CN104332506A - Photovoltaic cell and printing screen plate used for printing gate lines of photovoltaic cell - Google Patents

Photovoltaic cell and printing screen plate used for printing gate lines of photovoltaic cell Download PDF

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Publication number
CN104332506A
CN104332506A CN201410526022.1A CN201410526022A CN104332506A CN 104332506 A CN104332506 A CN 104332506A CN 201410526022 A CN201410526022 A CN 201410526022A CN 104332506 A CN104332506 A CN 104332506A
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screen
grid
grid lines
photovoltaic cell
printing
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CN104332506B (en
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黄强
黄家烨
刘江峰
耿晓菊
夏燕杰
冯岩
程涛
韩会丽
彭琪
陈华
余本海
刘彦明
卢克平
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Xinyang Normal University
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • H10F77/211Electrodes for devices having potential barriers for photovoltaic cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41FPRINTING MACHINES OR PRESSES
    • B41F15/00Screen printers
    • B41F15/14Details
    • B41F15/34Screens, Frames; Holders therefor
    • B41F15/36Screens, Frames; Holders therefor flat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

本发明涉及光伏组件技术领域,特别是一种光伏电池及用于印刷其栅线的印刷网版。该光伏电池的受光面具有栅线,距离最接近的电连接点越远,细栅线的截面积越小。位于相邻的两个电连接点之间的细栅线上具有预断栅。用于印刷上述栅线的印刷网版包括丝网网版和金属板网版,丝网网版通过调整纵向网丝的间隔和直径来配合细栅线的截面积的变化,而金属板网版通过调整金属板网版的网版开孔阵列的通透率,来实现细栅线的截面积变化。本发明的有益效果是:在不降低电流收集能力和产品品质的同时,大幅度减低制作栅线的贵金属使用量。其次,通过预断栅使断栅等缺陷只出现在预先设计的位置,从而控制缺陷的影响,大大提升光伏电池的可靠性和安全性。

The invention relates to the technical field of photovoltaic components, in particular to a photovoltaic cell and a printing screen for printing its grid lines. The light-receiving surface of the photovoltaic cell has grid lines, and the farther away from the closest electrical connection point, the smaller the cross-sectional area of the thin grid lines. There is a pre-break grid on the thin grid line between two adjacent electrical connection points. The printing screens used to print the above grid lines include screen screens and metal plate screens. The screen screens adjust the spacing and diameter of the longitudinal mesh to match the change in the cross-sectional area of the fine grid lines, while the metal plate screens By adjusting the permeability of the screen opening array of the metal plate screen, the cross-sectional area of the fine grid line can be changed. The beneficial effects of the invention are: while not reducing the current collection ability and product quality, the amount of precious metal used for making grid lines is greatly reduced. Secondly, by pre-breaking the grid, the defects such as broken grid only appear in the pre-designed position, so as to control the influence of the defect and greatly improve the reliability and safety of photovoltaic cells.

Description

光伏电池及用于印刷其栅线的印刷网版Photovoltaic cells and printing screens for printing their grid lines

技术领域technical field

本发明涉及光伏组件技术领域,特别是一种光伏电池及用于印刷其栅线的印刷网版。The invention relates to the technical field of photovoltaic components, in particular to a photovoltaic cell and a printing screen for printing its grid lines.

背景技术Background technique

2004年以来,中国光伏电池制造和应用迅猛发展。目前,中国不仅仅是全球第一的光伏制造大国,同时也已经成为全球最大的光伏市场。未来光伏发电产品的制造和应用将保持高速增长。贵金属Ag作为光伏电池产品中的核心材料,一直得到产业界的巨大关注。在欧洲光伏技术会议、上海光伏技术展览等不同场合,Martin Green等光伏界的技术专家都表示了对未来Ag产量能否满足光伏发展的担心。降低Ag在光伏电池中的使用用量,同时寻找能够取代或部分取代Ag的电池电极设计方案,成为光伏行业专家的共识。中电电气(南京)光伏公司的实用新型专利CN 203250753U中,比较简单清晰地描述了现有电极设计技术。Since 2004, China's photovoltaic cell manufacturing and application have developed rapidly. At present, China is not only the world's largest photovoltaic manufacturing country, but also has become the world's largest photovoltaic market. The manufacture and application of photovoltaic power generation products will maintain rapid growth in the future. The noble metal Ag, as the core material in photovoltaic cell products, has been receiving great attention from the industry. On different occasions such as the European Photovoltaic Technology Conference and the Shanghai Photovoltaic Technology Exhibition, Martin Green and other technical experts in the photovoltaic industry have expressed concerns about whether the future Ag production can meet the photovoltaic development. It has become the consensus of experts in the photovoltaic industry to reduce the amount of Ag used in photovoltaic cells and at the same time look for battery electrode designs that can replace or partially replace Ag. In the utility model patent CN 203250753U of China Power Electric (Nanjing) Photovoltaic Company, the existing electrode design technology is described in a relatively simple and clear manner.

目前业界的研究方向主要有5个:1)以杜邦和荷力士公司为代表的银浆公司,主要以降低银浆中的Ag用量,同时把Ag细栅线印制得更为“瘦高”。2)以天合光能等为代表的光伏组件制造商,主要是降低丝网印刷中主栅线中Ag用量。如实用新型专利ZL200920041761.6和在此基础上改进的实用新型专利CN202076273U,都是通过降低主栅银浆用量来节省Ag用量的方法。3)以尚德电力为代表的光伏组件制造商,采用“冥王星”技术,也就是使用Ni/Cu/Sn三层电镀细导电栅线的方式。由于电镀对环境保护的后处理要求高,可焊接性存在技术难度,需要投资新设备等原因,难以推向市场。4)以日立化成等公司为代表,试图通过导电膜(CF)膜来部分取代光伏电池主栅线下的导电银浆。5)以日本产业综合研究所(AIST)为代表,试图通过导电铜浆料来取代Ag浆,这一方向的研究才刚开始起步。At present, there are five main research directions in the industry: 1) Silver paste companies represented by DuPont and Hollis, mainly to reduce the amount of Ag in the silver paste, and at the same time print the Ag thin grid lines to be more "thin and taller" . 2) Photovoltaic module manufacturers represented by Trina Solar mainly reduce the amount of Ag used in the busbars in screen printing. For example, the utility model patent ZL200920041761.6 and the utility model patent CN202076273U improved on this basis are both ways to save the amount of Ag by reducing the amount of busbar silver paste. 3) Photovoltaic module manufacturers represented by Suntech Power adopt the "Pluto" technology, that is, the method of electroplating thin conductive grid lines with Ni/Cu/Sn three layers. Due to the high post-processing requirements of electroplating for environmental protection, the technical difficulty of weldability, and the need to invest in new equipment, it is difficult to introduce it to the market. 4) Represented by Hitachi Chemical and other companies, they try to partially replace the conductive silver paste under the busbar of photovoltaic cells through conductive film (CF) film. 5) Represented by Japan Industrial Research Institute (AIST), it is trying to replace Ag paste with conductive copper paste, and research in this direction has just begun.

