CN104292684A - Environment-friendly antibacterial PVC floor glue prepared from modified reworked materials - Google Patents
Environment-friendly antibacterial PVC floor glue prepared from modified reworked materials Download PDFInfo
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- CN104292684A CN104292684A CN201410445478.5A CN201410445478A CN104292684A CN 104292684 A CN104292684 A CN 104292684A CN 201410445478 A CN201410445478 A CN 201410445478A CN 104292684 A CN104292684 A CN 104292684A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Abstract
Relating to the field of resource regeneration, the invention provides an environment-friendly antibacterial PVC floor glue prepared from modified reworked materials. The PVC floor glue is composed of the following components by weight: 30-35 parts of recycled polyvinyl chloride, 15-20 parts of recycled polypropylene, 0.5-1 part of barium stearate, 2-4 parts of corn fiber, 4-6 parts of natural rubber, 1-3 parts of silicone oil, 4-6 parts of an adhesive, 0.5-1 part of alumina micro-powder, 0.5-2 parts of palm oil, 1-3 parts of carbon fiber, 4-6 parts of linear polyethylene, 2-4 parts of stearic acid, 0.5-2 parts of a flame retardant, 4-6 parts of gypsum powder, 2-4 parts of a degradation agent, 1-2 parts of calcium carbonate, 1-2 parts of olive oil, 1-3 parts of a pigment, and 1-2 parts of a modifying agent. The PVC floor glue is prepared by: mixing all the components evenly, conducting heat treatment at 80-90DEG C for 1h to make a glue material, and then sending the glue material into an extruder to carry out extrusion molding. According to the invention, waste materials are adopted as raw materials, the prepared product is neither too hard nor too soft, is acid and alkali resistant, anticorrosion, non-deforming and formaldehyde free, thus being a novel green and environment-friendly material.
Description
Technical field
The present invention relates to resource recovery technical field, be specifically related to a kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare.
Background technology
Along with industrial expansion, the application of plastics is throughout the every field of industrial or agricultural and daily life, the waste or used plastics rubbish of whole world generation every day cannot be estimated, but its large pressure of tool caused environment is apparent, in order to process these plastic garbages, existing method is generally landfill, burning etc.But because the natural degradation of common plastic garbage is chronic, generally will could degrade through more than 100 years, and also can produce the objectionable impuritiess such as a large amount of methane in degradation process, therefore landfill method has obtained denouncing of a lot of expert; And obnoxious flavour, flue dust etc. that burning method produces directly impact environment.Simultaneously because plastics are as petroleum chemicals, its main raw material produced is oil, and it is a kind of Nonrenewable resources, and current Global Oil contention is more and more fierce, crude oil cost is more and more higher, and therefore recycling for plastic prod is the best approach solving plastic garbage problem at present.It effectively solves the threat of plastic prod to environment, also can alleviate the usage quantity of oil to a certain extent simultaneously.
Plastic floor leather is to have from heavy and light, flexible, and physical strength is good, and feel intensity is good, comfortable foot feeling, wear-resisting, resistant, corrosion resistant, heat insulation, sound insulation, moistureproof, water-absorbent is little, good insulating, certainly puts out, easy to clean, construction is simple, easy to maintenance, the advantage such as cheap, in a large amount of covil construction and public place, requires to be used widely in higher factory building, laboratory to cleaning.Plastic floor leather belongs to soft floor, is be main raw material with polyvinyl chloride (PVC) RESINS, adds suitable adjuvants, the floor coil of the explained hereafter such as coated or calendering on sheet continuous base material.The flooring laminate retractility of current use is comparatively large, and in the environment that temperature variation is larger, stability in use is low, therefore needs to carry out enhanced stability by processing technology, processing units and formula.
Summary of the invention
It is low that technical problem to be solved by this invention is to provide a kind of cost, the environment-friendly antibacterial PVC ground glue that what performance was good utilize modification regeneration material to prepare.
