Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.
The thickening mechanism of cellulose thickener is that hydrophobic main chain passes through hydrogen bond association with surrounding water molecules, improves
The fluid volume of polymer itself, decreases the space that Particle free is movable, thus improves system viscosity.
The raising of viscosity can also be realized by the winding of strand, show as there is high viscosity at static and low sheraing,
It is low-viscosity under high shear.This is because when static state or low shearing speed, cellulose molecular chain is in unordered
State and make system present high viscosity;And when high shear rates, molecule is parallel to flow direction and makees row in order
Row, it is easy to mutually slide, so system viscosity degradation.By cellulose thickener, attapulgite and auxiliary agent
Mix by a certain percentage, can prepare use under neutral environment, have good thickening adhesive effect, do not contain
The binding agent of metal ion, is applicable in Building Ceramics Industry need to be fixed frit granule with bonding
Operation in.
Preparation-the embodiment 1 of frit granule agglomerant
The component of every 100kg frit granule agglomerant: (the unconcerned gram building materials science and technology in Guangzhou is limited for hydroxyethyl cellulose
Company buys) 5.0kg, attapulgite 2.5kg, polymethyl siloxane 1.1kg, organic-silicon-modified sodium phosphate
1.7kg, surplus is water.
The preparation method of above-mentioned frit granule agglomerant, comprises the following steps: a) be dissolved in by hydroxyethyl cellulose
In water, stir;B) add polymethyl siloxane and organic-silicon-modified sodium phosphate, stir;c)
Adding attapulgite and residue aqueous solvent, be uniformly mixing to obtain frit granule agglomerant, surveying its flow velocity is 26.8s
(30 DEG C, be coated with-4 glasss).It should be noted that organic-silicon-modified sodium phosphate can use poly-as dispersant
Sodium acrylate or sodium hexameta phosphate are replaced and also can be realized this programme.
Preparation-embodiment 1-1 of glazed tile
By transparent ice crystal frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 100 mesh) cloth
In in the billet surface of revenue stamp process, then spray the frit granule agglomerant that one layer of embodiment 1 prepares,
Send in kiln and burn till at 1100 DEG C, edging chamfering, obtain having be uniformly distributed, the glaze of complete ice crystal texture
Face brick finished product.At this it should be noted that the pebble frit granule that the present embodiment 1-1 selects is sintering
During sprawl, cover coat is formed argenteous ice crystal textured pattern, frit granule can pass through
Colour glaze company buys and obtains, and similar frit product also can realize this programme.
Comparative example 1-2
By the pebble frit granule cloth identical with embodiment 1-1 in the billet surface through revenue stamp process
On, then one layer of viscosity aqueous slurry being configured to by methylcellulose of spraying, send in kiln, at 1100 DEG C
Burn till, edging chamfering, obtain the glazed tile finished product with ice crystal texture, but texture exists a small amount of naked eyes can
Seeing pin hole, the seriality of ice crystal texture is the strongest.
Can be compared with the glazed tile end product quality of comparative example 1-2 by embodiment 1-1 and draw embodiment
The frit granule of the present invention that sprayed on the pebble frit granular layer have ice crystal effect in 1-1 bonds
Agent, make pebble frit particles stick on glaze, and in the preheating zone through kiln not by lower negative pressure
Impact, preferably retains on glaze and is not absorbed.In order to illustrate further, provide below enforcement
The frit granule agglomerant that example 1-1 uses glues with the motion of the viscosity aqueous slurry of use in comparative example 1-2
Angle value μ compares, and experimental data is shown in Table 1.
Kinematic viscosity value μ: be coated with-4 glasss at 30 DEG C measure liquid from the hole of predetermined hole diameter flow out needed for time
Between obtain flow velocity t, and can by t=0.223 μ+6.0 conversion draw kinematic viscosity value μ.
