CN104512074A - Composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and manufacture method thereof - Google Patents
Composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and manufacture method thereof Download PDFInfo
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- CN104512074A CN104512074A CN201310452036.9A CN201310452036A CN104512074A CN 104512074 A CN104512074 A CN 104512074A CN 201310452036 A CN201310452036 A CN 201310452036A CN 104512074 A CN104512074 A CN 104512074A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
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Abstract
The invention relates to a composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and a manufacture method thereof. The manufacture method comprises: arranging a first combination layer and a second combination layer respectively at the front side and the back side of base cloth, then pasting and fixing a rubber layer on the surface of the first combination layer, and pasting and fixing a thermoplastic polyvinyl layer on the back side of the second combination layer. Therefore, the thermosetting rubber and the thermoplastic material, which are heterogenous materials, are tightly combined, the added value of a rubber product is improved, and the functionality and the practicability of the product are increased.
Description
Technical field
The present invention relates to a kind of compound adhesive tape and manufacture method thereof, particularly relate to compound adhesive tape and the manufacture method thereof of a kind of thermoset rubber and thermoplastic polyvinyl chloride.
Background technology
Generally speaking, the rubber applications now for thin goods is more and more extensive, no matter be applied on the Related products such as resistance to burning vest, life raft or industrial raincoat quite universal, other are applied on industry and people's livelihood articles for use also quite common in addition.But, in practical application, the rubber Related product of the overwhelming majority is all homogeneous quality of rubber materials, because rubber belongs to thermosets, be difficult to utilize high frequency or solid to combine closely with thermoplastic, directly form thermoplastic/thermosetting composite although have at present with hot pressing mode, usually only can make bulk, being not suitable for for continuous seepage is thin goods.
For this reason, how to improve rubber and the manufacture method thereof of prior art, make to reach the tight joint with thermoplastic, become the important key promoting application of rubber product.
Summary of the invention
In view of above problem, main purpose of the present invention is the compound adhesive tape and the manufacture method thereof that provide a kind of thermoset rubber and thermoplastic polyvinyl chloride, thermoset rubber can be made to engage closely with thermoplastic, and then promote the surcharge of rubber, and increase the functional of product and practicality.Whereby, various problem and disappearance that prior art meets with can effectively be overcome.
To achieve these objectives, the invention provides the compound adhesive tape of a kind of thermoset rubber and thermoplastic polyvinyl chloride, it comprises Ji Bu, the first following layer, rubber layer, the second following layer and thermoplastic polyvinyl chloride's layer.Wherein, the first following layer is arranged at the front of base cloth, and rubber layer is arranged at the surface of the first following layer, and the second following layer is arranged at the back side of base cloth, and thermoplastic polyvinyl chloride's layer is arranged at the surface of the second following layer.
About base cloth fabric, the present invention selects nylon fabric or dacron fabric as base cloth.
About the composition of the first following layer and the second following layer, needing the material of compound rubber layer and thermoplastic polyvinyl chloride's layer respectively in principle, is good with same material; In embodiment, wherein the composition of the first following layer comprises neoprene 100 weight portion, calcium carbonate 25 weight portion, zinc oxide 5 weight portion and toluene 250 weight portion, and the composition of the second following layer is Polyurethane resin.
About the material of rubber layer, the composition of rubber layer can comprise ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber.In embodiment, the composition of rubber layer includes neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion.Wherein, inorganic filler is calcium carbonate, silica, talcum powder or clay, and organic filler is stearic acid or antioxidant, and vulcanizing agent is sulphur, zinc oxide or organic accelerator; Antioxidant can be four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester (antioxidant 1010), and organic accelerator can be dibenzothiazyl disulfide or trimethyl-2-thiocarbamide.
In addition, about the material of thermoplastic polyvinyl chloride's layer, its composition then can comprise polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate (DINP) and calcium carbonate 20 weight portion.
The present invention also provides the manufacture method of the compound adhesive tape of a kind of thermoset rubber and thermoplastic polyvinyl chloride, it comprises the following steps: first provide Ji Bu, form the first following layer in the front of Ji Bu, make rubber layer again, and rubber layer laminating is bonded to the surface of the first following layer, and form the second following layer in the back side of Ji Bu, then, form thermoplastic polyvinyl chloride's layer, and make thermoplastic polyvinyl chloride's laminating close the surface being bonded to the second following layer.
About base cloth fabric, the present invention selects nylon fabric or dacron fabric as base cloth.