Technical problem to be solved by this invention realizes by the following technical solutions:
The environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare, is made up of the component of following parts by weight: regeneration polyvinyl chloride 30-35 part, regenerating polypropylene 15-20 part, barium stearate 0.5-1 part, zein fiber 2-4 part, natural rubber 4-6 part, silicone oil 1-3 part, sizing agent 4-6 part, alumina powder 0.5-1 part, plam oil 0.5-2 part, carbon fiber 1-3 part, linear polyethylene 4-6 part, stearic acid 2-4 part, fire retardant 0.5-2 part, terra alba 4-6 part, degradation agents 2-4 part, calcium carbonate 1-2 part, sweet oil 1-2 part, pigment 1-3 part, properties-correcting agent 1-2 part; During preparation, each component mixed, at 80-90 DEG C of temperature, thermal treatment 1 hour, is made into sizing material, then sizing material is sent into extruder for shaping.
The better parts by weight of each component are: regeneration polyvinyl chloride 32 parts, regenerating polypropylene 18 parts, barium stearate 0.8 part, zein fiber 3 parts, natural rubber 5 parts, silicone oil 2 parts, sizing agent 5 parts, alumina powder 0.8 part, plam oil 0.8 part, 2 parts, carbon fiber, linear polyethylene 5 parts, stearic acid 3 parts, fire retardant 0.8 part, terra alba 5 parts, degradation agents 3 parts, 1.5 parts, calcium carbonate, 1.5 parts, sweet oil, pigment 2 parts, properties-correcting agent 1.5 parts;
Above-mentioned degradation agents is propylene glycol;
Above-mentioned properties-correcting agent is made up of the component of following parts by weight: modification purple sweet potato starch 4-6 part, Graphene 1-2 part, non-crystalline state quartz particles 1-3 part, citric acid 2-4 part, polydimethylsiloxane two quaternary amine 4-6 part, bamboo fibers 4-6 part, boron fibre 1-3 part, tealeaves alkaloid 4-6 part, Platinic chloride 1-3 part, methyl-silicone oil 1-2 part, calcium lignin sulphonate 0.2-0.5 part, lignocellulose 0.5-2 part, rosined soap 0.5-0.8 part, flyash 0.5-2 part; Its preparation method is as follows:
1) be dispersion medium by Graphene, non-crystalline state quartz particles, bamboo fibers and flyash with dehydrated alcohol, wherein the mass ratio of material and ethanol is 1:15, ultrasonic disperse 1 hour on supersonic cleaning machine;
2) compound through ultrasonic disperse is put into nylon ball grinder, add modification purple sweet potato starch, polydimethylsiloxane two quaternary amine, boron fibre and calcium lignin sulphonate again, take agate ball as abrading-ball, ball material mass ratio is 7:1, be under the condition of 150 revs/min at rotating speed, continuous ball milling 2 hours;
3) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the powder of drying is sieved, take out agate abrading-ball, grind, till the larger reunion of nothing, so far, the preparation of mixed powder is complete;
4) by step 3) in mixture mix with citric acid, tealeaves alkaloid, Platinic chloride, methyl-silicone oil, lignocellulose and rosined soap, low-temperature bake 2-3 hour under 50-70 DEG C of environment, to moisture content lower than 20%, take out, be ground into powder.