这5种方式中,第1)和第2)种方法,已经在业界广泛采用。其他几种尚在尝试之中。无论采取哪种方式,其主要目标都是在满足光伏电池严苛的可靠性要求情况下,最大限度地降低成本。Among these 5 methods, methods 1) and 2) have been widely adopted in the industry. Several others are still being tested. Either way, the main goal is to minimize cost while meeting the stringent reliability requirements of photovoltaic cells.

发明内容Contents of the invention

本发明所要解决的技术问题是:降低光伏电池的贵金属的用量。The technical problem to be solved by the invention is to reduce the amount of noble metal used in photovoltaic cells.

本发明解决其技术问题所采用的技术方案是:一种光伏电池,在电池片的受光面具有栅线,栅线由主栅线和细栅线构成,细栅线上具有电连接点,细栅线在电连接点处通过主栅线与互联条进行电连接,距离最接近的电连接点越远,细栅线的截面积越小,该处的远近不是指空间上的直线距离的远近而是指电流传输路径的远近,截面积减小的趋势为连续的或非连续过渡的,并且细栅线通过降低细栅线的高度来减小细栅线的截面积;或者所述的栅线仅由细栅线构成,细栅线在电连接点处直接与互联条进行电连接,距离最接近的电连接点越远,细栅线的截面积越小,截面积减小的趋势为连续的或非连续过渡的,并且细栅线通过降低细栅线的高度来减小细栅线的截面积。The technical scheme adopted by the present invention to solve the technical problem is: a photovoltaic cell, which has a grid line on the light-receiving surface of the battery sheet, the grid line is composed of a main grid line and a thin grid line, and the thin grid line has an electrical connection point. The grid line is electrically connected to the interconnection bar through the main grid line at the electrical connection point. The farther away from the closest electrical connection point, the smaller the cross-sectional area of the thin grid line. The distance here does not refer to the distance of the straight line in space. It refers to the distance of the current transmission path, the tendency of the cross-sectional area reduction is continuous or discontinuous transition, and the thin grid line reduces the cross-sectional area of the thin grid line by reducing the height of the thin grid line; or the grid The wire is only composed of thin grid wires, and the thin grid wires are directly electrically connected to the interconnection strips at the electrical connection points. The farther away from the nearest electrical connection point, the smaller the cross-sectional area of the thin grid wires, and the decreasing trend of the cross-sectional area is Continuous or non-continuous transition, and the thin grid lines reduce the cross-sectional area of the thin grid lines by reducing the height of the thin grid lines.

进一步限定,位于相邻的两个电连接点之间的细栅线上具有预断栅。It is further defined that there is a pre-break grid on the thin grid line between two adjacent electrical connection points.

进一步限定,预断栅的宽度为D,0mm<D≤3mm。Further defined, the width of the pre-break grid is D, where 0mm<D≤3mm.

进一步限定,预断栅位于细栅线的中间位置。It is further defined that the pre-break grid is located in the middle of the fine grid lines.

进一步限定,当栅线仅由细栅线构成时,互联条的数量为18~50根。It is further defined that when the grid lines are only composed of thin grid lines, the number of interconnection bars is 18-50.

进一步限定,互联条通过焊接或导电胶粘结的方式进行电连接。It is further defined that the interconnection strips are electrically connected by welding or conductive adhesive bonding.

为实现上述栅线的设计,本发明提供一种光伏电池丝网印刷网版,包括网版骨架和固定在网版骨架上的丝网,丝网由相互交错的横向网丝和纵向网丝构成,在丝网上通过覆盖掩膜的方式形成印刷栅线的透孔区和掩膜区,透孔区的用于印刷细栅线的细栅透孔区的延伸方向与横向网丝的延伸方向一致,横向网丝的直径以及横向网丝之间的间隔相同,在细栅透孔区内,纵向网丝之间的间隔相同,纵向网丝的直径与待印刷的细栅线的截面积成反比;或者纵向网丝的直径相同,纵向网丝之间的间隔与待印刷的细栅线的截面积成正比;或者纵向网丝的直径与待印刷的细栅线的截面积成反比,同时纵向网丝之间的间隔与待印刷的细栅线的截面积成正比。In order to realize the design of the above grid lines, the present invention provides a photovoltaic cell screen printing screen, including a screen frame and a screen fixed on the screen frame, and the screen is composed of interlaced horizontal meshes and longitudinal meshes , the through-hole area and the mask area of the printed grid line are formed on the screen by covering the mask, and the extension direction of the through-hole area of the through-hole area for printing the fine grid line is consistent with the extension direction of the transverse mesh , the diameter of the transverse mesh and the spacing between the horizontal meshes are the same, and in the fine grid through-hole area, the spacing between the vertical meshes is the same, and the diameter of the longitudinal mesh is inversely proportional to the cross-sectional area of the fine grid line to be printed ; or the diameter of the longitudinal mesh is the same, and the interval between the longitudinal mesh is proportional to the cross-sectional area of the fine grid line to be printed; or the diameter of the longitudinal mesh is inversely proportional to the cross-sectional area of the fine grid line to be printed, while the longitudinal The spacing between mesh wires is directly proportional to the cross-sectional area of the fine grid lines to be printed.

