CN104372364B - 一种高效金属清洗剂 - Google Patents
一种高效金属清洗剂 Download PDFInfo
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- CN104372364B CN104372364B CN201410597375.0A CN201410597375A CN104372364B CN 104372364 B CN104372364 B CN 104372364B CN 201410597375 A CN201410597375 A CN 201410597375A CN 104372364 B CN104372364 B CN 104372364B
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 21
- 239000002184 metal Substances 0.000 title claims abstract description 21
- 239000002516 radical scavenger Substances 0.000 title claims abstract description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 16
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract description 16
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims abstract description 8
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 8
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims abstract description 8
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 8
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 8
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000001632 sodium acetate Substances 0.000 claims abstract description 8
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 8
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 8
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 8
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940092714 benzenesulfonic acid Drugs 0.000 claims abstract description 7
- 239000001103 potassium chloride Substances 0.000 claims abstract description 5
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 5
- AHIBWURJLGCHAY-UHFFFAOYSA-N [S].C1=CC=CC=C1 Chemical compound [S].C1=CC=CC=C1 AHIBWURJLGCHAY-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000000280 densification Methods 0.000 abstract description 2
- 239000012459 cleaning agent Substances 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- -1 Chloro hydrocarbon Chemical class 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
一种高效金属清洗剂，由以下重量份数的原料制成：醋酸钠8‑14份，苯甲酸钠7‑11份，磷酸二氢钾5‑10份，硅藻土3‑8份，高氯酸2‑4份，苯磺酸4‑10份，氯化钾2‑9份，氢氟酸5‑10份，八乙烯基笼形倍半硅氧烷2‑6份，五水硫酸铜1‑5份，亚硝酸钠2‑6份，柠檬酸3‑8份，硫代硫酸钠4‑11份。本发明的有益效果是，本发明的高效金属清洗剂，具有良好的清洗效果，同时能够形成致密的保护膜，减少与空气中氧气、水分的接触。
Description
技术领域
本发明涉及一种高效金属清洗剂。
背景技术
清洗剂金属及其制品在加工过程中常会在表面沾染各种污物和杂质。清洗是金属表面处理中极其重要的一环。以去油脱脂为主要目标的常用清洗剂有石油系清洗剂、氯代烃系清洗剂、碱性清洗剂和含有表面活性剂的清洗剂等。石油系清洗剂主要有溶剂汽油、煤油或轻柴油等。它的作用原理主要是利用其对金属表面油脂的溶解作用。氯代烃系清洗剂常用的是三氯乙烯和四氯化碳。这类溶剂的特点是对油脂的溶解能力强，但沸点低，一般为不易燃物。碱性清洗剂主要有氢氧化钠、碳酸钠、硅酸钠、磷酸钠等，溶于水成为碱性清洗剂。它们的作用原理是能和油污中的脂肪酸甘油酯发生皂化作用形成初生皂，使油污成为水溶性的而被溶解去除。表面活性剂类清洗剂这类清洗剂的作用原理与表面活性剂的增溶、润湿、吸附、乳化、分散等性质有关。它们首先润湿金属表面,进入金属与污物连接的界面,使污物被拆开；或者使油脂类污物以球状聚集在金属表面上，然后逐渐从金属表面脱落、分散或悬浮成细小粒子。
发明内容
针对现有技术的不足，本发明要解决的技术问题是，提供一种高效金属清洗剂，具有良好的清洗效果，同时能够形成致密的保护膜，减少与空气中氧气、水分的接触。
为解决现有技术的不足，本发明采取的技术方案是：一种高效金属清洗剂，由以下重量份数的原料制成：
醋酸钠8-14份，苯甲酸钠7-11份，磷酸二氢钾5-10份，硅藻土3-8份，高氯酸2-4份，苯磺酸4-10份，氯化钾2-9份，氢氟酸5-10份，八乙烯基笼形倍半硅氧烷2-6份，五水硫酸铜1-5份，亚硝酸钠2-6份，柠檬酸3-8份，硫代硫酸钠4-11份。
本发明优化的技术方案是，一种高效金属清洗剂，由以下重量份数的原料制成：
醋酸钠11份，苯甲酸钠9份，磷酸二氢钾8份，硅藻土5份，高氯酸3份，苯磺酸7份，氯化钾6份，氢氟酸7份，八乙烯基笼形倍半硅氧烷4份，五水硫酸铜3份，亚硝酸钠4份，柠檬酸5份，硫代硫酸钠7份。