The invention has the beneficial effects as follows:
1) the present invention adopts waste as production starting material, and the product of preparation is neither too hard, nor too soft, acid and alkali-resistance, anticorrosive, indeformable, not containing formaldehyde, be a kind of new green environment protection material;
2) special treatment process be have employed to starting material, make the product prepared have higher stability, resistance to deterioration, the consistence of color and persistence.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
The environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare, is made up of the component of following parts by weight: regeneration polyvinyl chloride 32 parts, regenerating polypropylene 18 parts, barium stearate 0.8 part, zein fiber 3 parts, natural rubber 5 parts, silicone oil 2 parts, sizing agent 5 parts, alumina powder 0.8 part, plam oil 0.8 part, 2 parts, carbon fiber, linear polyethylene 5 parts, stearic acid 3 parts, fire retardant 0.8 part, terra alba 5 parts, propylene glycol 3 parts, 1.5 parts, calcium carbonate, 1.5 parts, sweet oil, pigment 2 parts, properties-correcting agent 1.5 parts; During preparation, each component mixed, at 80-90 DEG C of temperature, thermal treatment 1 hour, is made into sizing material, then sizing material is sent into extruder for shaping;
Above-mentioned properties-correcting agent is made up of the component of following parts by weight: modification purple sweet potato starch 5 parts, Graphene 1.5 parts, non-crystalline state quartz particles 2 parts, citric acid 3 parts, polydimethylsiloxane two quaternary amine 5 parts, bamboo fibers 5 parts, boron fibre 2 parts, tealeaves alkaloid 5 parts, Platinic chloride 2 parts, methyl-silicone oil 1.5 parts, calcium lignin sulphonate 0.3 part, lignocellulose 1 part, rosined soap 0.6 part, 0.6 part, flyash;
The preparation method of properties-correcting agent is as follows:
1) be dispersion medium by Graphene, non-crystalline state quartz particles, bamboo fibers and flyash with dehydrated alcohol, wherein the mass ratio of material and ethanol is 1:15, ultrasonic disperse 1 hour on supersonic cleaning machine;
2) compound through ultrasonic disperse is put into nylon ball grinder, add modification purple sweet potato starch, polydimethylsiloxane two quaternary amine, boron fibre and calcium lignin sulphonate again, take agate ball as abrading-ball, ball material mass ratio is 7:1, be under the condition of 150 revs/min at rotating speed, continuous ball milling 2 hours;
3) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the powder of drying is sieved, take out agate abrading-ball, grind, till the larger reunion of nothing, so far, the preparation of mixed powder is complete;
4) by step 3) in mixture mix with citric acid, tealeaves alkaloid, Platinic chloride, methyl-silicone oil, lignocellulose and rosined soap, low-temperature bake 2-3 hour under 50-70 DEG C of environment, to moisture content lower than 20%, take out, be ground into powder.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (3)
1. the environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare, it is characterized in that, be made up of the component of following parts by weight: regeneration polyvinyl chloride 30-35 part, regenerating polypropylene 15-20 part, barium stearate 0.5-1 part, zein fiber 2-4 part, natural rubber 4-6 part, silicone oil 1-3 part, sizing agent 4-6 part, alumina powder 0.5-1 part, plam oil 0.5-2 part, carbon fiber 1-3 part, linear polyethylene 4-6 part, stearic acid 2-4 part, fire retardant 0.5-2 part, terra alba 4-6 part, degradation agents 2-4 part, calcium carbonate 1-2 part, sweet oil 1-2 part, pigment 1-3 part, properties-correcting agent 1-2 part, during preparation, each component mixed, at 80-90 DEG C of temperature, thermal treatment 1 hour, is made into sizing material, then sizing material is sent into extruder for shaping.
2. a kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare according to claim 1, it is characterized in that: described properties-correcting agent is made up of the component of following parts by weight: modification purple sweet potato starch 4-6 part, Graphene 1-2 part, non-crystalline state quartz particles 1-3 part, citric acid 2-4 part, polydimethylsiloxane two quaternary amine 4-6 part, bamboo fibers 4-6 part, boron fibre 1-3 part, tealeaves alkaloid 4-6 part, Platinic chloride 1-3 part, methyl-silicone oil 1-2 part, calcium lignin sulphonate 0.2-0.5 part, lignocellulose 0.5-2 part, rosined soap 0.5-0.8 part, flyash 0.5-2 part, its preparation method is as follows:
1) be dispersion medium by Graphene, non-crystalline state quartz particles, bamboo fibers and flyash with dehydrated alcohol, wherein the mass ratio of material and ethanol is 1:15, ultrasonic disperse 1 hour on supersonic cleaning machine;
2) compound through ultrasonic disperse is put into nylon ball grinder, add modification purple sweet potato starch, polydimethylsiloxane two quaternary amine, boron fibre and calcium lignin sulphonate again, take agate ball as abrading-ball, ball material mass ratio is 7:1, be under the condition of 150 revs/min at rotating speed, continuous ball milling 2 hours;
3) pour in powder dish by powder complete for ball milling together with agate abrading-ball, dry at 80 DEG C, the powder of drying is sieved, take out agate abrading-ball, grind, till the larger reunion of nothing, so far, the preparation of mixed powder is complete;
4) by step 3) in mixture mix with citric acid, tealeaves alkaloid, Platinic chloride, methyl-silicone oil, lignocellulose and rosined soap, low-temperature bake 2-3 hour under 50-70 DEG C of environment, take out, be ground into powder.