为实现上述栅线的设计,本发明另外提供一种光伏电池金属板印刷网版,包括金属板,在金属板上开设由网版开孔构成的网版开孔阵列,在网版开孔阵列上通过覆盖掩膜的方式形成印刷栅线的透孔区和掩膜区,在透孔区的用于印刷细栅线的细栅透孔区内,网版开孔阵列的通透率与待印刷的细栅线的截面积成正比。In order to realize the design of the above-mentioned grid lines, the present invention additionally provides a photovoltaic cell metal plate printing screen, including a metal plate, and a screen opening array composed of screen openings is set on the metal plate, and the screen opening array is The through-hole area and the mask area of the printed grid line are formed by covering the mask. In the through-hole area of the fine grid through-hole area for printing the fine grid line, the transmittance of the screen opening array and the to-be The cross-sectional area of the printed fine grid lines is directly proportional.

进一步限定,网版开孔为简单几何图形,优选为椭圆形或者矩形。It is further defined that the screen opening is a simple geometric figure, preferably an ellipse or a rectangle.

本发明的有益效果是:在不降低电流收集能力和光伏产品品质的同时,大幅度减低制作栅线的贵金属的使用量。其次,通过预断栅促成断栅等缺陷只出现在预先设计的位置,从而控制缺陷的影响,大大提升光伏电池的可靠性和安全性。The beneficial effects of the invention are: while not reducing the current collecting ability and the quality of photovoltaic products, the amount of precious metal used for making grid lines is greatly reduced. Secondly, through pre-broken grids, defects such as broken grids only appear in pre-designed positions, thereby controlling the impact of defects and greatly improving the reliability and safety of photovoltaic cells.

附图说明Description of drawings

下面结合附图和实施例对本发明进一步说明;Below in conjunction with accompanying drawing and embodiment the present invention is further described;

图1为目前的光伏电池的栅线的整体结构示意图;FIG. 1 is a schematic diagram of the overall structure of grid lines of current photovoltaic cells;

图2是图1中的细栅线比例夸张后的俯视图;FIG. 2 is an exaggerated top view of the thin grid lines in FIG. 1;

图3是图1中的细栅线比例夸张后的侧视图;Fig. 3 is a side view of the exaggerated scale of the fine grid lines in Fig. 1;

图4是本发明的实施例1光伏电池的栅线的整体结构示意图;4 is a schematic diagram of the overall structure of the grid lines of the photovoltaic cell in Embodiment 1 of the present invention;

图5是本发明的实施例1的细栅线比例夸张后的俯视图;Fig. 5 is an exaggerated top view of the fine grid lines in Embodiment 1 of the present invention;

图6是本发明的实施例1的细栅线比例夸张后的侧视图;Fig. 6 is an exaggerated side view of the thin grid lines in Embodiment 1 of the present invention;

图7是本发明的实施例2的细栅线比例夸张后的俯视图;Fig. 7 is an exaggerated top view of the thin grid lines in Embodiment 2 of the present invention;

图8是本发明的实施例3的细栅线比例夸张后的俯视图;Fig. 8 is an exaggerated top view of the thin grid lines in Embodiment 3 of the present invention;

图9是本发明的实施例3的细栅线比例夸张后的侧视图;Fig. 9 is an exaggerated side view of the thin grid lines in Embodiment 3 of the present invention;

图10是本发明的不同根数的互联条下细栅线的电学输送距离和含Ag浆料节省上限的关系图;Fig. 10 is a relationship diagram between the electrical transmission distance of the fine grid lines and the saving limit of the Ag-containing paste under different numbers of interconnecting strips of the present invention;

图11a是本发明的掩膜处理前的第一种丝网网版的局部放大图;Fig. 11a is a partial enlarged view of the first silk screen version before mask processing of the present invention;

图11b是本发明的掩膜处理后的第一种丝网网版的局部放大图;Fig. 11b is a partial enlarged view of the first screen screen after the mask treatment of the present invention;

图11c是本发明的第二种丝网网版的局部放大图;Figure 11c is a partial enlarged view of the second silk screen version of the present invention;

图11d是本发明的第四种丝网网版的局部放大图;Figure 11d is a partial enlarged view of the fourth silk screen version of the present invention;

图12a是本发明的掩膜处理前的第一种金属板网版的局部放大图;Fig. 12a is a partial enlarged view of the first metal plate screen before the mask treatment of the present invention;

图12b是本发明的掩膜处理后的第一种金属板网版的局部放大图;Fig. 12b is a partially enlarged view of the first metal plate screen after the mask treatment of the present invention;

图12c是本发明的掩膜处理前的第二种金属板网版的局部放大图;Fig. 12c is a partial enlarged view of the second metal plate screen before the mask treatment of the present invention;

图12d是本发明的掩膜处理后的第二种金属板网版的局部放大图;Fig. 12d is a partially enlarged view of the second metal plate screen after the mask treatment of the present invention;

图12e是本发明的掩膜处理前的第三种金属板网版的局部放大图;Fig. 12e is a partial enlarged view of the third metal plate screen before the mask treatment of the present invention;

图12f是本发明的掩膜处理后的第三种金属板网版的局部放大图;Fig. 12f is a partial enlarged view of the third metal plate screen after the mask treatment of the present invention;

图中,1.细栅线,2.主栅线,3.互联条,4.预断栅,5.横向网丝,6.纵向网丝,7.掩膜,7-1.形成预断栅的掩膜,8.细栅透孔区,9.金属板,10.网版开孔。In the figure, 1. thin grid line, 2. main grid line, 3. interconnection bar, 4. pre-broken grid, 5. horizontal mesh, 6. vertical mesh, 7. mask, 7-1. forming pre-broken grid Mask, 8. Fine grid through-hole area, 9. Metal plate, 10. Screen opening.