About the making of the first following layer and the second following layer, wherein the first following layer is coated with by the first solid to form, and the preparation method of the first solid is by neoprene 100 weight portion, calcium carbonate 25 weight portion, zinc oxide 5 weight portion carry out mixing in mixing roll, the mixing blob of viscose completed is dissolved in the toluene of 250 weight portions again and is formed, second following layer is coated with by the second solid to form, and the composition of the second solid is Polyurethane resin.
About the making of rubber layer, its making step comprises: first provide rubber size, rubber size being inserted ten thousand horsepowers of mixing rolls carries out mixing, and via thick wheel and the fully mixing of thin wheel under temperature range between 80 to 100 DEG C, then, utilize calender lamination machine, after mixing and mixed rubber size is calendered to the first predetermined thickness, fit in the surface of the first following layer again, then carry out vulcanizing treatment, to form rubber layer.Between aforementioned first predetermined thickness is 0.1 to 2.0 centimeter, and between the rolling temperature of calendering and laminating step is 75 to 95 DEG C, between the curing temperature of vulcanizing treatment is 130 to 160 DEG C.Wherein, the composition of rubber size comprises ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber; In embodiment, the composition of rubber size comprises neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion.Wherein, inorganic filler is calcium carbonate, silica, talcum powder or clay, and organic filler is stearic acid or antioxidant, and vulcanizing agent is sulphur, zinc oxide or organic accelerator; Antioxidant is four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester (antioxidant 1010), and organic accelerator is dibenzothiazyl disulfide, trimethyl-2-thiocarbamide.
About the making of thermoplastic polyvinyl chloride's layer, its making step comprises: provide thermoplastic polyvinyl chloride sizing material, then, utilize calender lamination machine, after thermoplastic polyvinyl chloride's sizing material is calendered to the second predetermined thickness, then fit in the surface of the second following layer, to form thermoplastic polyvinyl chloride's layer.Between aforementioned second predetermined thickness is 0.1 to 2.0 centimeter, and calendering and laminating step rolling temperature be 140 to 170 DEG C between.In embodiment, thermoplastic polyvinyl chloride's sizing material comprises polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate (DINP) and calcium carbonate 20 weight portion.
The present invention has following all advantage relative to prior art:
1, the compound adhesive tape of thermoset rubber of the present invention and thermoplastic polyvinyl chloride has the characteristic that high-wearing feature can possess again rubber, can be applicable to and needs on the product of high abrasion, is also not easy to cause breakage or surface breakdown.
2, owing to being the composite of arranging in pairs or groups made by rubber via thermoplastic polyvinyl chloride, functional because of thermoplastic polyvinyl chloride, can make hardness range comparatively wide, and elevating mechanism intensity, and has oil resistant, water-fast with cold-resistant effect.
3, the present invention is different from existing hot pressing mode preparation process, non-ly only bulk can be made, the present invention is suitable for the thin goods that continuous seepage is long code sample (long code sample refers to that to be of a size of full width wide 150 centimeters, and length is (about 328 meters) more than 300 yards) very much.
4, the compound adhesive tape of thermoset rubber of the present invention and thermoplastic polyvinyl chloride, wherein rubber layer can more be combined by rubber solid and another rubber, and wherein thermoplastic polyvinyl chloride's layer can be made high frequency to other thermoplastic polyvinyl chlorides or be binded by solid again, so namely compound adhesive tape by changing the sandwich construction of rubber and thermoplastic polyvinyl chloride, increases its surcharge.
For making there is further understanding to object of the present invention, feature and function thereof, hereby coordinate graphic being described in detail as follows.
Accompanying drawing explanation
Fig. 1 is the flow chart of the manufacture method of the compound adhesive tape of thermoset rubber provided by the present invention and thermoplastic polyvinyl chloride;
Fig. 2 is the schematic diagram of the compound adhesive tape of thermoset rubber provided by the present invention and thermoplastic polyvinyl chloride.
Description of reference numerals: the compound adhesive tape of 1-rubber and thermoplastic polyvinyl chloride; 10-base cloth; 12-first following layer; 14-rubber layer; 16-second following layer; 18-thermoplastic polyvinyl chloride layer.
Detailed description of the invention
Be below embodiment and test data etc. thereof, but content of the present invention is not limited to the scope of these embodiments.
