CN104307863B - Serious pollution soil restoring device - Google Patents

Serious pollution soil restoring device Download PDF

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CN104307863B
CN104307863B CN201410563874.8A CN201410563874A CN104307863B CN 104307863 B CN104307863 B CN 104307863B CN 201410563874 A CN201410563874 A CN 201410563874A CN 104307863 B CN104307863 B CN 104307863B
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soil
waste gas
volatile waste
storage tank
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CN104307863A (en
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万玉山
陈艳秋
黄利
李定龙
杨彦
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Changzhou University
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Abstract

一种重度污染土壤修复装置,包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气净化系统;土壤添加和排放系统包括土壤排放斜斗、土壤筒、土壤添加口;土壤加热和搅拌系统包括进气管、空气加热系统、搅拌电机、搅拌传动轴及搅拌叶片;挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气碱化吸收区、除雾器、挥发废气酸化吸收区、活性炭吸附层和排气扇;或挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气酸化吸收区、除雾器、挥发废气碱化吸收区、活性炭吸附层和排气扇。

A heavily polluted soil remediation device, including a soil adding and discharging system, a soil heating and stirring system, and a volatile waste gas purification system; the soil adding and discharging system includes a soil discharge inclined bucket, a soil cylinder, and a soil adding port; the soil heating and stirring system includes Air intake pipe, air heating system, stirring motor, stirring drive shaft and stirring blades; volatile waste gas purification system consists of volatile waste gas oxidation absorption area, volatile waste gas alkalization absorption area, demister, volatile waste gas acidification absorption area, activated carbon from the bottom up Adsorption layer and exhaust fan; or volatile waste gas purification system, from bottom to top, consists of volatile waste gas oxidation absorption zone, volatile waste gas acidification absorption zone, mist eliminator, volatile waste gas alkalization absorption zone, activated carbon adsorption layer and exhaust fan.

Description

重度污染土壤修复装置Severely polluted soil remediation device

技术领域technical field

本发明涉及污染土壤修复治理技术领域,尤其是一种重度污染土壤修复装置。The invention relates to the technical field of remediation and treatment of polluted soil, in particular to a heavily polluted soil remediation device.

背景技术Background technique

现代石油勘探、开采、加工企业,以及化工、制药等企业的生产过程经常会对土壤造成严重污染,这些重污染场地中柴油、苯、甲苯、四氯化碳等挥发性物质含量很高,而这些污染物大多属于疏水性有机物,在水相中的溶解度较小,能长时间地滞留在土壤环境中,既破坏了土壤结构和功能,对土壤的理化性质产生严重影响,又成为地表水和地下水的长期污染源。目前对重度挥发性污染土壤的治理多采用将土壤挖走异地进行焚烧、填埋、水力冲洗等处理,但存在处理成本较高,易产生二次污染等问题。The production processes of modern petroleum exploration, mining, processing enterprises, as well as chemical and pharmaceutical enterprises often cause serious pollution to the soil. The volatile substances such as diesel oil, benzene, toluene, and carbon tetrachloride in these heavily polluted sites are very high, and Most of these pollutants are hydrophobic organic substances, which have low solubility in the water phase and can stay in the soil environment for a long time, which not only destroys the structure and function of the soil, but also has a serious impact on the physical and chemical properties of the soil. Long-term source of contamination of groundwater. At present, the treatment of heavily volatile polluted soil mostly adopts digging the soil away from the site for incineration, landfill, water flushing and other treatment, but there are problems such as high treatment cost and easy to produce secondary pollution.

中国专利《挥发性和半挥发性有机物污染土壤场外治理工艺及装置》(专利号:200410056888.7)公开了一种挥发性和半挥发性有机物污染土壤场外治理工艺及装置,该装置具有结构简单等优点;但该专利装置存在以下缺陷:挥发性和半挥发性有机物仅仅通过活性炭的吸附,难以满足大气的排放标准。Chinese patent "Volatile and semi-volatile organic compound polluted soil off-site treatment process and device" (patent number: 200410056888.7) discloses a volatile and semi-volatile organic compound polluted soil off-site treatment process and device, the device has a simple structure etc. advantages; but the patented device has the following defects: volatile and semi-volatile organic compounds are only adsorbed by activated carbon, and it is difficult to meet the emission standards of the atmosphere.

发明内容Contents of the invention

本发明要解决的技术问题是:克服上述专利的技术问题,提供一种重度污染土壤修复装置,能有效处理各种挥发性重度污染土壤,结构简单,操作方便,可在污染现场就地进行土壤修复治理。The technical problem to be solved by the present invention is: to overcome the technical problems of the above-mentioned patents, to provide a heavily polluted soil remediation device, which can effectively treat various volatile heavily polluted soils, has a simple structure, is easy to operate, and can perform soil restoration on the spot at the polluted site. Fix governance.

本发明解决其技术问题所采用的技术方案是:一种重度污染土壤修复装置,包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气净化系统;土壤添加和排放系统、土壤加热和搅拌系统位于整个重度污染土壤修复装置的下部,挥发废气净化系统位于整个重度污染土壤修复装置的中上部。The technical solution adopted by the present invention to solve its technical problems is: a heavily polluted soil remediation device, including soil addition and discharge system, soil heating and stirring system, volatile waste gas purification system; soil addition and discharge system, soil heating and stirring system Located at the lower part of the entire heavily polluted soil remediation device, the volatile exhaust gas purification system is located at the middle and upper part of the entire heavily polluted soil remediation device.

所述土壤添加和排放系统包括土壤排放斜斗、土壤筒、土壤添加口。The soil adding and discharging system includes a soil discharging inclined bucket, a soil cylinder and a soil adding port.

所述土壤排放斜斗位于土壤添加和排放系统的最低部,土壤排放斜斗的上部为圆锥形结构,下出口斜向整个重度污染土壤修复装置的一侧。The soil discharge inclined bucket is located at the lowest part of the soil addition and discharge system, the upper part of the soil discharge inclined bucket is a conical structure, and the lower outlet is inclined to one side of the entire heavily polluted soil remediation device.

所述土壤筒下部与土壤排放斜斗的上口连接,土壤筒与土壤排放斜斗中间用可抽放挡板隔开。所述土壤添加口位于土壤筒上部、土壤排放斜斗下出口相反的一侧,土壤添加口设有圆弧形上下打开的推拉门。The lower part of the soil cylinder is connected to the upper opening of the soil discharge slope bucket, and the middle of the soil cylinder and the soil discharge slope bucket is separated by a drawable baffle. The soil adding port is located on the upper part of the soil cylinder and on the side opposite to the lower outlet of the soil discharge inclined bucket, and the soil adding port is provided with an arc-shaped sliding door that opens up and down.

