8, sand filter tank 9 and reuse water tank 10, grid 1 includes coarse grid (0.5-1cm in diameter) and fine grid (0.05-0.15cm in diameter ), after removing coarse impurities through the grid 1, the water enters the sump 2 through the water inlet of the sump 2, and the water enters the first dosing barrel 3 from the water outlet of the sump 2, and enters the first dosing barrel 3 from the water inlet of the first dosing barrel 3. The water outlet of the first dosing barrel 3 enters the second dosing barrel 5 through the first water pump 4, and then enters the microwave processor 6, the aeration tank 7, the sedimentation tank 8, and the sand through the water outlet of the second dosing barrel 5 successively. Filter tank 9, after treatment, the water enters the reuse water pool 10 to collect, and the secondary circulation purification device is also set on the described reuse water pool 10, and the secondary circulation purification device includes the second water pump 11 connected by pipelines, activated carbon filter pool 12, fine filter 13 and reverse osmosis tank 14, the water inlet of the second water pump 11 is connected with the reuse water tank 10, and the water outlet of the reverse osmosis tank 14 is connected with the reuse water tank 10, and the water after secondary purification Send back to the reuse pool 10.
如图所示,本发明的混养鱼池废水处理工艺,具体涉及如下:As shown in the figure, the polyculture fish pond wastewater treatment process of the present invention specifically relates to the following:
1)将混养鱼池废水放出,先经过格栅1,除去杂草等物质后,进入集水池2收集;1) Release the waste water from the polyculture fish pond, first pass through the grid 1, remove weeds and other substances, and then enter the collection tank 2 for collection;
2)当集水池2内的水集至集水池2体积一半时,放入第一加药桶1中进行第一次净化,第一加药桶1培养有藻类和细菌,去废水中的厌氧废液,使水达到自净的作用;2) When the water in the sump 2 is collected to half the volume of the sump 2, it is put into the first dosing tank 1 for the first purification. The first dosing tank 1 is cultivated with algae and bacteria to remove the waste water. Oxygen waste liquid, so that the water can achieve self-purification;
3)净化后再由第一水泵4将水泵入第二加药桶5内,第二加药桶5内加入生物活化水处理剂,所述的生物活化水处理剂由以下重量份数的组分组成:氧化镁6-8份、氧化硅25-45份、氧化铝1-3份、甲基蓝0.5-1份、次氯酸钠2-6份、石灰10-16份,本发明实施例中生物活化水处理剂的组份成重量份数如下:氧化镁7份、氧化硅30份、氧化铝2份、甲基蓝0.8份、次氯酸钠4份、石灰15份,经上述具有增氧活化,消毒灭菌功能的生物活化水处理剂,起到养生健体及提高免疫力、促进动植物生长的作用,对废水进行消毒灭菌等处理,使废水得到二次净化,再经过微波处理器6处理,微波处理器6内加有敏化剂及无机絮剂剂,微波对菌、藻类有高频穿透作用,杀伤能力极强,在短时间内杀灭微生物,有很强的杀菌灭藻功能,其中蓝藻在微波场中只需非常短的时间即由微细粒汇聚呈大颗粒变黄沉降与水分离生剧烈的催化、物理化学反应,转化成不可溶物质或气体从水中分离,水中的大分子、难降解的有机污染物在微波及敏化剂的共同作用下,被分解为小分子,与无机絮剂剂结合生成速沉絮体物去除;金属离子可直接与无机絮剂剂结合生成速沉絮体物沉淀;氨氮转化为氨气逸出;水中磷转化为不可溶解磷酸盐沉淀去除;3) After purification, the first water pump 4 pumps the water into the second dosing tank 5, and the second dosing tank 5 is filled with a biologically activated water treatment agent. The biologically activated water treatment agent is composed of the following parts by weight: Composition: 6-8 parts of magnesium oxide, 25-45 parts of silicon oxide, 1-3 parts of aluminum oxide, 0.5-1 part of methylene blue, 2-6 parts of sodium hypochlorite, 10-16 parts of lime, biological The components and parts by weight of the activated water treatment agent are as follows: 7 parts of magnesia, 30 parts of silicon oxide, 2 parts of aluminum oxide, 0.8 part of methylene blue, 4 parts of sodium hypochlorite, 15 parts of lime, through the above-mentioned activation by increasing oxygen, disinfection The biologically activated water treatment agent with sterilizing function plays a role in health maintenance, improving immunity, and promoting the growth of animals and plants. It can sterilize and sterilize the wastewater, so that the wastewater can be purified twice, and then processed by microwave processor 6 , microwave processor 6 is added with sensitizer and