Please refer to Fig. 1, the flow process of the manufacture method of the compound adhesive tape of thermoset rubber provided by the present invention and thermoplastic polyvinyl chloride is described; And referring to Fig. 2, it illustrates the compound adhesive tape of thermoset rubber provided by the present invention and thermoplastic polyvinyl chloride.Below describe each step of manufacture method of the present invention in detail:
First, as described in step S100, provide base cloth 10, the fabric of base cloth can select nylon fabric and dacron fabric wherein a kind of, but practice is not limited to this.
Then, as described in step S110, form the first following layer 12 in the front of base cloth 10, the first following layer 12 can be formed with coating method by the first solid, and the first following layer 12 has the function engaging base cloth 10 and rubber layer 14.Specifically, the preparation method of the first solid can by neoprene 100 weight portion, and calcium carbonate 25 weight portion, zinc oxide 5 weight portion carry out mixing in mixing roll, and the mixing blob of viscose completed is dissolved in the toluene of 250 weight portions again and is formed.In principle, the composition of the first following layer 12, needs the material of compound rubber layer usually, is good with same material.
Then, as step S120, make rubber layer 14, and rubber layer 14 laminating is bonded to the surface of the first following layer 12.In more detail, making the mode of rubber layer 14, is first provide rubber size, rubber size is inserted carry out in ten thousand horsepowers of mixing rolls mixing, and via thick wheel and the fully mixing of thin wheel under temperature range between 80 to 100 DEG C.Wherein, rubber size can be arbitrarily synthesis and the natural and functional quality of rubber materials of tool, such as with ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber for main composition.Specifically, the composition of rubber size comprises neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion.Wherein, inorganic filler is calcium carbonate, silica, talcum powder or clay, and organic filler is stearic acid or antioxidant, and vulcanizing agent is sulphur, zinc oxide or organic accelerator; Antioxidant is four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester (antioxidant 1010), and organic accelerator is dibenzothiazyl disulfide or trimethyl-2-thiocarbamide.
Next, by calender lamination machine, mixing and mixed rubber size is calendered to the first predetermined thickness, and the first predetermined thickness is between 0.1 to 2.0 centimeter, the rubber size rolled is fitted in the surface of the first following layer 12, its rolling temperature controls between 75 to 95 DEG C again.
Afterwards, then the base cloth 10 posting rubber size is sent into high temperature vulcanized equipment, to carry out vulcanizing treatment, and form rubber layer 14 of the present invention.Wherein the curing temperature of vulcanizing treatment is between 130 to 160 DEG C, to make rubber layer 14 and base cloth 10 carry out building bridge and solidifying, and makes rubber layer 14 and base cloth 10 can reach by the first following layer 12 effect fitted tightly.
As described in step S130, form the second following layer 16 in the reverse side of base cloth 10.Second following layer 16 can be formed with coating method by the second solid, and the second following layer 16 has the function engaging base cloth 10 and thermoplastic polyvinyl chloride's layer 18.Specifically, the composition of the second solid is Polyurethane resin, and consumption can be 70 grams/m.Meanwhile, the composition of the second following layer 16, needing the material coordinating thermoplastic polyvinyl chloride's layer 18 in principle, is good with same material.
Afterwards, as described in step S140, make thermoplastic polyvinyl chloride layer 18, and thermoplastic polyvinyl chloride's layer 18 is fitted and is bonded to the surface of the second following layer 16.In more detail, make the mode of thermoplastic polyvinyl chloride's layer 18, that thermoplastic polyvinyl chloride is first provided sizing material, and thermoplastic polyvinyl chloride's sizing material is sent into the process of carrying out in calender lamination machine rolling and fitting with conveyer belt, that is, first thermoplastic polyvinyl chloride's sizing material is made to be melting state by calender lamination machine, be calendered to the second predetermined thickness again to form thermoplastic polyvinyl chloride's layer 18, second predetermined thickness is between 0.1 to 2.0 centimeter, again by calender lamination machine, thermoplastic polyvinyl chloride's layer 18 laminating is bonded to the surface of the second following layer 16, its rolling temperature controls between 140 to 170 DEG C.Specifically, thermoplastic polyvinyl chloride's sizing material comprises polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate (DINP) and calcium carbonate 20 weight portion.
Finally, after thermoplastic polyvinyl chloride's layer 18 of having fitted, the process of rolling can be carried out, namely complete the preparation process of the compound adhesive tape 1 of thermoset rubber and thermoplastic polyvinyl chloride.
