CN104264167A - Water-based metal cleaning agent - Google Patents

Water-based metal cleaning agent Download PDF

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Publication number
CN104264167A
CN104264167A CN201410504132.8A CN201410504132A CN104264167A CN 104264167 A CN104264167 A CN 104264167A CN 201410504132 A CN201410504132 A CN 201410504132A CN 104264167 A CN104264167 A CN 104264167A
Authority
CN
China
Prior art keywords
cleaning agent
metal cleaning
base metal
water base
parts
Prior art date
Application number
CN201410504132.8A
Other languages
Chinese (zh)
Inventor
陈孝炎
Original Assignee
巢湖广丰金属制品有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 巢湖广丰金属制品有限公司 filed Critical 巢湖广丰金属制品有限公司
Priority to CN201410504132.8A priority Critical patent/CN104264167A/en
Publication of CN104264167A publication Critical patent/CN104264167A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DEGREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions

Abstract

The invention discloses a water-based metal cleaning agent which comprises the following raw materials in parts by weight: 5-15 parts of a surfactant, 20-30 parts of hydrophilic alcohol, 2-4 parts of instant modified sodium disilicate, 3-5 parts of sodium carbonate, 1-3 parts of sodium bicarbonate, 10-15 parts of triethanolamine oleate, 5-15 parts of dodecanedioic triethanolamine, 5-15 parts of sodium 2-Mercaptobenzothiazole, 3-6 parts of sodium gluconate, and 100-150 parts of water. The water-based metal cleaning agent disclosed by the invention is strong in detergency, good in anti-rust property, environmental friendly, and less in pollution.