具体实施方式Detailed ways

本发明的核心是采用一种非均匀式的光伏电池受光面栅线设计,在不降低电流收集能力和光伏产品品质的同时,大幅度减低制作栅线的贵金属(一般为Ag)的使用量。在靠近栅线和互联条3的电连接点处的细栅线1的贵金属用量最多,导电性能最好。在最远离电连接点的电流收集末端部分的细栅线1的贵金属用量相对最少,导电性能最弱。在最接近电连接点和最远离电连接点之间的细栅线1的贵金属用量逐渐过渡。The core of the present invention is to adopt a non-uniform photovoltaic cell light-receiving surface grid line design, while not reducing the current collection capacity and photovoltaic product quality, while greatly reducing the amount of precious metal (generally Ag) used to make the grid line. The thin grid lines 1 close to the electrical connection points of the grid lines and the interconnection bars 3 have the most precious metals and the best electrical conductivity. The amount of precious metal used in the thin grid wire 1 at the end portion of the current collection farthest from the electrical connection point is relatively the least, and the conductivity is the weakest. The amount of noble metal in the thin grid lines 1 between the closest to the electrical connection point and the farthest from the electrical connection point transitions gradually.

下面在介绍现有电极设计的基础上,对比说明本发明的特点。In the following, on the basis of introducing the existing electrode design, the characteristics of the present invention will be described in comparison.

常见的光伏电池通常为125×125mm或156×156mm两种规格尺寸,主栅线2通常设计为2~5根。图1、2和3给出了现有通用的光伏电池的典型栅线设计。在图1中光伏电池的规格为156×156mm,该光伏电池的受光面具有3根主栅线2,和60~80根宽度为30~120um,高度为15~30um的细栅线1,细栅线为均匀分布设计。主栅线2和细栅线1由含Ag浆料通过丝网印刷的方式转移到光伏电池的受光面,然后在500~900℃的温度下高温烧结而成。这种含Ag浆料一般由导电相Ag粉、无机粘结剂玻璃料、有机载体及改善电池性能的微量添加剂组成,制备工艺复杂,价格高。为降低含Ag浆料成本,通常主栅线2的含Ag浆料的配方中会降低含Ag量,并通过镂空的方式来降低成本。互联条3通过焊接或导电胶粘结的方式通过主栅线2在电连接点处与细栅线1进行电连接,互联条3包括铜锡焊带、铜铟焊带。Common photovoltaic cells usually have two specifications of 125×125mm or 156×156mm, and the number of busbars 2 is usually designed to be 2 to 5. Figures 1, 2 and 3 show typical gridline designs of existing common photovoltaic cells. In Fig. 1, the specification of the photovoltaic cell is 156×156mm, and the light-receiving surface of the photovoltaic cell has 3 main grid lines 2, and 60-80 thin grid lines 1 with a width of 30-120um and a height of 15-30um. The grid lines are designed for uniform distribution. The main grid lines 2 and the thin grid lines 1 are formed by transferring the Ag-containing paste to the light-receiving surface of the photovoltaic cell by screen printing, and then sintering at a temperature of 500-900° C. at a high temperature. This Ag-containing slurry is generally composed of conductive phase Ag powder, inorganic binder glass frit, organic carrier and trace additives to improve battery performance, and the preparation process is complicated and the price is high. In order to reduce the cost of the Ag-containing paste, the formulation of the Ag-containing paste for the busbar 2 generally reduces the Ag content, and the cost is reduced by hollowing out. The interconnection bar 3 is electrically connected to the thin grid line 1 at the electrical connection point through the main grid line 2 by means of welding or conductive adhesive bonding, and the interconnection bar 3 includes copper-tin soldering strips and copper-indium soldering strips.

实施例1,如图4、5和6所示:Embodiment 1, as shown in Figures 4, 5 and 6:

一种光伏电池,在电池片的受光面具有栅线,栅线仅由细栅线1构成,省略主栅线2,细栅线1上具有电连接点,细栅线1在电连接点处直接与互联条3进行电连接,互联条3的数量为18~50根,在图中,互联条3的根数为22根。省去的主栅线2的Ag用量成本占光伏电池含Ag浆料成本的1/3,是一个显著进步。A photovoltaic cell, with a grid line on the light-receiving surface of the battery sheet, the grid line is only composed of a thin grid line 1, the main grid line 2 is omitted, and the thin grid line 1 has an electrical connection point, and the thin grid line 1 is at the electrical connection point It is directly electrically connected with the interconnecting bars 3, and the number of interconnecting bars 3 is 18-50. In the figure, the number of interconnecting bars 3 is 22. The cost of saving the amount of Ag for the busbar 2 accounts for 1/3 of the cost of the Ag-containing paste for the photovoltaic cell, which is a significant improvement.

对于3根主栅线2的设计,细栅线1的传输距离为52mm;对于22根互联条3的设计,细栅线1的运输距离为7mm。达成同样的传输能力,细栅线1的导电承载能力要求降低了8倍。对于30根互联条3的设计,细栅线1的运输距离为3.9mm,细栅线1的导电承载能力要求降低了10倍。这一部分的电流负荷被直接转移到了互联条3上,相当于使用互联条3取代了贵金属材质的栅线。显著多的互联条3的设计对含Ag浆料用量的节省作用见图10。For the design of 3 busbar lines 2, the transmission distance of the thin grid lines 1 is 52 mm; for the design of 22 interconnection bars 3, the transmission distance of the thin grid lines 1 is 7 mm. To achieve the same transmission capacity, the requirement for the conductive carrying capacity of the fine grid wire 1 is reduced by 8 times. For the design of 30 interconnecting bars 3, the transportation distance of the thin grid wire 1 is 3.9 mm, and the requirement for the conductive carrying capacity of the thin grid wire 1 is reduced by 10 times. This part of the current load is directly transferred to the interconnection bar 3 , which is equivalent to using the interconnection bar 3 to replace the grid lines made of noble metal. The saving effect of the design of significantly more interconnecting strips 3 on the amount of Ag-containing paste is shown in FIG. 10 .