As shown in Figure 2, the compound adhesive tape 1 of thermoset rubber of the present invention and thermoplastic polyvinyl chloride, it comprises base cloth 10, first following layer 12, rubber layer 14, second following layer 16 and thermoplastic polyvinyl chloride's layer 18.First following layer 12 is arranged at the front of base cloth 10, and rubber layer 14 is arranged at the surface of the first following layer 12, and the second following layer 16 is arranged at the back side of base cloth 10, and thermoplastic polyvinyl chloride's layer 18 is arranged at the surface of the second following layer 16.
Wherein, the material of base cloth 10 can be nylon fabric, dacron fabric or other fabrics.The composition of the first following layer 12 and the second following layer 16, needing the material of compound rubber layer 14 and thermoplastic polyvinyl chloride's layer 18 respectively in principle, is good with same material; Specifically, the composition of the first following layer 12 can comprise neoprene 100 weight portion, and calcium carbonate 25 weight portion, zinc oxide 5 weight portion and toluene 250 weight portion, the composition of the second following layer 16 can be Polyurethane resin.And rubber layer 14 can select arbitrarily synthesis and the natural and functional quality of rubber materials of tool, such as with ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber for main composition.Specifically, the composition of rubber layer 14 comprises neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion; Inorganic filler is calcium carbonate, silica, talcum powder or clay, organic filler is stearic acid or antioxidant, vulcanizing agent is sulphur, zinc oxide or organic accelerator, wherein, antioxidant can select phenols antiaging agent, such as four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester (antioxidant 1010), organic accelerator can select thio urea compounds, such as dibenzothiazyl disulfide or trimethyl-2-thiocarbamide.And the composition of thermoplastic polyvinyl chloride's layer 18 can comprise polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate (DINP) and calcium carbonate 20 weight portion.
Under please refer to Fig. 2, will be described in more detail the present invention by a preferred embodiment.
The manufacture method of the thermoset rubber of the present embodiment and the compound adhesive tape of thermoplastic polyvinyl chloride, its step comprises:
First, select nylon fabric as the fabric of base cloth 10.Then, by neoprene 100 weight portion, calcium carbonate 25 weight portion, zinc oxide 5 weight portion carry out mixing in mixing roll, and the mixing blob of viscose completed is dissolved in the toluene of 250 weight portions again and forms the first solid, again the first solid is coated the front of base cloth 10, to form the first following layer 12.
Should be noted that, as used in this description, the use amount of the composition of various material take " weight portion " as the unit of counting, according to the present embodiment content, wherein rubber size composition is be 100:25:5:250(weight portion/weight portion/weight portion/weight portion containing ratio) neoprene: calcium carbonate: zinc oxide: toluene, the namely neoprene of every 100 weight portions, the use amount of calcium carbonate is 25 weight portions, the use amount of zinc oxide is 5 weight portions, the use amount of toluene is 250 weight portions, as weight portion is converted to kilogram for digit, then be equivalent to the neoprene often using 100 kilograms, the use amount of calcium carbonate is 25 kilograms, the use amount of zinc oxide is 5 kilograms, the use amount of toluene is 250 kilograms.Below describing also is these situations, therefore repeats no more.
Then, rubber size is inserted and carries out mixing in ten thousand horsepowers of mixing rolls, and fully to mix via thick wheel and thin wheel at the temperature of 100 DEG C.Wherein, rubber size comprises neoprene 80 weight portion, ethylene-propylene rubber 20 weight portion, calcium carbonate 100 weight portion, stearic acid 5 weight portion and sulphur 3 weight portion.Then, at rolling temperature 80 DEG C, mixing and mixed rubber size is calendered to 1.0 centimeters, then fits in the surface of the first following layer 12.Afterwards, then the base cloth 10 posting rubber size is sent into high temperature vulcanized equipment, at curing temperature 160 DEG C, carry out vulcanizing treatment, with obtained rubber layer 14.
Then, Polyurethane resin is coated reverse side in base cloth 10 with the consumption of 70 grams/m, and forms the second following layer 16.
Afterwards, sent in calender lamination machine with conveyer belt by thermoplastic polyvinyl chloride sizing material, rolling temperature is 170 DEG C, is calendered to 1.0 centimeters, then laminating is bonded to the surface of the second following layer 16, to form thermoplastic polyvinyl chloride's layer 18.Wherein, thermoplastic polyvinyl chloride's sizing material comprises polyvinyl chloride 100 weight portion, DINP plasticizer 70 weight portion and calcium carbonate 20 weight portion.
Finally, after laminating thermoplastic polyvinyl chloride layer 18, can rolling be carried out, and the compound adhesive tape 1 of obtained thermoset rubber and thermoplastic polyvinyl chloride.