所述土壤加热和搅拌系统包括进气管、空气加热系统、搅拌电机、搅拌传动轴及搅拌叶片。所述空气加热系统位于土壤可抽放挡板的上部,采用电加热装置,由十字支架固定在土壤筒的内壁上。所述搅拌传动轴及搅拌叶片为中空结构,搅拌叶片上设有热空气出口。The soil heating and stirring system includes an air intake pipe, an air heating system, a stirring motor, a stirring drive shaft and stirring blades. The air heating system is located on the upper part of the soil pumpable baffle, adopts an electric heating device, and is fixed on the inner wall of the soil cylinder by a cross bracket. The stirring drive shaft and the stirring blade are hollow structures, and the stirring blade is provided with a hot air outlet.

所述的挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气碱化吸收区、除雾器、挥发废气酸化吸收区、活性炭吸附层和排气扇或所述的挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气酸化吸收区、除雾器、挥发废气碱化吸收区、活性炭吸附层。The volatile waste gas purification system consists of volatile waste gas oxidation absorption area, volatile waste gas alkalization absorption area, mist eliminator, volatile waste gas acidification absorption area, activated carbon adsorption layer and exhaust fan or the volatile waste gas purification system from the bottom up. From the bottom up, there are volatile waste gas oxidation absorption area, volatile waste gas acidification absorption area, mist eliminator, volatile waste gas alkalization absorption area, and activated carbon adsorption layer.

所述的挥发废气氧化吸收区位于土壤筒的上部;所述的挥发废气氧化吸收区内设有挥发废气氧化吸收组件,所述的挥发废气氧化吸收组件包括位于挥发废气氧化组件上部的臭氧氧化水喷淋装置、位于挥发废气氧化吸收组件下部的臭氧氧化水储水槽和置于臭氧氧化水储水槽中的臭氧曝气盘,所述的臭氧曝气盘通过曝气管连通臭氧发生器,还具有将臭氧氧化水储水槽中的臭氧氧化水泵入臭氧氧化水喷淋装置的臭氧氧化水循环泵。The volatile waste gas oxidation absorption zone is located on the upper part of the soil cylinder; the volatile waste gas oxidation absorption component is arranged in the volatile waste gas oxidation absorption zone, and the volatile waste gas oxidation absorption component includes ozone oxidized water located on the upper part of the volatile waste gas oxidation component. The spray device, the ozone oxidation water storage tank located at the lower part of the volatile waste gas oxidation absorption assembly, and the ozone aeration pan placed in the ozone oxidation water storage tank, the ozone aeration pan communicates with the ozone generator through the aeration tube, and also has Pump the ozonated water in the ozonated water storage tank into the ozonated water circulating pump of the ozonated water spraying device.

所述的挥发废气碱化吸收区设有挥发废气碱化吸收组件,所述的挥发废气碱化吸收组件包括位于挥发废气碱化组件上部的碱性溶液喷淋装置、位于挥发废气碱化吸收组件下部的碱性溶液储水槽和将碱性溶液储水槽中的碱性溶液泵入碱性溶液喷淋装置的碱性溶液循环泵。The volatile waste gas alkalization absorption area is provided with a volatile waste gas alkalization absorption component, and the volatile waste gas alkalization absorption component includes an alkaline solution spray device located on the upper part of the volatile waste gas alkalization component, and a volatile waste gas alkalinity absorption component located An alkaline solution water storage tank at the lower part and an alkaline solution circulation pump for pumping the alkaline solution in the alkaline solution water storage tank into the alkaline solution spraying device.

所述的挥发废气酸化吸收区设有挥发废气酸化吸收组件,所述的挥发废气酸化吸收组件包括位于挥发废气氧化组件上部的酸性溶液喷淋装置、位于挥发废气酸化吸收组件下部的酸性溶液储水槽和将酸性溶液储水槽中的酸性溶液泵入酸性溶液喷淋装置的酸性溶液循环泵。The volatile waste gas acidification absorption area is provided with a volatile waste gas acidification absorption component, and the volatile waste gas acidification absorption component includes an acid solution spray device located on the upper part of the volatile waste gas oxidation component, and an acid solution water storage tank located at the lower part of the volatile waste gas acidification absorption component and an acid solution circulation pump for pumping the acid solution in the acid solution storage tank into the acid solution spraying device.

所述的挥发废气碱化吸收组件与挥发废气酸化吸收组件之间设有除雾器,除雾器是将气体中的大液滴进行收集,并使之返回,减少气体中的水份,其工作原理是气体进入除雾器,经过一系列弯道,从顶部排出,而水滴由于其质量和动能的作用,在经过弯道部分时,直线下落,冲撞除雾器的表面,并在到重力作用下弹回。A demister is arranged between the volatile waste gas alkalization absorption component and the volatile waste gas acidification absorption component. The demister collects large liquid droplets in the gas and returns them to reduce the moisture in the gas. The working principle is that the gas enters the demister, passes through a series of bends, and is discharged from the top, while the water droplets, due to their mass and kinetic energy, fall straight down when passing through the bends, collide with the surface of the demister, and fall under the force of gravity. Rebound under action.

所述的挥发废气酸化吸收组件上部设有活性炭吸附层,所述的活性炭吸附层中设置活性炭,活性炭要求具有孔隙发达、比表面积大、吸附速度快、抗摩擦、耐冲洗等优点,如经过较长时间的运行,发现活性炭变粘,气速降低时就需及时更换活性炭。The upper part of the volatile waste gas acidification absorption component is provided with an activated carbon adsorption layer, and activated carbon is arranged in the activated carbon adsorption layer. The activated carbon is required to have the advantages of developed pores, large specific surface area, fast adsorption speed, anti-friction, and washing resistance. After running for a long time, it is found that the activated carbon becomes sticky, and the activated carbon needs to be replaced in time when the gas velocity decreases.

具体的,所述的重度污染土壤修复装置中间为圆柱形、上下两端为圆锥形罐体,所述罐体上开设有观测口和检修更换口,罐体体积大小可根据待处理土壤量的多少而定,采用立式竖直放置。Specifically, the middle of the heavily polluted soil remediation device is cylindrical, and the upper and lower ends are conical tanks. The tank is provided with an observation port and a maintenance and replacement port. The volume of the tank can be determined according to the amount of soil to be treated. It depends on how much it is, and it is placed vertically.

