CN104353418A - Preparation method of deodorization adsorbing material - Google Patents

Preparation method of deodorization adsorbing material Download PDF

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Publication number
CN104353418A
CN104353418A CN201410619005.2A CN201410619005A CN104353418A CN 104353418 A CN104353418 A CN 104353418A CN 201410619005 A CN201410619005 A CN 201410619005A CN 104353418 A CN104353418 A CN 104353418A
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China
Prior art keywords
asphalt
weight
activated carbon
spherical activated
preparation
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Pending
Application number
CN201410619005.2A
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Chinese (zh)
Inventor
郭军军
金彦任
魏锐强
裴佩
齐嘉豪
王德周
赵婷
安丽花
张金凤
周闯
范斌杰
温宇慧
乔亚丽
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Shanxi Xinhua Chemical Industry Co Ltd
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Shanxi Xinhua Chemical Industry Co Ltd
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Priority to CN201410619005.2A priority Critical patent/CN104353418A/en
Publication of CN104353418A publication Critical patent/CN104353418A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0281Sulfates of compounds other than those provided for in B01J20/045
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234Inorganic material layers

Abstract

The invention provides a deodorization adsorbing material and a preparation method thereof. The preparation method mainly comprises the following steps: with asphalt-based spherical active carbon as a carrier framework material, carrying active components copper and potassium on the carrier framework material, and performing procedures such as dipping and calcining to prepare the adsorbing material. Effective protection on materials such as ammonia gas, hydrogen sulfide, methyl mercaptan and methylamine can be realized.