Above-described embodiment is only be described the preferred embodiment of the present invention; not scope of the present invention is limited; under not departing from the present invention and designing the prerequisite of spirit; the various distortion that those of ordinary skill in the art make technical scheme of the present invention and improvement, all should fall in protection domain that claims of the present invention determines.
Claims (23)
1. a thermoset rubber and thermoplastic polyvinyl chloride's compound adhesive tape, is characterized in that including:
Ji Bu, has front and the back side;
First following layer, is arranged at this front of this base cloth;
Rubber layer, is arranged at the surface of this first following layer;
Second following layer, is arranged at this back side of this base cloth; And
Thermoplastic polyvinyl chloride's layer, is arranged at the surface of this second following layer.
2. the compound adhesive tape of thermoset rubber as claimed in claim 1 and thermoplastic polyvinyl chloride, is characterized in that: this base cloth is nylon fabric or dacron fabric.
3. the compound adhesive tape of thermoset rubber as claimed in claim 1 and thermoplastic polyvinyl chloride, it is characterized in that: the composition of this first following layer comprises neoprene 100 weight portion, calcium carbonate 25 weight portion, zinc oxide 5 weight portion and toluene 250 weight portion, the composition of this second following layer is Polyurethane resin.
4. the compound adhesive tape of thermoset rubber as claimed in claim 1 and thermoplastic polyvinyl chloride, is characterized in that: the composition of this rubber layer comprises ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber.
5. the compound adhesive tape of thermoset rubber as claimed in claim 1 and thermoplastic polyvinyl chloride, is characterized in that: the composition of this rubber layer comprises neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion.
6. the compound adhesive tape of thermoset rubber as claimed in claim 5 and thermoplastic polyvinyl chloride, it is characterized in that: this inorganic filler is calcium carbonate, silica, talcum powder or clay, this organic filler is stearic acid or antioxidant, and this vulcanizing agent is sulphur, zinc oxide or organic accelerator.
7. the compound adhesive tape of thermoset rubber as claimed in claim 6 and thermoplastic polyvinyl chloride, it is characterized in that: this antioxidant is four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester, this organic accelerator is dibenzothiazyl disulfide or trimethyl-2-thiocarbamide.
8. the compound adhesive tape of thermoset rubber as claimed in claim 1 and thermoplastic polyvinyl chloride, is characterized in that: the composition of this thermoplastic polyvinyl chloride's layer comprises polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate and calcium carbonate 20 weight portion.
9. a manufacture method for the compound adhesive tape of thermoset rubber and thermoplastic polyvinyl chloride, is characterized in that: comprise the following step:
There is provided Ji Bu, this base cloth has front and back;
Form the first following layer in this front of this base cloth;
Make rubber layer, and this rubber layer is fitted and is bonded to the surface of this first following layer;
Form the second following layer in this back side of this base cloth; And
Make thermoplastic polyvinyl chloride's layer, and make this thermoplastic polyvinyl chloride's laminating merge the surface being bonded to this second following layer.
10. the manufacture method of the compound adhesive tape of thermoset rubber as claimed in claim 9 and thermoplastic polyvinyl chloride, is characterized in that: this base cloth is nylon fabric or dacron fabric.
The manufacture method of the compound adhesive tape of 11. thermoset rubbers as claimed in claim 9 and thermoplastic polyvinyl chloride, it is characterized in that: this first following layer is coated with by the first solid to form, the preparation method of the first solid is by neoprene 100 weight portion, calcium carbonate 25 weight portion and zinc oxide 5 weight portion carry out mixing in mixing roll, the mixing blob of viscose completed is dissolved in the toluene of 250 weight portions again and is formed, and this second following layer is coated with by the second solid to form, the composition of this second solid is Polyurethane resin.
The manufacture method of the compound adhesive tape of 12. thermoset rubbers as claimed in claim 9 and thermoplastic polyvinyl chloride, is characterized in that the step making this rubber layer comprises:
Rubber size is provided, this rubber size is inserted ten thousand horsepowers of mixing rolls and carry out mixing, and via thick wheel and the fully mixing of thin wheel under temperature range between 80 to 100 DEG C;
After this rubber size mixing and mixed is calendered to the first predetermined thickness, then fit in the surface of this first following layer; And
Carry out vulcanizing treatment, to form this rubber layer.