为便于处理完的洁净气体排出,所述的重度污染土壤修复装置最上部的圆锥形罐体处安装有排气扇。In order to facilitate the discharge of the treated clean gas, an exhaust fan is installed at the uppermost conical tank of the heavily polluted soil remediation device.

进一步的与圆柱形罐体容器相匹配,所述的臭氧氧化水储水槽、碱性溶液储水槽和酸性溶液储水槽为圆盆形,臭氧氧化水储水槽、碱性溶液储水槽和酸性溶液储水槽上方均设有喷淋水聚集装置,所述的喷淋水聚集装置的下端直径小于臭氧氧化水储水槽、碱性溶液储水槽和酸性溶液储水槽的直径。喷淋水聚集装置可使喷淋水聚集回流至臭氧氧化水储水槽、碱性溶液储水槽和酸性溶液储水槽。Further matching with the cylindrical tank container, the ozonated water storage tank, alkaline solution storage tank and acid solution storage tank are in the shape of a round basin, and the ozonized water storage tank, alkaline solution storage tank and acid solution storage tank A spray water gathering device is arranged above the water tank, and the diameter of the lower end of the spray water gathering device is smaller than the diameters of the ozone oxidation water storage tank, the alkaline solution storage tank and the acid solution storage tank. The spray water gathering device can make the spray water gather and flow back to the ozone oxidation water storage tank, the alkaline solution storage tank and the acidic solution storage tank.

进一步的,为及时补充吸收溶液,所述的挥发废气碱化吸收组件还配有加碱装置,所述的加碱装置包括碱液罐和搅拌装置,碱液罐通过管路和阀门连通碱性溶液循环泵;挥发废气酸化组件还配有加酸装置,所述的加酸装置包括酸液罐和搅拌装置,酸液罐通过管路和阀门连通酸性溶液循环泵。吸收溶液的配比浓度根据处理的挥发废气量和挥发废气浓度来决定。Further, in order to replenish the absorption solution in time, the volatile waste gas alkalization absorption assembly is also equipped with an alkali addition device, and the alkali addition device includes a lye tank and a stirring device, and the lye tank is connected to the alkaline Solution circulation pump; the volatile exhaust gas acidification component is also equipped with an acid adding device, the acid adding device includes an acid tank and a stirring device, and the acid tank is connected to the acid solution circulation pump through pipelines and valves. The proportioning concentration of the absorption solution is determined according to the amount of volatile waste gas to be treated and the concentration of volatile waste gas.

进一步的,所述的臭氧氧化水喷淋装置、碱性溶液喷淋装置和酸性溶液喷淋装置为螺旋状喷淋装置;喷射出的水呈现雾状,且水雾之间交叉融合,不留死角,有利于扩大挥发废气与溶液的接触面积,提高吸收率和吸收效果。Further, the ozonated water spraying device, the alkaline solution spraying device and the acidic solution spraying device are spiral spraying devices; the sprayed water is in the form of mist, and the water mist intersects and merges without leaving The dead angle is beneficial to expand the contact area between the volatile waste gas and the solution, and improve the absorption rate and absorption effect.

所述的挥发废气碱化吸收组件采用的碱性溶液为氢氧化钠溶液或石灰水,所述的挥发废气酸化吸收组件采用的酸性溶液为硫酸或盐酸。The alkaline solution used in the volatile waste gas alkalization absorption component is sodium hydroxide solution or lime water, and the acidic solution used in the volatile waste gas acidification absorption component is sulfuric acid or hydrochloric acid.

进一步的优选设备,所述的臭氧发生器为中频臭氧发生器,耗电量少,占地面积小,能实现自动控制。As a further preferred device, the ozone generator is an intermediate frequency ozone generator, which consumes less power, occupies a small area, and can realize automatic control.

进一步的优选设备,除雾器为折流板除雾器或漩流板除雾器。As a further preferred device, the mist eliminator is a baffle plate mist eliminator or a swirl plate mist eliminator.

进一步的优选设备,整套装置的最底部设有三个支腿。Further preferred equipment, the bottom of the entire device is provided with three legs.

进一步的,为节省空间和美观,所述的臭氧发生器、臭氧氧化水循环泵、碱性溶液循环泵和酸性溶液循环泵布设在底部的三个支腿之间,所述的一体化装置的罐体上设有凹槽,凹槽中设有连接管,连接管把储水槽、喷淋装置、循环泵连接起来。Further, in order to save space and be attractive in appearance, described ozone generator, ozonated water circulating pump, alkaline solution circulating pump and acidic solution circulating pump are arranged between the three legs at the bottom, and the tank of the integrated device A groove is arranged on the body, and a connecting pipe is arranged in the groove, and the connecting pipe connects the water storage tank, the spraying device and the circulating pump.

本发明的有益效果是,首先打开土壤添加口,把污染土壤装入土壤筒内,空气加热系统对来自系统外的新鲜空气进行加热,在排气扇的抽排作用下,热空气由中空的搅拌传动轴及搅拌叶片和搅拌叶片上的热空气出口进入土壤,土壤在加热和搅拌的作用下带出挥发性物质,挥发废气上升到氧化吸收区内,臭氧氧化水从均布的臭氧氧化水喷淋装置喷出,形成无数细小雾滴,与挥发废气充分混合接触后发生化学反应,挥发废气中的有害物质被氧化成易于吸收和吸附的小分子物质,一部分被吸收在臭氧氧化水中;挥发废气继续上升与碱性溶液喷淋装置喷出的碱性溶液接触,挥发废气中酸性物质与碱性物质发生化学反应,反应生成物随碱性溶液流入下部碱性溶液储水槽中,然后进入除雾器,挥发废气中的液滴在这里被拦截下来;挥发废气继续上升与酸性溶液喷淋装置喷出的酸性溶液接触,挥发废气中的碱性物质与酸发生化学反应,反应生成物随酸性溶液流入下部酸性溶液储水槽中,然后进入活性炭吸附层,挥发废气中所夹杂的物质和液滴在这里被拦截吸附下来,至此挥发废气被处理成洁净的气体,实现达标排放;修复完成后抽出土壤筒与土壤排放斜斗中间的抽放挡板,土壤由土壤排放斜斗排出,回填原位;本发明的重度污染土壤修复装置结构简单,易于制造,能有效修复处理各种重度污染土壤。The beneficial effect of the present invention is that, firstly, the soil adding port is opened, and the polluted soil is put into the soil cylinder, and the air heating system heats the fresh air from outside the system, and under the pumping effect of the exhaust fan, the hot air is discharged from the hollow The stirring drive shaft, the stirring blades and the hot air outlet on the stirring blades enter the soil, and the soil will bring out volatile substances under the action of heating and stirring, and the volatile waste gas will rise to the oxidation absorption zone, and the ozone oxidized water will flow from the evenly distributed ozone oxidized water Sprayed by the spraying device, countless fine mist droplets are formed, which will undergo a chemical reaction after being fully mixed with the volatile waste gas. The exhaust gas continues to rise and contacts the alkaline solution sprayed by the alkaline solution spraying device. The acidic substances in the volatilized exhaust gas react chemically with the alkaline substances, and the reaction products flow into the lower alkaline solution storage tank with the alkaline solution, and then enter the removal The liquid droplets in the volatile exhaust gas are intercepted here; the volatile exhaust gas continues to rise and contacts the acidic solution sprayed by the acid solution spray device, and the alkaline substances in the volatile exhaust gas react with the acid, and the reaction products react with the acidic solution. The solution flows into the lower acidic solution storage tank, and then enters the activated carbon adsorption layer, where the substances and liquid droplets contained in the volatile waste gas are intercepted and adsorbed, and the volatile waste gas is processed into clean gas to achieve standard discharge; The extraction baffle between the soil cylinder and the soil discharge slant bucket, the soil is discharged from the soil discharge slant bucket, and backfilled in place; the heavily polluted soil remediation device of the present invention is simple in structure, easy to manufacture, and can effectively remediate various heavily polluted soils.