Description

The preparation method of deodorization sorbing material
Technical field
The invention belongs to impregnated carbon technical field, have for a kind of sorbing material protecting function admirable and preparation method thereof.
Background technology
At present, domestic general deodorizing sorbing material is mainly prepared by carrier with coal mass active carbon, but this take coal as sorbing material prepared by raw material, not only guard time is not high, and ash content is high, and loading density is uneven, and loading density is large, cause filling tank or filter weight greatly, volume is large, and particularly when limited space, shortcoming is more obvious.
Compare traditional active carbon, asphalt-base spherical activated carbon has the series of advantages such as good sphericity, loading density is even, specific area is comparatively large, intensity is high, wear-resistant, corrosion-resistant.What particularly use in militay space flight deodorizing tank now is exactly be sorbing material prepared by carrier with asphalt-base spherical activated carbon, improves a lot before comparing.But because the preparation technology of original asphalt-base spherical activated carbon goes wrong, cause the spherical activated charcoal hydraulic performance decline of production, so cause sorbing material obtain barrier propterty can not meet new demand under performance indications.Therefore, be necessary to research and develop a kind of sorbing material that can meet performance indications under new demand.
Summary of the invention
The object of the present invention is to provide a kind of deodorizing sorbing material and preparation method thereof, be mainly used in the effective protection to materials such as ammonia, hydrogen sulfide, methyl mercaptan, methylamines.The absorbent charcoal carrier selected is asphalt-base spherical activated carbon, it supports active component Cu, K.
The present invention adopts following technical scheme to realize:
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 5.1 ~ 10.2%(weight) Cu, 1.6 ~ 5.2%(weight) K, surplus is active carbon.
Wherein, in the weight of carrier active carbon for 100%.Such as carrier active carbon weight is 100g, then supported copper 5.1 ~ 10.2g, potassium 1.6 ~ 5.2g, so needs active component copper sulphate 12.8 ~ 25.6g(and cupric sulfate pentahydrate 20 ~ 40g), potassium chloride 3 ~ 10g.
The preparation technology of above-mentioned deodorization sorbing material mainly comprises active component and supports and activate two steps.
1, solution preparation
The active component of catalyst is mainly cupric sulfate pentahydrate and potassium chloride, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature is generally at 60 ~ 80 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 1 ~ 2h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls between 140 ~ 160 DEG C, and the duration is greater than 4h.
A certain amount of Cu and active component auxiliary agent are added in distilled water, prepares sorbing material according to above-mentioned technique.The sorbing material the performance test results of preparation sees the following form:
As seen from the above table, sorbing material provided by the invention is compared the barrier propterty of QZ09-4, MH-97-1 sorbing material to ammonia, hydrogen sulfide and is improved.
The blending constituent comprising Cu and K is impregnated on carrier framework material by the present invention, is converted into the active component with reactivity by heat-activated, and cupric impregnating agent, to alkaline toxic and harmful (as ammonia), chemisorption reaction occurs; Containing potassium impregnating agent, there is the elimination ability to acid toxic and harmful (as hydrogen sulfide).
Compared with prior art, its advantage is as follows:
1, comparatively large, the pore structure of specific area distributes rational absorbent charcoal carrier;
2, the kind of load active component, mainly includes Cu and active component auxiliary agent, but is not limited to add other component on this basis;
3, on described carrier material, load specified activity component prepares sorbing material, has the effective protective capacities to ammonia, hydrogen sulfide.
The present invention is reasonable in design, utilize asphalt-base spherical activated carbon as carrier material, adopt equivalent impregnation method, supported and activating process by active component, complete asphalt-base spherical activated carbon load active component Cu and K, realize the effective protection to materials such as ammonia, hydrogen sulfide, methyl mercaptan, methylamines.Simultaneously because the loading density of sorbing material is little, load the advantages such as even, during for loading protective equipment, can reduce weight, reduced volume, the design and the production that can be Chemical Agent Resistant Material provide certain convenience.
Preparation technology of the present invention is simple, easy to operate, can realize mass production capabilities, for protective equipment designs, produces and provide convenience, can be used as the core scavenging material of future submarine atmospheric environment control system, Shenzhou spacecraft space flight deodorizing tank.
Detailed description of the invention
Below specific embodiments of the invention are described in detail.
embodiment 1
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 7.7%(weight) Cu, 4.2%(weight) K, surplus is active carbon.In active carbon 100g, supported copper 7.7g, potassium 4.2g; So need active component Salzburg vitriol 30g, potassium chloride 8g.
Preparation technology mainly comprises active component and supports and activate two steps.
1, solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of the catalyst of ormal weight, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature 60 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 1.5h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls at 155 DEG C, and the duration is greater than 4h.
embodiment 2
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 10.2%(weight) Cu, 2.6%(weight) K, surplus is active carbon.In active carbon 100g, supported copper 10.2g, potassium 2.6g; So need active component Salzburg vitriol 40g, potassium chloride 5g.
Preparation technology mainly comprises active component and supports and activate two steps.
1, solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of the catalyst of ormal weight, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature 65 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 1h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls at 160 DEG C, and the duration is greater than 4h.
embodiment 3
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 6.4%(weight) Cu, 1.6%(weight) K, surplus is active carbon.In active carbon 100g, supported copper 6.4g, potassium 1.6g; So need active component Salzburg vitriol 25g, potassium chloride 3.1g.
Preparation technology mainly comprises active component and supports and activate two steps.
1, solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of the catalyst of ormal weight, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature 80 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 1h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls at 140 DEG C, and the duration is greater than 4h.
embodiment 4
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 5.1%(weight) Cu, 5.2%(weight) K, surplus is active carbon.In active carbon 100g, supported copper 5.1g, potassium 5.2g; So need active component Salzburg vitriol 20g, potassium chloride 10g.
Preparation technology mainly comprises active component and supports and activate two steps.
1, solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of the catalyst of ormal weight, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature 70 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 2h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls at 150 DEG C, and the duration is greater than 4h.
embodiment 5
A kind of deodorization sorbing material, adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 9%(weight) Cu, 3.1%(weight) K, surplus is active carbon.In active carbon 100g, supported copper 9g, potassium 3.1g; So need active component Salzburg vitriol 35g, potassium chloride 6g.
Preparation technology mainly comprises active component and supports and activate two steps.
1, solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of the catalyst of ormal weight, in solution preparation process, above-mentioned active component is joined successively (distilled water consumption calculates by the water capacity of carrier) in a certain amount of distilled water, ensure that each active component is fully dissolved, solution temperature 75 DEG C.
2, flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 2h.
3, calcine
Calcining is the process of giving the certain catalytic reaction activity of impregnated carbon, is critical process prepared by sorbing material.Temperature controls at 145 DEG C, and the duration is greater than 4h.