Table 1 embodiment 1 frit granule agglomerant and the kinematic viscosity value of viscosity aqueous slurry
Numbering |
Flow velocity/s |
Kinematic viscosity value/(mm2/s) |
Embodiment 1-1 |
26.8 |
85.19 |
Comparative example 1-2 |
7.4 |
8.05 |
Can obtain from table 1, its kinematic viscosity value of the frit granule agglomerant in embodiment 1-1 is comparative example
1-2 uses the kinematic viscosity value 10 times more than of the viscosity aqueous slurry being configured to by methylcellulose, faced by
During the lower negative pressure of kiln preheating zone, can be the most bonding frit granule so that it is remain and be not sucked away,
It is greatly improved adobe and burns till the integrity of texture and the flatness of rear surface, can avoid because frit granule is inhaled
Walk disappearance and the pin hole problems of generation may be left over.
Embodiment 1-3
375kg zirconium white frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 110 mesh) is added
Enter in the frit granule agglomerant of the 125kg that embodiment 1 prepares, mix homogeneously, obtain frit particle suspension liquid,
Frit granule solid content 75%, without visible bubble in bubble, flow velocity is 44.7s (30 DEG C, be coated with-4 glasss), and suspension is put
Still without lamination after putting 5 days, it is seen that frit granule agglomerant of the present invention still has after mixing with frit granule
Good stability.It should be noted that the zirconium white frit granule that the present embodiment 1-3 selects is in sintering process
Middle sprawling, form the effect of transparency ice crystallized reason on cover coat, frit granule can pass through colour glaze
Company buys and obtains, and similar frit product also can realize this programme.
Above-mentioned prepared frit particle suspension liquid is drenched at the base substrate table through revenue stamp process in the way of drenching glaze
Face, the thickness controlling billet surface frit particle suspension liquid is 2mm, and in kiln, 1100 DEG C are burnt till, edging
Chamfering, the glazed tile finished product obtained, flatness is high, and the transparency ice crystallized reason of formation has seriality with complete
Property, the bubble being visible by naked eyes and pin hole.
Comparative example 1-4
By the 375kg zirconium white frit granule of above-described embodiment 1-3 (buy from Zibo Boshan gold light colour glaze factory,
Fineness 110 mesh) add 125kg glue in, mix homogeneously, obtain frit particle suspension liquid, frit granule
Solid content 75%, flow velocity is 32.8s (30 DEG C, be coated with-4 glasss), and suspension lamination occurs after placing 5 days,
Not there is good stability, before using, need stirring and evenly mixing again.
Above-mentioned prepared frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze,
The thickness controlling billet surface frit particle suspension liquid is 2mm, and in kiln, 1100 DEG C are burnt till, edging chamfering,
The glazed tile finished product obtained, there is interval stricture of vagina, discontinuously, and leaves bubble in the transparency ice crystallized reason of formation.
In order to illustrate further, provide below the outstanding of the prepared frit granule agglomerant of use embodiment 1-3
Supernatant liquid compares with kinematic viscosity value μ of the suspension using glue to prepare in comparative example 1-4, tests number
According to being shown in Table 2.
Table 2 embodiment 1-3 and contrast experiment's data of comparative example 1-4
Numbering |
Flow velocity/s |
Kinematic viscosity value/(mm2/s) |
Phenomenon after placing 5 days |
Embodiment 1-3 |
44.7 |
168.23 |
Occur without layering |
Comparative example 1-4 |
32.8 |
103.45 |
Layering occurs |
As can be seen from Table 2, the suspension that the frit granule agglomerant in embodiment 1-3 and frit granule prepare
Its kinematic viscosity value is that the motion of the suspension using glue and frit granule to prepare in comparative example 1-4 is glued
Angle value 1.5 times, when in the face of the lower negative pressure of kiln preheating zone, can be the most bonding frit granule so that it is
Remain and be not sucked away, be greatly improved adobe and burn till the integrity of texture and the flatness of rear surface, can
Avoid to leave over the pin hole problems of generation because frit granule is sucked away disappearance.
Preparation-the embodiment 2 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 5.5kg, attapulgite 3.0kg, polymethyl siloxane 1.4kg, six
Polymeric sodium metaphosphate. 2.1kg, surplus is ethanol.