附图说明Description of drawings

下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1是本发明的实施例1结构示意图;Fig. 1 is the structural representation of embodiment 1 of the present invention;

图中:1.土壤排放斜斗,2.土壤筒,3.土壤添加口,4.可抽放挡板,5.进气管,6.空气加热系统,7.搅拌电机,8.搅拌传动轴,9.搅拌叶片,10.臭氧氧化水喷淋装置,11.臭氧氧化水储水槽,12.臭氧曝气盘,13.臭氧发生器,14.臭氧氧化水循环泵,15.碱性溶液喷淋装置,16.碱性溶液储水槽,17.碱性溶液循环泵,18.酸性溶液喷淋装置,19.酸性溶液储水槽,20.酸性溶液循环泵,21.除雾器,22.活性炭吸附层,23.排气扇,24.喷淋水聚集装置,25.支腿。In the figure: 1. Soil discharge inclined bucket, 2. Soil cylinder, 3. Soil adding port, 4. Withdrawable baffle, 5. Air intake pipe, 6. Air heating system, 7. Stirring motor, 8. Stirring drive shaft , 9. Stirring blade, 10. Ozone oxidation water spray device, 11. Ozone oxidation water storage tank, 12. Ozone aeration plate, 13. Ozone generator, 14. Ozone oxidation water circulation pump, 15. Alkaline solution spray Device, 16. Alkaline solution water storage tank, 17. Alkaline solution circulating pump, 18. Acidic solution spraying device, 19. Acidic solution water storage tank, 20. Acidic solution circulating pump, 21. Demister, 22. Activated carbon adsorption layer, 23. exhaust fan, 24. spray water gathering device, 25. outrigger.

具体实施方式detailed description

现在结合附图对本发明作进一步详细的说明。这些附图均为简化的示意图,仅以示意方式说明本发明的基本结构,因此其仅显示与本发明有关的构成。The present invention is described in further detail now in conjunction with accompanying drawing. These drawings are all simplified schematic diagrams, which only illustrate the basic structure of the present invention in a schematic manner, so they only show the configurations related to the present invention.

实施例1Example 1

如图1所示的本发明的一种重度污染土壤修复装置,包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气净化系统;土壤添加和排放系统、土壤加热和搅拌系统位于整个重度污染土壤修复装置的下部,挥发废气净化系统位于整个重度污染土壤修复装置的中上部。A heavily polluted soil remediation device of the present invention as shown in Figure 1 includes soil addition and discharge system, soil heating and stirring system, volatile waste gas purification system; soil addition and discharge system, soil heating and stirring system are located in the entire heavily polluted In the lower part of the soil remediation device, the volatile exhaust gas purification system is located in the middle and upper part of the entire heavily polluted soil remediation device.

所述土壤添加和排放系统包括土壤排放斜斗1、土壤筒2、土壤添加口3。The soil adding and discharging system comprises a soil discharging inclined bucket 1, a soil cylinder 2, and a soil adding port 3.

所述土壤排放斜斗1位于土壤添加和排放系统的最低部,土壤排放斜斗1的上部为圆锥形结构,下出口斜向整个重度污染土壤修复装置的一侧。The soil discharge inclined bucket 1 is located at the lowest part of the soil addition and discharge system, the upper part of the soil discharge inclined bucket 1 is a conical structure, and the lower outlet is inclined to one side of the whole heavily polluted soil remediation device.

所述土壤筒2下部与土壤排放斜斗1的上口连接,土壤筒2与土壤排放斜斗1中间用可抽放挡板4隔开;所述土壤添加口3位于土壤筒2的上部,在土壤排放斜斗1下出口相反的一侧,土壤添加口3设有圆弧形上下打开的推拉门。The lower part of the soil cylinder 2 is connected to the upper opening of the soil discharge slope 1, and the middle of the soil cylinder 2 and the soil discharge slope 1 is separated by a drawable baffle 4; the soil addition port 3 is located at the top of the soil cylinder 2, On the opposite side of the lower outlet of the soil discharge inclined bucket 1, the soil addition port 3 is provided with an arc-shaped sliding door that opens up and down.

所述土壤加热和搅拌系统包括进气管5、空气加热系统6、搅拌电机7、搅拌传动轴8及搅拌叶片9;所述空气加热系统6位于土壤可抽放挡板4的上部,采用电加热装置,由十字支架固定在土壤筒2的内壁上;所述搅拌电机7位于土壤筒2的上部,由十字支架固定在土壤筒2的内壁上,所述搅拌传动轴8及搅拌叶片9为中空结构,搅拌叶片9上设有热空气出口。The soil heating and stirring system includes an air intake pipe 5, an air heating system 6, a stirring motor 7, a stirring drive shaft 8 and a stirring blade 9; The device is fixed on the inner wall of the soil cylinder 2 by a cross bracket; the stirring motor 7 is located on the top of the soil cylinder 2, and is fixed on the inner wall of the soil cylinder 2 by a cross bracket, and the stirring drive shaft 8 and the stirring blade 9 are hollow structure, the stirring blade 9 is provided with a hot air outlet.