本发明的有益效果是，本发明的高效金属清洗剂，具有良好的清洗效果，同时能够形成致密的保护膜，减少与空气中氧气、水分的接触。
具体实施方式
实施例1
一种高效金属清洗剂，由以下重量份数的原料制成：
醋酸钠8份，苯甲酸钠7份，磷酸二氢钾5份，硅藻土3份，高氯酸2份，苯磺酸4份，氯化钾2份，氢氟酸5份，八乙烯基笼形倍半硅氧烷2份，五水硫酸铜1份，亚硝酸钠2份，柠檬酸3份，硫代硫酸钠4份。
实施例2
一种高效金属清洗剂，由以下重量份数的原料制成：
醋酸钠14份，苯甲酸钠11份，磷酸二氢钾10份，硅藻土8份，高氯酸4份，苯磺酸10份，氯化钾9份，氢氟酸10份，八乙烯基笼形倍半硅氧烷6份，五水硫酸铜5份，亚硝酸钠6份，柠檬酸8份，硫代硫酸钠11份。
实施例3
一种高效金属清洗剂，由以下重量份数的原料制成：
醋酸钠11份，苯甲酸钠9份，磷酸二氢钾8份，硅藻土5份，高氯酸3份，苯磺酸7份，氯化钾6份，氢氟酸7份，八乙烯基笼形倍半硅氧烷4份，五水硫酸铜3份，亚硝酸钠4份，柠檬酸5份，硫代硫酸钠7份。
Claims (2)
1.一种高效金属清洗剂，其特征在于：由以下重量份数的原料制成：
醋酸钠8-14份，苯甲酸钠7-11份，磷酸二氢钾5-10份，硅藻土3-8份，高氯酸2-4份，苯磺酸4-10份，氯化钾2-9份，氢氟酸5-10份，八乙烯基笼形倍半硅氧烷2-6份，五水硫酸铜1-5份，亚硝酸钠2-6份，柠檬酸3-8份，硫代硫酸钠4-11份。
2.根据权利要求1所述的高效金属清洗剂，其特征在于：由以下重量份数的原料制成：
醋酸钠11份，苯甲酸钠9份，磷酸二氢钾8份，硅藻土5份，高氯酸3份，苯磺酸7份，氯化钾6份，氢氟酸7份，八乙烯基笼形倍半硅氧烷4份，五水硫酸铜3份，亚硝酸钠4份，柠檬酸5份，硫代硫酸钠7份。
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| CN107059023A (zh) * | 2016-12-28 | 2017-08-18 | 河南恒润昌环保科技有限公司 | 一种金属表面处理用无磷清洗剂及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1418981A (zh) * | 2001-11-13 | 2003-05-21 | 李传斌 | 水性金属阻锈剂 |
| CN102586769A (zh) * | 2012-01-31 | 2012-07-18 | 马鞍山拓锐金属表面技术有限公司 | 一种无磷金属表面处理剂及其使用方法 |
| CN103436901A (zh) * | 2013-08-31 | 2013-12-11 | 青岛承天伟业机械制造有限公司 | 一种机械设备部件去油剂 |
| CN103469187A (zh) * | 2013-08-14 | 2013-12-25 | 南京久道科技有限公司 | 用于钢铁表面磷化黑化的处理液 |
| CN104046970A (zh) * | 2014-06-28 | 2014-09-17 | 青岛宝泰新能源科技有限公司 | 一种机械表面铁锈处理剂 |
| CN104087954A (zh) * | 2014-07-16 | 2014-10-08 | 周彩球 | 一种用于钢铁表面的除锈防锈处理剂 |
-
2014
- 2014-10-31 CN CN201410597375.0A patent/CN104372364B/zh active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1418981A (zh) * | 2001-11-13 | 2003-05-21 | 李传斌 | 水性金属阻锈剂 |
| CN102586769A (zh) * | 2012-01-31 | 2012-07-18 | 马鞍山拓锐金属表面技术有限公司 | 一种无磷金属表面处理剂及其使用方法 |
| CN103469187A (zh) * | 2013-08-14 | 2013-12-25 | 南京久道科技有限公司 | 用于钢铁表面磷化黑化的处理液 |
| CN103436901A (zh) * | 2013-08-31 | 2013-12-11 | 青岛承天伟业机械制造有限公司 | 一种机械设备部件去油剂 |
| CN104046970A (zh) * | 2014-06-28 | 2014-09-17 | 青岛宝泰新能源科技有限公司 | 一种机械表面铁锈处理剂 |
| CN104087954A (zh) * | 2014-07-16 | 2014-10-08 | 周彩球 | 一种用于钢铁表面的除锈防锈处理剂 |
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Address after: Room 828, 8th Floor, Industrial Plant, No. 3021, Mingzhu South Road, Qianshan Town, Xiangzhou District, Zhuhai City, Guangdong Province, 519000 Patentee after: Guangdong Jing shield Environmental Protection Technology Co.,Ltd. Address before: Room 828, 8th Floor, Industrial Plant, No. 3021, Mingzhu South Road, Qianshan Town, Xiangzhou District, Zhuhai City, Guangdong Province, 519000 Patentee before: ZHUHAI JINGDUN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20220831 Address after: Room 307, 3rd Floor, No. 55 Gongbei Street, Jieyong Village, Qianshan, Zhuhai City, Guangdong Province, 519000 Patentee after: Zhuhai IF Detection Technology Co.,Ltd. Address before: Room 828, 8th Floor, Industrial Plant, No. 3021, Mingzhu South Road, Qianshan Town, Xiangzhou District, Zhuhai City, Guangdong Province, 519000 Patentee before: Guangdong Jing shield Environmental Protection Technology Co.,Ltd. |