Preparation-embodiment 2-1 of glazed tile
By clear frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 130 mesh) cloth in warp
Cross in the billet surface of revenue stamp process, the frit granule agglomerant that then one layer of embodiment of spraying 2 prepares, send
Enter in kiln and burn till at 1120 DEG C, edging chamfering, obtain having be uniformly distributed, the glaze of complete ice crystal texture
Brick finished product.At this it should be noted that the clear frit granule of the present embodiment 2-1 selection is in sintering process
Sprawling, form transparency ice crystalline substance textured pattern on cover coat, frit granule can pass through colour glaze company
Buying and obtain, similar frit product also can realize this programme.The stream of the frit particles stick agent that this method prepares
Speed is 25.7s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 84.56mm2/s。
Preparation-embodiment 2-2 of glazed tile
375kg clear frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 110 mesh) is added
Enter in the frit granule agglomerant of the 125kg that embodiment 1 prepares, mix homogeneously, obtain frit particle suspension liquid,
Frit granule solid content 75%, without visible bubble in bubble, flow velocity is 46.8s (30 DEG C, be coated with-4 glasss), and suspension is put
Still without lamination after putting 5 days, it is seen that frit granule agglomerant of the present invention still has after mixing with frit granule
Good stability.It should be noted that the clear frit granule that the present embodiment 2-2 selects is in sintering process
Middle sprawling, form the effect of transparency ice crystallized reason on cover coat, frit granule can pass through colour glaze
Company buys and obtains, and similar frit product also can realize this programme.
Above-mentioned prepared frit particle suspension liquid is drenched at the base substrate table through revenue stamp process in the way of drenching glaze
Face, the thickness controlling billet surface frit particle suspension liquid is 2mm, and in kiln, 1120 DEG C are burnt till, edging
Chamfering, the glazed tile finished product obtained, flatness is high, and the transparency ice crystallized reason of formation has seriality with complete
Property, the bubble being visible by naked eyes and pin hole.This method prepare suspension for 46.8s (30 DEG C, be coated with-4
Cup), kinematic viscosity value is 173.18mm2/s。
Preparation-the embodiment 3 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 6.0kg, attapulgite 2.6kg, polymethyl siloxane 1.2kg, six
Polymeric sodium metaphosphate. 1.8kg, surplus is ethylene glycol.
Preparation-embodiment 3-1 of glazed tile
By the frit granule of red ice crystal effect (buying from Quincy card Robbie glaze company, fineness 180 mesh)
Cloth is in the billet surface of revenue stamp process, and the frit granule that then one layer of embodiment of spraying 3 prepares glues
Knot agent, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtain having be uniformly distributed, complete ice crystal stricture of vagina
The glazed tile finished product of reason.At this it should be noted that the clear frit granule that the present embodiment 3-1 selects is burning
Sprawling during knot, form red ice crystal flower textured pattern on cover coat, frit granule can pass through
Colour glaze company buys and obtains, and similar frit product also can realize this programme.The frit granule that this method prepares
The flow velocity of bonding agent is 25.2s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 84.98mm2/s。
Preparation-embodiment 3-2 of glazed tile
The frit granule of 350kg redness ice crystal effect (is bought from Quincy card Robbie glaze company, fineness 110
Mesh) add in the frit granule agglomerant of the 150kg that embodiment 3 prepares, frit granule solid content 70%,
Without visible bubble in bubble, flow velocity is 44.3s (30 DEG C, be coated with-4 glasss), and suspension is placed after 5 days still without lamination,
Visible frit granule agglomerant of the present invention still has good stability after mixing with frit granule.
Above-mentioned frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze, controls
The thickness of billet surface frit particle suspension liquid is 2mm, and in kiln, 1200 DEG C are burnt till, edging chamfering,
The glazed tile finished product arrived, flatness is high, and the transparency ice crystallized reason of formation has seriality and integrity, without meat
The visible bubble of eye and pin hole.
The flow velocity of the suspension that this method prepares is 44.3s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 172.38
mm2/s。
Preparation-the embodiment 4 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 3.0kg, hydroxyethyl cellulose 2.4kg, attapulgite 2.7kg, poly-
Methylsiloxane 1.3kg, sodium polyacrylate 1.9kg, surplus is water and ethylene glycol.