距离最接近的电连接点越远,细栅线1的截面积越小,使得电流收集末端部分细栅线1的贵金属用量相对最少,可以大量节省Ag的用量。在这个实施例中,光伏电池的细栅线1的宽度是一致的,与图1、2和3中现有的光伏电池的细栅线1的设计没有区别,细栅线1通过降低细栅线1的高度来减小细栅线1的截面积,距离最接近的电连接点越远,细栅线1的高度越小,高度降低的趋势可以是非连续过渡的。细栅线1的设计和现有的光伏电池的细栅线1设计相比可以节省约10%左右Ag用量。The farther away from the closest electrical connection point, the smaller the cross-sectional area of the thin grid wire 1 , so that the amount of precious metal used in the thin grid wire 1 at the end part of the current collection is relatively minimum, and the amount of Ag can be greatly saved. In this embodiment, the width of the fine grid lines 1 of the photovoltaic cell is consistent, which is no different from the design of the existing thin grid lines 1 of the photovoltaic cell in Figs. 1, 2 and 3. The height of the wire 1 is used to reduce the cross-sectional area of the fine grid line 1, the farther away from the closest electrical connection point, the smaller the height of the fine grid line 1, and the trend of height reduction can be a discontinuous transition. The design of the thin grid line 1 can save about 10% of Ag consumption compared with the design of the existing thin grid line 1 of photovoltaic cells.

实施例2,如图7所示,Embodiment 2, as shown in Figure 7,

和实施例1相比,光伏电池的细栅线1的宽度和高度都是不一致的,细栅线1通过同时降低细栅线1的高度和宽度来减小细栅线1的截面积,距离最接近的电连接点越远,细栅线1的高度越小,而且细栅线1的宽度越小。Compared with Example 1, the width and height of the thin grid lines 1 of the photovoltaic cell are inconsistent, and the thin grid lines 1 reduce the cross-sectional area of the thin grid lines 1 by reducing the height and width of the thin grid lines 1 at the same time. The farther the closest electrical connection point is, the smaller the height of the thin grid line 1 is, and the smaller the width of the thin grid line 1 is.

实施例3,如图8和9所示,Embodiment 3, as shown in Figures 8 and 9,

和实施例1相比,细栅线1高度降低的趋势是连续过渡的,而且位于相邻的两个电连接点之间的细栅线1上具有预断栅4。预断栅4的宽度为D,0mm<D≤3mm。预断栅4位于细栅线1的中间位置。在图4中,假设有78根水平设置的细栅线1,并且有22根垂直设置的互联条3,则有(22-1)×78=1638个预断栅4。Compared with embodiment 1, the trend of decreasing the height of the fine grid lines 1 is a continuous transition, and there is a pre-broken grid 4 on the thin grid lines 1 between two adjacent electrical connection points. The width of the pre-broken grid 4 is D, where 0mm<D≤3mm. The pre-break grid 4 is located in the middle of the fine grid line 1 . In FIG. 4 , assuming that there are 78 thin grid lines 1 arranged horizontally and 22 interconnection bars 3 arranged vertically, there are (22−1)×78=1638 pre-break grids 4 .

预断栅4的作用是:光伏电池的栅线在印刷过程中经常会发生断栅现象,而且发生断栅的部位都是不确实的,极大的影响了栅线对电流的收集,而在本实施例中通过在细栅线1的对电池电流收集能力和可靠性影响最小的地方设计预断栅4,预断栅4会消减可能发生断栅的薄弱点的应力,使得可能发生断栅的薄弱点不会断栅。同时预断栅4也有利于降低含Ag浆料的用量。The function of the pre-broken grid 4 is: the grid lines of the photovoltaic cell often break the grid during the printing process, and the parts where the grid breaks occur are not accurate, which greatly affects the collection of the current by the grid lines. In the embodiment, by designing the pre-broken grid 4 at the place where the thin grid wire 1 has the least impact on the battery current collection capability and reliability, the pre-broken grid 4 will reduce the stress of the weak point where the grid may be broken, so that the weak point where the grid may be broken Will not break the grid. At the same time, the pre-break grid 4 is also beneficial to reduce the amount of Ag-containing paste.

在实施例1和2中,因为在位于相邻的两个电连接点之间细栅线1的中间位置的截面积最小,当存在断栅的因素时该中间部位也会优先断裂,在一定程度上也具有防止细栅线1的其他部分发生断栅的作用。In Embodiments 1 and 2, because the cross-sectional area of the middle position of the fine grid wire 1 between two adjacent electrical connection points is the smallest, when there is a factor of broken grid, the middle position will also be broken preferentially. To a certain extent, it also has the effect of preventing other parts of the thin grid wire 1 from being broken.

根据上述实例1、2和3的思想,本行业的工程技术人员非常容易举一反三,对实施例1、2和3的方法进行组合,对于这些变化,都属于发明保护的范围,本发明专利中不再一一赘述。According to the thinking of above-mentioned example 1, 2 and 3, the engineering technical personnel of this industry is very easy to draw inferences about other cases from one instance, and the method of embodiment 1, 2 and 3 is combined, for these changes, all belong to the scope of invention protection, not in the patent of the present invention Let me repeat them one by one.

为更为简单和形象地说明本发明的实质,本发明的思想可以和大自然的树叶(或人类血管)的构造来类比。这些运输管道的特点是越到末端越细小,原因是末端这一段的管道所承担的采集和输运的负载也最小。普通树叶脉络或普通血管采用的是同一种材料,大自然无法采用不同材料,因此采用了最简单的生物设计。在本发明中,光伏电池的电极材料从原有的3种(高含Ag细栅线、低含Ag主栅线和互联条)改变为2种(高含Ag细栅线和互联条),同时,大幅度增加互联条3的数量,使得细栅线1的运输距离大大减小。In order to illustrate the essence of the present invention more simply and vividly, the thought of the present invention can be compared with the structure of leaves (or human blood vessels) in nature. The characteristics of these transportation pipelines are that they become smaller towards the end, because the collection and transportation load borne by the pipeline at the end is also the smallest. Ordinary leaf veins or ordinary blood vessels use the same material, and nature cannot use different materials, so the simplest biological design is used. In the present invention, the electrode materials of the photovoltaic cell are changed from the original 3 types (high Ag-containing thin grid lines, low Ag-containing bus bars and interconnecting bars) to 2 types (high Ag-containing thin grid lines and interconnecting bars), At the same time, the number of interconnection bars 3 is greatly increased, so that the transportation distance of the thin grid wires 1 is greatly reduced.