所述的挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气碱化吸收区、除雾器、挥发废气酸化吸收区、活性炭吸附层。The volatile waste gas purification system consists of volatile waste gas oxidation absorption area, volatile waste gas alkalization absorption area, mist eliminator, volatile waste gas acidification absorption area, and activated carbon adsorption layer from bottom to top.

所述的挥发废气氧化吸收区位于土壤筒2的上部;所述的挥发废气氧化吸收区内设有挥发废气氧化吸收组件,所述的挥发废气氧化吸收组件包括位于挥发废气氧化组件上部的臭氧氧化水喷淋装置10、位于挥发废气氧化吸收组件下部的臭氧氧化水储水槽11和置于臭氧氧化水储水槽中的臭氧曝气盘12,所述的臭氧曝气盘通过曝气管连通臭氧发生器13,还具有将臭氧氧化水储水槽中的臭氧氧化水泵入臭氧氧化水喷淋装置的臭氧氧化水循环泵14。The volatile waste gas oxidation absorption zone is located on the upper part of the soil cylinder 2; the volatile waste gas oxidation absorption component is arranged in the volatile waste gas oxidation absorption zone, and the volatile waste gas oxidation absorption component includes an ozone oxidation component located on the upper part of the volatile waste gas oxidation component. The water spray device 10, the ozone oxidation water storage tank 11 located at the lower part of the volatile waste gas oxidation absorption assembly and the ozone aeration pan 12 placed in the ozone oxidation water storage tank, the ozone aeration pan is connected to the ozone generator through the aeration tube Device 13 also has the ozone oxidation water circulation pump 14 that pumps the ozone oxidation water in the ozone oxidation water storage tank into the ozone oxidation water spraying device.

所述的挥发废气碱化吸收区设有挥发废气碱化吸收组件,所述的挥发废气碱化吸收组件包括位于挥发废气碱化组件上部的碱性溶液喷淋装置15、位于挥发废气碱化吸收组件下部的碱性溶液储水槽16和将碱性溶液储水槽中的碱性溶液泵入碱性溶液喷淋装置的碱性溶液循环泵17。The volatile waste gas alkalization absorption area is provided with a volatile waste gas alkalization absorption component, and the volatile waste gas alkalization absorption component includes an alkaline solution spray device 15 located on the upper part of the volatile waste gas alkalization component, and a volatile waste gas alkalization absorption unit located The alkaline solution water storage tank 16 at the lower part of the assembly and the alkaline solution circulation pump 17 that pumps the alkaline solution in the alkaline solution water storage tank into the alkaline solution spraying device.

所述的挥发废气酸化吸收区设有挥发废气酸化吸收组件,所述的挥发废气酸化吸收组件包括位于挥发废气氧化组件上部的酸性溶液喷淋装置18、位于挥发废气酸化吸收组件下部的酸性溶液储水槽19和将酸性溶液储水槽中的酸性溶液泵入酸性溶液喷淋装置的酸性溶液循环泵20。The volatile waste gas acidification absorption area is provided with a volatile waste gas acidification absorption assembly, and the volatile waste gas acidification absorption assembly includes an acid solution spray device 18 located on the upper part of the volatile waste gas oxidation assembly, and an acid solution storage device located at the lower part of the volatile waste gas acidification absorption assembly. Water tank 19 and the acidic solution circulating pump 20 that pumps the acidic solution in the acidic solution storage tank into the acidic solution spraying device.

所述的挥发废气碱化吸收组件与挥发废气酸化吸收组件之间设有除雾器21,除雾器21是将气体中的大液滴进行收集,并使之返回,减少气体中的水份,其工作原理是气体进入除雾器,经过一系列弯道,从顶部排出,而水滴由于其质量和动能的作用,在经过弯道部分时,直线下落,冲撞除雾器的表面,并在到重力作用下弹回。A demister 21 is provided between the volatile waste gas alkalization absorption component and the volatile waste gas acidification absorption component. The demister 21 collects large liquid droplets in the gas and returns them to reduce the moisture content in the gas , its working principle is that the gas enters the demister, passes through a series of bends, and is discharged from the top, while the water droplets, due to their mass and kinetic energy, fall straight down when passing through the bend, collide with the surface of the demister, and rebound under the force of gravity.

所述的挥发废气酸化吸收组件上部设有活性炭吸附层22,所述的活性炭吸附层22中设置活性炭,活性炭要求具有孔隙发达、比表面积大、吸附速度快、抗摩擦、耐冲洗等优点,如经过较长时间的运行,发现活性炭变粘,气速降低时就需及时更换活性炭。The upper part of the volatile waste gas acidification absorption component is provided with an activated carbon adsorption layer 22, and activated carbon is arranged in the activated carbon adsorption layer 22. The activated carbon is required to have the advantages of developed pores, large specific surface area, fast adsorption speed, anti-friction, and wash resistance, such as After a long period of operation, it is found that the activated carbon becomes sticky, and the activated carbon needs to be replaced in time when the gas velocity decreases.

具体的,所述的重度污染土壤修复装置中间为圆柱形、上下两端为圆锥形罐体,所述罐体上开设有观测口和检修更换口,罐体体积大小可根据待处理土壤量的多少而定,采用立式竖直放置。Specifically, the middle of the heavily polluted soil remediation device is cylindrical, and the upper and lower ends are conical tanks. The tank is provided with an observation port and a maintenance and replacement port. The volume of the tank can be determined according to the amount of soil to be treated. It depends on how much it is, and it is placed vertically.

为便于处理完的洁净气体排出,所述的重度污染土壤修复装置最上部的圆锥形罐体处安装有排气扇23。In order to facilitate the discharge of the treated clean gas, an exhaust fan 23 is installed at the uppermost conical tank of the heavily polluted soil remediation device.

进一步的与圆柱形罐体容器相匹配,所述的臭氧氧化水储水槽11、碱性溶液储水槽16和酸性溶液储水槽19为圆盆形,臭氧氧化水储水槽11、碱性溶液储水槽16和酸性溶液储水槽19上方均设有喷淋水聚集装置24,所述的喷淋水聚集装置24的下端直径小于臭氧氧化水储水槽11、碱性溶液储水槽16和酸性溶液储水槽19的直径;喷淋水聚集装置24可使喷淋水聚集回流到臭氧氧化水储水槽11、碱性溶液储水槽16和酸性溶液储水槽19中。Further matching with the cylindrical tank container, the ozonated water storage tank 11, the alkaline solution storage tank 16 and the acidic solution storage tank 19 are in the shape of a round basin, and the ozone oxidation water storage tank 11 and the alkaline solution storage tank 16 and acidic solution water storage tank 19 tops are all provided with spray water gathering device 24, and the lower end diameter of described spray water gathering device 24 is less than ozone oxidation water storage tank 11, alkaline solution water storage tank 16 and acidic solution water storage tank 19 diameter; the spray water gathering device 24 can make the spray water gather and return to the ozonized water storage tank 11, the alkaline solution storage tank 16 and the acidic solution storage tank 19.