Preparation-embodiment 4-1 of glazed tile
By the frit granule of green ice crystal effect (buying from Quincy card Robbie glaze company, fineness 180 mesh)
Cloth is in the billet surface of revenue stamp process, and the frit granule that then one layer of embodiment of spraying 4 prepares glues
Knot agent, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtain having be uniformly distributed, complete ice crystal stricture of vagina
The glazed tile finished product of reason.At this it should be noted that the clear frit granule that the present embodiment 4-1 selects is burning
Sprawling during knot, form red ice crystal flower textured pattern on cover coat, frit granule can pass through
Colour glaze company buys and obtains, and similar frit product also can realize this programme.The frit granule that this method prepares
The flow velocity of bonding agent is 26.4s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 86.28mm2/s。
Preparation-embodiment 4-2 of glazed tile
The frit granule of 350kg green ice crystal effect (is bought from Quincy card Robbie glaze company, fineness 200
Mesh) add in the frit granule agglomerant of the 150kg that embodiment 4 prepares, mix homogeneously, obtain frit granule
Suspension, frit granule solid content 70%, flow velocity is 45.8s (30 DEG C, be coated with-4 glasss), and suspension places 5
Still without lamination after it, it is seen that frit granule agglomerant of the present invention still has good after mixing with frit granule
Stability.
Above-mentioned frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze, controls
The thickness of billet surface frit particle suspension liquid is 2mm, and in kiln, 1200 DEG C are burnt till, edging chamfering,
The glazed tile finished product arrived, flatness is high, and the transparency ice crystallized reason of formation has seriality and integrity, without meat
The visible bubble of eye and pin hole.
The flow velocity of the suspension that this method prepares is 45.8s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 175.21
mm2/s。
Preparation-the embodiment 5 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 2.5kg, hydroxyethylmethyl-cellulose 2.8kg (Guangzhou Mo Ke building materials section
Skill company limited buys), attapulgite 2.9kg, polymethyl siloxane 1.2kg, sodium hexameta phosphate 0.8kg,
Organic-silicon-modified sodium phosphate 1.0kg, surplus is second alcohol and water.
Preparation-embodiment 5-1 of glazed tile
By clear frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 140 mesh) cloth in warp
Cross in the billet surface of revenue stamp process, the frit granule agglomerant that then one layer of embodiment of spraying 5 prepares, send
Enter in kiln and burn till at 1120 DEG C, edging chamfering, obtain having be uniformly distributed, the glaze of complete ice crystal texture
Brick finished product.At this it should be noted that the clear frit granule of the present embodiment 5-1 selection is in sintering process
Sprawling, form red ice crystal flower textured pattern on cover coat, frit granule can be public by colour glaze
Department buys and obtains, and similar frit product also can realize this programme.The frit particles stick agent that this method prepares
Flow velocity is 26.7s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 88.13mm2/s。
Preparation-embodiment 5-2 of glazed tile
By 375kg by clear frit granule (buying from Zibo Boshan gold light colour glaze factory, fineness 140 mesh)
Add in the frit granule agglomerant of the 125kg that embodiment 5 prepares, mix homogeneously, obtain frit granule and suspend
Liquid, frit granule solid content 75%, flow velocity is 45.4s (30 DEG C, be coated with-4 glasss), after suspension is placed 5 days
Still without lamination, it is seen that frit granule agglomerant of the present invention and frit granule still have good steady after mixing
Qualitative.
Above-mentioned frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze, controls
The thickness of billet surface frit particle suspension liquid is 2mm, and in kiln, 1200 DEG C are burnt till, edging chamfering,
The glazed tile finished product arrived, flatness is high, and the transparency ice crystallized reason of formation has seriality and integrity, without meat
The visible bubble of eye and pin hole.
The flow velocity of the suspension that this method prepares is 45.4s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is
171.31mm2/s。
Preparation-the embodiment 6 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose
(purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.) 3.0kg, hydroxyethyl cellulose (the unconcerned gram building materials science and technology in Guangzhou
Company limited buys) 2.2kg, attapulgite 2.8kg, polymethyl siloxane 1.2kg, sodium hexameta phosphate
1.4kg, sodium polyacrylate 0.6kg, surplus is ethylene glycol and ethanol.
