CN104449191A - Waterborne coating for glass door having magnetotherapeutic effect and preparation method of waterborne coating - Google Patents
Waterborne coating for glass door having magnetotherapeutic effect and preparation method of waterborne coating Download PDFInfo
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- CN104449191A CN104449191A CN201410568675.6A CN201410568675A CN104449191A CN 104449191 A CN104449191 A CN 104449191A CN 201410568675 A CN201410568675 A CN 201410568675A CN 104449191 A CN104449191 A CN 104449191A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Inorganic Chemistry (AREA)
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Abstract
The invention discloses a waterborne coating for a glass door having a magnetotherapeutic effect. The waterborne coating is characterized by being prepared from the following raw materials in parts by weight: 13-15 parts of EVA emulsion, 12-14 parts of maleic anhydride resin, 30-35 parts of amino resin, 1-2 parts of triethylenetetramine, 0.3-0.5 part of an aqueous solution of sodium polyacrylate, 0.2-0.3 part of stearic acid diethanolamide, 0.2-0.4 part of an aqueous solution of polyethylene glycol, 1-3 part of propylene glycol monoethyl ether, 0.2-0.4 part of a flatting agent BYK-333, 0.3-0.6 part of alkanolamine fatty acid titanate, 0.2-0.4 part of fluoroalkyl polyether modified polysiloxane, 2-3 parts of cinnamon oil, 0.3-0.5 part of sodium dodecyl sulfate, 0.6-1.0 part of magnetite powder, 1-2 parts of tourmaline powder, 3-5 parts of a modified nanometer titanium dioxide photocatalyst, 1-2 parts of pigment and 10-15 parts of deionized water. According to the coating, added tourmaline has biological electrode micro-current and a potential which can change, and by the interaction between magnetic field induction and magnetite powder, the metabolism of the human body can be promoted, the blood circulation can also be promoted, the disease resistance is enhanced, the incidence of diseases is decreased and the good benefit to the human body is achieved; by adding the modified nanometer titanium dioxide photocatalyst, the toxic and harmful gas in the air can be effectively degraded, a variety of bacteria are killed and a healthy and comfortable home environment is built.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of glass door use coating with magnetotherapy effect and preparation method thereof.
Background technology
Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings, using water as dispersion medium, only adopts a small amount of hypotoxicity alcohol ether organic solvent, safety and environmental protection, economizes on resources, and eliminates the danger of presence of fire during construction, is conducive to reducing topsoil.Water-borne coatings is very good to material surface adaptability, and can construct equally at wet environment, coating adhesion is strong.Glass and glasswork, because of attractive in appearance and needs that are performance, coating need be applied thereon, glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, the requirement having surmounted traditional decoration far away and beautified, the performances such as wear-resistant to it, anti-zoned quarter, weathering resistance propose requirements at the higher level.
Nano photo-catalytic refers under light illumination, there is not chemical transformation in self, but the material of chemical reaction can be promoted, nano TiO 2 is topmost photocatalyst material, when after the energy that it absorbs in sunlight or other light sources, a series of reaction occurs can become harmless carbonic acid gas and water by oxygenolysis such as most of organism, pollutent, foul smell, bacteriums.If but dispersing technology is not good in the product for nano-titania photocatalyst, thus cause reunion.This reunion directly has influence on photocatalyst activity, reduces the photo-catalysis capability of product, and then loses pollution degraded effect.Binchotan and diatomite support process according to this situation by the present invention, increase specific surface area, nano photo-catalytic is adsorbed on carrier, and utilize cupric ion, silver ions and rare earth element to carry out modification to nano photo-catalytic, increase the function such as sterilization, sterilization, avoid nano photocatalyst catalytic material in coating, disperse uneven generation to reunite and lose light-catalysed ability.