为实现上述栅线设计,本发明同时披露了一种光伏电池丝网印刷网版:In order to realize the above grid line design, the present invention also discloses a photovoltaic cell screen printing screen:

该光伏电池丝网印刷网版的第一种设计为:The first design of the photovoltaic cell screen printing stencil is:

如图11a和11b所示,该丝网印刷网版用于实现实施例1,包括网版骨架和固定在网版骨架上的丝网,丝网由相互交错的横向网丝5和纵向网丝6构成,在丝网上具有用于印刷栅线的透孔区,透孔区外的丝网的其他区域覆盖掩膜7,因为实施例1的光伏电池的受光面仅具有细栅线1,故丝网印刷网版的透孔区仅包括用于印刷细栅线1的细栅透孔区8,细栅透孔区8的延伸方向与横向网丝5的延伸方向一致,即横向网丝5的延伸方向与待印刷的细栅线1的延伸方向一致,横向网丝5的直径以及横向网丝5之间的间隔相同,掩膜7的制备方法为:首先在丝网上涂覆光敏胶体涂层,通过曝光显影和腐蚀的方法形成掩膜区和透孔区,含Ag浆料就会通过透孔区印刷到光伏电池的表面。在细栅透孔区8内,纵向网丝6之间的间隔相同,纵向网丝6的直径与待印刷的细栅线1的截面积成反比,这样在光伏电池的印刷制造过程中,含Ag浆料通过透孔区漏下到电池表面时,就可以形成实施例1的非均匀栅线。As shown in Figures 11a and 11b, the screen printing screen is used to realize Embodiment 1, including a screen skeleton and a screen fixed on the screen skeleton, and the screen is composed of interlaced horizontal mesh 5 and vertical mesh 6, there is a through-hole area for printing grid lines on the screen, and other areas of the screen outside the through-hole area cover the mask 7, because the light-receiving surface of the photovoltaic cell in embodiment 1 only has thin grid lines 1, so The through-hole area of the screen printing screen only includes the fine-grid through-hole area 8 for printing fine grid lines 1, and the extension direction of the fine-grid through-hole area 8 is consistent with the extension direction of the transverse mesh 5, that is, the transverse mesh 5 The extension direction of the mask 7 is consistent with the extension direction of the fine grid line 1 to be printed, the diameter of the transverse mesh 5 and the interval between the transverse mesh 5 are the same, and the preparation method of the mask 7 is: firstly, the photosensitive colloid is coated on the screen. layer, through exposure, development and etching to form a mask area and a through-hole area, and the Ag-containing paste will be printed on the surface of the photovoltaic cell through the through-hole area. In the fine grid through-hole area 8, the intervals between the longitudinal meshes 6 are the same, and the diameter of the longitudinal meshes 6 is inversely proportional to the cross-sectional area of the thin grid lines 1 to be printed, so that in the printing and manufacturing process of photovoltaic cells, the When the Ag paste leaks down to the surface of the battery through the through-hole region, the non-uniform grid lines of Embodiment 1 can be formed.

该光伏电池丝网印刷网版的第二种设计为:The second design of the photovoltaic cell screen printing stencil is:

如图11c所示,和丝网印刷网版的第一种设计相比,不同点在于,在细栅透孔区8内,纵向网丝6的直径相同,纵向网丝6之间的间隔与待印刷的细栅线1的截面积成正比。As shown in Figure 11c, compared with the first design of the screen printing screen, the difference is that in the fine grid through-hole area 8, the diameters of the longitudinal meshes 6 are the same, and the distance between the longitudinal meshes 6 is the same as The cross-sectional area of the fine grid lines 1 to be printed is directly proportional.

该光伏电池丝网印刷网版的第三种设计为:The third design of the photovoltaic cell screen printing stencil is:

和丝网印刷网版的第一种设计相比,不同点在于,在细栅透孔区8内,纵向网丝6的直径与待印刷的细栅线1的截面积成反比,同时纵向网丝6之间的间隔与待印刷的细栅线1的截面积成正比。Compared with the first design of the screen printing screen, the difference is that in the fine grid through-hole area 8, the diameter of the longitudinal mesh 6 is inversely proportional to the cross-sectional area of the fine grid line 1 to be printed, while the longitudinal mesh The distance between the wires 6 is directly proportional to the cross-sectional area of the fine grid lines 1 to be printed.

该光伏电池丝网印刷网版的第四种设计:The fourth design of the photovoltaic cell screen printing stencil:

如图11d所示,该丝网印刷网版用于实现实施例3,和丝网印刷网版的第一种设计相比,不同点在于,在细栅透孔区8内,纵向网丝6的直径相同,纵向网丝6之间的间隔与待印刷的细栅线1的截面积成正比,在每条细栅透孔区8之间具有形成预断栅的掩膜7-1,即距离形成预断栅的掩膜7-1越近,纵向网丝6的网丝间隔越小。As shown in Figure 11d, this screen printing screen is used to realize embodiment 3. Compared with the first design of the screen printing screen, the difference is that in the fine grid through-hole area 8, the longitudinal mesh 6 The diameters are the same, the spacing between the longitudinal meshes 6 is proportional to the cross-sectional area of the fine grid line 1 to be printed, and there is a mask 7-1 for forming a pre-broken grid between each fine grid through-hole area 8, that is, the distance The closer the mask 7-1 for forming the pre-break grid is, the smaller the mesh spacing of the longitudinal mesh 6 is.