Preparation-embodiment 6-1 of glazed tile
By the frit granule of brown ice crystal effect (buying from Quincy card Robbie glaze company, fineness 200 mesh)
Cloth is in the billet surface of revenue stamp process, and the frit granule that then one layer of embodiment of spraying 6 prepares glues
Knot agent, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtain having be uniformly distributed, complete ice crystal stricture of vagina
The glazed tile finished product of reason.At this it should be noted that the clear frit granule that the present embodiment 6-1 selects is burning
Sprawling during knot, form brown ice crystal flower textured pattern on cover coat, frit granule can pass through
Colour glaze company buys and obtains, and similar frit product also can realize this programme.The frit granule that this method prepares
The flow velocity of bonding agent is 25.8s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 85.45mm2/s。
Preparation-embodiment 6-2 of glazed tile
The frit granule of 325kg redness ice crystal effect (is bought from Quincy card Robbie glaze company, fineness 200
Mesh) add in the frit granule agglomerant of the 175kg that embodiment 6 prepares, mix homogeneously, obtain frit granule
Suspension, frit granule solid content 65%, flow velocity is 45.1s (30 DEG C, be coated with-4 glasss), and suspension places 5
Still without lamination after it, it is seen that frit granule agglomerant of the present invention still has good after mixing with frit granule
Stability.
Above-mentioned frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze, controls
The thickness of billet surface frit particle suspension liquid is 2mm, and in kiln, 1200 DEG C are burnt till, edging chamfering,
The glazed tile finished product arrived, flatness is high, and the transparency ice crystallized reason of formation has seriality and integrity, without meat
The visible bubble of eye and pin hole.
The flow velocity of the suspension that this method prepares is 45.1s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 168.14
mm2/s。
Preparation-the embodiment 7 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethyl cellulose is (wide
Zhou Moke building materials Science and Technology Ltd. buys) 5.6kg, attapulgite 3.0kg, polymethyl siloxane 1.4kg,
Sodium hexameta phosphate 1.8kg, surplus is ethylene glycol.
Preparation-embodiment 7-1 of glazed tile
By the frit granule of green ice crystal effect (buying from Quincy card Robbie glaze company, fineness 180 mesh)
Cloth is in the billet surface of revenue stamp process, and the frit granule that then one layer of embodiment of spraying 7 prepares glues
Knot agent, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtain having be uniformly distributed, complete ice crystal stricture of vagina
The glazed tile finished product of reason.At this it should be noted that the clear frit granule that the present embodiment 7-1 selects is burning
Sprawling during knot, form green ice crystal flower textured pattern on cover coat, frit granule can pass through
Colour glaze company buys and obtains, and similar frit product also can realize this programme.The frit granule that this method prepares
The flow velocity of bonding agent is 25.6s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 85.63mm2/s。
Preparation-embodiment 7-2 of glazed tile
The frit granule of 325kg redness ice crystal effect (is bought from Quincy card Robbie glaze company, fineness 90
Mesh) add in the frit granule agglomerant of the 175kg that embodiment 7 prepares, mix homogeneously, obtain frit granule
Suspension, frit granule solid content 65%, flow velocity is 43.9s (30 DEG C, be coated with-4 glasss), and suspension places 5
Still without lamination after it, it is seen that frit granule agglomerant of the present invention still has good after mixing with frit granule
Stability.
Above-mentioned frit particle suspension liquid is drenched in the billet surface through revenue stamp process in the way of drenching glaze, controls
The thickness of billet surface frit particle suspension liquid is 2mm, and in kiln, 1200 DEG C are burnt till, edging chamfering,
The glazed tile finished product arrived, flatness is high, and the transparency ice crystallized reason of formation has seriality and integrity, without meat
The visible bubble of eye and pin hole.
The flow velocity of the suspension that this method prepares is 43.9s (30 DEG C, be coated with-4 glasss), and kinematic viscosity value is 169.24
mm2/s。
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain this
The principle of invention, and limiting the scope of the invention can not be construed to by any way.Based on herein
Explaining, those skilled in the art need not pay performing creative labour can associate other tool of the present invention
Body embodiment, within these modes fall within protection scope of the present invention.