进一步的,为及时补充吸收溶液,所述的挥发废气碱化吸收组件还配有加碱装置,所述的加碱装置包括碱液罐和搅拌装置,碱液罐通过管路和阀门连通碱性溶液循环泵17;挥发废气酸化组件还配有加酸装置,所述的加酸装置包括酸液罐和搅拌装置,酸液罐通过管路和阀门连通酸性溶液循环泵20;吸收溶液的配比浓度根据处理的挥发废气量和挥发废气浓度来决定。Further, in order to replenish the absorption solution in time, the volatile waste gas alkalization absorption assembly is also equipped with an alkali addition device, and the alkali addition device includes a lye tank and a stirring device, and the lye tank is connected to the alkaline Solution circulation pump 17; the volatile exhaust gas acidification component is also equipped with an acid adding device, the acid adding device includes an acid tank and a stirring device, and the acid tank is connected to the acid solution circulation pump 20 through pipelines and valves; the ratio of the absorption solution The concentration is determined according to the amount of volatile waste gas to be treated and the concentration of volatile waste gas.

进一步的,所述的臭氧氧化水喷淋装置10、碱性溶液喷淋装置15和酸性溶液喷淋装置18为螺旋状喷淋装置;喷射出的水呈现雾状,且水雾之间交叉融合,不留死角,有利于扩大挥发废气与溶液的接触面积,提高吸收率和吸收效果。Further, the ozone-oxidized water spraying device 10, the alkaline solution spraying device 15 and the acidic solution spraying device 18 are spiral spraying devices; the sprayed water is in the form of mist, and the water mist is cross-fused , without leaving any dead angle, it is beneficial to expand the contact area between the volatile waste gas and the solution, and improve the absorption rate and absorption effect.

具体地,所述的挥发废气碱化吸收组件采用的碱性溶液为氢氧化钠溶液或石灰水,所述的挥发废气酸化吸收组件采用的酸性溶液为硫酸或盐酸。Specifically, the alkaline solution used in the volatile waste gas alkalization absorption component is sodium hydroxide solution or lime water, and the acidic solution used in the volatile waste gas acidification absorption component is sulfuric acid or hydrochloric acid.

进一步的优选设备,所述的臭氧发生器13采用中频臭氧发生器,耗电量少,占地面积小,能实现自动控制。Further preferred equipment, described ozone generator 13 adopts intermediate frequency ozone generator, consumes less power, occupies a small area, and can realize automatic control.

进一步的优选设备,除雾器21为折流板除雾器或漩流板除雾器。As a further preferred device, the demister 21 is a baffle plate demister or a swirl plate demister.

进一步的优选设备,整套装置的最底部设有三个支腿25。As a further preferred device, three legs 25 are provided at the bottom of the entire device.

进一步的,为节省空间和美观,所述的臭氧发生器13、臭氧氧化水循环泵14、碱性溶液循环泵17和酸性溶液循环泵20布设在底部的三个支腿25之间,所述的一体化装置的罐体上设有凹槽,凹槽中设有连接管,连接管把储水槽、喷淋装置、循环泵连接起来。Further, for saving space and attractive in appearance, described ozone generator 13, ozonated water circulation pump 14, alkaline solution circulation pump 17 and acid solution circulation pump 20 are arranged between the three legs 25 at the bottom, and described The tank body of the integrated device is provided with a groove, and a connecting pipe is arranged in the groove, and the connecting pipe connects the water storage tank, the spraying device and the circulating pump.

首先打开土壤添加口3,把污染土壤装入土壤筒2内,空气加热系统对来自系统外的新鲜空气进行加热,热空气由中空的搅拌传动轴8及搅拌叶片9和搅拌叶片9上的热空气出口进入土壤,在排气扇23的抽排作用下带出挥发性物质,挥发废气上升到氧化吸收区内,臭氧氧化水从均布的臭氧氧化水喷淋装置10喷出,形成无数细小雾滴,与挥发废气充分混合接触后发生化学反应,挥发废气中的有害物质被氧化成易于吸收和吸附的小分子物质,一部分被吸收在臭氧氧化水中;挥发废气继续上升与碱性溶液喷淋装置15喷出的碱性溶液接触,挥发废气中酸性物质与碱性物质发生化学反应,反应生成物随碱性溶液流入下部碱性溶液储水槽16中,然后进入除雾器21,挥发废气中的液滴在这里被拦截下来;挥发废气继续上升与酸性溶液喷淋装置18喷出的酸性溶液接触,挥发废气中的碱性物质与酸发生化学反应,反应生成物随酸性溶液流入下部酸性溶液储水槽19中,然后进入活性炭吸附层22,挥发废气中所夹杂的污染物和液滴在这里被拦截吸附下来,至此挥发废气被处理成洁净的气体,实现达标排放;修复完成后抽出土壤筒2与土壤排放斜斗1中间的可抽放挡板4,土壤由土壤排放斜斗1排出,回填原位。First open the soil adding port 3, put the polluted soil into the soil cylinder 2, the air heating system heats the fresh air from outside the system, and the hot air is heated by the hollow stirring drive shaft 8, the stirring blade 9 and the heat on the stirring blade 9. The air outlet enters the soil, and the volatile substances are brought out under the action of the exhaust fan 23, and the volatile waste gas rises into the oxidation absorption area, and the ozonated water is sprayed from the evenly distributed ozonated water spraying device 10, forming countless fine particles. Fog droplets, after being fully mixed with volatile waste gas, a chemical reaction occurs. Harmful substances in volatile waste gas are oxidized into small molecular substances that are easy to absorb and absorb, and part of them are absorbed in ozonated water; volatile waste gas continues to rise and spray with alkaline solution The alkaline solution ejected from the device 15 contacts, and the acidic substances in the volatilized waste gas react chemically with the alkaline substances, and the reaction product flows into the lower alkaline solution water storage tank 16 along with the alkaline solution, and then enters the demister 21, and is released into the volatilized waste gas. The droplets are intercepted here; the volatile waste gas continues to rise and contacts the acidic solution sprayed by the acid solution spraying device 18, the alkaline substances in the volatile waste gas react with the acid, and the reaction product flows into the lower acidic solution with the acidic solution. In the water storage tank 19, it enters the activated carbon adsorption layer 22, where the pollutants and liquid droplets contained in the volatile waste gas are intercepted and adsorbed, and the volatile waste gas is processed into clean gas to achieve standard discharge; after the restoration is completed, the soil cylinder is drawn out 2 and the removable baffle plate 4 in the middle of the soil discharge inclined bucket 1, the soil is discharged by the soil discharge inclined bucket 1, and backfilled to the original position.