Description

A kind of water base metal cleaning agent
Technical field
The present invention relates to clean-out system technical field, particularly relate to a kind of water base metal cleaning agent.
Background technology
Metal cleaner is applied very extensive in the industrial production, is usually used in the cleaning before the surface degreasing before and after intermetallic composite coating, scale removal and finished product assembling or packaging.Water base metal cleaning agent is underlying carrier with water, containing tensio-active agent, auxiliary agent etc., containing or containing few organic solvent.Water base metal cleaning agent has following characteristics: (1) good wetting, emulsification, characteristic of solubilizing; (2) preparation and use procedure in substantially pollution-free; (3) to the corrosion-free effect of metallic substance, the original gloss of metal after cleaning, can be kept, there is certain antirust effect; (4) cost performance is higher than organic cleaning solvent; (5) do not burn, security is high.But current cleaner for metal cleaning performance is not good enough, has residual after washing, awaits further research and development.
Summary of the invention
The invention provides a kind of water base metal cleaning agent, its strong detergency, rust-preventing characteristic is good, and environmental pollution is few.
The present invention proposes a kind of water base metal cleaning agent, its raw material comprises by weight:
Preferably, its raw material comprises by weight:
Preferably, its raw material also comprises essence 1-3 part by weight.
Preferably, described essence is one or more the combination in lavender oil, Mint Essence, Green tea essence, lemon flavour, apple flavour.
Preferably, described tensio-active agent is a kind of in sodium branched alkyl benzene sulfonate, polyoxyethylenated alcohol sodium sulfate or two kinds and the combination of a kind of in fatty alcohol-polyoxyethylene ether, non-ionic type fluorocarbon surfactant or two kinds.
Preferably, described hydrophilic polyol is one or more combination in ethylene glycol, glycol ether, triglycol, dipropylene glycol, tripropylene glycol, polyoxyethylene glycol.
Preferably, described hydrophilic polyol is polyoxyethylene glycol.
Preferably, described polyoxyethylene glycol is one or more the combination in Liquid Macrogol, Polyethylene Glycol-600, PEG 20000, cetomacrogol 1000, polyethylene glycol 1500, Macrogol 2000, Macrogol 4000, polyethylene glycol 6000.
Preferably, its raw material comprises by weight:
Preferably, its raw material comprises by weight:
In the present invention, by selecting suitable composition, optimizing the content of composition, obtaining strong detergency, the water base metal cleaning agent that rust-preventing characteristic is good; Concrete, after the tensio-active agent added, triethanolamine oleate, SL-AH trolamine, mercaptobenzothiazole sodium are composite in suitable ratio, reduce interfacial tension, enhance the infiltration to greasy dirt, emulsification and dispersiveness, improve detersive power and the rust-preventing characteristic of clean-out system; Coordinate the sodium carbonate and sodium bicarbonate that add, can with dirt generation saponification reaction, be distributed in solution, regulate the effect of clean-out system, and add the stability of clean-out system, reduce cost; The hydrophilic polyol added can the promoting agent cloud point of regulation system as solubilizing agent, makes it in the temperature range of cleaning, improves the cleaning performance of clean-out system; The instant modification sodium disilicate pH shock absorption of adding is strong, the basicity needed for clean-out system can be maintained, solubleness is high, to calcium, magnesium ion good in conjunction with exchange capacity, with energy emulsification greasy dirt settling after tensio-active agent, inhibiter and other additive compatibilities, dispersion suspension dirt particles, opposing dirt deposition, enhances cleaning performance and the rust-proof effect of clean-out system; Various raw material is in the clean-out system strong detergency obtained after described ratio compatibility, and favorable rust preventing effect, environmentally friendly, after cleaning, greasy dirt not easily deposits again.
The performance perameter of water base metal cleaning agent of the present invention is as shown in the table:
Test item Detected result
Outward appearance Evenly, not stratified, nothing precipitation
Moisture and volatile matter content (%) ≤85
PH value 8-10
Washing power (60 DEG C) % ≥97
Corrodibility (80 ± 2 DEG C) 45 steel 0 grade
Rust-preventing characteristic (35 ± 2 DEG C, 24h) 45 steel 0 grade
Rinsing performance (stainless steel substrates) Without visible clean-out system residue
High-temperature stability (60 ± 2 DEG C, 6h) Evenly, not stratified
Low-temperature stability (-5 ± 2 DEG C, 24h) Evenly, not stratified
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, water base metal cleaning agent of the present invention, in its raw material, the weight part of tensio-active agent can be 5.3, 6, 7, 8, 8.6, 9, 9.3, 10, 11, 12.5, 13.6, 14, 14.7 parts, the weight part of hydrophilic polyol can be 20.6, 21, 22, 23.6, 24, 25, 26, 26.7, 27, 28, 28.3, 29, 29.4 parts, the weight part of instant modification sodium disilicate can be 2.6, 3, 3.4, 3.8 parts, the weight part of sodium carbonate can be 3.6, 3.9, 4, 4.2, 4.6, 4.8 parts, the weight part of sodium bicarbonate can be 1.3, 1.7, 2.1, 2.5, 2.8 parts, the weight part of triethanolamine oleate can be 10.3, 11, 12, 12.5, 13, 13.8, 14, 14.6 parts, the weight part of SL-AH trolamine can be 5.9, 6, 6.5, 7, 7.8, 8, 9.3, 10, 11, 12.5, 13, 14, 14.6 parts, the weight part of mercaptobenzothiazole sodium can be 5.7, 6, 7, 7.3, 8, 8.4, 9, 9.1, 10, 11, 11.6, 12, 12.4, 13, 13.4, 14, 14.7 parts, the weight part of Sunmorl N 60S can be 3.6, 3.9, 4, 4.5, 5, 5.1, 5.6 parts, the weight part of water can be 103, 105, 107.6, 110, 112.3, 115.6, 116, 117.3, 118, 119, 121, 123, 124.6, 125, 126, 127, 128.3, 130, 133, 134, 136, 137.5, 138.9, 139, 140, 142, 144, 146, 147.6, 149, 149.2 part.
Embodiment 1
Water base metal cleaning agent of the present invention, its raw material comprises by weight:
Embodiment 2
Water base metal cleaning agent of the present invention, its raw material comprises by weight:
Embodiment 3
Water base metal cleaning agent of the present invention, is characterized in that, its raw material comprises by weight:
Embodiment 4
Water base metal cleaning agent of the present invention, its raw material comprises by weight:
Embodiment 5
Water base metal cleaning agent of the present invention, its raw material comprises by weight:
Wherein, described tensio-active agent is the combination of sodium branched alkyl benzene sulfonate, polyoxyethylenated alcohol sodium sulfate and fatty alcohol-polyoxyethylene ether; Described hydrophilic polyol is the combination of ethylene glycol, triglycol, tripropylene glycol, polyoxyethylene glycol.