用于实现上述栅线设计,除上述丝网印刷网版外,本发明还披露了一种光伏电池金属板印刷网版:In order to realize the above-mentioned grid line design, in addition to the above-mentioned screen printing screen, the present invention also discloses a photovoltaic cell metal plate printing screen:

该金属板印刷网版包括金属板9,在金属板9上开设由网版开孔10构成的网版开孔阵列,在网版开孔阵列上通过覆盖掩膜7的方式形成印刷栅线的透孔区和掩膜区,在透孔区的用于印刷细栅线1的细栅透孔区8内,网版开孔阵列的通透率与待印刷的细栅线1的截面积成正比。光伏电池金属板印刷网版的优点在于:一方面可以避免网丝编织造成的编织结点的凸起,实现完全处于同一平面的丝网图案,可以印制出高宽比更高的栅线;另一方面,金属板印刷网版也可以通过网版开孔阵列图案的变化,更方便地在栅线的不同部位,实现不同的通透率。因此,特别适宜于针对本发明的非均匀截面积栅线的印刷。The metal plate printing screen includes a metal plate 9, on which a screen opening array composed of screen openings 10 is set, and the pattern of printing grid lines is formed on the screen opening array by covering the mask 7. In the through-hole area and the mask area, in the through-hole area for printing the fine grid line 1 in the fine grid through-hole area 8, the permeability of the screen opening array is proportional to the cross-sectional area of the fine grid line 1 to be printed. Proportional. The advantages of the photovoltaic cell metal plate printing screen are: on the one hand, it can avoid the protrusion of the weaving node caused by the mesh weaving, realize the screen pattern completely on the same plane, and can print the grid line with a higher aspect ratio; On the other hand, the metal plate printing screen can also achieve different transmittances at different parts of the grid line more conveniently through the change of the opening array pattern of the screen. Therefore, it is particularly suitable for printing the non-uniform cross-sectional area grid lines of the present invention.

该光伏电池金属板印刷网版的第一种设计:The first design of this photovoltaic cell metal plate printing screen:

如图12a和12b所示,该金属板印刷网版用于实现实施例1,在金属板9上通过蚀刻的方式形成类似于图11a和11b的丝网图案的网版开孔阵列,金属板9为不锈钢薄板材料,网版开孔阵列的网版开孔10为方形,在网版开孔阵列上通过覆盖掩膜7的方式形成印刷栅线的透孔区和掩膜区,因为实施例1的光伏电池的受光面仅具有细栅线1,故金属板网版的透孔区仅包括用于印刷细栅线1的细栅透孔区8,在细栅透孔区8内,网版开孔阵列的通透率是非均匀的,与待印刷的细栅线1的截面积成正比。网版开孔阵列可以仅仅在透孔区及其周边一定范围内,掩膜7的制备方法为:首先在网版开孔阵列上涂覆光敏胶体涂层,通过曝光显影和腐蚀的方法在网版开孔阵列上形成掩膜区和透孔区,含Ag浆料就会通过透孔区的网版开孔10印刷到光伏电池的表面,因为网版开孔阵列的通透率是非均匀的,这样就可以形成实施例1的非均匀栅线。As shown in Figures 12a and 12b, the metal plate printing screen is used to realize Embodiment 1, and a screen opening array similar to the screen pattern of Figures 11a and 11b is formed on the metal plate 9 by etching, the metal plate 9 is a stainless steel thin plate material, and the screen opening 10 of the screen opening array is square, and the through-hole area and the mask area of the printed grid line are formed on the screen opening array by covering the mask 7, because the embodiment 1, the light-receiving surface of the photovoltaic cell only has fine grid lines 1, so the through-hole area of the metal plate screen only includes the fine grid through-hole area 8 for printing the fine grid lines 1, and in the fine grid through-hole area 8, the mesh The permeability of the plate opening array is non-uniform and proportional to the cross-sectional area of the fine grid lines 1 to be printed. The screen opening array can only be in the through hole area and a certain range around it. The preparation method of the mask 7 is as follows: firstly, a photosensitive colloid coating is coated on the screen opening array, and the screen is exposed, developed and etched. A mask area and a through-hole area are formed on the plate opening array, and the Ag-containing paste will be printed on the surface of the photovoltaic cell through the screen openings 10 in the through-hole area, because the permeability of the screen opening array is non-uniform , so that the non-uniform grid lines of Embodiment 1 can be formed.

该光伏电池金属板印刷网版的第二种设计:The second design of the photovoltaic cell metal plate printing screen:

如图12c和图12d所示,金属板网版的网版开孔阵列图案与丝网图案并不相同,虽然和金属板印刷网版的第一种设计相比网版开孔10都为方形,但是每条细栅透孔区8的纵向仅具有一排网版开孔10,每条细栅透孔区8的延伸方向为横向,,距离最接近的电连接点越远,细栅线1的截面积越小,网版开孔阵列的通透率越低,网版开孔10的孔径越小。As shown in Figure 12c and Figure 12d, the stencil opening array pattern of the metal plate screen is not the same as the screen pattern, although the screen openings 10 are all square compared to the first design of the metal plate printing screen , but there is only one row of screen openings 10 in the longitudinal direction of each fine grid through-hole area 8, and the extension direction of each fine grid through-hole area 8 is transverse, and the farther away from the closest electrical connection point, the finer grid line The smaller the cross-sectional area of 1 is, the lower the permeability of the screen hole array is, and the smaller the aperture of the screen hole 10 is.

该光伏电池金属板印刷网版的第三种设计:The third design of the photovoltaic cell metal plate printing screen:

如图12e和图12f所示,和金属板印刷网版的第二种设计相比,不同点在于,网版开孔10为椭圆形,距离最接近的电连接点越远,椭圆形的网版开孔10的孔径越小。As shown in Figure 12e and Figure 12f, compared with the second design of the metal plate printing screen, the difference is that the opening 10 of the screen is elliptical, and the farther away from the nearest electrical connection point, the elliptical screen The smaller the hole diameter of the plate opening 10 is.

事实上,金属板网版的网版开孔10还可以采用其他形状的图形,如正六边形,正五变形等,这里就不一一赘述了。熟悉本领域的专业技术人员可以很容易就举一反三,在不改变发明原理的情况下做合理变形。In fact, the screen opening 10 of the metal plate screen can also adopt other shapes of figures, such as regular hexagon, regular pentagonal shape, etc., which will not be repeated here. Those skilled in the art can easily draw inferences from one instance and make reasonable deformations without changing the principle of the invention.