实施例2Example 2

本发明的第2个实施例与第1个实施例的区别在于:土壤中的挥发性物质偏碱性,重度污染土壤修复装置中没有挥发废气碱化吸收区,所述重度污染土壤修复装置包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气氧化吸收区、挥发废气酸化吸收区、除雾器21、活性炭吸附层22和排气扇23。The difference between the second embodiment of the present invention and the first embodiment is that the volatile substances in the soil are slightly alkaline, and there is no volatile waste gas alkalization absorption area in the heavily polluted soil remediation device, and the heavily polluted soil remediation device includes Soil addition and discharge system, soil heating and stirring system, volatile waste gas oxidation absorption area, volatile waste gas acidification absorption area, mist eliminator 21, activated carbon adsorption layer 22 and exhaust fan 23.

实施例3Example 3

本发明的第3个实施例与第1个实施例的区别在于:土壤中的挥发性物质偏酸性,重度污染土壤修复装置中没有挥发废气酸化吸收区,所述重度污染土壤修复装置包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气氧化吸收区、挥发废气碱化吸收区、除雾器21、活性炭吸附层22和排气扇23。The difference between the third embodiment of the present invention and the first embodiment is that the volatile substances in the soil are slightly acidic, there is no volatile waste gas acidification absorption area in the heavily polluted soil remediation device, and the heavily polluted soil remediation device includes soil addition And discharge system, soil heating and stirring system, volatile waste gas oxidation absorption area, volatile waste gas alkalization absorption area, mist eliminator 21, activated carbon adsorption layer 22 and exhaust fan 23.

以上述依据本发明的理想实施例为启示,通过上述的说明内容,相关工作人员完全可以在不偏离本项发明技术思想的范围内,进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。Inspired by the above-mentioned ideal embodiment according to the present invention, through the above-mentioned description content, relevant workers can make various changes and modifications within the scope of not departing from the technical idea of the present invention. The technical scope of the present invention is not limited to the content in the specification, but must be determined according to the scope of the claims.

Claims (2)