Claims (10)

1. a water base metal cleaning agent, is characterized in that, its raw material comprises by weight:
2. water base metal cleaning agent according to claim 1, it is characterized in that, its raw material comprises by weight:
3. water base metal cleaning agent according to claim 1 or 2, is characterized in that, its raw material also comprises essence 1-3 part by weight.
4. water base metal cleaning agent according to claim 3, it is characterized in that, described essence is one or more the combination in lavender oil, Mint Essence, Green tea essence, lemon flavour, apple flavour.
5. water base metal cleaning agent according to any one of claim 1-4, it is characterized in that, described tensio-active agent is a kind of in sodium branched alkyl benzene sulfonate, polyoxyethylenated alcohol sodium sulfate or two kinds and the combination of a kind of in fatty alcohol-polyoxyethylene ether, non-ionic type fluorocarbon surfactant or two kinds.
6. water base metal cleaning agent according to any one of claim 1-5, is characterized in that, described hydrophilic polyol is one or more the combination in ethylene glycol, glycol ether, triglycol, dipropylene glycol, tripropylene glycol, polyoxyethylene glycol.
7. water base metal cleaning agent according to any one of claim 1-6, is characterized in that, described hydrophilic polyol is polyoxyethylene glycol.
8. water base metal cleaning agent according to claim 7, it is characterized in that, described polyoxyethylene glycol is one or more the combination in Liquid Macrogol, Polyethylene Glycol-600, PEG 20000, cetomacrogol 1000, polyethylene glycol 1500, Macrogol 2000, Macrogol 4000, polyethylene glycol 6000.
9. water base metal cleaning agent according to any one of claim 1-8, is characterized in that, its raw material comprises by weight:
10. water base metal cleaning agent according to claim 9, it is characterized in that, its raw material comprises by weight:
CN201410504132.8A 2014-09-25 2014-09-25 Water-based metal cleaning agent CN104264167A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410504132.8A CN104264167A (en) 2014-09-25 2014-09-25 Water-based metal cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410504132.8A CN104264167A (en) 2014-09-25 2014-09-25 Water-based metal cleaning agent

Publications (1)

Publication Number Publication Date
CN104264167A true CN104264167A (en) 2015-01-07

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CN201410504132.8A CN104264167A (en) 2014-09-25 2014-09-25 Water-based metal cleaning agent

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016176792A1 (en) * 2015-05-03 2016-11-10 南通启秀门窗有限公司 Metal door cleaning agent
CN107326375A (en) * 2017-06-29 2017-11-07 顾渊 One Albatra metal cleaning agent
CN108531927A (en) * 2018-04-25 2018-09-14 苏州锐耐洁电子科技新材料有限公司 A kind of metal product cleaning agent
CN109136940A (en) * 2018-09-07 2019-01-04 苏州安美润滑科技有限公司 Low bubble cleaning agent of a kind of environment-friendly type high performance ferrous metal antirust and preparation method thereof
CN110565106A (en) * 2019-10-12 2019-12-13 佛山市湾厦新材料科技有限公司 degreasing agent and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
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CN103590059A (en) * 2013-11-12 2014-02-19 东莞市安美润滑科技有限公司 Water-based cleaning agent for aluminum alloy part
CN103602138A (en) * 2013-11-20 2014-02-26 张家港任发化工材料有限公司 Water-based cleaning agent for printing ink
CN103613977A (en) * 2013-10-20 2014-03-05 安徽美翔塑业有限公司 Printing ink detergent
CN103613985A (en) * 2013-11-20 2014-03-05 张家港任发化工材料有限公司 Printing ink cleaning agent

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN103613977A (en) * 2013-10-20 2014-03-05 安徽美翔塑业有限公司 Printing ink detergent
CN103590059A (en) * 2013-11-12 2014-02-19 东莞市安美润滑科技有限公司 Water-based cleaning agent for aluminum alloy part
CN103602138A (en) * 2013-11-20 2014-02-26 张家港任发化工材料有限公司 Water-based cleaning agent for printing ink
CN103613985A (en) * 2013-11-20 2014-03-05 张家港任发化工材料有限公司 Printing ink cleaning agent

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Title
杨承凤: "钴基合金用高效缓蚀清洗剂及其性能研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016176792A1 (en) * 2015-05-03 2016-11-10 南通启秀门窗有限公司 Metal door cleaning agent
CN107326375A (en) * 2017-06-29 2017-11-07 顾渊 One Albatra metal cleaning agent
CN108531927A (en) * 2018-04-25 2018-09-14 苏州锐耐洁电子科技新材料有限公司 A kind of metal product cleaning agent
CN109136940A (en) * 2018-09-07 2019-01-04 苏州安美润滑科技有限公司 Low bubble cleaning agent of a kind of environment-friendly type high performance ferrous metal antirust and preparation method thereof
CN109136940B (en) * 2018-09-07 2021-01-15 苏州安美润滑科技有限公司 Environment-friendly high-performance rust-proof low-foam black metal cleaning agent and preparation method thereof
CN110565106A (en) * 2019-10-12 2019-12-13 佛山市湾厦新材料科技有限公司 degreasing agent and preparation method and application thereof

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