inorganic flocculant agent, microwave has high-frequency penetrating effect on bacteria and algae, strong killing ability, kills microorganisms in a short time, and has strong sterilization and algae killing function Among them, the cyanobacteria in the microwave field only need a very short time to gather from fine particles to large particles, turn yellow, settle and separate from water to produce violent catalytic, physical and chemical reactions, and transform into insoluble substances or gas to separate from water, and the large particles in water Molecular and refractory organic pollutants are decomposed into small molecules under the combined action of microwaves and sensitizers, and combined with inorganic flocculants to form quick-settling flocs for removal; metal ions can be directly combined with inorganic flocculants to generate Rapid precipitation of flocs; ammonia nitrogen is converted into ammonia gas and escaped; phosphorus in water is converted into insoluble phosphate and removed by precipitation;
4)将微波处理器6处理后的废水放入曝气池7使污水和砂砾旋流运动,从而使砂砾碰撞摩擦去除砂砾表面的有机物,降低沉砂的后续处理难度,再沉淀池8沉淀,液固分别,然后经砂滤池9过滤后进入回用水池10;4) Put the wastewater treated by the microwave processor 6 into the aeration tank 7 to make the sewage and the gravel swirl, so that the gravel collides and rubs to remove the organic matter on the surface of the gravel, reducing the difficulty of the subsequent treatment of the grit, and then settles in the sedimentation tank 8. Liquid and solid are separated, and then enter the reuse pool 10 after being filtered by the sand filter tank 9;
5)回用水池10内的水通过第二水泵11将回用水池中的水泵入活性碳滤池12吸附去色后,再经精滤器13过滤,最后经过反渗透池14作用后再回到回用水池10,得到净化后的能循环利用的水,精滤器13内设置至少一层微孔过滤膜,所述的微孔过滤膜的孔径大小为0.2-0.4 微米。5) The water in the reused water pool 10 is pumped into the activated carbon filter 12 through the second water pump 11 to absorb and remove the color, then filtered through the fine filter 13, and finally returned to the reverse osmosis pool 14 Reuse the water pool 10 to obtain purified water that can be recycled, and at least one layer of microporous filtration membrane is arranged in the fine filter 13, and the pore size of the microporous filtration membrane is 0.2-0.4 microns.
本发明的处理工艺简单、操作方便,先经过第一加药桶里的藻类等使废达到自净,再经第二加药桶里的生物活化水处理剂,有效除去水中的氮、磷等杂质,再依次经微波处理器、曝气池、沉淀池、砂滤池处理得到干净的水送至回用水池,回用水池内设置二次循环净化装置,经栅格除去粗杂质后,经活性碳滤池内活性碳的吸附、精滤器及反渗透池的处理,得到进一步的净化,得到纯净的水,可以回收利用;且处理装置结构简单、连接方便,结构简单,整体占地面积小,投资成本低,设计合理,而且使用的基本都是常用的设备,操作简单快捷,处理效果好,可保证水处理效果好,出水质量稳定,最终使水体达到水产养殖要求。The treatment process of the present invention is simple and easy to operate. The waste can be self-purified through the algae in the first dosing tank, and then the biologically activated water treatment agent in the second dosing tank can effectively remove impurities such as nitrogen and phosphorus in the water. , and then processed by microwave processor, aeration tank, sedimentation tank, and sand filter in turn, the clean water is sent to the reuse water pool, and a secondary cycle purification device is installed in the reuse water pool. After the coarse impurities are removed by the grid, the activated carbon The adsorption of activated carbon in the filter, the treatment of the fine filter and the reverse osmosis tank can be further purified to obtain pure water, which can be recycled; and the structure of the treatment device is simple, convenient to connect, simple in structure, small in overall footprint, and low in investment. The cost is low, the design is reasonable, and the commonly used equipment is basically used. The operation is simple and fast, and the treatment effect is good, which can ensure good water treatment effect and stable water quality, and finally make the water body meet the requirements of aquaculture.
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