Claims (10)

1.一种光伏电池,在电池片的受光面具有栅线,其特征是:所述的栅线由主栅线和细栅线构成,细栅线上具有电连接点,细栅线在电连接点处通过主栅线与互联条进行电连接,距离最接近的电连接点越远,细栅线的截面积越小,截面积减小的趋势为连续的或非连续过渡的,并且细栅线通过降低细栅线的高度来减小细栅线的截面积;1. A photovoltaic cell has a grid line on the light-receiving surface of the battery sheet, and it is characterized in that: the grid line is composed of a main grid line and a thin grid line, and the thin grid line has an electrical connection point, and the thin grid line is connected to the grid line. The connection point is electrically connected to the interconnection bar through the main grid line. The farther the distance from the closest electrical connection point is, the smaller the cross-sectional area of the thin grid line is. The tendency of the cross-sectional area reduction is continuous or discontinuous transition, and The grid line reduces the cross-sectional area of the thin grid line by reducing the height of the thin grid line; 或者所述的栅线仅由细栅线构成,细栅线在电连接点处直接与互联条进行电连接,距离最接近的电连接点越远,细栅线的截面积越小,截面积减小的趋势为连续的或非连续过渡的,并且细栅线通过降低细栅线的高度来减小细栅线的截面积。Or the grid lines are only composed of thin grid lines, and the thin grid lines are directly electrically connected to the interconnection bars at the electrical connection points. The farther away from the closest electrical connection point, the smaller the cross-sectional area of the thin grid lines is. The decreasing trend is continuous or discontinuous transition, and the thin grid lines reduce the cross-sectional area of the thin grid lines by reducing the height of the thin grid lines. 2.根据权利要求1所述的光伏电池,其特征是:位于相邻的两个电连接点之间的细栅线上具有预断栅。2. The photovoltaic cell according to claim 1, characterized in that: there is a pre-break grid on the thin grid line between two adjacent electrical connection points. 3.根据权利要求2所述的光伏电池,其特征是:所述的预断栅的宽度为D,0mm<D≤3mm。3. The photovoltaic cell according to claim 2, characterized in that: the width of the pre-broken grid is D, 0mm<D≤3mm. 4.根据权利要求2所述的光伏电池,其特征是:所述的预断栅位于细栅线的中间位置。4. The photovoltaic cell according to claim 2, characterized in that: said pre-break grid is located in the middle of the thin grid lines. 5.根据权利要求1所述的光伏电池,其特征是:当所述的栅线仅由细栅线构成时,互联条的数量为18~50根。5. The photovoltaic cell according to claim 1, characterized in that: when the grid lines are only composed of thin grid lines, the number of interconnecting bars is 18-50. 6.根据权利要求1所述的光伏电池,其特征是:所述的互联条通过焊接或导电胶粘结的方式进行电连接。6 . The photovoltaic cell according to claim 1 , characterized in that: the interconnection strips are electrically connected by welding or conductive adhesive bonding. 7.一种用于印刷权利要求1或2或3或4或5或6所述的光伏电池的受光面的栅线的光伏电池丝网印刷网版,其特征是:包括网版骨架和固定在网版骨架上的丝网,所述的丝网由相互交错的横向网丝和纵向网丝构成,在丝网上通过覆盖掩膜的方式形成印刷栅线的透孔区和掩膜区,7. A photovoltaic cell screen printing screen for printing the grid lines of the light-receiving surface of the photovoltaic cell according to claim 1 or 2 or 3 or 4 or 5 or 6, characterized in that: it includes a screen skeleton and a fixed The screen on the screen skeleton, the screen is composed of interlaced horizontal wires and vertical wires, and the through-hole area and mask area of the printed grid line are formed on the screen by covering the mask. 透孔区的用于印刷细栅线的细栅透孔区的延伸方向与横向网丝的延伸方向一致,横向网丝的直径以及横向网丝之间的间隔相同,The extension direction of the fine grid through hole area for printing fine grid lines in the through hole area is consistent with the extension direction of the transverse mesh, and the diameter of the transverse mesh and the interval between the transverse mesh are the same. 在细栅透孔区内,纵向网丝之间的间隔相同,纵向网丝的直径与待印刷的细栅线的截面积成反比;或者纵向网丝的直径相同,纵向网丝之间的间隔与待印刷的细栅线的截面积成正比;或者纵向网丝的直径与待印刷的细栅线的截面积成反比,同时纵向网丝之间的间隔与待印刷的细栅线的截面积成正比。In the fine grid through-hole area, the spacing between the longitudinal meshes is the same, and the diameter of the longitudinal meshes is inversely proportional to the cross-sectional area of the fine grid lines to be printed; or the diameter of the longitudinal meshes is the same, and the spacing between the longitudinal meshes It is directly proportional to the cross-sectional area of the fine grid lines to be printed; or the diameter of the longitudinal mesh is inversely proportional to the cross-sectional area of the fine grid lines to be printed, and the interval between the longitudinal meshes is proportional to the cross-sectional area of the fine grid lines to be printed Proportional. 8.一种用于印刷权利要求1或2或3或4或5或6所述的光伏电池的受光面的栅线的光伏电池金属板印刷网版,其特征是:包括金属板,在金属板上开设由网版开孔构成的网版开孔阵列,在网版开孔阵列上通过覆盖掩膜的方式形成印刷栅线的透孔区和掩膜区,8. A photovoltaic cell metal plate printing screen for printing the grid lines of the light-receiving surface of the photovoltaic cell described in claim 1 or 2 or 3 or 4 or 5 or 6, characterized in that: it comprises a metal plate, A screen opening array composed of screen openings is set on the board, and the through-hole area and mask area of the printed grid line are formed on the screen opening array by covering the mask. 在透孔区的用于印刷细栅线的细栅透孔区内,网版开孔阵列的通透率与待印刷的细栅线的截面积成正比。In the through-hole area of the through-hole area for printing fine grid lines, the transmittance of the screen opening array is directly proportional to the cross-sectional area of the fine grid lines to be printed. 9.根据权利要求8上所述的的光伏电池金属板印刷网版,其特征是:所述的网版开孔为简单几何图形。9. The photovoltaic cell metal plate printing screen according to claim 8, characterized in that: the openings of the screen are simple geometric figures. 10.根据权利要求9上所述的的光伏电池金属板印刷网版,其特征是:所述的网版开孔为椭圆形或者矩形。10. The photovoltaic cell metal plate printing screen according to claim 9, characterized in that: the opening of the screen is oval or rectangular.
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