Summary of the invention
The object of this invention is to provide a kind of glass door use coating with magnetotherapy effect and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of glass door use coating with magnetotherapy effect, be made up of the raw material of following weight part: EVA emulsion 13-15, apple anhydride dehydration resin 12-14, aminoresin 30-35, triethylenetetramine 1-2, aqueous sodium polyacrylate 0.3-0.5, Stearic acid diethanolamine salt 0.2-0.3, Aqueous Solutions of Polyethylene Glycol 0.2-0.4, dihydroxypropane single-ether 1-3, flow agent BYK-3330.2-0.4, hydramine lipid acid titanic acid ester 0.3-0.6, fluorine-based alkyl, polyether modified polyorganosiloxane 0.2-0.4, Oleum Cinnamomi 2-3, sodium laurylsulfonate 0.3-0.5, magnet powder 0.6-1.0, tourmaline powder 1-2, modified nano-titanium dioxide photocatalyst 3-5, pigment 1-2, deionized water 10-15,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part: nano-titania photocatalyst 40-50, nano silicon 15-20, nano-tourmaline 10-15, binchotan 10-15, rare earth element 0.5-1.0, copper powder 0.7-1.4, silver powder 0.6-1.2, cobalt oxide powder 0.4-0.8, diatomite 8-12, alkylphenol polyoxyethylene 0.6-1.2, Silane coupling agent KH550 0.7-1.4, the salpeter solution 20-40 of 20%, the sodium hydroxide solution 20-40 of 30%, polyvinyl alcohol 1-2, st-yrax n-butyl ether 0.3-0.5, ferric acetyl acetonade 0.2-0.4, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
A kind of glass door use coating with magnetotherapy effect of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-333, fluorine-based alkyl, polyether modified polyorganosiloxane, Oleum Cinnamomi, sodium laurylsulfonate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds aqueous sodium polyacrylate, Stearic acid diethanolamine salt, dihydroxypropane single-ether stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds EVA emulsion, apple anhydride dehydration resin, aminoresin, triethylenetetramine, Aqueous Solutions of Polyethylene Glycol stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine lipid acid titanic acid ester, pigment, magnet powder, tourmaline powder, modified nano-titanium dioxide photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: the tourmalinite that coating of the present invention adds has the atomic electric current of bioelectricity, there is current potential and potential variation occurs, interacted by magnetic field induction and magnet powder, the metabolism of human body can be promoted, stimulate circulation, strengthen resistance against diseases, reduce the generation of disease, have good benefit to human body, the present invention also adds the toxic and harmful that modified nano-titanium dioxide photocatalyst can effectively be degraded in air, kill various bacteria, build healthy comfortable domestic environment.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of glass door use coating with magnetotherapy effect, be made up of the raw material of following weight part (kilogram): EVA emulsion 14, apple anhydride dehydration resin 13, aminoresin 34, triethylenetetramine 2, aqueous sodium polyacrylate 0.4, Stearic acid diethanolamine salt 0.3, Aqueous Solutions of Polyethylene Glycol 0.4, dihydroxypropane single-ether 3, flow agent BYK-3330.3, hydramine lipid acid titanic acid ester 0.5, fluorine-based alkyl, polyether modified polyorganosiloxane 0.4, Oleum Cinnamomi 2, sodium laurylsulfonate 0.4, magnet powder 0.8, tourmaline powder 2, modified nano-titanium dioxide photocatalyst 4, pigment 1, deionized water 15,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part (kilogram): nano-titania photocatalyst 44, nano silicon 16, nano-tourmaline 12, binchotan 14, rare earth element 0.5, copper powder 0.8, silver powder 0.7, cobalt oxide powder 0.5, diatomite 10, alkylphenol polyoxyethylene 0.8, Silane coupling agent KH550 0.8, the salpeter solution 36 of 20%, the sodium hydroxide solution 34 of 30%, polyvinyl alcohol 1, st-yrax n-butyl ether 0.3, ferric acetyl acetonade 0.3, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
A kind of glass door use coating with magnetotherapy effect of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-333, fluorine-based alkyl, polyether modified polyorganosiloxane, Oleum Cinnamomi, sodium laurylsulfonate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds aqueous sodium polyacrylate, Stearic acid diethanolamine salt, dihydroxypropane single-ether stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds EVA emulsion, apple anhydride dehydration resin, aminoresin, triethylenetetramine, Aqueous Solutions of Polyethylene Glycol stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine lipid acid titanic acid ester, pigment, magnet powder, tourmaline powder, modified nano-titanium dioxide photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Glass paint sticking power experiment (frame method) of the present invention≤1 grade, snappiness experiment≤1mm, impact experiment: 50cm, hardness: 4H, cut resistance test: 2 grades, water tolerance test (leaching distilled water 500 hours): without exception, resistance to boiling water experiment (100 ° of C >=8 hour): unchanged, ethanol-tolerant experiment (90% soaks 24 hours): without exception, artificial ageing resistance is tested: 500 hours are non-foaming, do not peel off, flawless.