The manufacture method of the compound adhesive tape of 13. thermoset rubbers as claimed in claim 12 and thermoplastic polyvinyl chloride, is characterized in that: the composition of this rubber size comprises ethylene-propylene rubber, butadiene-styrene rubber, acrylonitrile-butadiene rubber, butyl rubber, butadiene rubber, neoprene or chlorosulfonation rubber.
The manufacture method of the compound adhesive tape of 14. thermoset rubbers as claimed in claim 12 and thermoplastic polyvinyl chloride, is characterized in that: the composition of this rubber size comprises neoprene 60 to 80 weight portion, ethylene-propylene rubber 20 to 40 weight portion, inorganic filler 100 to 200 weight portion, organic filler 5 to 20 weight portion and vulcanizing agent 2 to 5 weight portion.
The manufacture method of the compound adhesive tape of 15. thermoset rubbers as claimed in claim 14 and thermoplastic polyvinyl chloride, it is characterized in that: this inorganic filler is calcium carbonate, silica, talcum powder or clay, this organic filler is stearic acid or antioxidant, and this vulcanizing agent is sulphur, zinc oxide or organic accelerator.
The manufacture method of the compound adhesive tape of 16. thermoset rubbers as claimed in claim 15 and thermoplastic polyvinyl chloride, it is characterized in that: this antioxidant is four (3,5-di-t-butyl-4-hydroxyl) benzenpropanoic acid pentaerythritol ester, this organic accelerator is dibenzothiazyl disulfide, trimethyl-2-thiocarbamide.
The manufacture method of the compound adhesive tape of 17. thermoset rubbers as claimed in claim 12 and thermoplastic polyvinyl chloride, is characterized in that: between this first predetermined thickness is 0.1 to 2.0 centimeter.
The manufacture method of the compound adhesive tape of 18. thermoset rubbers as claimed in claim 12 and thermoplastic polyvinyl chloride, is characterized in that: this calendering and laminating step utilize calender lamination machine to carry out, between its rolling temperature is 75 to 95 DEG C.
The manufacture method of the compound adhesive tape of 19. thermoset rubbers as claimed in claim 12 and thermoplastic polyvinyl chloride, is characterized in that: between the curing temperature of this vulcanizing treatment step is 130 to 160 DEG C.
The manufacture method of the compound adhesive tape of 20. thermoset rubbers as claimed in claim 9 and thermoplastic polyvinyl chloride, is characterized in that the step making this thermoplastic polyvinyl chloride's layer comprises:
Thermoplastic polyvinyl chloride is provided sizing material; And
After this thermoplastic polyvinyl chloride's sizing material is calendered to the second predetermined thickness, then fit in the surface of this second following layer, to form this thermoplastic polyvinyl chloride's layer.
The manufacture method of the compound adhesive tape of 21. thermoset rubbers as claimed in claim 20 and thermoplastic polyvinyl chloride, is characterized in that: this thermoplastic polyvinyl chloride's sizing material comprises polyvinyl chloride 100 weight portion, plasticizer 70 weight portion of diisononyl phthalate and calcium carbonate 20 weight portion.
The manufacture method of the compound adhesive tape of 22. thermoset rubbers as claimed in claim 20 and thermoplastic polyvinyl chloride, is characterized in that: this calendering and laminating step utilize calender lamination machine to carry out, between its rolling temperature is 140 to 170 DEG C.
The manufacture method of the compound adhesive tape of 23. thermoset rubbers as claimed in claim 20 and thermoplastic polyvinyl chloride, is characterized in that: between this second predetermined thickness is 0.1 to 2.0 centimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310452036.9A CN104512074A (en) | 2013-09-27 | 2013-09-27 | Composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310452036.9A CN104512074A (en) | 2013-09-27 | 2013-09-27 | Composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and manufacture method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104512074A true CN104512074A (en) | 2015-04-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310452036.9A Pending CN104512074A (en) | 2013-09-27 | 2013-09-27 | Composite adhesive plaster of thermosetting rubber and thermoplastic polyvinyl chloride and manufacture method thereof |
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| Country | Link |
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| CN (1) | CN104512074A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115838522A (en) * | 2023-02-15 | 2023-03-24 | 邱县合众康复防护用品有限公司 | Special protection chemical-proof high-performance modified rubber adhesive tape |
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| CN103158304A (en) * | 2011-12-14 | 2013-06-19 | 常熟市新华化工有限公司 | Production process of special rubber fabric |
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| CN1506220A (en) * | 2002-12-10 | 2004-06-23 | 厚生股份有限公司 | Production process of continuous elastic cloth-rubber composition coil |
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