CN104445801B - 造纸废水处理工艺 - Google Patents
造纸废水处理工艺 Download PDFInfo
- Publication number
- CN104445801B CN104445801B CN201410570431.1A CN201410570431A CN104445801B CN 104445801 B CN104445801 B CN 104445801B CN 201410570431 A CN201410570431 A CN 201410570431A CN 104445801 B CN104445801 B CN 104445801B
- Authority
- CN
- China
- Prior art keywords
- waste water
- coal ash
- modified coal
- filtration
- ash zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- 230000008569 process Effects 0.000 title claims abstract description 41
- 239000002351 wastewater Substances 0.000 claims abstract description 44
- 238000001914 filtration Methods 0.000 claims abstract description 37
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 32
- 239000010883 coal ash Substances 0.000 claims abstract description 32
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000010457 zeolite Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 239000010802 sludge Substances 0.000 claims abstract description 18
- 230000001112 coagulating effect Effects 0.000 claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 241001148471 unidentified anaerobic bacterium Species 0.000 claims abstract description 12
- 238000005189 flocculation Methods 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 230000016615 flocculation Effects 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 7
- 238000004062 sedimentation Methods 0.000 claims description 7
- 239000006228 supernatant Substances 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- 230000000593 degrading effect Effects 0.000 claims description 3
- 229910001448 ferrous ion Inorganic materials 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000013618 particulate matter Substances 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 239000010893 paper waste Substances 0.000 abstract description 9
- 238000000746 purification Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 12
- 238000004065 wastewater treatment Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 4
- 239000010842 industrial wastewater Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- 238000013475 authorization Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 239000004155 Chlorine dioxide Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 235000019398 chlorine dioxide Nutrition 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000001471 micro-filtration Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- 241001086438 Euclichthys polynemus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/26—Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
- C02F2103/28—Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410570431.1A CN104445801B (zh) | 2014-10-24 | 2014-10-24 | 造纸废水处理工艺 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410570431.1A CN104445801B (zh) | 2014-10-24 | 2014-10-24 | 造纸废水处理工艺 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104445801A CN104445801A (zh) | 2015-03-25 |
| CN104445801B true CN104445801B (zh) | 2016-08-24 |
Family
ID=52892659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410570431.1A Active CN104445801B (zh) | 2014-10-24 | 2014-10-24 | 造纸废水处理工艺 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104445801B (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105110518A (zh) * | 2015-09-30 | 2015-12-02 | 河北泽世康化工有限公司 | 酸性有机废水的处理方法 |
| CN106630415A (zh) * | 2016-12-19 | 2017-05-10 | 天津凯英科技发展股份有限公司 | 一种废纸浆造纸废水处理工艺 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101254987B (zh) * | 2007-04-13 | 2010-11-24 | 东莞市英硫净水服务有限公司 | 小水量难降解废水深度净化回用的处理方法及实施设备 |
| CN101781049B (zh) * | 2010-03-03 | 2012-01-25 | 北京桑德环境工程有限公司 | 草浆造纸废水中水回用处理系统及处理方法 |
| CN101955305A (zh) * | 2010-10-19 | 2011-01-26 | 江苏省环境科学研究院 | 一种造纸废水组合处理工艺 |
| CN102849893B (zh) * | 2012-08-06 | 2014-08-13 | 南京凯盛国际工程有限公司 | 一种高浓度难降解有机废水的处理方法 |
| CN103626323B (zh) * | 2012-08-20 | 2015-08-12 | 杰瑞能源服务有限公司 | 一种制药、造纸废水深度处理的工艺方法及专用装置 |
| CN203144244U (zh) * | 2013-03-27 | 2013-08-21 | 重庆地质矿产研究院 | 一种难降解工业废水的高效处理系统 |
-
2014
- 2014-10-24 CN CN201410570431.1A patent/CN104445801B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104445801A (zh) | 2015-03-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lin Qinghua Inventor before: You Wei |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160706 Address after: 362000, room 2803, Ronghua Pavilion, Nanan Mei Cheng Building, Fujian, China Applicant after: Lin Qinghua Address before: Room 214000, science and Technology Park, No. 7 Changjiang Road, New District, Wuxi, Jiangsu, China Applicant before: Wuxi Epic Technology Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170512 Address after: 214000 No. 47, Zhujianglu Road New District, Jiangsu, Wuxi Patentee after: Wei Tai Technology (Wuxi) Co., Ltd. Address before: 362000, room 2803, Ronghua Pavilion, Nanan Mei Cheng Building, Fujian, China Patentee before: Lin Qinghua |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20200715 Address after: 214000 No. 47, Zhujianglu Road New District, Jiangsu, Wuxi Patentee after: WUXI LANWAN RESOURCE REGENERATION TECHNOLOGY Co.,Ltd. Address before: 214000 No. 47, Zhujianglu Road New District, Jiangsu, Wuxi Patentee before: WEITAI TECHNOLOGY (WUXI) Co.,Ltd. |
|
| TR01 | Transfer of patent right |