3. a kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare according to claim 1, is characterized in that: above-mentioned degradation agents is propylene glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445478.5A CN104292684B (en) | 2014-09-03 | 2014-09-03 | A kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410445478.5A CN104292684B (en) | 2014-09-03 | 2014-09-03 | A kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare |
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| Publication Number | Publication Date |
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| CN104292684A true CN104292684A (en) | 2015-01-21 |
| CN104292684B CN104292684B (en) | 2016-06-15 |
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| CN201410445478.5A Expired - Fee Related CN104292684B (en) | 2014-09-03 | 2014-09-03 | A kind of environment-friendly antibacterial PVC ground glue utilizing modification regeneration material to prepare |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038020A (en) * | 2015-07-31 | 2015-11-11 | 苏州天健竹业科技有限公司 | Composite material for yoga balls and preparation method of composite material |
| CN105602228A (en) * | 2016-01-21 | 2016-05-25 | 苏州法斯特信息科技有限公司 | Fireproof high-strength plastic floor material and preparation method thereof |
| CN106541653A (en) * | 2016-10-25 | 2017-03-29 | 东台市富安合成材料有限公司 | A kind of Household ornament wallpaper synthetic leather and preparation method thereof |
| TWI688589B (en) * | 2018-08-31 | 2020-03-21 | 吳同發 | Method for manufacturing waste rubber, plastic foam material, waste plant fiber and mineral regenerated products |
| CN114410032A (en) * | 2022-02-11 | 2022-04-29 | 重庆海宇环保新材料有限公司 | Plastic coiled material and preparation process thereof |
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| JPH1192606A (en) * | 1997-05-30 | 1999-04-06 | Hanhwa Chem Co Ltd | Synthetic resin composition and products therefrom |
| CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
| CN102757590A (en) * | 2012-07-31 | 2012-10-31 | 王鸿 | Floor, manufacture method and application thereof |
-
2014
- 2014-09-03 CN CN201410445478.5A patent/CN104292684B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1192606A (en) * | 1997-05-30 | 1999-04-06 | Hanhwa Chem Co Ltd | Synthetic resin composition and products therefrom |
| CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
| CN102757590A (en) * | 2012-07-31 | 2012-10-31 | 王鸿 | Floor, manufacture method and application thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038020A (en) * | 2015-07-31 | 2015-11-11 | 苏州天健竹业科技有限公司 | Composite material for yoga balls and preparation method of composite material |
| CN105602228A (en) * | 2016-01-21 | 2016-05-25 | 苏州法斯特信息科技有限公司 | Fireproof high-strength plastic floor material and preparation method thereof |
| CN106541653A (en) * | 2016-10-25 | 2017-03-29 | 东台市富安合成材料有限公司 | A kind of Household ornament wallpaper synthetic leather and preparation method thereof |
| TWI688589B (en) * | 2018-08-31 | 2020-03-21 | 吳同發 | Method for manufacturing waste rubber, plastic foam material, waste plant fiber and mineral regenerated products |
| CN114410032A (en) * | 2022-02-11 | 2022-04-29 | 重庆海宇环保新材料有限公司 | Plastic coiled material and preparation process thereof |
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| CN104292684B (en) | 2016-06-15 |
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