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White glues and manufacturing process thereof

Abstract

A kind of modified polyethylene alcohol formal white glues and manufacturing process thereof.This white glues comprises polyvinyl formal.Tackifier, filler, softening agent, emulsifying agent and formaldehyde wedding agent.This white glues cost is low, and raw material obtains easily, can replace the Vinyl Acetate Copolymer white glues, is widely used in the bonding and the unsewn binding on timber, wall paper, floor.

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CN1043953A

China

Other languages
Chinese
Inventor
李正文
王萍
Current Assignee
Individual

Worldwide applications
1988 CN

Application CN 89105454 events
Pending

Description

White glues and manufacturing process thereof
The present invention relates to a kind of binding agent, particularly a kind of white glues of modified polyvinyl formal.
Existing formaldehyde polyvinyl acetal is nontoxic, do not fire, cohesive force is strong, is applicable to and directly pastes Wooden mosaic floor boards and other decorative materials (plastic floor, carpet etc.) on the cement floor.But because the solid content of polyvinyl formal is lower, cohesive strength is than polyvinyl acetate difference and certain free formaldehyde is arranged, and therefore the purposes of existing polyalkenylalcohols formal glue is subjected to certain limitation.
The purpose of this invention is to provide a kind of white glues of modified polyethylene alcohol formal, compare with existing formaldehyde polyvinyl acetal, its cohesive strength, solid content aspect all are improved, and free formaldehyde also reduces significantly.
Modified polyvinyl formal white glues of the present invention is compared with existing formaldehyde polyvinyl acetal, and it is strong to have cohesive force, the high and low characteristics of free formaldehyde content of solid content.Compare with vinyl acetate emulsion, low price, waterproof and resistance to frost all increase, and raw material obtains easily, and is easy to manufacture, non-environmental-pollution.
Modified polyvinyl formal white glues of the present invention can replace polyvinyl acetate, is widely used in the bonding and the unsewn binding on timber, wall paper and floor.
Embodiment:
Make formaldehyde polyvinyl acetal by existing formaldehyde polyvinyl acetal manufacturing process earlier: get the reactor that 50 kilograms of polyvinyl alcohol are put into the carrying vapour chuck, add 450 kg of water, heating is under agitation dissolved polyvinyl alcohol fully then.With hydrochloric acid solution is regulated pH and be approximately 2, solution is heated to 85~90 ℃ again, add 15 kilograms in formaldehyde then, reacted about 20 minutes, be cooled to 50 ℃, adding liquid caustic soda, to be neutralized to the pH value be 7.Meanwhile, in another reactor, add 100 kilograms of polyvinyl acetate emulsions, add OP-10 500 grams again, 15 kilograms of 5 kilograms of plasticizer phthalic acid dibutylesters and 300 order light calcium carbonates, after fully stirring, resulting mixture is joined in the formaldehyde polyvinyl acetal that has prepared, add again, fully stir discharging after 3 hours with suitable quantity of water dissolved 500 gram urea.
When preparation modified polyvinyl formal white glues, the content of polyvinyl alcohol can be controlled between 8~13%, the content of formaldehyde should be controlled below 4.5%, in order to avoid generation insoluble polymer, poly-acetic acid second dilute emulsion content can be 10~30%, emulsifying agent can be used the product of OP series or TX series, used formaldehyde condensation agent has urea, trimeric cyanamide, Resorcinol etc., it is fixed as the case may be that it adds number needs, said filler is 200~400 purpose lime carbonate, titanium dioxide, talcum powder or a kind of mixture of forming by monomethylolurea and dimethylolurea, the content of filler is about 3~10%, and amount of filler too much occurs precipitation easily and influences the product cohesive strength.

Claims (4)
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1, a sharp binding agent comprises formaldehyde polyvinyl acetal, it is characterized in that containing in the said formaldehyde polyvinyl acetal tackifier, filler, softening agent, tensio-active agent and formaldehyde wedding agent.
2, according to the binding agent of claim 1, it is characterized in that said tackifier are that polyvinyl acetate, softening agent are dibutyl phthalates, tensio-active agent is the tensio-active agent of OP or TX series.
3,, it is characterized in that said formaldehyde wedding agent is a urea according to the binding agent of claim 2.
4,, it is characterized in that said filler is the mixture of monomethylolurea or dimethylolurea according to the binding agent of claim 2.