1.一种重度污染土壤修复装置,其特征在于:所述装置包括土壤添加和排放系统、土壤加热和搅拌系统、挥发废气净化系统;土壤添加和排放系统、土壤加热和搅拌系统位于整个重度污染土壤修复装置的下部,挥发废气净化系统位于整个重度污染土壤修复装置的中上部;1. A heavily polluted soil remediation device, characterized in that: the device includes soil addition and discharge system, soil heating and stirring system, volatile waste gas purification system; soil addition and discharge system, soil heating and stirring system are located in the entire heavily polluted The lower part of the soil remediation device, the volatile exhaust gas purification system is located in the middle and upper part of the entire heavily polluted soil remediation device; 所述土壤添加和排放系统包括土壤排放斜斗(1)、土壤筒(2)、土壤添加口(3);The soil adding and discharging system comprises a soil discharging inclined bucket (1), a soil cylinder (2), and a soil adding port (3); 所述土壤排放斜斗(1)位于土壤添加和排放系统的最低部,土壤排放斜斗(1)的上部为圆锥形结构,下出口斜向整个重度污染土壤修复装置的一侧;The soil discharge inclined bucket (1) is located at the lowest part of the soil addition and discharge system, the upper part of the soil discharge inclined bucket (1) is a conical structure, and the lower outlet is inclined to one side of the entire heavily polluted soil restoration device; 所述土壤筒(2)下部与土壤排放斜斗(1)的上口连接,土壤筒(2)与土壤排放斜斗(1)中间用可抽放挡板(4)隔开;所述土壤添加口(3)位于土壤筒(2)的上部,在土壤排放斜斗(1)下出口相反的一侧,土壤添加口(3)设有圆弧形上下打开的推拉门;The lower part of the soil cylinder (2) is connected to the upper opening of the soil discharge slope (1), and the soil cylinder (2) is separated from the soil discharge slope (1) by a drawable baffle (4); the soil The adding port (3) is located on the upper part of the soil cylinder (2), on the side opposite to the outlet of the soil discharge inclined bucket (1), and the soil adding port (3) is provided with an arc-shaped sliding door that opens up and down; 所述土壤加热和搅拌系统包括进气管(5)、空气加热系统(6)、搅拌电机(7)、搅拌传动轴(8)及搅拌叶片(9);所述空气加热系统(6)位于可抽放挡板(4)的上部,采用电加热装置,由十字支架固定在土壤筒(2)的内壁上;所述搅拌电机(7)位于土壤筒(2)的上部,由十字支架固定在土壤筒(2)的内壁上,所述搅拌传动轴(8)及搅拌叶片(9)为中空结构,搅拌叶片(9)上设有热空气出口;Described soil heating and stirring system comprise air intake pipe (5), air heating system (6), stirring motor (7), stirring transmission shaft (8) and stirring blade (9); Described air heating system (6) is positioned at The upper part of the extraction baffle (4) adopts an electric heating device, and is fixed on the inner wall of the soil cylinder (2) by a cross bracket; the stirring motor (7) is located on the top of the soil cylinder (2), and is fixed on the On the inner wall of the soil cylinder (2), the stirring drive shaft (8) and the stirring blade (9) are hollow structures, and the stirring blade (9) is provided with a hot air outlet; 所述的挥发废气净化系统从底部向上依次为挥发废气氧化吸收区、挥发废气碱化吸收区、除雾器、挥发废气酸化吸收区、活性炭吸附层和排气扇;The volatile waste gas purification system consists of volatile waste gas oxidation absorption area, volatile waste gas alkalization absorption area, mist eliminator, volatile waste gas acidification absorption area, activated carbon adsorption layer and exhaust fan from bottom to top; 所述的挥发废气氧化吸收区位于土壤筒(2)的上部;所述的挥发废气氧化吸收区内设有挥发废气氧化吸收组件,所述的挥发废气氧化吸收组件包括位于挥发废气氧化组件上部的臭氧氧化水喷淋装置(10)、位于挥发废气氧化吸收组件下部的臭氧氧化水储水槽(11)和置于臭氧氧化水储水槽中的臭氧曝气盘(12),所述的臭氧曝气盘通过曝气管连通臭氧发生器(13),还具有将臭氧氧化水储水槽中的臭氧氧化水泵入臭氧氧化水喷淋装置的臭氧氧化水循环泵(14);The volatile waste gas oxidation absorption zone is located on the upper part of the soil cylinder (2); the volatile waste gas oxidation absorption component is arranged in the volatile waste gas oxidation absorption zone, and the volatile waste gas oxidation absorption component includes a Ozone oxidation water spraying device (10), the ozone oxidation water storage tank (11) that is positioned at the lower part of volatile exhaust gas oxidation absorption assembly and the ozone aeration disc (12) that is placed in the ozone oxidation water storage tank, described ozone aeration The disc communicates with the ozone generator (13) through the aeration pipe, and also has the ozone oxidation water circulation pump (14) that pumps the ozone oxidation water in the ozone oxidation water storage tank into the ozone oxidation water spraying device; 所述的挥发废气碱化吸收区设有挥发废气碱化吸收组件,所述的挥发废气碱化吸收组件包括位于挥发废气碱化组件上部的碱性溶液喷淋装置(15)、位于挥发废气碱化吸收组件下部的碱性溶液储水槽(16)和将碱性溶液储水槽中的碱性溶液泵入碱性溶液喷淋装置的碱性溶液循环泵(17);The volatile waste gas alkalization absorption area is provided with a volatile waste gas alkalization absorption assembly, and the volatile waste gas alkalization absorption assembly includes an alkaline solution spraying device (15) located on the upper part of the volatile waste gas alkalization assembly, a volatile waste gas alkali The alkaline solution water storage tank (16) at the lower part of the chemical absorption assembly and the alkaline solution circulation pump (17) that pumps the alkaline solution in the alkaline solution water storage tank into the alkaline solution spraying device; 所述的挥发废气酸化吸收区设有挥发废气酸化吸收组件,所述的挥发废气酸化吸收组件包括位于挥发废气氧化组件上部的酸性溶液喷淋装置(18)、位于挥发废气酸化吸收组件下部的酸性溶液储水槽(19)和将酸性溶液储水槽中的酸性溶液泵入酸性溶液喷淋装置的酸性溶液循环泵(20);所述的挥发废气碱化吸收组件与挥发废气酸化吸收组件之间设有除雾器(21);所述的挥发废气酸化吸收组件上部设有活性炭吸附层(22),所述的活性炭吸附层(22)中设置活性炭;The volatile waste gas acidification absorption area is provided with a volatile waste gas acidification absorption assembly, and the volatile waste gas acidification absorption assembly includes an acid solution spray device (18) located on the upper part of the volatile waste gas oxidation assembly, and an acid solution spray device (18) located at the lower part of the volatile waste gas acidification absorption assembly. A solution water storage tank (19) and an acidic solution circulation pump (20) that pumps the acidic solution in the acidic solution water storage tank into the acidic solution spraying device; There is a demister (21); an activated carbon adsorption layer (22) is arranged on the upper part of the volatile waste gas acidification absorption component, and activated carbon is arranged in the activated carbon adsorption layer (22); 所述的重度污染土壤修复装置中间为圆柱形、上下两端为圆锥形罐体,采用立式竖直放置;所述的重度污染土壤修复装置最上部的圆锥形罐体处安装有排气扇(23);所述的臭氧氧化水储水槽(11)、碱性溶液储水槽(16)和酸性溶液储水槽(19)为圆盆形,臭氧氧化水储水槽(11)、碱性溶液储水槽(16)和酸性溶液储水槽(19)上方均设有喷淋水聚集装置(24),所述的喷淋水聚集装置(24)的下端直径小于臭氧氧化水储水槽(11)、碱性溶液储水槽(16)和酸性溶液储水槽(19)的直径;喷淋水聚集装置(24)可使喷淋水聚集回流到臭氧氧化水储水槽(11)、碱性溶液储水槽(16)和酸性溶液储水槽(19)中;The middle of the heavily polluted soil remediation device is cylindrical, and the upper and lower ends are conical tanks, which are placed vertically; the uppermost conical tank of the heavily polluted soil remediation device is equipped with an exhaust fan (23); described ozonated water storage tank (11), alkaline solution storage tank (16) and acidic solution storage tank (19) are round basin shape, and ozone oxidation water storage tank (11), alkaline solution storage tank Water tank (16) and acidic solution water storage tank (19) tops are all provided with spray water gathering device (24), and the lower end diameter of described spray water gathering device (24) is less than ozone oxidation water storage tank (11), alkali The diameter of the water storage tank (16) and acidic solution storage tank (19); the spray water gathering device (24) can make the spray water gather and flow back to the ozonized water storage tank (11), the alkaline solution storage tank (16 ) and acidic solution water storage tank (19); 所述的挥发废气碱化吸收组件还配有加碱装置,所述的加碱装置包括碱液罐和搅拌装置,碱液罐通过管路和阀门连通碱性溶液循环泵(17);挥发废气酸化组件还配有加酸装置,所述的加酸装置包括酸液罐和搅拌装置,酸液罐通过管路和阀门连通酸性溶液循环泵(20);整套装置的最底部设有三个支腿(25)。The volatile waste gas alkalization absorption assembly is also equipped with an alkali-adding device, and the described alkali-adding device includes a lye tank and a stirring device, and the lye tank is connected to the alkaline solution circulating pump (17) through a pipeline and a valve; the volatile waste gas The acidification component is also equipped with an acid adding device, which includes an acid tank and a stirring device, and the acid tank is connected to the acid solution circulation pump (20) through a pipeline and a valve; the bottom of the whole set of devices is provided with three legs (25). 2.根据权利要求1所述的重度污染土壤修复装置,其特征在于:所述的臭氧发生器(13)、臭氧氧化水循环泵(14)、碱性溶液循环泵(17)和酸性溶液循环泵(20)布设在底部的三个支腿(25)之间,所述的重度污染土壤修复装置的罐体上设有凹槽,凹槽中设有连接管,连接管把储水槽、喷淋装置、循环泵连接起来。2. The heavily polluted soil remediation device according to claim 1, characterized in that: the ozone generator (13), the ozonated water circulation pump (14), the alkaline solution circulation pump (17) and the acid solution circulation pump (20) Arranged between the three legs (25) at the bottom, the tank body of the heavily polluted soil remediation device is provided with a groove, and a connecting pipe is arranged in the groove, and the connecting pipe connects the water storage tank, spray device and circulation pump.
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