Claims (2)
1. one kind has the glass door use coating of magnetotherapy effect, it is characterized in that, be made up of the raw material of following weight part: EVA emulsion 13-15, apple anhydride dehydration resin 12-14, aminoresin 30-35, triethylenetetramine 1-2, aqueous sodium polyacrylate 0.3-0.5, Stearic acid diethanolamine salt 0.2-0.3, Aqueous Solutions of Polyethylene Glycol 0.2-0.4, dihydroxypropane single-ether 1-3, flow agent BYK-3330.2-0.4, hydramine lipid acid titanic acid ester 0.3-0.6, fluorine-based alkyl, polyether modified polyorganosiloxane 0.2-0.4, Oleum Cinnamomi 2-3, sodium laurylsulfonate 0.3-0.5, magnet powder 0.6-1.0, tourmaline powder 1-2, modified nano-titanium dioxide photocatalyst 3-5, pigment 1-2, deionized water 10-15,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part: nano-titania photocatalyst 40-50, nano silicon 15-20, nano-tourmaline 10-15, binchotan 10-15, rare earth element 0.5-1.0, copper powder 0.7-1.4, silver powder 0.6-1.2, cobalt oxide powder 0.4-0.8, diatomite 8-12, alkylphenol polyoxyethylene 0.6-1.2, Silane coupling agent KH550 0.7-1.4, the salpeter solution 20-40 of 20%, the sodium hydroxide solution 20-40 of 30%, polyvinyl alcohol 1-2, st-yrax n-butyl ether 0.3-0.5, ferric acetyl acetonade 0.2-0.4, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
2. a kind of glass door use coating with magnetotherapy effect according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-333, fluorine-based alkyl, polyether modified polyorganosiloxane, Oleum Cinnamomi, sodium laurylsulfonate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds aqueous sodium polyacrylate, Stearic acid diethanolamine salt, dihydroxypropane single-ether stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds EVA emulsion, apple anhydride dehydration resin, aminoresin, triethylenetetramine, Aqueous Solutions of Polyethylene Glycol stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine lipid acid titanic acid ester, pigment, magnet powder, tourmaline powder, modified nano-titanium dioxide photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568675.6A CN104449191A (en) | 2014-10-23 | 2014-10-23 | Waterborne coating for glass door having magnetotherapeutic effect and preparation method of waterborne coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410568675.6A CN104449191A (en) | 2014-10-23 | 2014-10-23 | Waterborne coating for glass door having magnetotherapeutic effect and preparation method of waterborne coating |
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| CN104449191A true CN104449191A (en) | 2015-03-25 |
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| CN201410568675.6A Pending CN104449191A (en) | 2014-10-23 | 2014-10-23 | Waterborne coating for glass door having magnetotherapeutic effect and preparation method of waterborne coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199448A (en) * | 2015-11-02 | 2015-12-30 | 阜阳市六合净环保科技有限公司 | Organosilicone modified photocatalyst nano coating and preparation method thereof |
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| CN1366006A (en) * | 2001-11-30 | 2002-08-28 | 李铁辉 | Environment protection type multifunctional catalytic paint |
| WO2003106525A1 (en) * | 2002-06-14 | 2003-12-24 | Agrolinz Melamin Gmbh | Method for curing aminoplasts |
| CN1687268A (en) * | 2005-05-02 | 2005-10-26 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN101182383A (en) * | 2006-11-13 | 2008-05-21 | 柏仲元 | Tourmaline composite polymer ecological function membrane material as well as preparation method and use thereof |
| CN103102763A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | Environment-friendly water-based glass paint and preparation method thereof |
-
2014
- 2014-10-23 CN CN201410568675.6A patent/CN104449191A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1366006A (en) * | 2001-11-30 | 2002-08-28 | 李铁辉 | Environment protection type multifunctional catalytic paint |
| WO2003106525A1 (en) * | 2002-06-14 | 2003-12-24 | Agrolinz Melamin Gmbh | Method for curing aminoplasts |
| CN1687268A (en) * | 2005-05-02 | 2005-10-26 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN101182383A (en) * | 2006-11-13 | 2008-05-21 | 柏仲元 | Tourmaline composite polymer ecological function membrane material as well as preparation method and use thereof |
| CN103102763A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | Environment-friendly water-based glass paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199448A (en) * | 2015-11-02 | 2015-12-30 | 阜阳市六合净环保科技有限公司 | Organosilicone modified photocatalyst nano coating and preparation method thereof |
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