Claims (2)

1. a preparation method for deodorization sorbing material, is characterized in that: comprise the steps:
(1), raw material prepares
Adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 5.1 ~ 10.2%(weight) Cu, 1.6 ~ 5.2%(weight) K; Wherein, Cu comes from cupric sulfate pentahydrate, and K comes from potassium chloride;
(2), solution preparation
Take active component cupric sulfate pentahydrate and the potassium chloride of ormal weight, join successively in distilled water, wherein distilled water consumption presses the water capacity calculating of carrier, ensures that each component is fully dissolved, solution temperature 60 ~ 80 DEG C;
(3), flood
Adopt equivalent impregnation method, the mixed solution prepared is joined in load weighted asphalt-base spherical activated carbon, constantly stirs, maceration extract is fully contacted with asphalt-base spherical activated carbon, ensure that dipping evenly, fully, then sealing and standing 1 ~ 2h;
(4), calcine
Temperature controls between 140 ~ 160 DEG C, and the duration is greater than 4h.
2. the preparation method of deodorization sorbing material according to claim 1, is characterized in that: adopt asphalt-base spherical activated carbon as carrier framework material, on it, load has 7.7%(weight) Cu, 4.2%(weight) K.
CN201410619005.2A 2014-11-06 2014-11-06 Preparation method of deodorization adsorbing material Pending CN104353418A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251447A (en) * 2015-11-14 2016-01-20 山西新华化工有限责任公司 Impregnated carbon for balance protection against NH3 and SO2 and preparing method
CN106492751A (en) * 2016-10-31 2017-03-15 山西新华化工有限责任公司 Impregnated carbon of protection methacrylaldehyde and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4556547A (en) * 1982-02-01 1985-12-03 Takeda Chemical Industries, Ltd. Process for treatment of gases
CN1830542A (en) * 2006-03-03 2006-09-13 中国人民解放军63971部队 Immesion active carbon and its preparation method
CN101580294A (en) * 2009-06-05 2009-11-18 江苏工业学院 Method for processing landfill leachate through heterogeneous catalytic ozonation
CN101862640A (en) * 2010-06-28 2010-10-20 克拉玛依金叶化工有限责任公司 Method for preparing desulfurizer used for removing H2S from natural gas
CN102120176A (en) * 2010-12-11 2011-07-13 山西新华化工有限责任公司 Preparation method of asphalt ball impregnation carbon for protecting H2S and NH3

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4556547A (en) * 1982-02-01 1985-12-03 Takeda Chemical Industries, Ltd. Process for treatment of gases
CN1830542A (en) * 2006-03-03 2006-09-13 中国人民解放军63971部队 Immesion active carbon and its preparation method
CN101580294A (en) * 2009-06-05 2009-11-18 江苏工业学院 Method for processing landfill leachate through heterogeneous catalytic ozonation
CN101862640A (en) * 2010-06-28 2010-10-20 克拉玛依金叶化工有限责任公司 Method for preparing desulfurizer used for removing H2S from natural gas
CN102120176A (en) * 2010-12-11 2011-07-13 山西新华化工有限责任公司 Preparation method of asphalt ball impregnation carbon for protecting H2S and NH3

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251447A (en) * 2015-11-14 2016-01-20 山西新华化工有限责任公司 Impregnated carbon for balance protection against NH3 and SO2 and preparing method
CN106492751A (en) * 2016-10-31 2017-03-15 山西新华化工有限责任公司 Impregnated carbon of protection methacrylaldehyde and preparation method thereof

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Application publication date: 20150218